CN105440339A - Anti-aging rubber ring material composition and anti-aging rubber ring preparation method - Google Patents
Anti-aging rubber ring material composition and anti-aging rubber ring preparation method Download PDFInfo
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- CN105440339A CN105440339A CN201510976141.1A CN201510976141A CN105440339A CN 105440339 A CN105440339 A CN 105440339A CN 201510976141 A CN201510976141 A CN 201510976141A CN 105440339 A CN105440339 A CN 105440339A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention discloses an anti-aging rubber ring material composition and an anti-aging rubber ring preparation method. The anti-aging rubber ring material composition comprises, by weight, 100 parts of a natural rubber, 30-70 parts of styrene butadiene rubber, 10-30 parts f ethylene propylene diene monomer, 5-20 parts of a coumatone resin, 1-10 parts of sulphur, 1-5 parts of nanometer magnesium oxide, 1-5 parts of nanometer zinc oxide, 5-15 parts of paraffin, and 5-15 parts of calcium carbonate. According to the present invention, with the technical scheme, the effects of effective aging resistance, substantial service life prolonging, use cost reducing and maintenance cost reducing are achieved.
Description
Technical field
The present invention relates to the manufacture field of rubber ring, particularly, relate to the preparation method of a kind of ageing-resistant rubber loop material composition and ageing-resistant rubber circle.
Background technology
The component that rubber ring is commonly used as automobile, use is had in many parts of automobile, such as, automobile clutch etc., but, often because temperature in automobile is higher, in environment, impurity etc. are more, make rubber ring in use very easily the phenomenons such as aging occur, and and then make to need often to change rubber ring, not only waste time and energy, and considerably increase maintenance cost.
Therefore, provide one can be effectively ageing-resistant, greatly improve work-ing life, reducing use cost and the ageing-resistant rubber loop material composition of maintenance cost and the preparation method of ageing-resistant rubber circle be the problem that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, the object of the invention is to overcome in prior art often because temperature in automobile is higher, in environment, impurity etc. are more, rubber ring is made in use very easily the phenomenons such as aging to occur, and and then make to need often to change rubber ring, not only waste time and energy, and considerably increase the problem of maintenance cost, thus provide one can be effectively ageing-resistant, greatly improve work-ing life, reduce use cost and the ageing-resistant rubber loop material composition of maintenance cost and the preparation method of ageing-resistant rubber circle.
To achieve these goals, the invention provides a kind of ageing-resistant rubber loop material composition, wherein, described composition comprises natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate; Wherein,
Relative to the described natural rubber of 100 weight parts, the content of described styrene-butadiene rubber(SBR) is 30-70 weight part, the content of described terpolymer EP rubber is 10-30 weight part, the content of described coumarone indene resin is 5-20 weight part, the content of described sulphur is 1-10 weight part, and the content of described nano magnesia is 1-5 weight part, and the content of described nano zine oxide is 1-5 weight part, the content of described paraffin is 5-15 weight part, and the content of described calcium carbonate is 5-15 weight part.
Present invention also offers a kind of preparation method of ageing-resistant rubber circle, wherein, described preparation method comprises: by extrusion moulding after natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate mixed smelting, obtained ageing-resistant rubber circle; Wherein,
Relative to the described natural rubber of 100 weight parts, the consumption of described styrene-butadiene rubber(SBR) is 30-70 weight part, the consumption of described terpolymer EP rubber is 10-30 weight part, the consumption of described coumarone indene resin is 5-20 weight part, the consumption of described sulphur is 1-10 weight part, and the consumption of described nano magnesia is 1-5 weight part, and the consumption of described nano zine oxide is 1-5 weight part, the consumption of described paraffin is 5-15 weight part, and the consumption of described calcium carbonate is 5-15 weight part.
Pass through technique scheme, natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate mix rear according to certain ratio and carry out melting by the present invention, then by the mixture extrusion moulding after melting, obtained rubber ring, thus make the rubber ring obtained by the way effectively can improve ageing-resistant performance when reality uses, greatly improve and reduce use cost work-ing life.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of ageing-resistant rubber loop material composition, wherein, described composition comprises natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate; Wherein,
Relative to the described natural rubber of 100 weight parts, the content of described styrene-butadiene rubber(SBR) is 30-70 weight part, the content of described terpolymer EP rubber is 10-30 weight part, the content of described coumarone indene resin is 5-20 weight part, the content of described sulphur is 1-10 weight part, and the content of described nano magnesia is 1-5 weight part, and the content of described nano zine oxide is 1-5 weight part, the content of described paraffin is 5-15 weight part, and the content of described calcium carbonate is 5-15 weight part.
