CN101265379A - Spraying agent capable of curing to color pasting film - Google Patents

Spraying agent capable of curing to color pasting film Download PDF

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Publication number
CN101265379A
CN101265379A CN 200710088057 CN200710088057A CN101265379A CN 101265379 A CN101265379 A CN 101265379A CN 200710088057 CN200710088057 CN 200710088057 CN 200710088057 A CN200710088057 A CN 200710088057A CN 101265379 A CN101265379 A CN 101265379A
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CN
China
Prior art keywords
solvent
sprays
film
spraying agent
photostabilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200710088057
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Chinese (zh)
Inventor
张振霞
郑玉忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanshan Normal University
Original Assignee
Hanshan Normal University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hanshan Normal University filed Critical Hanshan Normal University
Priority to CN 200710088057 priority Critical patent/CN101265379A/en
Publication of CN101265379A publication Critical patent/CN101265379A/en
Pending legal-status Critical Current

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  • Paints Or Removers (AREA)

Abstract

The invention relates to a spraying agent which can be solidified into colored adhesive films and a preparation method thereof, and belongs to the chemical engineering field. The spraying agent is a special coating. The film forming spraying agent primarily consists of a material to be formed into films, pigment and a solvent. The material to be formed into films is an innoxious high-molecular material. Before the film forming spraying agent is used, the film forming spraying agent is in the state of solution, and can be sprayed on various smooth surfaces. The dried film forming spraying agent becomes a colored high-molecular material film, and is suitable to be used as the colored glass adhesive film with excellent adhesion and weatherability. In addition, the film is flaky and can be stripped off easily. The sprayability of the spraying agent avoids the fussy manual sticking procedure of the prior glass adhesive film, and the nonuniformity of the prior glass adhesive film. As the adhesive film can be stripped off easily, the problem that sticking marks are left when the prior glass adhesive film is removed is solved. In addition, the invention can be used for drawing patterns on glass surfaces or dust prevention on glass surfaces.

