CN110656502A - Preparation process of soft anti-static textile fabric - Google Patents
Preparation process of soft anti-static textile fabric Download PDFInfo
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- CN110656502A CN110656502A CN201910784787.8A CN201910784787A CN110656502A CN 110656502 A CN110656502 A CN 110656502A CN 201910784787 A CN201910784787 A CN 201910784787A CN 110656502 A CN110656502 A CN 110656502A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to the technical field of textile fabrics, in particular to a preparation process of a soft anti-static textile fabric. A preparation process of a soft antistatic textile fabric at least comprises the following steps: (1) preparing a primary blended fabric: the blended fabric is prepared from protein fibers and polyester fibers through slivering, spinning and weaving; (2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 10-30min at normal temperature, then heating to 20-50 ℃, standing and soaking for 10-15min, taking out and washing with clear water to obtain the impregnated primary blended fabric; the mass concentration of the protease solution is 0.05 wt% -0.1 wt%; (3) washing and drying: soaking the soaked fabric in 70-90 deg.C water tank for 0.2-0.8 hr, taking out, vacuum drying the blended fabric at 60-80 deg.C for 4-6 hr, drying, and storing. The textile fabric has the advantages of softness, antistatic performance and good air permeability, and can be widely applied to the fields of clothes and home textiles.
Description
Technical Field
The invention relates to the technical field of textile fabrics, in particular to a soft anti-static textile fabric and a preparation process and application thereof.
Background
The textile fabric has wide application range and cannot be limited by the performance. Functional improvements in textile fabrics have long been an important direction of research. Changes in weather, changes in the surrounding environment and the influence of fabric rubbing can cause fabrics to have certain static charges, and even people with serious fabric static charges threaten human health. Therefore, whether the antistatic polyester fabric has good antistatic performance or not is also an important factor influencing the market.
Along with the improvement of living standard, people need to be higher and higher to various functions of surface fabric, and the traditional ventilative type that has a veneer soft layer prevents static surface fabric only possesses single function, and lacks the third dimension. Therefore, it is important to find a multifunctional soft, antistatic and breathable fabric.
Therefore, aiming at the problems, the invention provides the preparation process of the soft anti-static textile fabric, and the prepared soft anti-static textile fabric has soft and comfortable hand feeling and good anti-static performance.
Disclosure of Invention
In order to solve the technical problems, the invention provides a preparation process of a soft anti-static textile fabric in a first aspect, which at least comprises the following steps,
(1) preparing a primary blended fabric: the blended fabric is prepared from protein fibers and polyester fibers through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 10-30min at normal temperature, then heating to 20-50 ℃, standing and soaking for 10-15min, taking out and washing with clear water to obtain the impregnated primary blended fabric; the mass concentration of the protease solution is 0.05 wt% -0.1 wt%;
(3) washing and drying: soaking the soaked fabric in 70-90 deg.C water tank for 0.2-0.8 hr, taking out, vacuum drying the blended fabric at 60-80 deg.C for 4-6 hr, drying, and storing.
As a preferable technical scheme, the polyester fiber is modified polyester fiber obtained by modifying polyester fiber with modified graphene oxide.
As a preferable technical solution of the present invention, the modified graphene oxide is a graphene oxide modified by an aminosiloxane derivative.
In a preferred embodiment of the present invention, the aminosiloxane derivative is one or a combination of N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine, 1, 3-bis (4-aminobutyl) tetramethyldisiloxane, 2-amino-1- (butyldimethylsiloxy) butane, 3-aminopropylbis (trimethylsiloxy) methylsilane.
As a preferable technical solution of the present invention, the weight ratio of the aminosiloxane derivative to the graphene oxide is 1: (2-5).
As a preferable technical scheme, the addition amount of the modified graphene oxide is 2-6% of the total mass of the modified polyester fiber.
As a preferable technical scheme of the invention, the weight ratio of the protein fibers to the polyester fibers is 1: (0.5-1.5).
As a preferable technical scheme of the invention, the thickness of the fiber in the primary blended fabric is 50-100D; the warp density is 250-350 pieces/10 cm; the weft density is 300-400 pieces/10 cm.
In a second aspect of the invention, a soft antistatic textile fabric prepared by the preparation process is provided.
