Summary of the invention
One of purpose of the present invention is to overcome the deficiencies in the prior art, and a kind of resistance toheat requirement that can satisfy anti-high hot conveyer belt is provided, and has again the intermediate rubber of fine bond properties.
Another object of the present invention provides a kind of preparation method of anti-high hot conveyer belt intermediate rubber.
According to technical scheme provided by the invention, a kind of anti-high hot conveyer belt intermediate rubber, formula rate by weight component is as follows:
Natural rubber 0-40 part, ethylene-propylene rubber(EPR) 40-100 part, styrene-butadiene rubber(SBR) 0-60 part, chlorosulfonated polyethylene 0-20 part, reinforced filling 10-60 part, vulcanization leveller 4-12 part, coupling agent 0.8-3 part, vulcanization accelerator 0.2-6 part, softening agent 5-40 part, anti-aging agent 1-5 part and vulcanizing agent 0.2-6 part;
Described ethylene-propylene rubber(EPR) is oil-filled ethylene-propylene rubber(EPR) or not oil-filled ethylene-propylene rubber(EPR), and the 3rd monomer content is 4%-11% by weight percentage in the described ethylene-propylene rubber(EPR), and ethylene content is 52%-72% by weight percentage.
Described styrene-butadiene rubber(SBR) is oil-extended styrene-butadiene rubber or oil-extended styrene-butadiene rubber not, and combined styrene content is 22.5%-24.5% by weight percentage in the described styrene-butadiene rubber(SBR);
Described natural rubber is the 10# natural rubber;
Cl content is 27%-45% by weight percentage in the described chlorosulfonated polyethylene, and sulphur content is 1%-5% by weight percentage;
Get first natural rubber and in mill, plasticate and obtain broken-(down)rubber, then carry out mixing; Mixing minute two sections carry out, one section is mixing with ethylene-propylene rubber(EPR), styrene-butadiene rubber(SBR), chlorosulfonated polyethylene and broken-(down)rubber drop into banburying in the Banbury mixer; Then open floating weight and add reinforced filling, vulcanization leveller, coupling agent, vulcanization accelerator, softening agent and anti-aging agent, through turn refining, slice, the cooling of normal temperature blower fan make one section rubber unvulcanizate; Carry out subsequently two-stage mixing, get one section rubber unvulcanizate making and vulcanizing agent drop in the Banbury mixer mixing through turn refining, slice, the cooling of normal temperature blower fan, namely get the anti-high hot conveyer belt intermediate rubber of product.
Described reinforced filling is one or more among white carbon black, carbon black N220, carbon black N330, carbon black N550 or the carbon black N660.
Described vulcanizing agent is one or more among sulphur, the DCP or two 2,5.
Described vulcanization accelerator is sulfenamide type accelerators CZ, sulfenamide type accelerators NOBS, one or more among thiazole accelerator DM or the thiazole accelerator M.
Described vulcanization leveller is one or more among zinc oxide, magnesium oxide, stearic acid or the TAIC.
Described coupling agent is silane coupling agent SI-69.
Described softening agent is one or more among aromatic hydrocarbon oil, coumarone, paraffin oil, carbon 9 resins or the octyl group phenolic aldehyde BN-1.
Described anti-aging agent is one or more in anti-aging agent RD, antioxidant 4010NA, antioxidant MB or the antioxidant BLE.
The described anti-high hot conveyer belt preparation method of intermediate rubber, formula rate by weight step is as follows:
(1) plasticate: get natural rubber 0-40 part and in mill, plasticate, roll spacing 2-4mm, the roller temperature control is at 40-50 ℃, and the 10-15min that plasticates obtains broken-(down)rubber;
(2) mixing: mixing minute two sections carry out, one section is mixing with ethylene-propylene rubber(EPR) 40-100 part, styrene-butadiene rubber(SBR) 0-60 part, chlorosulfonated polyethylene 0-20 part and step (1) gained broken-(down)rubber drops in the Banbury mixer, banburying 2-4min; Then open floating weight and add reinforced filling 10-60 part, vulcanization leveller 4-12 part, coupling agent 0.8-3 part, vulcanization accelerator 0.2-6 part, softening agent 5-40 part and anti-aging agent 1-5 part, banburying 3-5min, dump temperature are controlled at 130-150 ℃, through turning refining, making one section rubber unvulcanizate by thickness 8-12mm slice, the cooling of normal temperature blower fan, park 6-10h; Carry out subsequently two-stage mixing, get the one section rubber unvulcanizate and the 0.2-6 part vulcanizing agent that make and drop in the Banbury mixer, mixing 3-5min, dump temperature are controlled at 130-140 ℃, through turning refining, cooling off by thickness 8-12mm slice, normal temperature blower fan, namely get the anti-high hot conveyer belt intermediate rubber of product.
