CN110684367A - Preparation process of children safety color mud with antibacterial function - Google Patents
Preparation process of children safety color mud with antibacterial function Download PDFInfo
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- CN110684367A CN110684367A CN201910777820.4A CN201910777820A CN110684367A CN 110684367 A CN110684367 A CN 110684367A CN 201910777820 A CN201910777820 A CN 201910777820A CN 110684367 A CN110684367 A CN 110684367A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L99/00—Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups C08L89/00 - C08L97/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2399/00—Characterised by the use of natural macromolecular compounds or of derivatives thereof not provided for in groups C08J2301/00 - C08J2307/00 or C08J2389/00 - C08J2397/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
Abstract
The invention relates to the technical field of color clay preparation, and discloses a preparation process of children safety color clay with an antibacterial function, which comprises the following steps of firstly adding polyvinyl alcohol into water for soaking, then boiling the soaked polyvinyl alcohol into a colloidal solution by an antimony pot for standby, then placing flour and water into the same container, kneading the flour and the colloidal solution, adding polyvinyl alcohol and the colloidal solution into the container to obtain a flour mixture, kneading the flour mixture into clay to obtain finished product color clay, scattering a filler on the surface of the finished product color clay, fully scattering the surface of the finished product color clay, wherein the filler is prepared by adopting a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, wherein the plastic hollow microparticles can effectively reduce the density of the color clay because of the very small density, and an excellent cohesive water-soluble resin system is formed by the polyvinyl alcohol, the filler and the water, so that the color clay after moisture volatilization can not be dehydrated and pulverized, thereby effectively improving the preservation time of the color clay.
Description
Technical Field
The invention relates to the technical field of color clay preparation, in particular to a preparation process of children safety color clay with an antibacterial function.
Background
The colour clay is used for making creative toy for children, but its technological process and material are greatly raised, and it is soft and not sticky. The color clay has dried later and can resume soft with appropriate amount of water, possess the environmental protection effect, be fit for being used for holding between fingers creative work, the color clay has red respectively, it is yellow, blue, it is green, the powder, the orange, multiple colours such as purple, and can be through two liang of mixings, create the color clay of other colours, for example red + yellow = orange, yellow + green = grass green, the preparation of the color clay on the current market is mostly only formed through flour plus oil mixing modulation, this kind of color clay finished product is after placing a period of time, the surface of color clay can dewater the pulverization, lead to the cracked situation of color clay surface emergence, thereby make the unable long-term preservation of color clay.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a preparation process of children safety color mud with an antibacterial function, which has the effect of improving the storage time of the color mud, and solves the problems that most of the color mud on the market is prepared by mixing flour and oil, and the surface of the color mud is dehydrated and pulverized after the color mud finished product is placed for a period of time, so that the surface of the color mud is cracked, and the color mud cannot be stored for a long time.
(II) technical scheme
In order to achieve the purpose of prolonging the storage time of the color clay, the invention provides the following technical scheme: the formula of the children safety color mud with the antibacterial function comprises the following components:
4-18 parts of polyvinyl alcohol, 0.1-3 parts of gelling agent, 30-70 parts of water, 10-40 parts of flour, 1-10 parts of mixed solution of HAc and NaAc, 1-8 parts of higher alcohol fatty acid ester compound, 10-40 parts of filler and 5-15 parts of colorant.
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding polyvinyl alcohol into water for soaking, and then boiling the mixture into colloidal solution for later use by using an antimony pot;
(b) placing the flour and water in the same container, kneading, and adding polyvinyl alcohol and a gelling agent into the container to obtain a flour mixture;
(c) heating and mixing the mixed solution of HAc and NaAc with a high-carbon alcohol fatty acid ester compound, and heating the temperature to obtain a mixed liquid;
(d) adding a coloring agent into the flour mixture, adding the mixed liquid into the flour mixture, and kneading the flour mixture into mud to obtain finished colored mud;
(e) spreading a filler on the finished product color clay, and spreading the filler to the outside of the finished product color clay;
(f) and putting the finished product of the colored mud into a sealed container, and putting the container into a refrigerator for refrigeration.
