CN110684983B - Neutral scale remover and preparation method thereof - Google Patents
Neutral scale remover and preparation method thereof Download PDFInfo
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- CN110684983B CN110684983B CN201911246412.2A CN201911246412A CN110684983B CN 110684983 B CN110684983 B CN 110684983B CN 201911246412 A CN201911246412 A CN 201911246412A CN 110684983 B CN110684983 B CN 110684983B
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
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Abstract
The invention discloses a neutral scale remover and a preparation method thereof, the neutral scale remover comprises a supermolecule scale remover monomer solution, a surfactant and a pH regulator, the supermolecule scale remover monomer is prepared by adopting a special raw material proportion, is safe and long-acting, does not have chemical reaction with scale and metal, realizes stripping and scale decomposition through dispersion and molecular assembly, and is finally stably attached to the surface of the metal, so that insoluble scales such as oil scale, mud scale, crystallization scale, rust scale and the like which are difficult to clean by conventional chemical cleaning can be removed, a compact protective film is formed, the long-term stable operation of an oil well can be maintained, the formation of subsequent scales is prevented, and the long-acting scale removal and scale inhibition are realized.
Description
Technical Field
The invention belongs to the technical field of a scale remover, and particularly relates to a neutral scale remover and a preparation method thereof.
Background
Scaling of the oil field downhole pipe string can cause production stoppage of an oil-water well, yield reduction, service life shortening and the like. The existing descaling agent commonly used in oil fields is mainly an acid system, so that the pipe column is corroded by acid descaling, the pipe column is damaged, the cost is increased, the production period is shortened, and even the production is stopped; meanwhile, the treated pipe column still continues to scale, so that scaling-descaling circulation is caused.
However, the strong acid cleaning agent has large addition amount, strong corrosivity and large toxicity, wastes water, labor and time in the whole cleaning process, pollutes the environment, has certain danger to equipment and operators, and is inconvenient to transport and store. In addition, many expensive industrial equipment is not suitable for use due to the strong corrosiveness of the strong acid cleaning agent. Compared with inorganic acid cleaning agents, organic acid cleaning agents are expensive, need to be operated at higher temperature, and are long in cleaning time and labor-intensive.
Disclosure of Invention
The invention provides a neutral detergent and a preparation method thereof, and solves the problems of corrosion of an acid detergent to a pipe column, high cost and low safety in the prior art and the problem of low scale removal rate of the conventional neutral detergent.
The specific technical scheme is as follows:
a neutral scale remover comprises the following raw materials in parts by weight: 90-105 parts of supermolecule scale remover monomer solution, 5-10 parts of surfactant and 0-1 part of pH regulator; wherein, the synthesis steps of the supermolecule detergent monomer solution are as follows: adding 50 parts of absolute ethyl alcohol into a reaction kettle, then adding 2-3 parts of polyethylene glycol, stirring at 1000r/min, after complete dissolution, adding 5-6 parts of p-aminobenzoic acid or 5-6 parts of 4-aminobenzenesulfonic acid, stirring at 1000r/min for 10min, raising the temperature to 60 ℃, then dropwise adding 7-9 parts of benzotriazole, simultaneously dropwise adding an acid activation initiator, raising the temperature to 80 ℃, and reacting for 8h to obtain the supermolecule scale remover monomer solution.
Preferably, the synthesis steps of the acidic activated initiator are as follows:
dissolving 2-3 parts of sodium silicate in 20 parts of absolute ethyl alcohol, stirring and dissolving at the normal temperature of 25 ℃ and 1000r/min, then slowly dropwise adding 4-6 parts of ethylenediamine sodium triacetate or 3-5 parts of ethylenediamine tetraacetic acid disodium salt for 5min, dropwise adding 20-30 parts of polyepoxysuccinic acid for 15min, continuously dropwise adding 3-5 parts of initiator hydroxyethylidene diphosphonic acid for 5min, and then heating to 60 ℃ to prepare the acid activation initiator.
Preferably, the dropping of the benzotriazole and the acidic activation initiator is completed simultaneously, and the dropping time is 20-30 min.
Preferably, the surfactant is one of fatty alcohol-polyoxyethylene ether or octadecyl dimethyl betaine.
Preferably, the pH regulator is one of sodium hydroxide or potassium hydroxide.
Preferably, the method comprises the following steps: mixing and stirring the supermolecule scale remover monomer solution and the surfactant at the normal temperature of 25 ℃ at 1000r/min for 55-65min in proportion, and then adding a pH regulator to prepare the neutral scale remover.