The third aspect of the invention provides application of the soft anti-static textile fabric, which can be applied to the fields of clothing and home textiles.
The above-described and other features, aspects, and advantages of the present application will become more apparent with reference to the following detailed description.
Has the advantages that: the invention provides a preparation process of a soft anti-static textile fabric. The soft antistatic textile fabric is prepared by three steps of preparing a primary blended fabric of protein fibers and modified graphene oxide modified polyester fibers, dipping the primary blended fabric, washing and drying, and is widely applied to the fields of clothing and home textiles. The textile fabric has the advantages of softness, antistatic performance and good air permeability. The inventor unexpectedly finds that the fabric also has a windproof effect in a severe environment, and is a functional fabric which plays different roles in different environments.
Detailed Description
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when a range of "1 to 5" is disclosed, the described range should be interpreted to include the ranges "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
The singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise. "optional" or "any" means that the subsequently described event or events may or may not occur, and that the description includes instances where the event occurs and instances where it does not.
Approximating language, as used herein throughout the specification and claims, is intended to modify a quantity, such that the invention is not limited to the specific quantity, but includes portions that are literally received for modification without substantial change in the basic function to which the invention is related. Accordingly, the use of "about" to modify a numerical value means that the invention is not limited to the precise value. In some instances, the approximating language may correspond to the precision of an instrument for measuring the value. In the present description and claims, range limitations may be combined and/or interchanged, including all sub-ranges contained therein if not otherwise stated.
In addition, the indefinite articles "a" and "an" preceding an element or component of the invention are not intended to limit the number requirement (i.e., the number of occurrences) of the element or component. Thus, "a" or "an" should be read to include one or at least one, and the singular form of an element or component also includes the plural unless the stated number clearly indicates that the singular form is intended.
"Polymer" means a polymeric compound prepared by polymerizing monomers of the same or different types. The generic term "polymer" embraces the terms "homopolymer", "copolymer", "terpolymer" and "interpolymer".
"interpolymer" means a polymer prepared by polymerizing at least two different monomers. The generic term "interpolymer" includes the term "copolymer" (which is generally used to refer to polymers prepared from two different monomers) and the term "terpolymer" (which is generally used to refer to polymers prepared from three different monomers). It also includes polymers made by polymerizing four or more monomers. "blend" means a polymer formed by two or more polymers being mixed together by physical or chemical means.
The invention provides a preparation process of a soft anti-static textile fabric, which at least comprises the following steps,
(1) preparing a primary blended fabric: the blended fabric is prepared from protein fibers and polyester fibers through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 10-30min at normal temperature, then heating to 20-50 ℃, standing and soaking for 10-15min, taking out and washing with clear water to obtain the impregnated primary blended fabric; the mass concentration of the protease solution is 0.05 wt% -0.1 wt%;
(3) washing and drying: soaking the soaked fabric in 70-90 deg.C water tank for 0.2-0.8 hr, taking out, vacuum drying the blended fabric at 60-80 deg.C for 4-6 hr, drying, and storing.
In a preferred embodiment, the preparation process of the soft antistatic textile fabric at least comprises the following steps,
(1) preparing a primary blended fabric: the blended fabric is prepared from protein fibers and polyester fibers through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 20min at normal temperature, then heating to 40 ℃, standing and soaking for 15min, taking out and washing with clear water to obtain the impregnated primary blended fabric; the mass concentration of the protease solution is 0.08 wt%;
(3) washing and drying: and (3) soaking the impregnated fabric in a 90 ℃ water tank for 0.5h, taking out, drying the blended fabric at 70 ℃ for 6h in vacuum, and storing after drying.
In the invention, the polyester fiber is modified polyester fiber obtained by modifying polyester fiber with modified graphene oxide.
Modified graphene oxide
In the invention, the modified graphene oxide is modified porous graphene oxide.
