CN110684248A - Wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt and manufacturing method thereof - Google Patents

Wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt and manufacturing method thereof Download PDF

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Publication number
CN110684248A
CN110684248A CN201911122903.6A CN201911122903A CN110684248A CN 110684248 A CN110684248 A CN 110684248A CN 201911122903 A CN201911122903 A CN 201911122903A CN 110684248 A CN110684248 A CN 110684248A
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parts
resistant
rubber
wear
agent
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Inventor
宋鑫
宋长江
王巍
魏雪梅
李朝红
周震宇
汪健
袁陆海
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ANHUI ZHONGYI RUBBER BELTS Co Ltd
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ANHUI ZHONGYI RUBBER BELTS Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G15/00Conveyors having endless load-conveying surfaces, i.e. belts and like continuous members, to which tractive effort is transmitted by means other than endless driving elements of similar configuration
    • B65G15/30Belts or like endless load-carriers
    • B65G15/32Belts or like endless load-carriers made of rubber or plastics
    • B65G15/34Belts or like endless load-carriers made of rubber or plastics with reinforcing layers, e.g. of fabric
    • B65G15/36Belts or like endless load-carriers made of rubber or plastics with reinforcing layers, e.g. of fabric the layers incorporating ropes, chains, or rolled steel sections
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ropes Or Cables (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt and a manufacturing method thereof, wherein natural rubber/styrene-butadiene rubber/butadiene rubber is selected as a main material, N234 carbon black is used as a reinforcing agent, a CMoSSI wear-resistant agent is added, the wear-resistant cold-resistant impact-resistant rubber composite material prepared by optimizing a formula and a process is used as a covering layer of the steel wire rope core conveying belt, the conveying belt has excellent wear resistance and impact resistance, still has good mechanical property and long service life under the conditions of low temperature and impact load, meets the use requirement of the steel wire rope core conveying belt in a low-temperature environment, and is simple in process and easy to manufacture.

Description

Wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt and manufacturing method thereof
Technical Field
The invention relates to the technical field of mining conveying belts, in particular to a steel wire rope core conveying belt with wear resistance, cold resistance and impact resistance and a manufacturing method thereof.
Background
The steel wire rope core conveying belt used in mines, ports, open coal mines and other workplaces is required to have the characteristics of high wear resistance, impact resistance, good low temperature resistance and the like due to severe working environment and large borne impact load. Particularly, in mines and open pit mines in northeast and northwest areas of China, the low temperature in a severe cold period is below-50 ℃, the steel wire rope core conveying belt in the prior art can become hard and brittle when used at the environmental temperature, the mechanical property is seriously reduced, the service life is short under the condition of impact load, and even the service performance is lost. In the prior art, the mechanical property of the steel wire rope core conveyer belt under the conditions of normal temperature and high temperature is researched more, but the research on how to improve the mechanical property and the service life of the steel wire rope core conveyer belt under the conditions of low temperature and impact load is less.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, and provides a steel wire rope core conveying belt which is wear-resistant, cold-resistant and impact-resistant, has excellent wear resistance and impact resistance, still has good mechanical properties and long service life under the conditions of low temperature and impact load, and meets the use requirements of steel wire rope core conveying belts in workplaces such as mines, ports, opencast coal mines and the like.
The second purpose of the invention is to provide a preparation method of the conveying adhesive tape, which has simple process and easy manufacture.
The purpose of the invention is realized by the following scheme:
the invention relates to a wear-resistant, cold-resistant and impact-resistant steel wire rope core conveying belt, which comprises a steel wire rope core, a middle rubber layer, an upper covering rubber layer and a lower covering rubber layer, and is characterized in that the upper covering rubber layer and the lower covering rubber layer consist of the following components in percentage by weight:
20-30 parts of Natural Rubber (NR), 20-30 parts of styrene butadiene rubber (SBR 1500), 50 parts of butadiene rubber (BR 9000), 4-6 parts of zinc oxide, 1-3 parts of stearic acid, 1.5-2.0 parts of sulfur, 1.5-2.0 parts of an accelerator, 2-3 parts of an anti-aging agent, 1-2 parts of protective wax, 0.5-1 part of a scorch retarder CTP, 50-60 parts of carbon black (N234), 4-6 parts of a CMoSSI wear resistant agent, 4-6 parts of coumarone resin and 2-4 parts of aromatic oil.