Preferably, the pH value of the neutral detergent is 6.5-7.0.
Has the advantages that:
1. the scale remover prepared by the invention is safe and long-acting, can not have chemical reaction with scale and metal, can realize stripping and decomposition of the scale through dispersion and molecular assembly, and finally stably adheres to the surface of the metal, can remove oil scale, mud scale, crystal scale, rust scale and other insoluble scales which are difficult to be cleaned by conventional chemical cleaning, forms a compact protective film, can keep long-term stable operation of an oil well to prevent subsequent scale from being formed, and realizes long-acting scale removal and scale inhibition.
2. When in use, the neutral descaling agent is added into the system through a pump according to a certain proportion without pulling out a pipe column, so that online cleaning and descaling are realized, the operation cost is reduced, the economic loss is reduced, and the labor and maintenance cost is saved.
3. The pH value of the scale remover disclosed by the invention is 6.5-7.0, the agent does not corrode equipment, the corrosion degree of the agent on metal surfaces is far lower than the I-level standard specified by the oil field industry standard, and the scale remover belongs to an environment-friendly, pollution-free and long-acting scale removing and inhibiting system; the neutral scale remover has no heavy metal pollution, no pollution to the environment and safety to operators and equipment; the method is environment-friendly, the medicament is hermetically conveyed along with the crude oil, and the method has no environmental pollution and is green and environment-friendly.
Detailed Description
Example 1:
the neutral scale remover in the implementation comprises the following raw materials in parts by weight: 90 parts of supermolecule scale remover monomer solution, 7 parts of surfactant and 1 part of pH regulator; wherein, the synthesis steps of the supermolecule detergent monomer solution are as follows: adding 50 parts of absolute ethyl alcohol into a reaction kettle, then adding 2 parts of polyethylene glycol, stirring at 1000r/min, after complete dissolution, adding 5 parts of p-aminobenzoic acid, stirring at 1000r/min for 10min, raising the temperature to 60 ℃, then dropwise adding 7 parts of benzotriazole, and simultaneously dropwise adding an acidic activation initiator for 25 min. Heating to 80 ℃, and reacting for 8 hours to obtain the supermolecule scale remover monomer solution.
The acidic activated initiator comprises the following synthetic steps:
dissolving 3 parts of sodium silicate in 20 parts of absolute ethyl alcohol, stirring and dissolving at the normal temperature of 25 ℃ and 1000r/min, then slowly dropwise adding 4 parts of ethylenediamine sodium triacetate for 5min, dropwise adding 20 parts of polyepoxysuccinic acid for 15min, continuously dropwise adding 3 parts of initiator hydroxy ethylidene diphosphonic acid for 5min, and then heating to 60 ℃ to prepare the acidic activation initiator.
The surfactant is fatty alcohol-polyoxyethylene ether. The pH regulator is sodium hydroxide.
The preparation method of the neutral detergent comprises the following steps: mixing and stirring the supermolecule scale remover monomer solution and the surfactant at the normal temperature of 25 ℃ at 1000r/min for 55min, and then adding a pH regulator to prepare the neutral scale remover.
20g of the prepared neutral detergent stock solution capable of forming the long-acting scale-inhibiting film is diluted by distilled water or deionized water to prepare 100g, and the pH value is measured to be 6.8.
Example 2:
the neutral scale remover in the implementation comprises the following raw materials in parts by weight: 100 parts of supermolecule scale remover monomer solution, 5 parts of surfactant and 1 part of pH regulator; wherein, the synthesis steps of the supermolecule detergent monomer solution are as follows: adding 50 parts of absolute ethyl alcohol into a reaction kettle, then adding 3 parts of polyethylene glycol, stirring at 1000r/min, after complete dissolution, adding 5 parts of 4-aminobenzenesulfonic acid, stirring at 1000r/min for 10min, raising the temperature to 60 ℃, then dropwise adding 8 parts of benzotriazole, and dropwise adding an acid activation initiator for 30 min. Heating to 80 ℃, and reacting for 8 hours to obtain the supermolecule scale remover monomer solution.
The acidic activated initiator comprises the following synthetic steps:
dissolving 3 parts of sodium silicate in 20 parts of absolute ethyl alcohol, stirring and dissolving at the normal temperature of 25 ℃ and 1000r/min, then slowly dropwise adding 4 parts of sodium ethylene diamine tetracetate for 5min, dropwise adding 30 parts of polyepoxysuccinic acid for 15min, continuously dropwise adding 4 parts of initiator hydroxy ethylidene diphosphonic acid for 5min, and then heating to 60 ℃ to prepare the acid activation initiator.