Description

A kind of curable be the sprays of color pasting film
Technical field
The invention belongs to chemical field, speciality coating is specifically related to a kind of curable sprays for color pasting film and preparation method thereof.
Background technology
In daily life, the transparency that people regular meeting regulates window-glass with dissimilar glass pasters or pad pasting is to reach the purpose of shading or protection privacy.One deck viscose glue is arranged on these pasters or the pad pasting, can be with itself and glass surface close adhesion.But the main drawback that these products exist is: (1) is difficult to paste neat when using, and pastes also to stay bubble easily, influences attractive in appearance; (2) in the place to go or when changing these products, can stay a lot of viscose glue markings, be difficult to remove.Therefore, in a single day these pasters or pad pasting stick, and people just are difficult to arbitrary the replacing.
A kind of product aerosol, that easily divest can solve the problem of present existence satisfactorily, but this pointed product does not also occur at present.Once there was Japanese Patent " the used in air exchange fan overlay film forms agent " (the clear and 55-69665 of publication number) world, and this invention is a matrix by trimerization nylon, is the brush-type solution of solvent with ethanol.After the film forming, easily crisp hard because the winter hardiness of rete is poor, and wetting ability is strong, the usage period lacks and is not developed.Domestic have " spary coating type, greasy-dirt separation film capable of stripping-off " (publication number CNI129237A) and " strippability, transparent fit protective film " (a publication number CN1563225), these two patents are mainly used in anti-greasy dirt or anti-dust, the membranous ground of its formation is fine and smooth inadequately, is not suitable for use in adhering film to glass.And outstanding feature of the present invention is, the every technical feature and the strippability of rete have good result of use; And added different dyestuffs, can form coloury adhering film to glass layer.Therefore comparing obvious improvement with existing technology, and on functions of use and scope, be improved.
Summary of the invention
Purpose of the present invention provides a kind of film forming spraying agent and preparation method thereof for solving the shortcoming that present common paster or pad pasting exist.This sprays can evenly be sprayed on glue the top layer of glass, after the drying, becomes colored polymer material film, has good bonding strength and weathering resistance, and what the while also can be in blocks well divests.
The glue of this film forming spraying agent is made of by weight percentage solute, solvent and other annexation.Wherein, solute comprises polyvinyl butyral acetal, Vltra tears and polymeric amide; Solvent is that propyl carbinol and ethyl acetate are to mix at 1: 1 by volume; Other annexation comprise softening agent, flow agent, oxidation inhibitor, photostabilizer and dyestuff.
The weight percent of each composition is in this sprays:
Polyvinyl butyral acetal 3-8%
Vltra tears 1-20%
Kymene-5%
Solvent 75-93%
Softening agent 0.2-0.5%
Flow agent 0.05-0.2%
Antioxidant 0.05-0.2%
Photostabilizer 0.05-0.2%
Dyestuff 0.01-1%
Softening agent is that ether ricinoleic acid butyl ester and stearyl alcohol are to mix at 2: 1 by weight percentage.Flow agent is the methyl alkyl polysiloxane.Antioxidant is 1,1,3 one three one (2 monomethyls, one 4 monohydroxies, one 5 one tert-butyl-phenyls) butane.Photostabilizer is two (2,2,6,6 one tetramethyl-piperidyl) sebates.
Dyestuff is one or more mixing in C.I. solvent red 27, C.I. solvent red 111, C.I. solvent yellow 14, C.I. solvent yellow 93, C.I. solvent royal purple 13, C.I. solvent royal purple 37, C.I. solvent green 3, C.I. solvent green 28 or the C.I. solvent blue 19 04.
This sprays is applied to all kinds of smooth surfaces, after the drying, can form colored polymer material film, is suitable for and makes the adhering film to glass layer, has good bonding strength and weathering resistance, and what the while also can be in blocks well divests.Sprayability of the present invention has been avoided the loaded down with trivial details and inhomogeneous of simple glass pad pasting hand paste; Its easy separability also can solve in the removing simple glass pad pasting process, stays the problem of the viscose glue marking easily.Simultaneously, also be used in the dustproof effect that glass surface draws a design or is used for glass surface.
Embodiment
Embodiment one
The first step preparing solvent: propyl carbinol and ethyl acetate are to mix at 1: 1 by volume;
The preparation of softening agent: ether ricinoleic acid butyl ester and stearyl alcohol are to mix at 2: 1 by weight percentage.
Second step was got polyvinyl butyral acetal 30g, Vltra tears 20g, and kymene 0g mixes.
It is an amount of that the 3rd step was got the solvent of preparation, puts in the encloses container, stirs down slowly to add said mixture, is enclosed on the shaking table jolting to all dissolvings.After treating to dissolve fully, in solution, add softening agent 2g, flow agent 0.5g, antioxidant 0.5g, photostabilizer 0.5g, dyestuff 0.1g stirring and dissolving, the solvent that adds preparation makes full dose become 1000ml.
The 4th step quantitatively poured into solution in the spray bottle on request, and is airtight.
The 5th step packing.
As mentioned above, can realize the present invention preferably.
Embodiment two
The first step preparing solvent: propyl carbinol and ethyl acetate are to mix at 1: 1 by volume;
The preparation of softening agent: ether ricinoleic acid butyl ester and stearyl alcohol are to mix at 2: 1 by weight percentage.
Second step was got polyvinyl butyral acetal 80g, Vltra tears 150g, and polymeric amide 50g mixes.
It is an amount of that the 3rd step was got the solvent of preparation, puts in the encloses container, stirs down slowly to add said mixture, is enclosed on the shaking table jolting to all dissolvings.After treating to dissolve fully, in solution, add softening agent 5g, flow agent 2g, antioxidant 2g, photostabilizer 2g, dyestuff 1g stirring and dissolving, the solvent that adds preparation makes full dose become 1000ml.
The 4th step quantitatively poured into solution in the spray bottle on request, and is airtight.
The 5th step packing.
As mentioned above, can realize the present invention preferably.
Embodiment three
The first step preparing solvent; Propyl carbinol and ethyl acetate are to mix at 1: 1 by volume;
The preparation of softening agent: ether ricinoleic acid butyl ester and stearyl alcohol are to mix at 2: 1 by weight percentage.
Second step was got polyvinyl butyral acetal 70g, Vltra tears 80g, and polymeric amide 40g mixes.
It is an amount of that the 3rd step was got the solvent of preparation, puts in the encloses container, stirs down slowly to add said mixture, is enclosed on the shaking table jolting to all dissolvings.After treating to dissolve fully, in solution, add softening agent 4g, flow agent 1g, antioxidant 1g, photostabilizer 0.5g, dyestuff 0.05g stirring and dissolving, the solvent that adds preparation makes full dose become 1000ml.
The 4th step quantitatively poured into solution in the spray bottle on request, and is airtight.
The 5th step packing.
As mentioned above, can realize the present invention preferably.

