CN110669401A - Environment-friendly waterproof material for building - Google Patents
Environment-friendly waterproof material for building Download PDFInfo
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- CN110669401A CN110669401A CN201910986489.7A CN201910986489A CN110669401A CN 110669401 A CN110669401 A CN 110669401A CN 201910986489 A CN201910986489 A CN 201910986489A CN 110669401 A CN110669401 A CN 110669401A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The invention discloses an environment-friendly waterproof material for buildings, which comprises the following raw materials in parts by weight: 25-45 parts of acrylic acid, 8-14 parts of elastic fiber, 4-10 parts of filler, 1-6 parts of solvent, 1-3 parts of defoaming agent, 15-35 parts of epoxy resin adhesive, 10-30 parts of epoxy resin curing agent, 8-16 parts of thickening agent, 2-10 parts of antioxidant, 3-6 parts of compatilizer, 2-8 parts of antistatic agent, 6-12 parts of lubricant and 4-12 parts of pigment, wherein the elastic fiber is one or more of cellulose acetate, cellulose acetate butyrate and microcrystalline cellulose, and the invention relates to the technical field of building materials. This environment-friendly waterproof material for building makes building material through the raw materials that adopts the environment-friendly, has improved building material's environmental protection performance, and after using, the smell is lighter, has reduced the pollution to environment and human body, gives other people the living environment of comfort level, and building material has certain waterproof nature moreover, can avoid building material to receive the destruction of aqueous vapor, has prolonged building material's life.
Description
Technical Field
The invention relates to the technical field of building materials, in particular to an environment-friendly waterproof material for buildings.
Background
Materials used in civil engineering and construction engineering can be collectively called as structural materials, decorative materials and some special materials, wherein the structural materials comprise wood, bamboo, stone, cement, concrete, metal, tiles, ceramics, glass, engineering plastics, composite materials and the like; the decorative material comprises various coatings, paints, plating layers, veneers, ceramic tiles with various colors, glass with special effects and the like; the special material is used for water proofing, moisture proofing, corrosion resistance, fire proofing, flame retardance, sound insulation, heat preservation, sealing and the like, the building material bears wind, sunshine, rain, abrasion, corrosion and the like for a long time, the performance can be gradually changed, the reasonable selection of the building material is vital, the building material is safe and durable firstly, the consumption of the building material is large, the construction cost of a project is directly influenced, generally, the construction material cost accounts for more than half of the total construction cost of the project, therefore, the economic performance must be considered, and the waterproof material is the building envelope of the building and is used for preventing the penetration of rainwater, snow water and underground water; to prevent the erosion of moisture, steam and other harmful gases and liquids in the air; the partition structure is to prevent the water supply and drainage from being turned over, and the materials for preventing seepage, seepage and erosion are collectively called as materials for preventing rainwater, underground water, industrial and civil water supply and drainage, corrosive liquid, moisture, vapor and the like in the air from invading into the building, and the parts of the building which need to be subjected to waterproof treatment are mainly roofs, walls, floors and basements.
According to the existing development, people pursue living standards more and more, the environmental protection performance of the existing building materials is poor, after the building materials are used, the building materials have heavy smell, certain pollution to the environment and human bodies can be caused, the environment protection performance is not achieved, the waterproof performance of the building materials is poor, after the building materials are used for a long time, the surface of the building materials is easily damaged, and the service life of the building materials is shortened.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an environment-friendly waterproof material for buildings, which solves the problems that the existing building material has poor environmental protection performance, has heavy smell after use, can pollute the environment and human bodies to a certain extent, has no environmental protection performance, has poor waterproof performance, is easy to damage the surface after long-term use and shortens the service life.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: an environment-friendly waterproof material for buildings comprises the following raw materials in parts by weight: 25-45 parts of acrylic acid, 8-14 parts of elastic fiber, 4-10 parts of filler, 1-6 parts of solvent, 1-3 parts of defoaming agent, 15-35 parts of epoxy resin adhesive, 10-30 parts of epoxy resin curing agent, 8-16 parts of thickening agent, 2-10 parts of antioxidant, 3-6 parts of compatilizer, 2-8 parts of antistatic agent, 6-12 parts of lubricant and 4-12 parts of pigment.
