CN110682203B - Diamond composite material and preparation method and application thereof - Google Patents
Diamond composite material and preparation method and application thereof Download PDFInfo
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- CN110682203B CN110682203B CN201810730645.9A CN201810730645A CN110682203B CN 110682203 B CN110682203 B CN 110682203B CN 201810730645 A CN201810730645 A CN 201810730645A CN 110682203 B CN110682203 B CN 110682203B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/12—Lapping plates for working plane surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/12—Lapping plates for working plane surfaces
- B24B37/14—Lapping plates for working plane surfaces characterised by the composition or properties of the plate materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/009—Tools not otherwise provided for
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00362—Friction materials, e.g. used as brake linings, anti-skid materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
Abstract
The invention provides a diamond composite material, and relates to the field of fine grinding of hard and brittle materials. According to the invention, when the diamond composite material is used for fine grinding, slight dissolution can occur after the diamond composite material is contacted with purified water, diamond abrasive particles can be released at the moment, and form grinding fluid with water, the honeycomb core material has a certain mechanical supporting force, the grinding fluid can climb onto the top surface of the core material wall to act with a processed sample during grinding, meanwhile, slight depressions can be generated by slightly soluble grinding blocks, and large particles generated by grinding can roll down into the depressions, so that the sample is prevented from being scratched. In the structure, the loss of the water-soluble gypsum foam is synchronous with the abrasion rate of the honeycomb core material, so that the frequent grooving like a copper plate is avoided, the diamond grinding fluid does not need to be additionally dripped, and the utilization efficiency of the diamond abrasive particles is improved.
Description
Technical Field
The invention relates to the technical field of fine grinding of hard and brittle materials, in particular to a diamond composite material and a preparation method and application thereof.
Background
The ultrahard materials such as zirconia ceramics and artificial sapphire have great potential in application to smart phones, such as fingerprint identification sheets, ceramic rear covers, lens protection sheets and the like. Hard material products are produced by fine grinding and polishing of the material surface to give it a shiny surface.
The surface polishing of the hard material needs to be carried out through three working sections of rough grinding, fine grinding and polishing, wherein the fine grinding process uses an abrasive material free type processing method, namely, diamond grinding fluid with the grain size of 2-4 mu m is dripped on a rotating plane copper disc, and the processed surface of a sample is pressed on the copper disc for processing. Because the metal copper has good ductility, part of diamond abrasive particles are embedded on the surface of a copper disc under the pressure action of a sample, the fixed abrasive particles act on the sample together with the abrasive rolling on the surface of the disc, and the surface of the sample is gradually polished. Occasionally, large sample particles are broken off during refining, and the superhard particles, if wandering across the disc, can scratch the entire batch of samples. Therefore, the key scheme for solving the problem of fine grinding processing scratch is as follows: a series of concentric annular shallow grooves with the depth of about 0.5mm, the width of about 1mm and the interval of about 1mm are engraved on the surface of the copper disc. Particles that fall off during processing will roll down into these shallow grooves rather than wandering over the disk surface. In addition, the shallow grooves on the disc surface cannot be too deep, otherwise, the grinding fluid cannot climb back to the copper disc surface, and the cutting efficiency is greatly reduced or even disappears.
The problems of the fine grinding processing by the copper disc are as follows: the copper disc is worn during use, so that the groove depth is reduced and the plane precision of the disc surface is reduced, and therefore the disc surface needs to be frequently grooved and trimmed. Meanwhile, the processing mode involves the use of a large amount of expensive diamond grinding fluid, and a lot of diamonds flow away without being fully utilized, so that the processing cost is high.
Disclosure of Invention
In view of the above, the present invention aims to provide a diamond composite material, a preparation method and applications thereof. The invention solves the problem that the regular grooving deepening is needed for the accurate grinding of the copper disc, and simultaneously, the diamond grinding fluid is not needed to be dripped, thereby reducing the consumption of diamond abrasive particles and saving the material cost.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a diamond composite material, which comprises a honeycomb core material and water-soluble gypsum foam filled in the pores of the honeycomb core material, wherein the water-soluble gypsum foam comprises the following components in percentage by weight: 30-80% of inorganic composite binder, 1-30% of diamond abrasive particles, 10-30% of talcum powder, 0.5-15% of aqueous adhesive, 5-20% of foam, 0.2-1% of glass fiber, 0.3-1% of polycarboxylic acid water reducing agent and 8-50% of water, wherein the sum of the weight percentages of the components of the water-soluble gypsum foam is 100%.