The promoter is a combination of a promoter CZ and a promoter TMTD, and the anti-aging agent is a combination of an anti-aging agent RD and an anti-aging agent 4020.
The CMoSSI wear-resistant agent is a composition of graphite powder with the fineness of 1000 meshes, molybdenum disulfide with the fineness of 1000 meshes and a Si69 silane coupling agent, and the mass ratio of the three components is 75%: 23%: 2 percent.
The steel wire rope core is a galvanized steel wire rope with an open structure of 6 multiplied by 7-WSC, 6 multiplied by 19-WSC and 6 multiplied by 19W-WSC, the middle layer rubber material is permeated into the steel wire rope structure through cold press molding and flat vulcanization processes to form a strength layer, and the strength layer and the upper and lower covering rubber layers are vulcanized into a compact whole.
The manufacturing method of the steel wire rope core conveyer belt with wear resistance, cold resistance and impact resistance, which is disclosed by the invention, comprises the following steps of:
(1) preparing an upper covering layer sizing material and a lower covering layer sizing material:
the sizing materials of the upper and lower covering glue layers comprise the following components in percentage by weight:
20-30 parts of Natural Rubber (NR), 20-30 parts of styrene-butadiene rubber (SBR 1500), 50 parts of butadiene rubber (BR 9000), 4-6 parts of zinc oxide, 1-3 parts of stearic acid, 1.5-2.0 parts of sulfur, 1.5-2.0 parts of an accelerator, 2-3 parts of an anti-aging agent, 1-2 parts of protective wax, 0.5-1 part of a scorch retarder CTP, 50-60 parts of carbon black (N234), 4-6 parts of a CMoSSI wear-resistant agent, 4-6 parts of coumarone resin and 2-4 parts of aromatic oil;
preparing the mixture into an upper covering layer sizing material and a lower covering layer sizing material:
1) plasticating natural rubber:
plasticating the natural rubber by using an internal mixer, wherein the rotor speed of the internal mixer is 40 r/min, the plasticating time is 180-;
2) preparing a CmoSSI wear-resistant agent:
putting graphite powder with the fineness of 1000 meshes and molybdenum disulfide with the fineness of 1000 meshes into a kneader, heating and stirring at the stirring speed of 350-400 r/min, heating to 40-60 ℃, spraying a Si69 silane coupling agent, continuously heating and stirring, and stirring at the temperature of 110-120 ℃ for 10-15 min to prepare the CMoSSI wear-resistant agent, wherein the mass ratio of the graphite powder/the molybdenum disulfide/the Si69 in the CMoSSI wear-resistant agent is 75%/23%/2%;
3) first-stage mixing:
firstly, plasticated natural rubber, styrene butadiene rubber and butadiene rubber are put into an internal mixer for mixing for 40-50 seconds, carbon black (50%), a CMoSSI wear-resistant agent and aromatic oil are put into the internal mixer, mixing is continued for 150-180 seconds, then zinc oxide, stearic acid, an anti-aging agent, protective wax, carbon black (50%), coumarone resin are put into the internal mixer for further mixing for 150-180 seconds, the rubber discharge temperature is 140-150 ℃, sheets are taken out and cooled, a section of mixed rubber is prepared, and the mixed rubber is used after being placed for 8 hours;
4) and (3) second-stage mixing:
an internal mixer is used in the second-stage mixing, the rotor speed of the internal mixer is 20 r/min, the first-stage mixed rubber, sulfur, an accelerant and an anti-scorching agent are put into the internal mixer for mixing for 100 and 120 seconds, the rubber discharge temperature is 90-100 ℃, and the second-stage mixed rubber is obtained by sheet discharging and cooling, namely the upper and lower covering layer rubber materials and is used after being placed for 8 hours;
(2) preparing an intermediate layer sizing material:
the middle layer rubber material is used for a common steel wire rope core conveying belt;
(3) rolling out a sheet:
upper and lower covering layer rubber sheets and middle layer rubber sheets are produced by a cold feed extruder and a four-roller calender and are used after being parked for 8 hours;
(4) cold press molding:
cold press molding the upper and lower covering layer rubber sheets and the middle layer rubber sheet and the steel wire rope in a constant tension state by a cold press molding machine to prepare a belt blank;
(5) plate vulcanization:
and vulcanizing the cold-pressed and molded belt blank into a finished product through a flat vulcanizing machine, namely the wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt.