Preferably, the polyvinyl alcohol is generated by polyvinyl acetate alcoholysis, wherein-OCOCH 3 groups in the polyvinyl acetate are partially or completely substituted by-OH, and the substitution degree is 78-100%.
Preferably, the polyvinyl alcohol condenses with the-OH in the gelling agent to form crosslinks that become a gel.
Preferably, the gelling agent can adopt most of water-soluble borax salts.
Preferably, the filler is made of plastic particles, calcium carbonate, talc, mica and other compounds.
(III) advantageous effects
Compared with the prior art, the invention provides a preparation process of children safety color mud with an antibacterial function, which has the following beneficial effects:
1. the preparation process of the children safety color clay with the antibacterial function comprises the steps of scattering filler on the surface of a finished product color clay, fully scattering the surface of the finished product color clay, wherein the filler is made of a mixture of plastic micro-particles, calcium carbonate, talcum powder, mica and the like, the plastic hollow micro-particles can effectively reduce the density of the color clay because the density of the plastic hollow micro-particles is very small, and a good cohesive water-soluble resin system is formed by polyvinyl alcohol, the filler and water, so that the color clay after moisture volatilization cannot be dehydrated, pulverized and cracked, and the storage time of the color clay is effectively prolonged.
2. According to the preparation process of the children safety color clay with the antibacterial function, the wetting agent is added into the flour mixture, the wetting agent is mainly added to increase the plasticity of the clay dough, so that the clay dough is not easy to break, and the hand feeling of a user for kneading the clay dough is better due to the plasticizing effect of the clay dough.
3. According to the preparation process of the children safety color mud with the antibacterial function, isothiazolinone is added into the mixed liquid, so that the service life of mud lumps is prolonged, the generation of bacteria is prevented, and the antibacterial effect of the color mud is effectively improved.
4. This children's safety color clay preparation technology with antibacterial function through adding polyvinyl alcohol, wherein polyvinyl alcohol is the binder, is used for the bonding filler, avoids color clay to take place the situation of fracture, pulverization and breakage, makes color clay soft plastic when moist simultaneously, but as the polyvinyl alcohol of resin, is very sticky, can reduce the viscidity of color clay through adding the gelling agent this moment, and then effectively strengthens the compliance of wet color clay.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, are within the scope of the present invention.
Example one
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding 4 parts by mass of polyvinyl alcohol into 10 parts by mass of water, soaking for 2 hours, and then cooking the mixture into a colloidal solution for later use by using an antimony pot;
(b) placing 10 parts by mass of flour and 30 parts by mass of water in the same container, kneading for 30 minutes, adding 5 parts by mass of polyvinyl alcohol and 0.3 part by mass of a gelling agent into the container to obtain a flour mixture, wherein the polyvinyl alcohol is generated by alcoholysis of polyvinyl acetate, a part or all of-OCOCH 3 groups in the polyvinyl acetate are substituted by-OH, the substitution degree is 78-100%, and the polyvinyl alcohol is condensed with-OH in the gelling agent to form crosslinking and become gel;
(c) heating and mixing 3 parts by mass of HAc and NaAc mixed solution with 2 parts by mass of higher alcohol fatty acid ester compound, wherein the higher alcohol fatty acid ester compound is mainly used for eliminating bubbles generated in the mixing process, the temperature is heated to 65 degrees to obtain mixed liquid, and 1.6 parts by mass of isothiazolinone is added into the mixed liquid, so that the use and storage life of mud pies are prolonged, and bacteria are prevented from being generated;
(d) adding 6 parts by mass of a coloring agent into a flour mixture, adding a mixed liquid into the flour mixture, kneading the flour mixture into mud, adding 1 part by mass of a wetting agent into the flour mixture in the kneading process, wherein the wetting agent is mainly added to increase the plasticity of mud dough, so that the mud dough is not easy to break, the hand feeling of the mud dough is better due to the plasticizing effect of the wetting agent, the wetting agent is preferably selected from glycerol, diethylene glycol and triethylene glycol, and can also be selected from propylene glycol, polyethylene glycol and the like which are moisture absorbents, so that the mud dough put in the air can not be dried quickly, and then obtaining 60 parts by mass of finished colored mud;
(e) 20 parts by mass of filler is scattered on 60 parts by mass of finished product color clay, the filler is scattered outside the finished product color clay and is made of a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, wherein the density of the plastic hollow microparticles is very low, so that the density of the color clay can be effectively reduced;
(f) and putting 60 parts by mass of the finished colored mud into a sealed container, and putting the container into a refrigerator for refrigeration.