The surfactant is octadecyl dimethyl betaine.
The pH regulator is sodium hydroxide.
The preparation method of the neutral detergent comprises the following steps: mixing and stirring the supermolecule scale remover monomer solution and the surfactant at the normal temperature of 25 ℃ at 1000r/min for 60min in proportion, and then adding a pH regulator to prepare the neutral scale remover.
20g of the prepared neutral detergent stock solution capable of forming the long-acting scale-inhibiting film is diluted by distilled water or deionized water to prepare 100g, and the pH value is measured to be 6.5.
Example 3:
the neutral scale remover in the implementation comprises the following raw materials in parts by weight: 101 parts of supermolecule scale remover monomer solution, 10 parts of surfactant and 1 part of pH regulator; wherein, the synthesis steps of the supermolecule detergent monomer solution are as follows: adding 50 parts of absolute ethyl alcohol into a reaction kettle, then adding 2 parts of polyethylene glycol, stirring at 1000r/min, after complete dissolution, adding 6 parts of p-aminobenzoic acid, stirring at 1000r/min for 10min, raising the temperature to 60 ℃, then dropwise adding 9 parts of benzotriazole, and simultaneously dropwise adding an acidic activation initiator for 20 min. Heating to 80 ℃, and reacting for 8 hours to obtain the supermolecule scale remover monomer solution.
The acidic activated initiator comprises the following synthetic steps:
dissolving 2 parts of sodium silicate in 20 parts of absolute ethyl alcohol, stirring and dissolving at the normal temperature of 25 ℃ and 1000r/min, then slowly dropwise adding 6 parts of ethylenediamine sodium triacetate for 5min, dropwise adding 25 parts of polyepoxysuccinic acid for 15min, continuously dropwise adding 5 parts of initiator hydroxy ethylidene diphosphonic acid for 5min, and then heating to 60 ℃ to prepare the acidic activation initiator.
The surfactant is fatty alcohol-polyoxyethylene ether. The pH regulator is potassium hydroxide.
The preparation method of the neutral detergent comprises the following steps: mixing and stirring the supermolecule scale remover monomer solution and the surfactant for 58min at the normal temperature of 25 ℃ at 1000r/min in proportion, and then adding a pH regulator to prepare the neutral scale remover.
20g of the prepared neutral detergent stock solution capable of forming the long-acting scale-inhibiting film is diluted by distilled water or deionized water to prepare 100g, and the pH value is measured to be 6.6.
Example 4:
the neutral scale remover in the implementation comprises the following raw materials in parts by weight: 105 parts of supermolecule scale remover monomer solution, 8 parts of surfactant and 1 part of pH regulator; wherein, the synthesis steps of the supermolecule detergent monomer solution are as follows: adding 50 parts of absolute ethyl alcohol into a reaction kettle, then adding 3 parts of polyethylene glycol, stirring at 1000r/min, after complete dissolution, adding 6 parts of 4-aminobenzenesulfonic acid, stirring at 1000r/min for 10min, raising the temperature to 60 ℃, then dropwise adding 7 parts of benzotriazole, and dropwise adding an acid activation initiator for 28 min. Heating to 80 ℃, and reacting for 8 hours to obtain the supermolecule scale remover monomer solution.
The acidic activated initiator comprises the following synthetic steps:
dissolving 2 parts of sodium silicate in 20 parts of absolute ethyl alcohol, stirring and dissolving at the normal temperature of 25 ℃ and 1000r/min, then slowly dropwise adding 5 parts of sodium ethylene diamine tetracetate for 5min, dropwise adding 30 parts of polyepoxysuccinic acid for 15min, continuously dropwise adding 4 parts of initiator hydroxy ethylidene diphosphonic acid for 5min, and then heating to 60 ℃ to prepare the acid activation initiator.
The surfactant is octadecyl dimethyl betaine.
The pH regulator is potassium hydroxide.
The preparation method of the neutral detergent comprises the following steps: mixing and stirring the supermolecule scale remover monomer solution and the surfactant at the normal temperature of 25 ℃ at 1000r/min for 65min, and then adding a pH regulator to prepare the neutral scale remover.
20g of the prepared neutral detergent stock solution capable of forming the long-acting scale-inhibiting film is diluted by distilled water or deionized water to prepare 100g, and the pH value is measured to be 6.9.
And (3) performance testing:
firstly, respectively taking the scale remover prepared by the invention, taking 5g of scale sample washed out from the oil field well, carrying out a scale removal experiment, and detecting the dissolution rate and the decomposition rate of soluble substances, wherein the experiment results are shown in the following table.