Preferably, the raw materials comprise the following components: 35 parts of acrylic acid, 11 parts of elastic fiber, 7 parts of filler, 4 parts of solvent, 2 parts of defoaming agent, 25 parts of epoxy resin glue, 20 parts of epoxy resin curing agent, 12 parts of thickening agent, 6 parts of antioxidant, 4 parts of compatilizer, 5 parts of antistatic agent, 9 parts of lubricant and 8 parts of pigment.
Preferably, the raw materials comprise the following components: 25 parts of acrylic acid, 8 parts of elastic fiber, 4 parts of filler, 1 part of solvent, 1 part of defoaming agent, 15 parts of epoxy resin glue, 10 parts of epoxy resin curing agent, 8 parts of thickening agent, 2 parts of antioxidant, 3 parts of compatilizer, 2 parts of antistatic agent, 6 parts of lubricant and 4 parts of pigment.
Preferably, the raw materials comprise the following components: 45 parts of acrylic acid, 14 parts of elastic fiber, 10 parts of filler, 6 parts of solvent, 3 parts of defoaming agent, 35 parts of epoxy resin glue, 30 parts of epoxy resin curing agent, 16 parts of thickening agent, 10 parts of antioxidant, 6 parts of compatilizer, 8 parts of antistatic agent, 12 parts of lubricant and 12 parts of pigment.
Preferably, the elastic fiber is one or more of cellulose acetate, cellulose acetate butyrate and microcrystalline cellulose, and the filler is one or more of talcum powder, expanded perlite and tourmaline powder.
Preferably, the solvent is one or more of methanol, n-propanol, n-butanol, isobutanol and ethylene glycol, and the defoaming agent is tributyl phosphate or phosphate.
Preferably, the antioxidant is a 1: 1 compound of phenothiazine and phosphite ester, the compatilizer is PP-g-MAH, the antistatic agent is graphene oxide, and the lubricant is one or more of zinc stearate, calcium stearate or potassium stearate.
The pigment is a mixture of titanium dioxide and zinc oxide.
Acrylic acid is an important organic synthetic raw material and a synthetic resin monomer, is an ethylene monomer with very high polymerization speed, is the simplest unsaturated carboxylic acid, consists of a vinyl group and a carboxyl group, is a colorless clear liquid, has characteristic pungent smell, can be mutually dissolved with water, alcohol, ether and chloroform, is prepared from propylene obtained from an oil refinery, is mainly used for preparing acrylic esters such as methyl acrylate, ethyl acrylate, butyl acrylate, hydroxyethyl acrylate and the like, can be homopolymerized and copolymerized, and is used for industrial departments such as synthetic resin, synthetic fiber, super absorbent resin, building materials, coating and the like.
The epoxy resin adhesive generally refers to an adhesive prepared by taking epoxy resin as a main body, and the epoxy resin adhesive generally also comprises an epoxy resin curing agent, otherwise, the adhesive cannot be cured.
The thickener is a food additive, is mainly used for improving and increasing the viscosity of food, keeping the color, the fragrance, the taste and the stability of fluid food and jelly food, improving the physical properties of the food, and enabling the food to have a feeling of lubrication and palatability, can improve the viscosity of the food or form gel, thereby changing the physical properties of the food, endowing the food with sticky and smooth mouthfeel, and having the functions of emulsification, stabilization or suspension.
Preferably, the preparation method of the environment-friendly waterproof material for buildings specifically comprises the following steps:
s1, selecting a proper amount of acrylic acid, epoxy resin glue, a thickening agent, a compatilizer, an antioxidant and a defoaming agent, mixing and stirring the raw materials, then heating the raw materials to 90-110 ℃, and continuously stirring the raw materials to uniformly heat the raw materials, wherein the stirring speed is 60-100 revolutions per minute, and the stirring time is 30-50 minutes;
s2, weighing a proper amount of elastic fiber, an antistatic agent, a lubricant and a filler, pouring the elastic fiber, the antistatic agent, the lubricant and the filler into the mixture prepared in the step S1, stirring and mixing the mixture, wherein the stirring speed is 60-100 revolutions per minute, the stirring time is 30-50 minutes, and after the mixture is uniformly mixed, dissolving and polymerizing the mixture for 6-8 hours;
s3, adding a proper amount of solvent, epoxy resin curing agent and pigment, stirring and mixing to mix uniformly, wherein the stirring speed is 110-.