Claims (9)

  1. One kind curable be the sprays of color pasting film, its glue is made of by weight percentage solute, solvent and other annexation.It is characterized in that solute comprises polyvinyl butyral acetal, Vltra tears and polymeric amide, other annexation comprise softening agent, flow agent, oxidation inhibitor, photostabilizer and dyestuff.
  2. 2. sprays according to claim 1 is characterized in that the weight percent of each composition is:
    Polyvinyl butyral acetal 3-8%
    Vltra tears 15-25%
    Kymene-5%
    Solvent 75-85%
    Softening agent 0.2-0.5%
    Flow agent 0.05-0.2%
    Antioxidant 0.05-0.2%
    Photostabilizer 0.05-0.2%
    Dyestuff 0.01-1%
  3. 3. sprays according to claim 1 and 2 is characterized in that solvent is that propyl carbinol and ethyl acetate are to mix at 1: 1 by volume.
  4. 4. sprays according to claim 1 and 2 is characterized in that softening agent is that ether ricinoleic acid butyl ester and stearyl alcohol are to mix at 2: 1 by weight percentage.
  5. 5. sprays according to claim 1 and 2 is characterized in that flow agent is the methyl alkyl polysiloxane.
  6. 6. sprays according to claim 1 and 2 is characterized in that antioxidant is 1,1,3 one three one (2 monomethyls, one 4 monohydroxies, one 5 one tert-butyl-phenyls) butane.
  7. 7. sprays according to claim 1 and 2 is characterized in that photostabilizer is two (2,2,6,6 one tetramethyl-piperidyl) sebates.
  8. 8. sprays according to claim 1 and 2 is characterized in that dyestuff is one or more mixing in C.I. solvent red 27, C.I. solvent red 111, C.I. solvent yellow 14, C.I. solvent yellow 93, C.I. solvent royal purple 13, C.I. solvent royal purple 37, C.I. solvent green 3, C.I. solvent green 28 or the C.I. solvent blue 19 04.
  9. 9. according to the described sprays of one of claim 1 to 8, it is characterized in that sprays is applied to all kinds of smooth surfaces, dry back forms colored polymer material film, is suitable for and makes colored adhering film to glass layer, have good bonding strength and weathering resistance, what the while also can be in blocks well divests.
CN 200710088057 2007-03-13 2007-03-13 Spraying agent capable of curing to color pasting film Pending CN101265379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200710088057 CN101265379A (en) 2007-03-13 2007-03-13 Spraying agent capable of curing to color pasting film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200710088057 CN101265379A (en) 2007-03-13 2007-03-13 Spraying agent capable of curing to color pasting film

Publications (1)

Publication Number Publication Date
CN101265379A true CN101265379A (en) 2008-09-17

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200710088057 Pending CN101265379A (en) 2007-03-13 2007-03-13 Spraying agent capable of curing to color pasting film

Country Status (1)

Country Link
CN (1) CN101265379A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062253A (en) * 2015-09-07 2015-11-18 王璐 Paint for aluminum alloy sections
US10428246B2 (en) 2017-12-19 2019-10-01 Industrial Technology Research Institute Adhesive composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062253A (en) * 2015-09-07 2015-11-18 王璐 Paint for aluminum alloy sections
US10428246B2 (en) 2017-12-19 2019-10-01 Industrial Technology Research Institute Adhesive composition

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Open date: 20080917