Preferably, the preparation method of the porous graphene oxide comprises the following steps:
(1) preparing polystyrene nano-spheres:
introducing nitrogen to remove air in the three-mouth bottle at room temperature, adding deionized water and styrene monomer, continuously introducing nitrogen to remove air in the solution, and magnetically stirring for 20-40 min; gradually raising the temperature to 30-90 ℃, dissolving an initiator potassium persulfate in deionized water, then adding the solution into a three-necked bottle at one time, continuing to react for 10-24h, and centrifugally drying to obtain polystyrene spheres;
(2) preparing graphene oxide with a three-dimensional porous structure:
preparing graphene oxide into a solution with the concentration of 2-5g/L, ultrasonically mixing polystyrene spheres and the graphene oxide for 2-3h to form colloidal particles, adjusting the pH value of the solution to 6-8 to uniformly disperse the polystyrene nano spheres in the graphene oxide, performing suction filtration and drying, calcining at high temperature in a nitrogen environment to thermally decompose the polystyrene spheres, and thermally reducing the graphene oxide to obtain the porous graphene oxide.
Preferably, the volume ratio of the deionized water to the styrene monomer in the step (1) is 10: (0.5-3), wherein the mass of the initiator is 0.2-1% of that of the styrene monomer.
Preferably, the mass ratio of the polystyrene to the graphene oxide in the step (2) is (2-5): 1; the temperature for calcining the polystyrene spheres by heat at high temperature is 300-550 ℃, and the calcining time is 1-2 h; the temperature of the high-temperature thermal reduction graphite oxide is 700-.
The graphene oxide is not particularly limited, and may be obtained by purchase or preparation.
Preferably, the preparation method of the graphene oxide comprises the following steps: under the condition of ice-water bath, 30g of graphite powder and 15g of NaNO are mixed3And 900mL of concentrated H2SO4(H2SO498 percent of the mass fraction) is put into a three-neck flask and stirred for 0.5 h; then 90g KMnO was slowly added4Keeping the ice-water bath condition to continue stirring and reacting for 2 hours, and at the moment, changing the reactant from black to dark green; transferring the three-neck flask into a 35 ℃ constant temperature water bath, stirring for 3h, then dropwise adding 2000mL of distilled water, controlling the temperature not to exceed 98 ℃, and then continuing to react for 30min at 70 ℃ until the solution is yellow brown; then 100mL of 30% H2O2Adding the reactant and stirring for 30min, wherein the solution turns bright yellow; and (3) centrifugally washing by using 0.01mol/L HCl to remove metal ions in the solution, centrifugally washing by using absolute ethyl alcohol and deionized water respectively until the pH value of the filtrate is neutral, carrying out ultrasonic treatment, and carrying out freeze drying to obtain the product.
In a preferred embodiment, the preparation method of the porous graphene oxide comprises the following steps:
(1) adding 90mL of deionized water and 9mL of styrene monomer into a three-necked bottle, continuously introducing nitrogen to remove air in the solution, and magnetically stirring for 30 min; gradually raising the temperature to 70 ℃, and adding 10mL of 0.03g/mL potassium persulfate; continuously reacting for 24 hours, and centrifugally drying to obtain polystyrene spheres;
(2) ultrasonically stripping the prepared graphite oxide at room temperature to obtain a graphene oxide solution with the concentration of 5g/L, adding polystyrene spheres and the graphene oxide into the solution according to the mass ratio of 3:1, mixing and ultrasonically treating for 2h to form colloidal particles, adjusting the pH value to 8, uniformly dispersing the polystyrene nanospheres in the graphene oxide, filtering and drying, calcining at high temperature in a nitrogen environment to thermally decompose the polystyrene nanospheres, and thermally reducing the graphene oxide to obtain the porous graphene oxide.
In the invention, the modified porous graphene oxide is porous graphene oxide modified by aminosiloxane derivatives.
In the present invention, the aminosiloxane derivative is one or a combination of N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine, 1, 3-bis (4-aminobutyl) tetramethyldisiloxane, 2-amino-1- (butyldimethylsilyloxy) butane, 3-aminopropylbis (trimethylsilyloxy) methylsilane.
In the invention, the weight ratio of the aminosiloxane derivative to the porous graphene oxide is 1: (2-5).
Preferably, the weight ratio of the aminosiloxane derivative to the porous graphene oxide is 1: 4.
preferably, the aminosiloxane derivative is N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine.
The N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine, CAS number: 49869-07-0.