Example two
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding 5 parts by mass of polyvinyl alcohol into 15 parts by mass of water, soaking for 1 hour, and then cooking into a colloidal solution by using an antimony pot for later use;
(b) placing 15 parts by mass of flour and 20 parts by mass of water in the same container, kneading for 30 minutes, and adding 1 part by mass of polyvinyl alcohol and 0.5 part by mass of a gelling agent into the container to obtain a flour mixture;
(c) heating and mixing 4 parts by mass of HAc and NaAc mixed solution and 3 parts by mass of higher alcohol fatty acid ester compound, wherein the higher alcohol fatty acid ester compound is mainly used for eliminating bubbles generated in the mixing process, the temperature is heated to 65 degrees to obtain mixed liquid, and 1.8 parts by mass of isothiazolinone is added into the mixed liquid, so that the use and storage life of mud pies are prolonged, and bacteria are prevented from being generated;
(d) adding 7 parts by mass of a coloring agent into a flour mixture, adding a mixed liquid into the flour mixture, kneading the flour mixture into mud, adding 1.5 parts by mass of a wetting agent into the flour mixture in the kneading process, wherein the wetting agent is mainly added to increase the plasticity of mud dough, so that the mud dough is not easy to break, and the hand feeling of the mud dough is better due to the plasticizing effect of the wetting agent, the wetting agent is preferably selected from glycerol, diethylene glycol and triethylene glycol, and can also be selected from propylene glycol, polyethylene glycol and the like which are moisture absorbents, so that the mud dough put in the air is not dried quickly, and then obtaining 55 parts by mass of finished color mud;
(e) spreading 15 parts by mass of filler on 55 parts by mass of finished color mud, and spreading the filler outside the finished color mud, wherein the filler is prepared from a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, and the density of the plastic hollow microparticles can be effectively reduced because the density of the plastic hollow microparticles is very low;
(f) putting 55 parts by mass of finished color clay into a sealed container, and putting into a refrigerator for refrigeration.
EXAMPLE III
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding 7 parts by mass of polyvinyl alcohol into 16 parts by mass of water, soaking for 2 hours, and then cooking into a colloidal solution by using an antimony pot for later use;
(b) placing 20 parts by mass of flour and 35 parts by mass of water in the same container, kneading for 30 minutes, and adding 6 parts by mass of polyvinyl alcohol and 0.8 part by mass of a gelling agent into the container to obtain a flour mixture;
(c) heating and mixing 8 parts by mass of HAc and NaAc mixed solution with 5 parts by mass of higher alcohol fatty acid ester compound, wherein the higher alcohol fatty acid ester compound is mainly used for eliminating bubbles generated in the mixing process, the temperature is heated to 65 degrees to obtain mixed liquid, and 1.9 parts by mass of isothiazolinone is added into the mixed liquid, so that the use and the storage life of mud pies are prolonged, and bacteria are prevented from being generated;
(d) adding 8 parts by mass of a coloring agent into a flour mixture, adding a mixed liquid into the flour mixture, kneading the flour mixture into mud, adding 2.5 parts by mass of a wetting agent into the flour mixture in the kneading process, wherein the wetting agent is mainly added to increase the plasticity of mud dough, so that the mud dough is not easy to break;
(e) the color clay is prepared by scattering 26 parts by mass of filler on 56 parts by mass of finished color clay, and scattering the filler outside the finished color clay, wherein the filler is prepared from a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, and the density of the plastic hollow microparticles can be effectively reduced because the density of the plastic hollow microparticles is very low;
(f) putting 56 parts by mass of finished color clay into a sealed container, sealing the finished color clay by adopting a preservative film in the sealed container, and putting the sealed container into a refrigerator for refrigeration.