Preferably, the weight ratio of the honeycomb core material to the water-soluble gypsum foam is 0.2-0.05: 1.
preferably, the particle size of the diamond abrasive particles is 0.5-5 μm.
Preferably, the inorganic composite binder comprises semi-hydrated gypsum and silica fume, wherein the mass ratio of the semi-hydrated gypsum to the silica fume is 90-97: 1 to 10.
Preferably, the aqueous adhesive is acrylic emulsion, polyvinyl alcohol aqueous solution, polyurethane emulsion or ethylene-vinyl acetate emulsion.
Preferably, the honeycomb shape of the honeycomb core material is hexagonal, and the side length of a honeycomb hole of the honeycomb core material is 3-10 mm.
Preferably, the material of the honeycomb core is aluminum or copper.
The invention also provides a preparation method of the diamond composite material, which comprises the following steps:
mixing water and an aqueous adhesive to obtain an aqueous adhesive solution;
mixing an inorganic composite binder, diamond abrasive particles, talcum powder, a polycarboxylic acid water reducing agent and glass fibers to obtain a premix;
mixing the aqueous adhesive solution and the premix to obtain slurry;
mixing the slurry with foam to obtain foam diamond composite slurry;
and pouring the foam diamond composite slurry into the holes of the honeycomb core material, and baking to obtain the diamond composite material.
Preferably, the baking temperature is 100-120 ℃, and the baking time is 3-5 h.
The invention also provides the application of the diamond composite material in the technical scheme or the diamond composite material prepared by the preparation method in the technical scheme in the field of fine grinding.
The invention provides a diamond composite material, which comprises a honeycomb core material and water-soluble gypsum foam filled in the pores of the honeycomb core material, wherein the water-soluble gypsum foam comprises the following components in percentage by weight: 30-80% of inorganic composite binder, 1-30% of diamond abrasive particles, 10-30% of talcum powder, 0.5-15% of aqueous adhesive, 5-20% of foam, 0.2-1% of glass fiber, 0.3-1% of polycarboxylic acid water reducing agent and 8-50% of water, wherein the sum of the weight percentages of the components of the water-soluble gypsum foam is 100%. In the invention, the diamond abrasive is bonded by the inorganic composite adhesive; the diamond abrasive particles are fine grinding abrasive materials; the talcum powder is a filler and is used for dispersing diamond grinding materials, and the diamond grinding materials drop off in a uniform and controllable micro-scale manner; after the aqueous adhesive is cured, an elastic polymer film is formed among the inorganic particles, the inorganic particles are bonded together to play a toughening role, and the peeling rate of the diamond abrasive particles can be adjusted by adjusting the using amount of the aqueous adhesive; the glass fiber can form a mutually staggered network, so that the toughness of the gypsum foam can be increased, and the gypsum foam is prevented from breaking in a whole block; the foam plays a foaming role to form a porous foaming composite grinding block, and the existence of the holes can help the diamond abrasive particles to fall off. According to the invention, when the diamond composite material is used for fine grinding, slight dissolution can occur after the diamond composite material is contacted with purified water, diamond abrasive particles can be released at the moment, and form grinding fluid with water, the honeycomb core material has a certain mechanical supporting force, the grinding fluid can climb onto the top surface of the core material wall to act with a processed sample during grinding, meanwhile, slight depressions can be generated by slightly soluble grinding blocks, and large particles generated by grinding can roll down into the depressions, so that the sample is prevented from being scratched. In the structure, the loss of the water-soluble gypsum foam is synchronous with the abrasion rate of the honeycomb core material, so that the frequent grooving like a copper plate is avoided, the diamond grinding fluid does not need to be additionally dripped, and the utilization efficiency of the diamond abrasive particles is improved.
Drawings
Fig. 1 is a schematic view of the structure of a refining plate manufactured in example 1 of the present invention, in which 100-refining plate; 101-honeycomb core material wall; 200-water soluble gypsum foam containing diamond grit;
FIG. 2 is a schematic view showing the structure of a refining plate for refining according to the present invention, in which 200-water-soluble gypsum foam containing diamond abrasive grains; 201-bubbles; 202-a gypsum wall containing diamond grit; 203-diamond abrasive grains.
Detailed Description
The invention provides a diamond composite material, which comprises a honeycomb core material and water-soluble gypsum foam filled in the pores of the honeycomb core material, wherein the water-soluble gypsum foam comprises the following components in percentage by weight: 30-80% of inorganic composite binder, 1-30% of diamond abrasive particles, 10-30% of talcum powder, 0.5-15% of aqueous adhesive, 5-20% of foam, 0.2-1% of glass fiber, 0.3-1% of polycarboxylic acid water reducing agent and 8-50% of water, wherein the sum of the weight percentages of the components of the water-soluble gypsum foam is 100%.