Above-mentioned design is by mixing rear by natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate according to certain ratio and carrying out melting, then by the mixture extrusion moulding after melting, obtained rubber ring, thus make the rubber ring obtained by the way effectively can improve ageing-resistant performance when reality uses, greatly improve and reduce use cost work-ing life.
One of the present invention preferred embodiment in, in order to make the ageing-resistant performance of the rubber ring obtained better, relative to the described natural rubber of 100 weight parts, the content of described styrene-butadiene rubber(SBR) is 40-60 weight part, the content of described terpolymer EP rubber is 15-25 weight part, the content of described coumarone indene resin is 10-15 weight part, the content of described sulphur is 3-7 weight part, the content of described nano magnesia is 2-4 weight part, the content of described nano zine oxide is 2-4 weight part, the content of described paraffin is 8-12 weight part, the content of described calcium carbonate is 8-12 weight part.
One of the present invention more preferred embodiment in, described composition can also comprise processing aid.
The processing aid type that the type of described processing aid can select this area routine to use, such as, one of the present invention preferred embodiment in, described processing aid can be selected from oxidation inhibitor, anti-aging agent, promotor and anti ultraviolet agent one or more.
Present invention also offers a kind of preparation method of ageing-resistant rubber circle, wherein, described preparation method comprises: by extrusion moulding after natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate mixed smelting, obtained ageing-resistant rubber circle; Wherein,
Relative to the described natural rubber of 100 weight parts, the consumption of described styrene-butadiene rubber(SBR) is 30-70 weight part, the consumption of described terpolymer EP rubber is 10-30 weight part, the consumption of described coumarone indene resin is 5-20 weight part, the consumption of described sulphur is 1-10 weight part, and the consumption of described nano magnesia is 1-5 weight part, and the consumption of described nano zine oxide is 1-5 weight part, the consumption of described paraffin is 5-15 weight part, and the consumption of described calcium carbonate is 5-15 weight part.
One of the present invention preferred embodiment in, in order to make the rubber ring ageing-resistant performance that obtains better, relative to the described natural rubber of 100 weight parts, the consumption of described styrene-butadiene rubber(SBR) is 40-60 weight part, the consumption of described terpolymer EP rubber is 15-25 weight part, the consumption of described coumarone indene resin is 10-15 weight part, the consumption of described sulphur is 3-7 weight part, the consumption of described nano magnesia is 2-4 weight part, the consumption of described nano zine oxide is 2-4 weight part, the consumption of described paraffin is 8-12 weight part, the consumption of described calcium carbonate is 8-12 weight part.
The mode that described fusion process can adopt according to this area routine operate, such as, one of the present invention preferred embodiment in, described fusion process can be carry out melting under the condition of 200-280 DEG C for being placed in temperature.
One of the present invention more preferred embodiment in, in order to make the rubber ring that obtains better shaping, described preparation method cools after can also being included in extrusion moulding.
Described process of cooling can be arranged according to the mode of this area routine, such as, one of the present invention preferred embodiment in, described process of cooling is quenching.
One of the present invention more preferred embodiment in, described preparation method can also comprise and add processing aid and carry out melting, described processing aid be selected from oxidation inhibitor, anti-aging agent, promotor and anti ultraviolet agent one or more.
Below will be described the present invention by embodiment.In following examples, described natural rubber, described styrene-butadiene rubber(SBR), described terpolymer EP rubber, described coumarone indene resin, described sulphur, described nano magnesia, described nano zine oxide, described paraffin and described calcium carbonate are conventional commercial product.
Embodiment 1
The mixing of 100g natural rubber, 40g styrene-butadiene rubber(SBR), 15g terpolymer EP rubber, 10g coumarone indene resin, 3g sulphur, 2g nano magnesia, 2g nano zine oxide, 8g paraffin and 8g calcium carbonate being placed on temperature is extrusion moulding after melting under the condition of 200 DEG C, then blow cooling, obtained ageing-resistant rubber circle A1.
Embodiment 2
The mixing of 100g natural rubber, 60g styrene-butadiene rubber(SBR), 25g terpolymer EP rubber, 15g coumarone indene resin, 7g sulphur, 4g nano magnesia, 4g nano zine oxide, 12g paraffin and 12g calcium carbonate being placed on temperature is extrusion moulding after melting under the condition of 280 DEG C, then blow cooling, obtained ageing-resistant rubber circle A2.