Compared with the prior art, the invention has the following beneficial effects:
the invention selects natural rubber/butadiene styrene rubber/butadiene rubber as a main material, N234 carbon black as a reinforcing agent, adds a CMoSSI wear-resistant agent, and prepares the wear-resistant, cold-resistant and impact-resistant rubber composite material as a covering layer of the steel wire rope core conveying belt by optimizing a formula and a process.
Detailed Description
The following examples are given to aid in the understanding of the invention, but are not intended to limit the scope of the invention.
Example 1
The embodiment provides a wear-resisting cold-resistant steel wire rope core conveyer belt that shocks resistance, including steel wire rope core, middle glue film, go up the cover glue film, cover the glue film down, its characterized in that go up the cover glue film, cover the glue film down and constitute by following component according to the weight ratio:
NR 20 parts, SBR 150030 parts, BR 900050 parts, zinc oxide 4 parts, stearic acid 3 parts, sulfur 2.0 parts, accelerator CZ 1 part, accelerator TMTD 1 part, anti-aging agent RD 1 part, anti-aging agent 40201 part, protective wax 2 parts, antiscorching agent CTP 0.5 part, carbon black N23450 part, CmoSSI wear-resistant agent 6 parts, coumarone resin 6 parts, and aromatic oil 2 parts.
The CMoSSI wear-resistant agent is a composition of graphite powder with the fineness of 1000 meshes, molybdenum disulfide with the fineness of 1000 meshes and a Si69 silane coupling agent, and the mass ratio of the three components is 75%/23%/2%.
The manufacturing method of the steel wire rope core conveying belt with wear resistance, cold resistance and impact resistance, which is described in the embodiment, comprises the following steps:
(1) preparing an upper covering layer sizing material and a lower covering layer sizing material:
the sizing materials of the upper and lower covering glue layers comprise the following components in percentage by weight:
NR 20 parts, SBR 150030 parts, BR 900050 parts, zinc oxide 4 parts, stearic acid 3 parts, sulfur 2.0 parts, accelerator CZ 1 part, accelerator TMTD 1 part, anti-aging agent RD 1 part, anti-aging agent 40201 part, protective wax 2 parts, antiscorching agent CTP 0.5 part, carbon black N23450 part, CmoSSI wear-resistant agent 6 parts, coumarone resin 6 parts, and aromatic oil 2 parts;
preparing the mixture into a two-stage rubber compound of an upper covering layer rubber compound and a lower covering layer rubber compound:
1) plasticating natural rubber:
plasticating the natural rubber by using an internal mixer, wherein the rotor speed of the internal mixer is 40 r/min, the plasticating time is 180-;
2) preparing a CmoSSI wear-resistant agent:
putting graphite powder with the fineness of 1000 meshes and molybdenum disulfide with the fineness of 1000 meshes into a kneader, heating and stirring at the stirring speed of 350-400 r/min, heating to 40-60 ℃, spraying a Si69 silane coupling agent, continuously heating and stirring, and stirring at the temperature of 110-120 ℃ for 10-15 min to prepare the CMoSSI wear-resistant agent, wherein the mass ratio of the graphite powder/the molybdenum disulfide/the Si69 in the CMoSSI wear-resistant agent is 75%/23%/2%;
3) first-stage mixing:
the first mixing stage uses an internal mixer, and the rotating speed of the rotor of the internal mixer is 40 r/min. Firstly, plasticated natural rubber, styrene butadiene rubber and butadiene rubber are put into an internal mixer for mixing for 40-50 seconds, carbon black (50%), a CMoSSI wear-resistant agent and aromatic oil are put into the internal mixer for continuously mixing for 150-180 seconds, then zinc oxide, stearic acid, an anti-aging agent, protective wax, carbon black (50%) and coumarone resin are put into the internal mixer for continuously mixing for 150-180 seconds, the rubber discharge temperature is 140-150 ℃, and the mixture is taken out of a sheet and cooled to prepare a section of mixed rubber which is used after being placed for 8 hours;