Beneficial effect of the present invention: the present invention considers from aspects such as heat resistance, bond properties and processing characteristicies, the formula system of selected anti-high hot conveyer belt intermediate rubber can reach splendid effect, anti-high hot conveyer belt intermediate rubber of the present invention is after use, cement mill, steel mill's convey materials had both been satisfied to resistant to elevated temperatures requirement, simultaneously can play good bonding transitional function to rubber cover, the core glue of anti-high hot conveyer belt, prevent the generation of delamination, greatly improve the work-ing life of conveying belt, realized good economic benefit.
Embodiment
The present invention will be further described below by embodiment, but not as limitation of the present invention.Described equipment is conventional production unit.
1 one kinds of anti-high hot conveyer belts intermediate rubbers and preparation method thereof of embodiment,
Its formula rate is by weight: 40 parts in ethylene-propylene rubber(EPR), 30 parts in styrene-butadiene rubber(SBR), 40 parts of natural rubbers, 35 parts of carbon black N330,15 parts of white carbon blacks, 2 parts in sulphur, vulcanizing agent two 2,53 parts, 1.5 parts of TAIC, 0.8 part of sulfenamide type accelerators NOBS, 1 part of thiazole accelerator DM, 1 part of thiazole accelerator M, 5 parts in zinc oxide, 2 parts of stearic acid, 0.8 part of coupling agent SI-69,8 parts of coumarones, 2 parts of bakelite B N-1 (guest king chemical plant, Wuxi), 8 parts of aromatic hydrocarbon oil, 8 parts of paraffin oils, 1 part of antioxidant 4010NA, 1 part of antioxidant BLE, 1.5 parts of 1 part of antioxidant MB and anti-aging agent RDs.
The preparation method of described anti-high hot conveyer belt intermediate rubber, concrete steps are:
(1) plasticate: natural rubber is plasticated in mill, roll spacing 2-4mm, the roller temperature control is at 40-50 ℃, and the 15min that plasticates makes broken-(down)rubber.
(2) mixing: mixing minute two sections carry out, one section mixing is first broken-(down)rubber, ethylene-propylene rubber(EPR), styrene-butadiene rubber(SBR) to be dropped in the Banbury mixer banburying 3min; Then open floating weight and add carbon black, white carbon black, zinc oxide, stearic acid, coupling agent SI-69, coumarone, bakelite B N-1, aromatic hydrocarbon oil, paraffin oil, sulfenamide type accelerators NOBS, thiazole accelerator M, DM, antioxidant 4010NA, antioxidant BLE, antioxidant MB and anti-aging agent RD, banburying 5min, dump temperature is controlled at 130-150 ℃, through turning refining, making one section rubber unvulcanizate by thickness 8-12mm slice, the cooling of normal temperature blower fan, park 6h; Two-stage mixing is with one section rubber unvulcanizate and sulphur, two 2,5 and TAIC, drops in the Banbury mixer, and mixing 4min, dump temperature are controlled at 130-140 ℃, through turning refining, namely getting the anti-high hot conveyer belt intermediate rubber of product by thickness 8-12mm slice, the cooling of normal temperature blower fan.