In the invention, the preparation method of the modified porous graphene oxide comprises the following steps: adding 5g of porous graphene oxide into 1.5L of absolute ethyl alcohol, performing ultrasonic dispersion for 10min, adding an aminosiloxane derivative with a certain mass ratio, continuing to perform ultrasonic dispersion for 1h, adding the dispersion into a three-neck flask, and performing magnetic stirring reaction for 24h at 80 ℃; cooling the product to room temperature, centrifugally washing the product with absolute ethyl alcohol for 6 times, and then washing the product with distilled water for 1 time to remove residual aminosiloxane derivatives; and completely drying the product at 60 ℃ to obtain the aminosiloxane derivative modified graphene oxide.
In a preferred embodiment, the preparation method of the modified graphene oxide comprises the following steps: adding 5g of porous graphene oxide into 1.5L of absolute ethyl alcohol, performing ultrasonic dispersion for 10min, adding 20g of N- [3- [ tri (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine, continuing to perform ultrasonic dispersion for 1h, adding the dispersion into a three-neck flask, and performing magnetic stirring reaction at 80 ℃ for 24 h; after the product was cooled to room temperature, it was washed 6 times by centrifugation with anhydrous ethanol and 1 time with distilled water to remove the residual N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine; and completely drying the product at the temperature of 60 ℃ to obtain the N- [3- [ tri (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine modified graphene oxide.
Modified polyester fiber
In the invention, the addition amount of the modified porous graphene oxide is 2-6% of the total mass of the modified polyester fiber.
Preferably, the addition amount of the modified porous graphene oxide is 5% of the total mass of the modified polyester fiber.
Preferably, the blending spinning process of the modified porous graphene oxide modified polyester fiber comprises the following steps:
(1) melting: taking a certain amount of polyester fiber and modified porous graphene oxide as raw materials according to a mass ratio, and melting the raw materials into a spinning solution by a screw;
(2) metering and spinning: the spinning stock solution is sprayed out of a 12-hole spinneret plate for spinning and forming after the flow of the spinning stock solution is regulated by a metering pump, so that modified polyester fiber tows are prepared; a slow cooling heating device is arranged below the spinneret plate; the temperature of the slow cooling heating device is 8-12 ℃ higher than the plate surface temperature of the spinneret plate;
(3) cooling and oiling: carrying out circular blowing cooling on the modified polyester fiber tows through hot air equipment, and then carrying out double-oil-nozzle oiling treatment by adopting a polyester oiling agent, wherein the oiling rate is 0.85-0.95;
(4) pre-networking: pre-meshing the oiled modified polyester fiber tows by a pre-interlacer;
(5) stretching and shaping: adopting three pairs of rollers to stretch and shape the pre-networked modified polyester fiber tows, wherein the stretching ratio is 1.75-1.85;
(6) a main network: carrying out main networking on the stretched and shaped modified polyester fiber tows by a main networking device;
(7) winding: and (4) fully automatically winding the modified polyester fiber tows passing through the main network at the winding speed of 2450 and 2500m/min to obtain a modified polyester fiber finished product.
Preferably, in the step (1), the temperature at the time of melting is 272 ℃ to 275 ℃.
Preferably, in the step (2), the temperature of the plate surface of the spinneret plate is controlled to be between 293 ℃ and 295 ℃.
Preferably, in the step (2), the diameter of the spinneret plate is 0.13 mm.
Preferably, in the step (3), the air temperature when the modified polyester fiber tows are cooled by blowing air through the hot air device is 20 ℃ +/-1 ℃.
Preferably, in the step (5), the temperatures of the three pairs of rollers during the stretching and setting are respectively: 90-100 ℃, 120-130 ℃ and 210-220 ℃.
More preferably, in the step (5), the temperatures of the three pairs of rolls during the stretching and setting are respectively: 95 ℃, 125 ℃ and 215 ℃.