4) and (3) second-stage mixing:
an internal mixer is used in the second-stage mixing, the rotor speed of the internal mixer is 20 r/min, the first-stage mixed rubber, sulfur, an accelerant and an anti-scorching agent are put into the internal mixer for mixing for 100 and 120 seconds, the rubber discharge temperature is 90-100 ℃, and the second-stage mixed rubber is obtained after sheet discharging and cooling, namely the upper and lower covering layer rubber materials and is used after being parked for 8 hours;
(2) preparing an intermediate layer sizing material:
the middle layer rubber material is used for a common steel wire rope core conveying belt;
(3) rolling out the sheet;
upper and lower covering layer rubber sheets and middle layer rubber sheets are produced by a cold feed extruder and a four-roller calender and are used after being parked for 8 hours;
(4) cold press forming
Cold press molding the upper and lower covering layer rubber sheets and the middle layer rubber sheet and the steel wire rope in a constant tension state by a cold press molding machine to prepare a belt blank;
(5) curing of flat sheets
And vulcanizing the cold-pressed and molded belt blank into a finished product through a flat vulcanizing machine, namely the wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt.
Example 2
The embodiment provides a wear-resisting cold-resistant steel wire rope core conveyer belt that shocks resistance, including steel wire rope core, middle glue film, go up the cover glue film, cover the glue film down, its characterized in that go up the cover glue film, cover the glue film down and constitute by following component according to the weight ratio:
NR 25 parts, SBR 150025 parts, BR 900050 parts, zinc oxide 5 parts, stearic acid 2 parts, sulfur 1.8 parts, accelerator CZ 1 part, accelerator TMTD 0.8 part, antioxidant RD 1.5 parts, antioxidant 40201 parts, protective wax 1.5 parts, antiscorching agent CTP 0.8 part, carbon black N23455 parts, CMoSSI wear-resistant agent 5 parts, coumarone resin 5 parts, and aromatic oil 3 parts.
The CMoSSI wear-resistant agent is a composition of graphite powder with the fineness of 1000 meshes, molybdenum disulfide with the fineness of 1000 meshes and a Si69 silane coupling agent, and the mass ratio of the three components is 75%/23%/2%.
The manufacturing method of the steel wire rope core conveying belt with wear resistance, cold resistance and impact resistance, which is described in the embodiment, comprises the following steps:
(1) preparing an upper covering layer sizing material and a lower covering layer sizing material:
the sizing materials of the upper and lower covering glue layers comprise the following components in percentage by weight:
NR 25 parts, SBR 150025 parts, BR 900050 parts, zinc oxide 5 parts, stearic acid 2 parts, sulfur 1.8 parts, accelerator CZ 1 part, accelerator TMTD 0.8 part, antioxidant RD 1.5 parts, antioxidant 40201 parts, protective wax 1.5 parts, antiscorching agent CTP 0.8 part, carbon black N23455 parts, CMoSSI wear-resistant agent 5 parts, coumarone resin 5 parts, and aromatic oil 3 parts;
preparing the mixture into a two-stage rubber compound of an upper covering layer rubber compound and a lower covering layer rubber compound:
1) plasticating natural rubber:
plasticating the natural rubber by using an internal mixer, wherein the rotor speed of the internal mixer is 40 r/min, the plasticating time is 180-;