(III) advantageous effects
The invention provides an environment-friendly waterproof material for buildings. Compared with the prior art, the method has the following beneficial effects: the environment-friendly waterproof material for buildings comprises the following raw materials in parts by weight: 25-45 parts of acrylic acid, 8-14 parts of elastic fiber, 4-10 parts of filler, 1-6 parts of solvent, 1-3 parts of defoaming agent, 15-35 parts of epoxy resin adhesive, 10-30 parts of epoxy resin curing agent, 8-16 parts of thickener, 2-10 parts of antioxidant, 3-6 parts of compatilizer, 2-8 parts of antistatic agent, 6-12 parts of lubricant and 4-12 parts of pigment, wherein the elastic fiber is one or more of cellulose acetate, cellulose acetate butyrate and microcrystalline cellulose, the filler is one or more of talcum powder, expanded perlite and tourmaline powder, the solvent is one or more of methanol, n-propanol, n-butanol, isobutanol and ethylene glycol, the defoaming agent is tributyl phosphate or phosphate, the antioxidant is a 1: 1 complex of phenothiazine and phosphite ester, the compatilizer is PP-g-MAH, the antistatic agent is graphene oxide, the lubricant is one or more of zinc stearate, calcium stearate or potassium stearate, the building material is manufactured by adopting environment-friendly raw materials, the environment-friendly performance of the building material is improved, after the building material is used, the smell is light, the pollution to the environment and human bodies is reduced, the living environment with comfortable degree is brought to people, the building material has certain waterproofness, the building material can be prevented from being damaged by water vapor, and the service life of the building material is prolonged.
Drawings
FIG. 1 is a statistical table of comparative experimental data according to the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1, the embodiment of the present invention provides three technical solutions: a preparation method of an environment-friendly waterproof material for buildings specifically comprises the following embodiments:
example 1
S1, selecting 35 parts of acrylic acid, 25 parts of epoxy resin adhesive, 12 parts of thickening agent, 4 parts of compatilizer, 6 parts of antioxidant and 2 parts of defoaming agent, mixing and stirring the raw materials, then heating the raw materials to 100 ℃, and continuing stirring to uniformly heat the raw materials, wherein the stirring speed is 80 revolutions per minute, and the stirring time is 40 minutes;
s2, weighing 11 parts of elastic fiber, 5 parts of antistatic agent, 9 parts of lubricant and 7 parts of filler, pouring the elastic fiber, the antistatic agent, the lubricant and the filler into the mixture prepared in the step S1, stirring and mixing the mixture at a stirring speed of 80 revolutions per minute for 40 minutes, and after the mixture is uniformly mixed, dissolving and polymerizing the mixture for 7 hours;
and S3, adding 4 parts of solvent, 20 parts of epoxy resin curing agent and 8 parts of pigment, stirring and mixing uniformly at a stirring speed of 150 revolutions per minute for 65 minutes, and cooling to room temperature after stirring is finished to obtain the environment-friendly waterproof material for buildings.
Example 2
S1, selecting 25 parts of acrylic acid, 15 parts of epoxy resin adhesive, 8 parts of thickening agent, 3 parts of compatilizer, 2 parts of antioxidant and 1 part of defoaming agent, mixing and stirring the raw materials, then heating the raw materials to 90 ℃, and continuing stirring to uniformly heat the raw materials, wherein the stirring speed is 60 revolutions per minute, and the stirring time is 30 minutes;
s2, weighing 8 parts of elastic fiber, 2 parts of antistatic agent, 6 parts of lubricant and 4 parts of filler, pouring the elastic fiber, 2 parts of antistatic agent, 6 parts of lubricant and 4 parts of filler into the mixture prepared in the step S1, stirring and mixing the mixture at the stirring speed of 60 revolutions per minute for 30 minutes, and after the mixture is uniformly mixed, dissolving and polymerizing the mixture for 6 hours;
and S3, adding 1 part of solvent, 10 parts of epoxy resin curing agent and 4 parts of pigment, stirring and mixing uniformly at a stirring speed of 110 revolutions per minute for 50 minutes, and cooling to room temperature after stirring is finished to obtain the environment-friendly waterproof material for buildings.