In a preferred embodiment, the modified porous graphene oxide modified polyester fiber blend spinning process comprises the following steps:
(1) melting: weighing 95 parts of polyester fiber and 5 parts of modified porous graphene oxide as raw materials in parts by mass, and melting the raw materials by a screw to form a spinning solution; the temperature at the time of the melting was 275 ℃;
(2) metering and spinning: the spinning stock solution is sprayed out of a 12-hole spinneret plate for spinning and forming after the flow of the spinning stock solution is regulated by a metering pump, so that modified polyester fiber tows are prepared; a slow cooling heating device is arranged below the spinneret plate; the temperature of the slow cooling heating device is 10 ℃ higher than the plate surface temperature of the spinneret plate; the plate surface temperature of the spinneret plate is 295 ℃; the aperture of the spinneret plate is 0.13 mm;
(3) cooling and oiling: carrying out circular air blow cooling on the modified polyester fiber tows through hot air equipment, and then carrying out double-oil-nozzle oiling treatment by adopting a polyester oiling agent, wherein the oiling rate is 0.9; the air temperature of the hot air equipment is 20 ℃ when the modified polyester fiber tows are cooled by blowing air;
(4) pre-networking: pre-meshing the oiled modified polyester fiber tows by a pre-interlacer;
(5) stretching and shaping: stretching and shaping the pre-networked modified polyester fiber tows by three pairs of rollers, wherein the stretching ratio is 1.85; the temperatures of the three pairs of rollers during stretching and setting are respectively as follows: 95 ℃, 125 ℃ and 215 ℃;
(6) a main network: carrying out main networking on the stretched and shaped modified polyester fiber tows by a main networking device;
(7) winding: and (3) fully automatically winding the modified polyester fiber tows passing through the main network at a winding speed of 2500m/min to obtain a modified polyester fiber finished product.
Primary blended fabric
In the invention, the weight ratio of the protein fiber to the polyester fiber is 1: (0.5-1.5).
Preferably, the weight ratio of the protein fibers to the polyester fibers is 1: 1.2.
the primary blended fabric is prepared from protein fibers and polyester fibers through the processes of slivering, spinning, weaving and the like.
Preferably, the protein fiber can be selected from milk fiber or/and soybean protein fiber.
In the invention, the thickness of the fiber in the primary blended fabric is 50-100D; the warp density is 250-350 pieces/10 cm; the weft density is 300-400 pieces/10 cm.
Preferably, the thickness of the fiber in the primary blended fabric is 80D; the warp density is 300 pieces/10 cm; the weft density was 350 pieces/10 cm.
The natural protein fiber is used as a substrate raw material, has the advantages of soft hand feeling, soft luster, excellent moisture absorption, moisture conduction and heat preservation performance, good skin-friendly performance, obvious antibacterial function, and especially excellent characteristics of very soft and good moisture absorption effect. According to the invention, the protein fiber and the terylene are blended, so that the softness of the terylene fiber can be well improved, the fabric can keep the high strength and wear resistance of the terylene, and the comfortable, soft and skin-friendly performance of the fabric is improved. However, after the graphene oxide modified by the aminosiloxane is selected to modify the terylene, the phenomenon of static electricity generation in the use process of the fabric can be effectively improved, the antistatic effect is improved, and the quality and the flexibility of the fiber can be obviously improved.
The inventor thinks that the graphene oxide adopted by the invention has certain conductive performance, and the graphene oxide can conduct and disperse charges after modifying fibers, so that the accumulation of the charges is avoided, and the antistatic effect is improved. The invention uses aminosiloxane to modify graphene oxide, especially the selected N- [3- [ tri (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine has special claw-shaped structural characteristics, and each claw has a plurality of oxygen atoms, and the monomer with the special structure is attached to the surface of the polyester fiber. Because the soybean protein fiber has more polar groups, the cohesive force effect of the polyester fiber on the soybean protein fiber can be improved in the blending process, the quality uniformity of the blended fiber is improved, and the product quality is improved.
Impregnation with an impregnating solution
In the invention, the prepared primary blended fabric is impregnated by the impregnating solution, and the impregnating method comprises the following steps: and (3) paving the primary blended fabric, slowly adding 0.08 wt% of protease aqueous solution, heating to 40 ℃, standing and soaking for 15min, taking out, repeatedly washing with clear water, placing in a 80 ℃ water tank for soaking for 0.5h, taking out, and drying for 5h at 90 ℃ to obtain the impregnated fabric.