2) preparing a CmoSSI wear-resistant agent:
putting graphite powder with the fineness of 1000 meshes and molybdenum disulfide with the fineness of 1000 meshes into a kneader, heating and stirring at the stirring speed of 350-400 r/min, heating to 40-60 ℃, spraying a Si69 silane coupling agent, continuously heating and stirring, and stirring at the temperature of 110-120 ℃ for 10-15 min to prepare the CMoSSI wear-resistant agent, wherein the mass ratio of the graphite powder/the molybdenum disulfide/the Si69 in the CMoSSI wear-resistant agent is 75%/23%/2%;
3) first-stage mixing:
the first mixing stage uses an internal mixer, and the rotating speed of the rotor of the internal mixer is 40 r/min. Firstly, plasticated natural rubber, styrene butadiene rubber and butadiene rubber are put into an internal mixer for mixing for 40-50 seconds, carbon black (50%), a CMoSSI wear-resistant agent and aromatic oil are put into the internal mixer for continuously mixing for 150-180 seconds, then zinc oxide, stearic acid, an anti-aging agent, protective wax, carbon black (50%) and coumarone resin are put into the internal mixer for continuously mixing for 150-180 seconds, the rubber discharge temperature is 140-150 ℃, sheets are taken out and cooled, and a section of mixed rubber is prepared, namely an upper covering layer rubber material and a lower covering layer rubber material and is used after being placed for 8 hours;
4) and (3) second-stage mixing:
the two-stage mixing was carried out using an internal mixer with a rotor speed of 20 rpm. The first-stage rubber compound, the sulfur, the accelerator and the anti-scorching agent are put into an internal mixer for mixing for 100-120 seconds, the rubber discharge temperature is 90-100 ℃, the rubber sheet is taken out and cooled, and the second-stage rubber compound, namely the upper and lower covering layer rubber materials, is prepared and is used after being placed for 8 hours;
(2) preparing an intermediate layer sizing material:
the middle layer rubber material is used for a common steel wire rope core conveying belt;
(3) rolling out a sheet:
upper and lower covering layer rubber sheets and middle layer rubber sheets are produced by a cold feed extruder and a four-roller calender and are used after being parked for 8 hours;
(4) cold press molding:
cold press molding the upper and lower covering layer rubber sheets and the middle layer rubber sheet and the steel wire rope in a constant tension state by a cold press molding machine to prepare a belt blank;
(5) plate vulcanization:
and vulcanizing the cold-pressed and molded belt blank into a finished product through a flat vulcanizing machine, namely the wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt.
Example 3
The embodiment provides a wear-resisting cold-resistant steel wire rope core conveyer belt that shocks resistance, including steel wire rope core, middle glue film, go up the cover glue film, cover the glue film down, its characterized in that go up the cover glue film, cover the glue film down and constitute by following component according to the weight ratio:
30 parts of NR, 150020 parts of SBR, 900050 parts of BR, 6 parts of zinc oxide, 1 part of stearic acid, 1.5 parts of sulfur, 1 part of accelerator CZ, 0.5 part of accelerator TMTD, 2 parts of anti-aging agent RD, 40201 parts of anti-aging agent, 1 part of protective wax, 1 part of anti-scorching agent CTP, N23460 parts of carbon black, 4 parts of CMoSSI wear-resistant agent, 4 parts of coumarone resin and 4 parts of aromatic oil.
The CMoSSI wear-resistant agent is a composition of graphite powder with the fineness of 1000 meshes, molybdenum disulfide with the fineness of 1000 meshes and a Si69 silane coupling agent, and the mass ratio of the three components is 75%/23%/2%.