Example four
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding 4.5 parts by mass of polyvinyl alcohol into 20 parts by mass of water, soaking for 2 hours, and then cooking into a colloidal solution by using an antimony pot for later use;
(b) placing 25 parts by mass of flour and 40 parts by mass of water in the same container, kneading for 30 minutes, and adding 5.5 parts by mass of polyvinyl alcohol and 1.5 parts by mass of a gelling agent into the container to obtain a flour mixture;
(c) heating and mixing 3.5 parts by mass of HAc and NaAc mixed solution and 6.5 parts by mass of higher alcohol fatty acid ester compound, wherein the higher alcohol fatty acid ester compound is mainly used for eliminating bubbles generated in the mixing process, the temperature is heated to 65 degrees to obtain mixed liquid, and 2.5 parts by mass of isothiazolinone is added into the mixed liquid, and the isothiazolinone is used for prolonging the service life and the storage life of mud pies and preventing bacteria from generating;
(d) adding 7.5 parts by mass of a coloring agent into a flour mixture, adding a mixed liquid into the flour mixture, kneading the flour mixture into mud, adding 1.3 parts by mass of a wetting agent into the flour mixture in the kneading process, wherein the wetting agent is mainly added to increase the plasticity of a mud dough so that the mud dough is not easy to break, and the hand feeling of the mud dough is better due to the plasticizing effect of the wetting agent;
(e) spreading 35 parts by mass of filler on 65 parts by mass of finished color mud, and spreading the filler outside the finished color mud, wherein the filler is prepared from a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, and the density of the plastic hollow microparticles can be effectively reduced because the density of the plastic hollow microparticles is very low;
(f) and putting 65 parts by mass of the finished colored mud into a sealed container, and putting the container into a refrigerator for refrigeration.
EXAMPLE five
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding 10 parts by mass of polyvinyl alcohol into 31 parts by mass of water, soaking for 2 hours, and then cooking the mixture into a colloidal solution for later use by using an antimony pot;
(b) placing 36 parts by mass of flour and 21 parts by mass of water in the same container, kneading for 30 minutes, and adding 5 parts by mass of polyvinyl alcohol and 0.8 part by mass of a gelling agent into the container to obtain a flour mixture;
(c) heating and mixing 6 parts by mass of HAc and NaAc mixed solution with 8 parts by mass of higher alcohol fatty acid ester compound, wherein the higher alcohol fatty acid ester compound is mainly used for eliminating bubbles generated in the mixing process, the temperature is heated to 65 degrees to obtain mixed liquid, and 2.4 parts by mass of isothiazolinone is added into the mixed liquid, so that the use and the storage life of mud pies are prolonged, and bacteria are prevented from being generated;
(d) adding 11 parts by mass of a coloring agent into a flour mixture, adding mixed liquid into the flour mixture, kneading the flour mixture into mud, adding 2.3 parts by mass of a wetting agent into the flour mixture in the kneading process, wherein the wetting agent is mainly added to increase the plasticity of mud dough, so that the mud dough is not easy to break, and the hand feeling of the mud dough is better due to the plasticizing effect of the wetting agent, the wetting agent is preferably selected from glycerol, diethylene glycol and triethylene glycol, and can also be selected from propylene glycol, polyethylene glycol and the like which are moisture absorbents, so that the mud dough put in the air is not dried quickly, and then obtaining 67 parts by mass of finished color mud;
(e) spreading 22 parts by mass of filler on 67 parts by mass of finished color mud, and spreading the filler outside the finished color mud, wherein the filler is prepared from a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, and the density of the plastic hollow microparticles can be effectively reduced because the density of the plastic hollow microparticles is very low;
(f) putting 67 parts by mass of finished colored mud into a sealed container, and putting the container into a refrigerator for refrigeration.