Example 3
S1, selecting 45 parts of acrylic acid, 35 parts of epoxy resin adhesive, 16 parts of thickening agent, 6 parts of compatilizer, 10 parts of antioxidant and 3 parts of defoaming agent, mixing and stirring the raw materials, then heating the raw materials to 110 ℃, and continuing stirring to uniformly heat the raw materials, wherein the stirring speed is 100 revolutions per minute, and the stirring time is 50 minutes;
s2, weighing 14 parts of elastic fiber, 8 parts of antistatic agent, 12 parts of lubricant and 10 parts of filler, pouring the elastic fiber, the antistatic agent, the lubricant and the filler into the mixture prepared in the step S1, stirring and mixing the mixture at the stirring speed of 100 revolutions per minute for 50 minutes, and dissolving and polymerizing the mixture for 8 hours after the mixture is uniformly mixed;
and S3, adding 6 parts of solvent, 30 parts of epoxy resin curing agent and 12 parts of pigment, stirring and mixing uniformly, wherein the stirring speed is 180 revolutions per minute, the stirring time is 80 minutes, and after the stirring is finished, cooling to room temperature to obtain the environment-friendly waterproof material for the building.
And those not described in detail in this specification are well within the skill of those in the art.
Comparative experiment
A certain building material processing plant randomly selects 30 workers to test the environment-friendly waterproof material for the building, the ratio of the environment-friendly waterproof material for the building to water is 1:0.8-1.2, the mixture is coated for use, 10 workers are selected to test the environment-friendly waterproof material for the building manufactured by the manufacturing method of the embodiment 1 of the invention, 10 workers are selected to test the environment-friendly waterproof material for the building manufactured by the manufacturing method of the embodiment 2 of the invention, the remaining 10 workers test the environment-friendly waterproof material for the building manufactured by the manufacturing method of the embodiment 3 of the invention, and after 30 workers test, the test result is recorded.
As shown in table 1, in embodiment 1 of the present invention, the environment-friendly waterproof material for building has almost no odor, and after the surface of the material is sprinkled with water, water drops directly slide off from the surface, so that the material has good waterproof performance.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. An environment-friendly waterproof material for buildings is characterized in that: the raw materials comprise the following components in parts by weight: 25-45 parts of acrylic acid, 8-14 parts of elastic fiber, 4-10 parts of filler, 1-6 parts of solvent, 1-3 parts of defoaming agent, 15-35 parts of epoxy resin adhesive, 10-30 parts of epoxy resin curing agent, 8-16 parts of thickening agent, 2-10 parts of antioxidant, 3-6 parts of compatilizer, 2-8 parts of antistatic agent, 6-12 parts of lubricant and 4-12 parts of pigment.
2. The environment-friendly waterproof material for buildings as claimed in claim 1, wherein: the raw materials comprise the following components: 35 parts of acrylic acid, 11 parts of elastic fiber, 7 parts of filler, 4 parts of solvent, 2 parts of defoaming agent, 25 parts of epoxy resin glue, 20 parts of epoxy resin curing agent, 12 parts of thickening agent, 6 parts of antioxidant, 4 parts of compatilizer, 5 parts of antistatic agent, 9 parts of lubricant and 8 parts of pigment.
3. The environment-friendly waterproof material for buildings as claimed in claim 1, wherein: the raw materials comprise the following components: 25 parts of acrylic acid, 8 parts of elastic fiber, 4 parts of filler, 1 part of solvent, 1 part of defoaming agent, 15 parts of epoxy resin glue, 10 parts of epoxy resin curing agent, 8 parts of thickening agent, 2 parts of antioxidant, 3 parts of compatilizer, 2 parts of antistatic agent, 6 parts of lubricant and 4 parts of pigment.
4. The environment-friendly waterproof material for buildings as claimed in claim 1, wherein: the raw materials comprise the following components: 45 parts of acrylic acid, 14 parts of elastic fiber, 10 parts of filler, 6 parts of solvent, 3 parts of defoaming agent, 35 parts of epoxy resin glue, 30 parts of epoxy resin curing agent, 16 parts of thickening agent, 10 parts of antioxidant, 6 parts of compatilizer, 8 parts of antistatic agent, 12 parts of lubricant and 12 parts of pigment.
5. The environment-friendly waterproof material for buildings according to any one of claims 1 to 4, wherein: the elastic fiber is one or more of cellulose acetate, cellulose acetate butyrate and microcrystalline cellulose, and the filler is one or more of talcum powder, expanded perlite and tourmaline powder.