In the invention, the weight ratio of the honeycomb core material to the water-soluble gypsum foam is preferably 0.2-0.05: 1, more preferably 0.1 to 0.15: 1.
the diamond composite material provided by the invention preferably comprises 2-5 wt% of diamond abrasive particles, and more preferably 3 wt%. In the invention, the particle size of the diamond abrasive particles is preferably 0.5-5 μm, more preferably 1-4 μm, and most preferably 2-3 μm. In the present invention, the diamond abrasive grains are finely ground abrasives.
The diamond composite material provided by the invention preferably comprises 39-52% by weight of inorganic composite binder, and more preferably 42-47%. In the invention, the inorganic composite binder preferably comprises semi-hydrated gypsum and silica fume, and the mass ratio of the semi-hydrated gypsum to the silica fume is preferably 90-97: 1 to 10. In the present invention, the inorganic composite binder binds the diamond abrasive. In the invention, the particle size of the silica fume is preferably 50-200 nm. In the invention, the semi-hydrated gypsum is subjected to hydration reaction after the action of the semi-hydrated gypsum and water and then solidified, the semi-hydrated gypsum is brittle, the diamond grinding material is easy to fall off under the grinding pressure condition, and the fallen diamond grinding material participates in the fine grinding process; the silica fume is microscopically spherical powder, can be filled into the semi-hydrated gypsum to increase the compressive strength of the semi-hydrated gypsum binder, has a pozzolan effect and can also generate a certain hydration reaction with water; the inorganic composite binder formed by combining the silica fume and the semi-hydrated gypsum can effectively improve the strength of the binder.
The diamond composite material provided by the invention preferably comprises 12-25 wt% of talcum powder, and more preferably 15%. In the invention, the talcum powder is a filler and is used for dispersing diamond grinding materials, and the diamond grinding materials drop off in a uniform and controllable micro-scale manner. The source of the talc powder in the present invention is not particularly limited, and commercially available products known to those skilled in the art may be used.
The diamond composite material provided by the invention preferably comprises 2-10 wt% of water-based adhesive, and more preferably 5 wt%. In the present invention, the aqueous adhesive is preferably an acrylic emulsion, a polyvinyl alcohol aqueous solution, a polyurethane emulsion, or an ethylene-vinyl acetate emulsion. According to the invention, after the aqueous adhesive is cured, an elastic polymer film is formed among the inorganic particles, the inorganic particles are bonded to play a toughening role, and the peeling rate of the diamond abrasive particles can be adjusted by adjusting the using amount of the aqueous adhesive.
In the invention, the mass fraction of the polyvinyl alcohol aqueous solution is preferably 3-5%.
The diamond composite material provided by the invention preferably comprises 0.3-1% by weight of polycarboxylic acid water reducing agent, and more preferably 0.5%. The source of the polycarboxylic acid water reducing agent is not particularly limited in the present invention, and commercially available products known to those skilled in the art may be used.
The diamond composite material provided by the invention preferably comprises 8-16 wt% of foam, and more preferably 12-14 wt%. In the invention, the foam plays a foaming role to form the porous foaming composite grinding block, and the existence of the holes can help the diamond abrasive grains to fall off.
In the present invention, the foam is preferably prepared from a blowing agent solution. In the present invention, the foaming agent solution preferably includes a foaming agent, an aqueous adhesive and water. In the invention, the mass concentration of the foaming agent in the foaming agent solution is preferably 10-30%, and the mass proportion of the aqueous adhesive in the foaming agent solution is 3-5%.
In the present invention, the foaming agent is preferably an animal or vegetable protein foaming agent; the aqueous adhesive is preferably the same as described above, and is not described in detail herein.
In the invention, the density of the foam is preferably 50-80 kg/m3More preferably 60 to 70kg/m3。
The diamond composite material provided by the invention preferably comprises 0.3-0.5% of glass fiber by weight. In the invention, the glass fiber can form an interlaced network, thereby increasing the toughness of the gypsum foam and preventing the gypsum foam from breaking in a whole block. The source of the glass fiber is not particularly limited in the present invention, and commercially available products known to those skilled in the art may be used.
In the invention, the honeycomb shape of the honeycomb core material is preferably hexagonal, and the side length of the honeycomb holes of the honeycomb core material is preferably 3-10 mm, and more preferably 5-6 mm.