EXAMPLE six
A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding 4.9 parts by mass of polyvinyl alcohol into 25 parts by mass of water, soaking for 2 hours, and then cooking into a colloidal solution by using an antimony pot for later use;
(b) placing 34 parts by mass of flour and 37 parts by mass of water in the same container, kneading for 30 minutes, and adding 5.6 parts by mass of polyvinyl alcohol and 2.8 parts by mass of gelling agent into the container to obtain a flour mixture;
(c) heating and mixing 4.5 parts by mass of HAc and NaAc mixed solution with 2.6 parts by mass of higher alcohol fatty acid ester compound, wherein the higher alcohol fatty acid ester compound is mainly used for eliminating bubbles generated in the mixing process, the temperature is heated to 65 degrees to obtain mixed liquid, and 3.8 parts by mass of isothiazolinone is added into the mixed liquid, so that the use and storage life of mud pies are prolonged, and bacteria are prevented from being generated;
(d) adding 6.5 parts by mass of a coloring agent into a flour mixture, adding a mixed liquid into the flour mixture, kneading the flour mixture into mud, adding 1.1 parts by mass of a wetting agent into the flour mixture in the kneading process, wherein the wetting agent is mainly added to increase the plasticity of a mud dough so that the mud dough is not easy to break, and the hand feeling of the mud dough is better due to the plasticizing effect of the wetting agent, the wetting agent is preferably selected from glycerol, diethylene glycol and triethylene glycol, and can also be selected from propylene glycol, polyethylene glycol and the like which are moisture absorbents, so that the mud dough put in the air cannot be dried quickly, and then obtaining 58 parts by mass of finished color mud;
(e) spreading 26 parts by mass of a filler on 58 parts by mass of the finished product color clay, and spreading the filler outside the finished product color clay, wherein the filler is prepared from a mixture of plastic microparticles, calcium carbonate, talcum powder, mica and the like, and the density of the plastic hollow microparticles can be effectively reduced because the density of the plastic hollow microparticles is very low;
(f) putting 58 parts by mass of finished colored mud into a sealed container, and putting the container into a refrigerator for refrigeration.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. The formula of the children safety color mud with the antibacterial function is characterized in that: the children safety color clay comprises the following components:
4-18 parts of polyvinyl alcohol, 0.1-3 parts of gelling agent, 30-70 parts of water, 10-40 parts of flour, 1-10 parts of mixed solution of HAc and NaAc, 1-8 parts of higher alcohol fatty acid ester compound, 10-40 parts of filler and 5-15 parts of colorant.
2. A preparation process of children safety color mud with an antibacterial function comprises the following steps:
(a) firstly, adding polyvinyl alcohol into water for soaking, and then boiling the mixture into colloidal solution for later use by using an antimony pot;
(b) placing the flour and water in the same container, kneading, and adding polyvinyl alcohol and a gelling agent into the container to obtain a flour mixture;
(c) heating and mixing the mixed solution of HAc and NaAc with a high-carbon alcohol fatty acid ester compound, and heating the temperature to obtain a mixed liquid;
(d) adding a coloring agent into the flour mixture, adding the mixed liquid into the flour mixture, and kneading the flour mixture into mud to obtain finished colored mud;
(e) spreading a filler on the finished product color clay, and spreading the filler to the outside of the finished product color clay;
(f) and putting the finished product of the colored mud into a sealed container, and putting the container into a refrigerator for refrigeration.
3. The preparation process of the children safety color mud with the antibacterial function according to claim 2, characterized in that: 1-3 parts by mass of wetting agent is also added into the flour mixture in the kneading process.
4. The preparation process of the children safety color mud with the antibacterial function according to claim 2, characterized in that: the preparation process of the children safety color mud with the antibacterial function adopts gels with different components for synthesis.