The manufacturing method of the steel wire rope core conveying belt with wear resistance, cold resistance and impact resistance, which is described in the embodiment, comprises the following steps:
(1) preparing an upper covering layer sizing material and a lower covering layer sizing material:
the sizing materials of the upper and lower covering glue layers comprise the following components in percentage by weight:
30 parts of NR, 150020 parts of SBR, 900050 parts of BR, 6 parts of zinc oxide, 1 part of stearic acid, 1.5 parts of sulfur, 1 part of accelerator CZ, 0.5 part of accelerator TMTD, 2 parts of anti-aging agent RD, 40201 parts of anti-aging agent, 1 part of protective wax, 1 part of anti-scorching agent CTP, N23460 parts of carbon black, 4 parts of CMoSSI wear-resistant agent, 4 parts of coumarone resin and 4 parts of aromatic oil;
preparing the mixture into a two-stage rubber compound of an upper covering layer rubber compound and a lower covering layer rubber compound:
1) plasticating natural rubber:
plasticating the natural rubber by using an internal mixer, wherein the rotor speed of the internal mixer is 40 r/min, the plasticating time is 180-;
2) preparing a CmoSSI wear-resistant agent:
putting graphite powder with the fineness of 1000 meshes and molybdenum disulfide with the fineness of 1000 meshes into a kneader, heating and stirring at the stirring speed of 350-400 r/min, heating to 40-60 ℃, spraying a Si69 silane coupling agent, continuously heating and stirring, and stirring at the temperature of 110-120 ℃ for 10-15 min to prepare the CMoSSI wear-resistant agent, wherein the mass ratio of the graphite powder/the molybdenum disulfide/the Si69 in the CMoSSI wear-resistant agent is 75%/23%/2%;
3) first-stage mixing:
the first mixing stage uses an internal mixer, and the rotating speed of the rotor of the internal mixer is 40 r/min. Firstly, plasticated natural rubber, styrene butadiene rubber and butadiene rubber are put into an internal mixer for mixing for 40-50 seconds, carbon black (50%), a CMoSSI wear-resistant agent and aromatic oil are put into the internal mixer for continuously mixing for 150-180 seconds, then zinc oxide, stearic acid, an anti-aging agent, protective wax, carbon black (50%) and coumarone resin are put into the internal mixer for continuously mixing for 150-180 seconds, the rubber discharge temperature is 140-150 ℃, and the mixture is taken out of a sheet and cooled to prepare a section of mixed rubber which is used after being placed for 8 hours;
4) and (3) second-stage mixing:
the two-stage mixing was carried out using an internal mixer with a rotor speed of 20 rpm. The first-stage rubber compound, the sulfur, the accelerator and the anti-scorching agent are put into an internal mixer for mixing for 100-120 seconds, the rubber discharge temperature is 90-100 ℃, the rubber sheet is taken out and cooled, and the second-stage rubber compound, namely the upper and lower covering layer rubber materials, is prepared and is used after being placed for 8 hours;
(2) preparing an intermediate layer sizing material:
the middle layer rubber material is used for a common steel wire rope core conveying belt;
(3) rolling out a sheet:
upper and lower covering layer rubber sheets and middle layer rubber sheets are produced by a cold feed extruder and a four-roller calender and are used after being parked for 8 hours;
(4) cold press molding:
cold press molding the upper and lower covering layer rubber sheets and the middle layer rubber sheet and the steel wire rope in a constant tension state by a cold press molding machine to prepare a belt blank;
(5) plate vulcanization:
and vulcanizing the cold-pressed and molded belt blank into a finished product through a flat vulcanizing machine, namely the wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt.
The test data for the above examples are shown in the following table:
Figure 574287DEST_PATH_IMAGE001

Claims (5)

1. the utility model provides a wear-resisting cold-resistant steel wire rope core conveyer belt that shocks resistance, includes steel wire rope core, middle glue film, goes up the cover glue film, covers the glue film down, its characterized in that go up the cover glue film, cover the glue film down and constitute by following component according to the weight ratio:
20-30 parts of natural rubber NR, 150020-30 parts of styrene butadiene rubber SBR, 900050 parts of butadiene rubber, 4-6 parts of zinc oxide, 1-3 parts of stearic acid, 1.5-2.0 parts of sulfur, 1.5-2.0 parts of an accelerator, 2-3 parts of an anti-aging agent, 1-2 parts of a protective wax, 0.5-1 part of a scorch retarder CTP, 50-60 parts of carbon black N23450, 4-6 parts of a CMoSSI wear-resistant agent, 4-6 parts of coumarone resin and 2-4 parts of aromatic oil.
2. The steel cord conveyor belt of claim 1, characterized in that: the promoter is a combination of a promoter CZ and a promoter TMTD.
3. The steel cord conveyor belt of claim 1, characterized in that: the anti-aging agent is a combination of an anti-aging agent RD and an anti-aging agent 4020.
4. The steel cord conveyor belt of claim 1, characterized in that: the CMoSSI wear-resistant agent is a composition of graphite powder with the fineness of 1000 meshes, molybdenum disulfide with the fineness of 1000 meshes and a Si69 silane coupling agent, and the mass ratio of the three components is 75%/23%/2%.