In the present invention, the material of the honeycomb core is preferably aluminum or copper. The source of the honeycomb core material in the present invention is not particularly limited, and commercially available products known to those skilled in the art may be used.
The invention also provides a preparation method of the diamond composite material, which comprises the following steps:
mixing water and an aqueous adhesive to obtain an aqueous adhesive solution;
mixing an inorganic composite binder, diamond abrasive particles, talcum powder, a polycarboxylic acid water reducing agent and glass fibers to obtain a premix;
mixing the aqueous adhesive solution and the premix to obtain slurry;
mixing the slurry with foam to obtain foam diamond composite slurry;
and pouring the foam diamond composite slurry into the holes of the honeycomb core material, and baking to obtain the diamond composite material.
According to the invention, water and an aqueous adhesive are mixed to obtain an aqueous adhesive solution.
According to the invention, an inorganic composite binder, diamond abrasive particles, talcum powder, a polycarboxylic acid water reducing agent and glass fibers are mixed to obtain the premix.
The mixing method is not particularly limited, and the mixing method known to those skilled in the art can be adopted, specifically, stirring.
After the aqueous adhesive solution and the premix are obtained, the aqueous adhesive solution and the premix are mixed to obtain slurry. In the present invention, it is preferable to add the premix to the aqueous adhesive solution.
After the slurry is obtained, the slurry is mixed with foam to obtain the foam diamond composite slurry. The mixing method of the present invention is not particularly limited, and a mixing method known to those skilled in the art may be used.
After the foam diamond composite slurry is obtained, the foam diamond composite slurry is poured into holes of the honeycomb core material and baked to obtain the diamond composite material. In the invention, the baking temperature is preferably 100-120 ℃, and the baking time is preferably 3-5 h.
The invention also provides the application of the diamond composite material in the technical scheme or the diamond composite material prepared by the preparation method in the technical scheme in the field of fine grinding.
In the present invention, the diamond composite material is preferably leveled by a water mill to obtain a fine grinding flat plate for use in the fine grinding field. The concrete mode of leveling the water mill is not limited in the invention, and the mode known by the person skilled in the art can be adopted.
The diamond composite material and the method for manufacturing the same according to the present invention will be described in detail with reference to the following examples, which should not be construed as limiting the scope of the present invention.
Example 1
Weighing the following components in percentage by weight: 37% of semi-hydrated gypsum, 2% of silica fume, 3% of diamond abrasive particles, 15% of talcum powder, 5% of polyvinyl alcohol solution (with the concentration of 5%), 16% of foam, 0.5% of glass fiber, 0.3% of polycarboxylic acid water reducing agent and 21.2% of water;
wherein the foam is prepared by the following method: preparing foaming agent aqueous solution, wherein the concentration of the animal and plant foaming agent is 10%, the proportion of the polyvinyl alcohol aqueous solution is 3%, then sending the foaming agent solution to a foaming machine, and preparing the foaming agent aqueous solution with the density of 50kg/m3The foam of (4);
the grain diameter of the diamond abrasive grains is 0.5 mu m;
adding water and polyvinyl alcohol solution into a stirring kettle; premixing semi-hydrated gypsum, silica fume, diamond abrasive particles, talcum powder, glass fiber and solid components of a polycarboxylic acid water reducing agent, and gradually adding the premixed materials into a stirring kettle under the stirring condition after the premixing is finished so as to fully mix the solid components and the liquid components to prepare slurry;
feeding the foam into a stirring kettle, and uniformly stirring at a low speed to prepare foam diamond composite slurry;
pouring the foam diamond composite slurry into holes of a honeycomb core material, baking for 3 hours at the temperature of 100 ℃, evaporating water, forming a water-soluble diamond composite foam grinding block by the diamond composite slurry, fixing the water-soluble diamond composite foam grinding block in the holes of the honeycomb core material, thus obtaining a honeycomb core material plate containing the diamond composite foam grinding block, flattening the front surface and the back surface of the honeycomb core material plate by using a water grinder, and obtaining a plate for fine grinding, wherein the structure is shown in figure 1. Wherein 100-refining the flat plate; 101-honeycomb core material wall; 200-water soluble gypsum foam containing diamond grit.
Examples 2 to 8
Examples 2 to 8 are comparative tests of 7 different formulations. These formulations are listed in Table 1 along with the formulation of example 1, and were prepared according to the procedure of example 1.