5. The preparation process of the children safety color mud with the antibacterial function according to claim 2, characterized in that: after the preparation of the mixed liquid is finished, 1-4 parts by mass of isothiazolinone is also added.
6. The preparation process of the children safety color mud with the antibacterial function according to claim 2, characterized in that: the polyvinyl alcohol is generated by polyvinyl acetate alcoholysis, wherein a-OCOCH 3 group in the polyvinyl acetate is partially or completely substituted by-OH, and the substitution degree is 78-100%.
7. The preparation process of the children safety color mud with the antibacterial function according to claim 6, characterized in that: the polyvinyl alcohol is condensed with-OH in the gel to form cross-linking, and the gel is formed.
8. The preparation process of the children safety color mud with the antibacterial function according to claim 2, characterized in that: the sealing container can adopt a preservative film to seal the finished product color clay.
9. The preparation process of the children safety color mud with the antibacterial function according to claim 3, characterized in that: the humectant can be selected from glycerol, diethylene glycol, triethylene glycol, propylene glycol, polyethylene glycol, etc.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115353699A (en) * | 2022-09-06 | 2022-11-18 | 博士爱玩具有限公司 | Preparation method of antibacterial children safety color mud |
| CN117050011A (en) * | 2023-10-11 | 2023-11-14 | 湖南工程学院 | Method for synthesizing 2-methylquinoline by using vinyl acetate as raw material |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101648789A (en) * | 2008-08-15 | 2010-02-17 | 宁波松鹤文具有限公司 | Light color clay and production method thereof |
| CN102010524A (en) * | 2009-09-08 | 2011-04-13 | 真彩文具有限公司 | Non-toxic color mud |
| CN105440428A (en) * | 2015-12-31 | 2016-03-30 | 苏州冰心文化用品有限公司 | Light and antibacterial resin-clay composition and preparation method thereof |
| CN106866024A (en) * | 2015-12-10 | 2017-06-20 | 青岛华南盛源果业有限公司 | A kind of lightweight Noctilucent color daub |
| CN108727851A (en) * | 2017-10-12 | 2018-11-02 | 广东意之趣科技有限公司 | A kind of non-toxic light coloured silk mud and preparation method thereof |
| CN108727845A (en) * | 2017-10-13 | 2018-11-02 | 广东意之趣科技有限公司 | A kind of color mud and preparation method thereof can be used for making teaching aid |
-
2019
- 2019-08-22 CN CN201910777820.4A patent/CN110684367A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101648789A (en) * | 2008-08-15 | 2010-02-17 | 宁波松鹤文具有限公司 | Light color clay and production method thereof |
| CN102010524A (en) * | 2009-09-08 | 2011-04-13 | 真彩文具有限公司 | Non-toxic color mud |
| CN106866024A (en) * | 2015-12-10 | 2017-06-20 | 青岛华南盛源果业有限公司 | A kind of lightweight Noctilucent color daub |
| CN105440428A (en) * | 2015-12-31 | 2016-03-30 | 苏州冰心文化用品有限公司 | Light and antibacterial resin-clay composition and preparation method thereof |
| CN108727851A (en) * | 2017-10-12 | 2018-11-02 | 广东意之趣科技有限公司 | A kind of non-toxic light coloured silk mud and preparation method thereof |
| CN108727845A (en) * | 2017-10-13 | 2018-11-02 | 广东意之趣科技有限公司 | A kind of color mud and preparation method thereof can be used for making teaching aid |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115353699A (en) * | 2022-09-06 | 2022-11-18 | 博士爱玩具有限公司 | Preparation method of antibacterial children safety color mud |
| CN117050011A (en) * | 2023-10-11 | 2023-11-14 | 湖南工程学院 | Method for synthesizing 2-methylquinoline by using vinyl acetate as raw material |
| CN117050011B (en) * | 2023-10-11 | 2024-01-23 | 湖南工程学院 | Method for synthesizing 2-methylquinoline by using vinyl acetate as raw material |
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