Although the invention adopts the protein fiber and the polyester fiber for blending, the softness and comfort performance of the fabric can be obviously improved. However, the inventor finds that the air permeability of the fabric after blending is reduced, and the wide application of the fabric is not facilitated. The inventor soaks the fabric with special steeping liquor, so that not only can the comfortable softness of the fabric be further improved, but also the air permeability of the fabric can be effectively improved. The inventor thinks that probably, because the invention chooses to carry out special enzyme solution dipping treatment to the fabric, the protease is utilized to carry out certain degradation to the protein fiber in the fabric, so that more three-dimensional void structures can be generated on the fiber surface, the air permeability of the fabric can be improved, and simultaneously, the fabric surface has some micropore structures, namely certain micropores can be generated on the fiber surface, so that the internal structure of the fiber can be loosened to a certain degree, and the fabric is softer and more comfortable.
However, the degradation of the protein fiber by the enzyme solution is difficult to control, which easily causes the quality unevenness of the fabric and the poor control effect of the cavity. The inventor finds that the polyester fiber modified by N- [3- [ tri (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine and the special arrangement for controlling the radial density and the weft density of the fabric are combined, so that the uniformity of the fabric after the impregnation of the enzyme solution is excellent, and the air permeability of the whole fabric is uniform. The inventors believe that the possible reason is that the claw-like multiple oxygen atom structure characteristic of N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine allows for greater compactness between fibers and, in concert with the areal density of the web, allows for control over the exposure of the soy protein fibers in the web without causing localized degradation of the protein fibers. The inventor surprisingly finds that when the graphene oxide is in a three-dimensional porous structure, the air permeability is increased, and the windproof property of the fabric can be further improved. The inventor thinks that the cavity formed by the protein fiber on the surface layer of the fabric and the cavity of different layers formed by the three-dimensional porous structure of the graphene oxide in the fabric can form a serpentine channel, so that the air permeability of the fabric can be improved, and the fabric can also have a windproof function in a severe environment, so that the fabric has different functions in different environments.
In a second aspect of the invention, a soft antistatic textile fabric prepared by the preparation process is provided.
The third aspect of the invention provides application of the soft anti-static textile fabric, which can be applied to the fields of clothing and home textiles.
The present invention will be specifically described below by way of examples. It should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention, and that the insubstantial modifications and adaptations of the present invention by those skilled in the art based on the above disclosure are still within the scope of the present invention.
In addition, the raw materials used are commercially available from national chemical reagents, unless otherwise specified.
Examples
In the following examples:
1. the preparation method of the porous graphene oxide comprises the following steps:
(1) adding 90mL of deionized water and 9mL of styrene monomer into a three-necked bottle, continuously introducing nitrogen to remove air in the solution, and magnetically stirring for 30 min; gradually raising the temperature to 70 ℃, and adding 10mL of 0.03g/mL potassium persulfate; continuously reacting for 24 hours, and centrifugally drying to obtain polystyrene spheres;
(2) ultrasonically stripping prepared graphite oxide at room temperature to obtain a graphene oxide solution with the concentration of 5g/L, adding polystyrene spheres and the graphene oxide into the solution according to the mass ratio of 3:1, mixing and ultrasonically treating for 2h to form colloidal particles, adjusting the pH value to 8, uniformly dispersing the polystyrene nanospheres in the graphene oxide, filtering and drying, calcining at high temperature in a nitrogen environment to thermally decompose the polystyrene nanospheres, and thermally reducing the graphene oxide to obtain the graphene with the three-dimensional porous structure.
2. The preparation method of the modified porous graphene oxide comprises the following steps:
adding 5g of porous graphene oxide into 1.5L of absolute ethyl alcohol, performing ultrasonic dispersion for 10min, adding an aminosiloxane derivative with a certain mass ratio, continuing to perform ultrasonic dispersion for 1h, adding the dispersion into a three-neck flask, and performing magnetic stirring reaction for 24h at 80 ℃; cooling the product to room temperature, centrifugally washing the product with absolute ethyl alcohol for 6 times, and then washing the product with distilled water for 1 time to remove residual aminosiloxane derivatives; and completely drying the product at 60 ℃ to obtain the modified porous graphene oxide.
