CN110670096A - Novel practical electroplating solution for plating nickel iron - Google Patents
Novel practical electroplating solution for plating nickel iron Download PDFInfo
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- CN110670096A CN110670096A CN201911123559.2A CN201911123559A CN110670096A CN 110670096 A CN110670096 A CN 110670096A CN 201911123559 A CN201911123559 A CN 201911123559A CN 110670096 A CN110670096 A CN 110670096A
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- Prior art keywords
- chloride
- nickel
- iron
- electroplating solution
- plating
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
Abstract
Novel practical electroplating solution (g.kg) for plating nickel iron‑1) Which consists of the following components: 600-610 parts of 1-hexyl-3-methylimidazole chloride, and the weight ratio of ferric chloride: 40-50, nickel chloride: 320-330, sulfamic acid: 0.1 to 1, boric acid: 3.5-5, 15-20 parts of sodium chloride (NaCl), sodium dodecyl sulfate: 0.1 to 0.5. Besides being applied to traditional copper-nickel-chromium decorative protective coatings in a large number, nickel plating is also widely used as a coating with corrosion resistance, particularly alkali resistance and high-temperature oxidation resistance, and a functional coating with magnetism and the like. The addition of iron to nickel to save nickel is a relatively productive method, which not only reduces the consumption of nickel, but also improves the performance of the coating to the desired extent; it has more silvery appearance and stronger corrosion resistance.
Description
Technical Field
The invention relates to an electroplating solution, in particular to a novel and practical electroplating solution for plating nickel iron.
Background
The research and development of the magnetic alloy plating layer such as the nickel iron and the like are always paid attention, and a large number of research reports and application reports are available. The magnetic coating comprises a quinary alloy coating which has been developed for soft magnetism, development of orientation, vertical memory and the like. In the research on various kinds of nickel-based alloys, some new proposals have been made to replace electroless nickel and chromium plating with alloy plating layers, to adjust the hysteresis characteristics of the alloy plating layers by controlling the sulfur content, to develop and utilize non-aqueous plating solutions in order to obtain new and specific characteristics, and so on.
Disclosure of Invention
In order to achieve the purpose, the invention adopts the technical scheme that:
novel practical electroplating solution (g.kg) for plating nickel iron-1) The formula of (A) consists of the following components:
600 to 610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 40 to 50
Nickel chloride: 320 to 330
Sulfamic acid: 0.1 to 1
Boric acid: 3.5 to 5
15-20% of sodium chloride (NaCl)
Sodium lauryl sulfate: 0.1 to 0.5;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 50
Nickel chloride: 325
Sulfamic acid: 0.5
Boric acid: 4
Sodium chloride (NaCl):20
Sodium lauryl sulfate: 0.5;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 48
Nickel chloride: 330
Sulfamic acid: 0.9
Boric acid: 5
Sodium chloride (NaCl) 16
Sodium lauryl sulfate: 0.1;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 46
Nickel chloride: 330
Sulfamic acid: 0.3
Boric acid: 4.5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.2;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 46
Nickel chloride: 325
Sulfamic acid: 0.5
Boric acid: 5
Sodium chloride (NaCl):18
Sodium lauryl sulfate: 0.5;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 44
Nickel chloride: 328
Sulfamic acid: 0.4
Boric acid: 3.5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.1;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 45
Nickel chloride: 327
Sulfamic acid: 1
Boric acid: 3.5
Sodium chloride (NaCl):18
Sodium lauryl sulfate: 0.5;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 48
Nickel chloride: 320
Sulfamic acid: 0.5
Boric acid: 5
Sodium chloride (NaCl) 16
Sodium lauryl sulfate: 0.5;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 40
Nickel chloride: 330
Sulfamic acid: 0.6
Boric acid: 4
Sodium chloride (NaCl):15
Sodium lauryl sulfate: 0.4;
preferably, the formulation of the novel and practical electroplating solution (g.kg-1) for nickel-iron plating consists of:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 42
Nickel chloride: 323
Sulfamic acid: 0.8
Boric acid: 5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.2.
the invention has the beneficial effects that:
the novel practical electroplating solution for plating nickel iron does not have the problems of hydration, hydrolysis, hydrogen evolution and the like, and has the properties which green solvents have such as small corrosion and small pollution; the plating solution also has unique properties such as low melting point, adjustable Lewis acidity, good conductivity, negligible vapor pressure, wide application temperature and special solubility.
The specific implementation mode is as follows:
the raw materials are used: 1-hexyl-3-methylimidazole chloride; ferric chloride; nickel chloride; sulfamic acid; boric acid; sodium chloride; sodium lauryl sulfate.
The raw materials are used: 1-hexyl-3-methylimidazole chloride; ferric chloride; nickel chloride; sulfamic acid; boric acid; sodium chloride; sodium lauryl sulfate.
Example 1:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 50
Nickel chloride: 325
Sulfamic acid: 0.5
Boric acid: 4
Sodium chloride (NaCl):20
Sodium lauryl sulfate: 0.5
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 2:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 48
Nickel chloride: 330
Sulfamic acid: 0.9
Boric acid: 5
Sodium chloride (NaCl) 16
Sodium lauryl sulfate: 0.1
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 3:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 46
Nickel chloride: 330
Sulfamic acid: 0.3
Boric acid: 4.5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.2
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 4:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 46
Nickel chloride: 325
Sulfamic acid: 0.5
Boric acid: 5
Sodium chloride (NaCl):18
Sodium lauryl sulfate: 0.5
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 5:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 44
Nickel chloride: 328
Sulfamic acid: 0.4
Boric acid: 3.5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.1
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 6:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 45
Nickel chloride: 327
Sulfamic acid: 1
Boric acid: 3.5
Sodium chloride (NaCl):18
Sodium lauryl sulfate: 0.5
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 7:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 48
Nickel chloride: 320
Sulfamic acid: 0.5
Boric acid: 5
Sodium chloride (NaCl) 16
Sodium lauryl sulfate: 0.5
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 8:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 40
Nickel chloride: 330
Sulfamic acid: 0.6
Boric acid: 4
Sodium chloride (NaCl):15
Sodium lauryl sulfate: 0.4
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron.