Embodiment 3
The mixing of 100g natural rubber, 50g styrene-butadiene rubber(SBR), 20g terpolymer EP rubber, 12g coumarone indene resin, 5g sulphur, 3g nano magnesia, 3g nano zine oxide, 10g paraffin and 10g calcium carbonate being placed on temperature is extrusion moulding after melting under the condition of 240 DEG C, then blow cooling, obtained ageing-resistant rubber circle A3.
Embodiment 4
Be prepared according to the preparation method of embodiment 1, unlike, the consumption of described styrene-butadiene rubber(SBR) is 30g, and the consumption of described terpolymer EP rubber is 10g, and the consumption of described coumarone indene resin is 5g, the consumption of described sulphur is 1g, the consumption of described nano magnesia is 1g, and the consumption of described nano zine oxide is 1g, and the consumption of described paraffin is 5g, the consumption of described calcium carbonate is 5g, obtained ageing-resistant rubber circle A4.
Embodiment 5
Be prepared according to the preparation method of embodiment 2, unlike, the consumption of described styrene-butadiene rubber(SBR) is 70g, and the consumption of described terpolymer EP rubber is 30g, and the consumption of described coumarone indene resin is 20g, the consumption of described sulphur is 10g, the consumption of described nano magnesia is 5g, and the consumption of described nano zine oxide is 5g, and the consumption of described paraffin is 15g, the consumption of described calcium carbonate is 15g, obtained ageing-resistant rubber circle A5.
Comparative example 1
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described styrene-butadiene rubber(SBR) is 10g, and the consumption of described terpolymer EP rubber is 5g, and the consumption of described coumarone indene resin is 2g, the consumption of described sulphur is 0.5g, the consumption of described nano magnesia is 0.5g, and the consumption of described nano zine oxide is 0.5g, and the consumption of described paraffin is 2g, the consumption of described calcium carbonate is 2g, obtained rubber ring D1.
Comparative example 2
Be prepared according to the preparation method of embodiment 3, unlike, the consumption of described styrene-butadiene rubber(SBR) is 100g, and the consumption of described terpolymer EP rubber is 50g, and the consumption of described coumarone indene resin is 40g, the consumption of described sulphur is 20g, the consumption of described nano magnesia is 10g, and the consumption of described nano zine oxide is 10g, and the consumption of described paraffin is 30g, the consumption of described calcium carbonate is 30g, obtained rubber ring D2.
Test case
Above-mentioned A1-A5, D1 and D2 being placed in respectively temperature is place 1 day under the condition of 120 DEG C, and detect its degree of aging, carry out acid mist experiment simultaneously, detect its degree of aging, the result obtained is as shown in table 1.
Table 1
| Numbering | 120℃ | Acid mist is tested |
| A1 | Unaged | Unaged |
| A2 | Unaged | Unaged |
| A3 | Unaged | Unaged |
| A4 | Unaged | Without obviously aging |
| A5 | Without obviously aging | Unaged |
| D1 | Obviously aging | Obviously aging |
| D2 | Obviously aging | Obviously aging |
More than describe the preferred embodiment of the present invention in detail; but the present invention is not limited to the detail in above-mentioned embodiment, within the scope of technical conceive of the present invention; can carry out multiple simple variant to technical scheme of the present invention, these simple variant all belong to protection scope of the present invention.
It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.
In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. an ageing-resistant rubber loop material composition, is characterized in that, described composition comprises natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate; Wherein,
Relative to the described natural rubber of 100 weight parts, the content of described styrene-butadiene rubber(SBR) is 30-70 weight part, the content of described terpolymer EP rubber is 10-30 weight part, the content of described coumarone indene resin is 5-20 weight part, the content of described sulphur is 1-10 weight part, and the content of described nano magnesia is 1-5 weight part, and the content of described nano zine oxide is 1-5 weight part, the content of described paraffin is 5-15 weight part, and the content of described calcium carbonate is 5-15 weight part.
2. composition according to claim 1, wherein, relative to the described natural rubber of 100 weight parts, the content of described styrene-butadiene rubber(SBR) is 40-60 weight part, the content of described terpolymer EP rubber is 15-25 weight part, the content of described coumarone indene resin is 10-15 weight part, the content of described sulphur is 3-7 weight part, the content of described nano magnesia is 2-4 weight part, the content of described nano zine oxide is 2-4 weight part, the content of described paraffin is 8-12 weight part, and the content of described calcium carbonate is 8-12 weight part.