6. The environment-friendly waterproof material for buildings according to any one of claims 1 to 4, wherein: the solvent is one or more of methanol, n-propanol, n-butanol, isobutanol and ethylene glycol, and the defoaming agent is tributyl phosphate or phosphate.
7. The environment-friendly waterproof material for buildings according to any one of claims 1 to 4, wherein: the antioxidant is a compound of phenothiazine and phosphite ester in a ratio of 1: 1, the compatilizer is PP-g-MAH, the antistatic agent is graphene oxide, and the lubricant is one or more of zinc stearate, calcium stearate or potassium stearate.
8. The environment-friendly waterproof material for buildings according to any one of claims 1 to 4, wherein: the preparation method specifically comprises the following steps:
s1, selecting a proper amount of acrylic acid, epoxy resin glue, a thickening agent, a compatilizer, an antioxidant and a defoaming agent, mixing and stirring the raw materials, then heating the raw materials to 90-110 ℃, and continuously stirring the raw materials to uniformly heat the raw materials, wherein the stirring speed is 60-100 revolutions per minute, and the stirring time is 30-50 minutes;
s2, weighing a proper amount of elastic fiber, an antistatic agent, a lubricant and a filler, pouring the elastic fiber, the antistatic agent, the lubricant and the filler into the mixture prepared in the step S1, stirring and mixing the mixture, wherein the stirring speed is 60-100 revolutions per minute, the stirring time is 30-50 minutes, and after the mixture is uniformly mixed, dissolving and polymerizing the mixture for 6-8 hours;
s3, adding a proper amount of solvent, epoxy resin curing agent and pigment, stirring and mixing to mix uniformly, wherein the stirring speed is 110-.
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| CN201910986489.7A CN110669401A (en) | 2019-10-17 | 2019-10-17 | Environment-friendly waterproof material for building |
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| CN201910986489.7A CN110669401A (en) | 2019-10-17 | 2019-10-17 | Environment-friendly waterproof material for building |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111471341A (en) * | 2020-05-19 | 2020-07-31 | 苏州德加画材科技有限公司 | Graphene-based conductive pigment and preparation method thereof |
| CN111548460A (en) * | 2020-05-19 | 2020-08-18 | 广东合胜实业股份有限公司 | Manufacturing process of building environment-friendly waterproof material |
| CN111763093A (en) * | 2020-06-28 | 2020-10-13 | 江苏国盛新材料有限公司 | Zirconium modified aluminum oxide material |
| CN112976854A (en) * | 2021-02-07 | 2021-06-18 | 江苏瑞彩包装有限公司 | Cigarette packaging box printing process capable of improving printing yield |
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| KR101711910B1 (en) * | 2016-06-22 | 2017-03-03 | 주식회사 경암이앤씨 | Painting Method for Waterproof, Antifouling and Color Using Eco-Friendly Waterproof Material |
| CN109608769A (en) * | 2018-12-25 | 2019-04-12 | 邵成杰 | Polymeric antistatic PP composite material and preparation method for mascara bottle body |
| CN110016275A (en) * | 2019-03-09 | 2019-07-16 | 李筠 | Water garden and swimming pool dedicated liquid ceramics waterproof and anticorrosion new material and preparation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR101711910B1 (en) * | 2016-06-22 | 2017-03-03 | 주식회사 경암이앤씨 | Painting Method for Waterproof, Antifouling and Color Using Eco-Friendly Waterproof Material |
| CN109608769A (en) * | 2018-12-25 | 2019-04-12 | 邵成杰 | Polymeric antistatic PP composite material and preparation method for mascara bottle body |
| CN110016275A (en) * | 2019-03-09 | 2019-07-16 | 李筠 | Water garden and swimming pool dedicated liquid ceramics waterproof and anticorrosion new material and preparation method |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111471341A (en) * | 2020-05-19 | 2020-07-31 | 苏州德加画材科技有限公司 | Graphene-based conductive pigment and preparation method thereof |
| CN111548460A (en) * | 2020-05-19 | 2020-08-18 | 广东合胜实业股份有限公司 | Manufacturing process of building environment-friendly waterproof material |
| CN111763093A (en) * | 2020-06-28 | 2020-10-13 | 江苏国盛新材料有限公司 | Zirconium modified aluminum oxide material |
| CN112976854A (en) * | 2021-02-07 | 2021-06-18 | 江苏瑞彩包装有限公司 | Cigarette packaging box printing process capable of improving printing yield |
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