Example 9:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 42
Nickel chloride: 323
Sulfamic acid: 0.8
Boric acid: 5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.2
The components are taken and mixed into 1000 g of novel and practical electroplating solution for plating nickel iron. When the electroplating solution is used for electroplating, the pH value of the solution is required to be 3.0-4.0, and the temperature (DEG C) of the solution is required to be as follows: 50 to 80, current density (A/dm)2):2.2～ 2.6。
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.
Claims (10)
1. Novel practical plating solution for plating nickel iron, its characterized in that: novel practical electroplating solution (g.kg) for plating nickel iron-1) The formula of (A) consists of the following components:
600 to 610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 40 to 50
Nickel chloride: 320 to 330
Sulfamic acid: 0.1 to 1
Boric acid: 3.5 to 5
15-20% of sodium chloride (NaCl)
Sodium lauryl sulfate: 0.1 to 0.5.
2. The novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 50
Nickel chloride: 325
Sulfamic acid: 0.5
Boric acid: 4
Sodium chloride (NaCl):20
Sodium lauryl sulfate: 0.5.
3. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 48
Nickel chloride: 330
Sulfamic acid: 0.9
Boric acid: 5
Sodium chloride (NaCl) 16
Sodium lauryl sulfate: 0.1.
4. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
chloride of 1-hexyl-3-methylimidazole 600
Iron chloride: 46
Nickel chloride: 330
Sulfamic acid: 0.3
Boric acid: 4.5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.2.
5. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 46
Nickel chloride: 325
Sulfamic acid: 0.5
Boric acid: 5
Sodium chloride (NaCl):18
Sodium lauryl sulfate: 0.5.
6. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 44
Nickel chloride: 328
Sulfamic acid: 0.4
Boric acid: 3.5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.1.
7. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
chlorinated 1-hexyl-3-methylimidazole 605
Iron chloride: 45
Nickel chloride: 327
Sulfamic acid: 1
Boric acid: 3.5
Sodium chloride (NaCl):18
Sodium lauryl sulfate: 0.5.
8. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 48
Nickel chloride: 320
Sulfamic acid: 0.5
Boric acid: 5
Sodium chloride (NaCl) 16
Sodium lauryl sulfate: 0.5.
9. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 40
Nickel chloride: 330
Sulfamic acid: 0.6
Boric acid: 4
Sodium chloride (NaCl):15
Sodium lauryl sulfate: 0.4.
10. the novel practical electroplating solution for ferronickel plating according to claim 1, characterized in that: the formula of the novel practical electroplating solution (g.kg-1) for plating nickel iron comprises the following components:
610 parts of 1-hexyl-3-methylimidazole chloride
Iron chloride: 42
Nickel chloride: 323
Sulfamic acid: 0.8
Boric acid: 5
Sodium chloride (NaCl):19
Sodium lauryl sulfate: 0.2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911123559.2A CN110670096A (en) | 2019-11-17 | 2019-11-17 | Novel practical electroplating solution for plating nickel iron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911123559.2A CN110670096A (en) | 2019-11-17 | 2019-11-17 | Novel practical electroplating solution for plating nickel iron |
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| Publication Number | Publication Date |
|---|---|
| CN110670096A true CN110670096A (en) | 2020-01-10 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463532A (en) * | 2015-12-29 | 2016-04-06 | 沈阳师范大学 | Novel electroplating liquid for ferronickel plating |
| CN105525314A (en) * | 2015-12-29 | 2016-04-27 | 沈阳师范大学 | Novel nickel chloride/iron chloride system electroplating solution |
| CN105780069A (en) * | 2015-12-29 | 2016-07-20 | 沈阳师范大学 | Chloride 1-hexyl-3-methyl glyoxaline/ferric chloride system electroplating solution |
| CN106661753A (en) * | 2014-04-15 | 2017-05-10 | 尼奥工业有限责任公司 | Ionic liquid electrolyte and method to electrodeposit metals |
| CN106757187A (en) * | 2016-12-30 | 2017-05-31 | 沈阳师范大学 | A kind of new nickel-plating bath containing sulfamate |
| CN106868553A (en) * | 2016-12-30 | 2017-06-20 | 沈阳师范大学 | The nickel-plating bath of new chloride |
-
2019
- 2019-11-17 CN CN201911123559.2A patent/CN110670096A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106661753A (en) * | 2014-04-15 | 2017-05-10 | 尼奥工业有限责任公司 | Ionic liquid electrolyte and method to electrodeposit metals |
| CN105463532A (en) * | 2015-12-29 | 2016-04-06 | 沈阳师范大学 | Novel electroplating liquid for ferronickel plating |
| CN105525314A (en) * | 2015-12-29 | 2016-04-27 | 沈阳师范大学 | Novel nickel chloride/iron chloride system electroplating solution |
| CN105780069A (en) * | 2015-12-29 | 2016-07-20 | 沈阳师范大学 | Chloride 1-hexyl-3-methyl glyoxaline/ferric chloride system electroplating solution |
| CN106757187A (en) * | 2016-12-30 | 2017-05-31 | 沈阳师范大学 | A kind of new nickel-plating bath containing sulfamate |
| CN106868553A (en) * | 2016-12-30 | 2017-06-20 | 沈阳师范大学 | The nickel-plating bath of new chloride |
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Application publication date: 20200110 |
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