The final residue is mainly silt, and the neutral scale remover prepared by the method has good dissolution rate and decomposition rate on the scale washed out from the oil field well.
Secondly, taking 5g of oil field oil pipe column scale sample to carry out a scale removal experiment, and detecting the dissolution rate and the decomposition rate of soluble substances, wherein the experiment results are shown in the following table.
The final residue is mainly scrap iron and silt, and the neutral scale remover prepared by the method has good dissolution rate and decomposition rate on oil field oil pipe column scale as can be seen from the table.
It is to be understood that the invention is not limited to the specific embodiments described above, but is intended to cover various insubstantial modifications of the inventive process concepts and solutions, or its application to other applications without modification.
Claims (4)
1. The neutral scale remover is characterized by comprising the following raw materials in parts by weight: 90-105 parts of supermolecule scale remover monomer solution, 5-10 parts of surfactant and 0-1 part of pH regulator; wherein, the synthesis steps of the supermolecule detergent monomer solution are as follows: adding 50 parts of absolute ethyl alcohol into a reaction kettle, then adding 2-3 parts of polyethylene glycol, stirring at 1000r/min, after completely dissolving, adding 5-6 parts of p-aminobenzoic acid or 5-6 parts of 4-aminobenzenesulfonic acid, stirring at 1000r/min for 10min, heating to 60 ℃, then dropwise adding 7-9 parts of benzotriazole, simultaneously dropwise adding an acid activation initiator, heating to 80 ℃, and reacting for 8 hours to obtain a supermolecule scale remover monomer solution;
the acidic activated initiator comprises the following synthetic steps:
dissolving 2-3 parts of sodium silicate in 20 parts of absolute ethyl alcohol, stirring and dissolving at the normal temperature of 25 ℃ and 1000r/min, then slowly dropwise adding 4-6 parts of ethylenediamine sodium triacetate or 3-5 parts of ethylenediamine tetraacetic acid disodium salt for 5min, dropwise adding 20-30 parts of polyepoxysuccinic acid for 15min, continuously dropwise adding 3-5 parts of initiator hydroxyethylidene diphosphonic acid for 5min, and then heating to 60 ℃ to prepare an acid activation initiator;
the dropping of the benzotriazole and the acidic activation initiator is completed simultaneously, and the dropping time is 20-30 min;
mixing and stirring the supermolecule scale remover monomer solution and the surfactant at the normal temperature of 25 ℃ at 1000r/min for 55-65min in proportion, and then adding a pH regulator to prepare the neutral scale remover.
2. The neutral detergent of claim 1, wherein the surfactant is one of fatty alcohol-polyoxyethylene ether or octadecyl dimethyl betaine.
3. The neutral detergent of claim 1, wherein the pH adjuster is one of sodium hydroxide or potassium hydroxide.
4. The neutral detergent of claim 1, having a pH of 6.5-7.0.
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| CN111662783A (en) * | 2020-05-13 | 2020-09-15 | 河北冀研能源科学技术研究院有限公司 | Online descaling agent for voltage-sharing electrode of internal cooling water system of high-voltage direct-current transmission converter valve |
| CN114426822B (en) * | 2020-09-18 | 2023-06-16 | 中国石油化工股份有限公司 | Self-identification detergent and preparation method thereof |
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|---|---|---|---|---|
| CN105949395A (en) * | 2016-05-24 | 2016-09-21 | 华南理工大学 | Molecular cluster material of supramolecular polymer and preparation method and application of molecular cluster material |
| CN106219799A (en) * | 2016-07-13 | 2016-12-14 | 金保全 | Industrial wastewater open and close type recirculated water comprehensive processing zero discharge system and using method |
| WO2018060517A1 (en) * | 2016-09-30 | 2018-04-05 | Biotensidon International Ag | Mixture containing rhamnolipids, alginate, and supramolecular rhamnolipid/alginate/pyoverdine complex |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949395A (en) * | 2016-05-24 | 2016-09-21 | 华南理工大学 | Molecular cluster material of supramolecular polymer and preparation method and application of molecular cluster material |
| CN106219799A (en) * | 2016-07-13 | 2016-12-14 | 金保全 | Industrial wastewater open and close type recirculated water comprehensive processing zero discharge system and using method |
| WO2018060517A1 (en) * | 2016-09-30 | 2018-04-05 | Biotensidon International Ag | Mixture containing rhamnolipids, alginate, and supramolecular rhamnolipid/alginate/pyoverdine complex |
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