TABLE 1 Diamond composite materials weight percentage formulation
The diamond composite material provided by the invention can be used for fine grinding of a plane hard and brittle material, and when the hard and brittle material is subjected to plane processing, the plane of the hard and brittle material is pressed and attached to a diamond flat plate, and water is added for grinding. As shown in fig. 2, where 200-water soluble gypsum foam containing diamond grit; 201-bubbles; 202-a gypsum wall containing diamond grit; 203-diamond abrasive grains. The diamond composite foam grinding block is composed of a large number of bubbles, a bonding agent and diamond abrasive grains. When the diamond composite foam abrasive brick can take place slightly soluble after contacting the pure water, diamond grit can be released this moment, forms the lapping liquid with water, and the honeycomb core has certain mechanical support power, and the lapping liquid can climb on the top surface of core wall and be acted on by the processing sample during the grinding, and the abrasive brick of slightly soluble can produce slight sunkenly simultaneously, and the large granule that the grinding produced can roll down these pits, avoids the fish tail sample. In this configuration, the water soluble diamond composite foam abrasive block wear is synchronized with the wear rate of the honeycomb core, thus avoiding the need for frequent grooving as with copper discs. And the diamond grinding fluid does not need to be additionally dripped, so that the utilization efficiency of the diamond abrasive particles is improved.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (6)
1. A diamond composite material comprises a honeycomb core material and water-soluble gypsum foam filled in the pores of the honeycomb core material, wherein the water-soluble gypsum foam comprises the following components in percentage by weight: 30-80% of inorganic composite binder, 1-30% of diamond abrasive particles, 10-30% of talcum powder, 0.5-15% of aqueous adhesive, 5-20% of foam, 0.2-1% of glass fiber, 0.3-1% of polycarboxylic acid water reducer and 8-50% of water, wherein the sum of the weight percentages of the components of the water-soluble gypsum foam is 100%; the inorganic composite binder comprises semi-hydrated gypsum and silica fume, wherein the mass ratio of the semi-hydrated gypsum to the silica fume is 90-97: 1-10; the particle size of the silica fume is 50-200 nm; the honeycomb core material is made of aluminum or copper; the weight ratio of the honeycomb core material to the water-soluble gypsum foam is 0.2-0.05: 1; the particle size of the diamond abrasive particles is 0.5-5 mu m.
2. The diamond composite of claim 1, wherein the aqueous binder is an acrylic emulsion, an aqueous polyvinyl alcohol solution, a polyurethane emulsion, or an ethylene-vinyl acetate emulsion.
3. The diamond composite material according to claim 1, wherein the honeycomb shape of the honeycomb core material is hexagonal, and the honeycomb hole side length of the honeycomb core material is 3-10 mm.
4. A method of producing a diamond composite as claimed in any one of claims 1 to 3 comprising the steps of:
mixing water and an aqueous adhesive to obtain an aqueous adhesive solution;
mixing an inorganic composite binder, diamond abrasive particles, talcum powder, a polycarboxylic acid water reducing agent and glass fibers to obtain a premix;
mixing the aqueous adhesive solution and the premix to obtain slurry;
mixing the slurry with foam to obtain foam diamond composite slurry;
and pouring the foam diamond composite slurry into the holes of the honeycomb core material, and baking to obtain the diamond composite material.
5. The preparation method according to claim 4, wherein the baking temperature is 100-120 ℃, and the baking time is 3-5 h.
6. Use of the diamond composite material according to any one of claims 1 to 3 or the diamond composite material produced by the production method according to any one of claims 4 to 5 in the field of fine grinding.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810730645.9A CN110682203B (en) | 2018-07-05 | 2018-07-05 | Diamond composite material and preparation method and application thereof |
| PCT/CN2018/125415 WO2020007015A1 (en) | 2018-07-05 | 2018-12-29 | Diamond composite material, preparation method therefor, and application thereof |
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| CN201810730645.9A CN110682203B (en) | 2018-07-05 | 2018-07-05 | Diamond composite material and preparation method and application thereof |
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| CN107020580A (en) * | 2017-06-08 | 2017-08-08 | 泉州众志新材料科技有限公司 | A kind of artificial stone honeycomb is ground material |
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- 2018-07-05 CN CN201810730645.9A patent/CN110682203B/en active Active
- 2018-12-29 WO PCT/CN2018/125415 patent/WO2020007015A1/en active Application Filing
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| CN1717501A (en) * | 2002-10-29 | 2006-01-04 | 六号元素(控股)公司 | Composite material |
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Also Published As
| Publication number | Publication date |
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| WO2020007015A1 (en) | 2020-01-09 |
| CN110682203A (en) | 2020-01-14 |
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