2 one kinds of anti-high hot conveyer belts intermediate rubbers and preparation method thereof of embodiment
Its formula rate is by weight: 50 parts in ethylene-propylene rubber(EPR), 30 parts in styrene-butadiene rubber(SBR), 20 parts of natural rubbers, 40 parts of carbon black N550,15 parts of white carbon blacks, 1.5 parts in sulphur, 4 parts of DCP, TAIC1.5 part, 0.5 part of sulfenamide type accelerators NOBS, 1 part of thiazole accelerator DM, 1 part of thiazole accelerator M, 5 parts in zinc oxide, 2 parts of stearic acid, 1.5 parts of coupling agent SI-69,5 parts of coumarones, 5 parts of bakelite B N-1 (guest king chemical plant, Wuxi), 5 parts of aromatic hydrocarbon oil, 15 parts of paraffin oils, 1 part of antioxidant 4010NA, 1 part of antioxidant BLE, 1.5 parts of antioxidant MBs, 1.5 parts of anti-aging agent RDs.
The preparation method of described anti-high hot conveyer belt intermediate rubber, concrete steps are:
(1) plasticate: natural rubber is plasticated in mill, roll spacing 2-4mm, the roller temperature control is at 40-50 ℃, and the 15min that plasticates makes broken-(down)rubber.
(2) mixing: mixing minute two sections carry out, one section mixing is first broken-(down)rubber, ethylene-propylene rubber(EPR), styrene-butadiene rubber(SBR) to be dropped in the Banbury mixer banburying 3min; Then open floating weight and add carbon black, white carbon black, zinc oxide, stearic acid, coupling agent SI-69, coumarone, bakelite B N-1, aromatic hydrocarbon oil, paraffin oil, accelerant NOBS, DM, M, antioxidant 4010NA, antioxidant BLE, antioxidant MB and anti-aging agent RD, banburying 5min, dump temperature is controlled at 130-150 ℃, through turning refining, making one section rubber unvulcanizate by thickness 8-12mm slice, the cooling of normal temperature blower fan, park 8h.Two-stage mixing is that one section rubber unvulcanizate and sulphur, DCP and TAIC are dropped in the Banbury mixer, and mixing 4min, dump temperature are controlled at 130-140 ℃, through turning refining, namely getting the anti-high hot conveyer belt intermediate rubber of product by thickness 8-12mm slice, the cooling of normal temperature blower fan normal temperature.
3 one kinds of anti-high hot conveyer belts intermediate rubbers and preparation method thereof of embodiment
Its formula rate is by weight: 90 parts in ethylene-propylene rubber(EPR), 10 parts of chlorosulfonated polyethylenes, 40 parts of carbon black N660,15 parts of white carbon blacks, 0.5 part in sulphur, 5 parts of DCP, 0.5 part of sulfonamides accelerant NOBS, 1 part of thiazole accelerator DM, 2 parts of TAIC, 5 parts in zinc oxide, 10 parts in magnesium oxide, 2 parts of stearic acid, 1.5 parts of coupling agent SI-69,5 parts of coumarones, guest king chemical plant, bakelite B N-1(Wuxi) 8 parts, 20 parts of paraffin oils, 1 part of antioxidant 4010NA, 1 part of antioxidant BLE, 1 part of antioxidant MB, 1.5 parts of anti-aging agent RDs.
The preparation method of described anti-high hot conveyer belt intermediate rubber, concrete steps are:
Mixing: as first ethylene-propylene rubber(EPR) and chlorosulfonated polyethylene to be dropped in the Banbury mixer banburying 2min; Then open floating weight and add carbon black, white carbon black, sulphur, DCP, sulfonamides accelerant NOBS, thiazole accelerator DM, TAIC, zinc oxide, magnesium oxide, stearic acid, coupling agent SI-69, coumarone, bakelite B N-1, paraffin oil, antioxidant 4010NA, antioxidant BLE, antioxidant MB, anti-aging agent RD, banburying 5min, dump temperature are controlled at 130-150 ℃, through turning refining, making one section rubber unvulcanizate by thickness 8-12mm slice, the cooling of normal temperature blower fan, park 8h.Two-stage mixing is that mixing 3min, dump temperature are controlled at 130-140 ℃ with in one section rubber unvulcanizate and sulphur and the DCP input Banbury mixer, through turning refining, namely getting the heat-resisting high conveying belt intermediate rubber of product by thickness 8-12mm slice, the cooling of normal temperature blower fan normal temperature.