3. composition according to claim 1 and 2, wherein, described composition also comprises processing aid.
4. composition according to claim 3, wherein, described processing aid be selected from oxidation inhibitor, anti-aging agent, promotor and anti ultraviolet agent one or more.
5. the preparation method of an ageing-resistant rubber circle, it is characterized in that, described preparation method comprises: by extrusion moulding after natural rubber, styrene-butadiene rubber(SBR), terpolymer EP rubber, coumarone indene resin, sulphur, nano magnesia, nano zine oxide, paraffin and calcium carbonate mixed smelting, obtained ageing-resistant rubber circle; Wherein,
Relative to the described natural rubber of 100 weight parts, the consumption of described styrene-butadiene rubber(SBR) is 30-70 weight part, the consumption of described terpolymer EP rubber is 10-30 weight part, the consumption of described coumarone indene resin is 5-20 weight part, the consumption of described sulphur is 1-10 weight part, and the consumption of described nano magnesia is 1-5 weight part, and the consumption of described nano zine oxide is 1-5 weight part, the consumption of described paraffin is 5-15 weight part, and the consumption of described calcium carbonate is 5-15 weight part.
6. preparation method according to claim 5, wherein, relative to the described natural rubber of 100 weight parts, the consumption of described styrene-butadiene rubber(SBR) is 40-60 weight part, the consumption of described terpolymer EP rubber is 15-25 weight part, the consumption of described coumarone indene resin is 10-15 weight part, the consumption of described sulphur is 3-7 weight part, the consumption of described nano magnesia is 2-4 weight part, the consumption of described nano zine oxide is 2-4 weight part, the consumption of described paraffin is 8-12 weight part, and the consumption of described calcium carbonate is 8-12 weight part.
7. the preparation method according to claim 5 or 6, wherein, described fusion process is that to be placed in temperature be carry out melting under the condition of 200-280 DEG C.
8. the preparation method according to claim 5 or 6, wherein, described preparation method cools after being also included in extrusion moulding.
9. preparation method according to claim 8, wherein, described process of cooling is quenching.
10. the preparation method according to claim 5 or 6, wherein, described preparation method also comprises and adds processing aid and carry out melting, described processing aid be selected from oxidation inhibitor, anti-aging agent, promotor and anti ultraviolet agent one or more.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105713247A (en) * | 2016-04-27 | 2016-06-29 | 芜湖真空科技有限公司 | Rubber ring material composition for transporting roller and preparation method of rubber ring |
| CN106189240A (en) * | 2016-07-22 | 2016-12-07 | 长泰鑫润橡塑有限公司 | A kind of ageing-resistant rubber ring and preparation method thereof |
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| CN101481473A (en) * | 2008-01-07 | 2009-07-15 | 严晓敏 | Rubber composition and product thereof |
| CN102585732A (en) * | 2012-02-14 | 2012-07-18 | 无锡宝通带业股份有限公司 | Intermediate adhesive for high-heat-resistant conveying belt and preparation method thereof |
| CN104277250A (en) * | 2014-05-26 | 2015-01-14 | 安徽宁国尚鼎橡塑制品有限公司 | Preparation process of rubber material for seal ring of automobile |
| CN105086007A (en) * | 2015-08-13 | 2015-11-25 | 枞阳县金源汽车零部件有限公司 | Rubber material for car vibration reducing part and production method thereof |
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2015
- 2015-12-22 CN CN201510976141.1A patent/CN105440339A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481473A (en) * | 2008-01-07 | 2009-07-15 | 严晓敏 | Rubber composition and product thereof |
| CN102585732A (en) * | 2012-02-14 | 2012-07-18 | 无锡宝通带业股份有限公司 | Intermediate adhesive for high-heat-resistant conveying belt and preparation method thereof |
| CN104277250A (en) * | 2014-05-26 | 2015-01-14 | 安徽宁国尚鼎橡塑制品有限公司 | Preparation process of rubber material for seal ring of automobile |
| CN105086007A (en) * | 2015-08-13 | 2015-11-25 | 枞阳县金源汽车零部件有限公司 | Rubber material for car vibration reducing part and production method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105713247A (en) * | 2016-04-27 | 2016-06-29 | 芜湖真空科技有限公司 | Rubber ring material composition for transporting roller and preparation method of rubber ring |
| CN106189240A (en) * | 2016-07-22 | 2016-12-07 | 长泰鑫润橡塑有限公司 | A kind of ageing-resistant rubber ring and preparation method thereof |
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