5. The method for manufacturing a steel cord conveyor belt resistant to wear, cold, and impact as claimed in claim 1, comprising the steps of:
(1) preparing an upper covering layer sizing material and a lower covering layer sizing material:
the rubber material of the upper and lower covering rubber layers is a wear-resistant cold-resistant impact-resistant rubber composite material and comprises the following components in percentage by weight:
20-30 parts of natural rubber NR, 150020-30 parts of styrene butadiene rubber SBR, 900050 parts of butadiene rubber, 4-6 parts of zinc oxide, 1-3 parts of stearic acid, 1.5-2.0 parts of sulfur, 1.5-2.0 parts of an accelerator, 2-3 parts of an anti-aging agent, 1-2 parts of a protective wax, 0.5-1 part of a scorch retarder CTP, 50-60 parts of carbon black N23450, 4-6 parts of a CMoSSI wear-resistant agent, 4-6 parts of coumarone resin and 2-4 parts of aromatic oil;
preparing the mixture into a two-stage rubber compound:
1) plasticating natural rubber:
plasticating the natural rubber by using an internal mixer, wherein the rotor speed of the internal mixer is 40 r/min, the plasticating time is 180-;
2) preparing a CmoSSI wear-resistant agent:
putting graphite powder with the fineness of 1000 meshes and molybdenum disulfide with the fineness of 1000 meshes into a kneader, heating and stirring at the stirring speed of 350-400 r/min, heating to 40-60 ℃, spraying a Si69 silane coupling agent, continuously heating and stirring, and stirring at the temperature of 110-120 ℃ for 10-15 min to prepare the CMoSSI wear-resistant agent, wherein the mass ratio of the graphite powder/the molybdenum disulfide/the Si69 in the CMoSSI wear-resistant agent is 75%/23%/2%;
3) first-stage mixing:
firstly, plasticated natural rubber, styrene butadiene rubber and butadiene rubber are put into an internal mixer for mixing for 40-50 seconds, 50% of carbon black, CMoSSI wear-resistant agent and aromatic oil are put into the internal mixer, mixing is continued for 180 seconds after 150-fold addition of materials, then zinc oxide, stearic acid, anti-aging agent, protective wax, 50% of carbon black and coumarone resin are put into the internal mixer for 180 seconds after 150-fold addition of materials, the rubber discharge temperature is 140-fold addition of materials at 150 ℃, sheets are taken out and cooled, a section of mixed rubber is prepared, and the mixed rubber is used after being placed for 8 hours;
4) and (3) second-stage mixing:
the two-stage mixing uses an internal mixer, and the rotor speed of the internal mixer is 20 r/min;
the first-stage rubber compound, sulfur, an accelerant and an anti-scorching agent are put into an internal mixer for mixing for 100-120 seconds, the rubber discharge temperature is 90-100 ℃, and the mixture is taken out and cooled to prepare a second-stage rubber compound;
(2) preparing an intermediate layer rubber material;
(3) rolling out the sheet;
(4) cold press molding;
(5) and (4) vulcanizing the flat plate.
CN201911122903.6A 2019-11-16 2019-11-16 Wear-resistant cold-resistant impact-resistant steel wire rope core conveying belt and manufacturing method thereof Pending CN110684248A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116285024A (en) * 2023-02-09 2023-06-23 山东威普斯橡胶股份有限公司 Preparation process of tubular steel wire rope core conveyer belt

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713264A (en) * 2016-05-09 2016-06-29 郭秀珍 Wear-resistant glove for electric power
CN110283367A (en) * 2019-07-16 2019-09-27 无锡宝通科技股份有限公司 Super abrasive conveyer belt coating rubber and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713264A (en) * 2016-05-09 2016-06-29 郭秀珍 Wear-resistant glove for electric power
CN110283367A (en) * 2019-07-16 2019-09-27 无锡宝通科技股份有限公司 Super abrasive conveyer belt coating rubber and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116285024A (en) * 2023-02-09 2023-06-23 山东威普斯橡胶股份有限公司 Preparation process of tubular steel wire rope core conveyer belt
CN116285024B (en) * 2023-02-09 2024-02-27 山东威普斯橡胶股份有限公司 Preparation process of tubular steel wire rope core conveyer belt

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Application publication date: 20200114