3. The modified porous graphene oxide modified polyester fiber blending spinning process comprises the following steps:
(1) melting: weighing a certain amount of polyester fiber and modified porous graphene oxide as raw materials according to parts by mass, and melting the raw materials by a screw to form a spinning solution; the temperature at the time of the melting was 275 ℃;
(2) metering and spinning: the spinning stock solution is sprayed out of a 12-hole spinneret plate for spinning and forming after the flow of the spinning stock solution is regulated by a metering pump, so that modified polyester fiber tows are prepared; a slow cooling heating device is arranged below the spinneret plate; the temperature of the slow cooling heating device is 10 ℃ higher than the plate surface temperature of the spinneret plate; the plate surface temperature of the spinneret plate is 295 ℃; the aperture of the spinneret plate is 0.13 mm;
(3) cooling and oiling: carrying out circular air blow cooling on the modified polyester fiber tows through hot air equipment, and then carrying out double-oil-nozzle oiling treatment by adopting a polyester oiling agent, wherein the oiling rate is 0.9; the air temperature of the hot air equipment is 20 ℃ when the modified polyester fiber tows are cooled by blowing air;
(4) pre-networking: pre-meshing the oiled modified polyester fiber tows by a pre-interlacer;
(5) stretching and shaping: stretching and shaping the pre-networked modified polyester fiber tows by three pairs of rollers, wherein the stretching ratio is 1.85; the temperatures of the three pairs of rollers during stretching and setting are respectively as follows: 95 ℃, 125 ℃ and 215 ℃;
(6) a main network: carrying out main networking on the stretched and shaped modified polyester fiber tows by a main networking device;
(7) winding: and (3) fully automatically winding the modified polyester fiber tows passing through the main network at a winding speed of 2500m/min to obtain a modified polyester fiber finished product.
4. The primary blended fabric is prepared from protein fibers and polyester fibers through the processes of slivering, spinning, weaving and the like.
5. The impregnation method of the primary blended fabric comprises the following steps: and (3) paving the primary blended fabric, slowly adding a protease aqueous solution with a certain concentration, heating to 40 ℃, standing and soaking for 15min, taking out, repeatedly washing with clear water, placing in a 80 ℃ water tank for soaking for 0.5h, taking out, and drying at 90 ℃ for 5h to obtain the impregnated fabric.
Example 1
Embodiment 1 provides a preparation process of a soft antistatic textile fabric, which at least comprises the following steps:
(1) preparing a primary blended fabric: the blended fabric comprises protein fibers and polyester fibers; the fabric is made into a primary blended fabric through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 20h at normal temperature, then heating to 40 ℃, standing and soaking for 15min, taking out, and washing with clear water to obtain the impregnated fabric;
(3) washing and drying: and (3) placing the impregnated fabric in a 90 ℃ water tank for soaking for 0.5h, taking out and drying, drying the blended fabric in vacuum at 70 ℃ for 6h, and storing after drying.
In the step (1), the weight ratio of the protein fibers to the polyester fibers is 1: 0.5; the fiber thickness is 50D, and the warp density is 250 pieces/10 cm; the weft density is 300 pieces/10 cm; the polyester fiber is modified by porous graphene oxide modified by 1, 3-bis (4-aminobutyl) tetramethyldisiloxane; the weight ratio of the 1, 3-bis (4-aminobutyl) tetramethyldisiloxane to the porous graphene oxide is 1: 2; the addition amount of the modified graphene oxide is 2% of the total mass of the blend fiber.
In the step (2), the mass concentration of the protease solution is 0.05 wt%.
Example 2
Embodiment 2 provides a preparation process of a soft antistatic textile fabric, which at least comprises the following steps:
(1) preparing a primary blended fabric: the blended fabric comprises protein fibers and polyester fibers; the fabric is made into a primary blended fabric through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 20min at normal temperature, then heating to 40 ℃, standing and soaking for 15min, taking out, and washing with clear water to obtain the impregnated fabric;
(3) washing and drying: and (3) placing the impregnated fabric in a 90 ℃ water tank for soaking for 0.5h, taking out and drying, drying the blended fabric in vacuum at 70 ℃ for 6h, and storing after drying.
In the step (1), the weight ratio of the protein fibers to the polyester fibers is 1: 1.5; the thickness of the fiber is 100D, and the warp density is 350 pieces/10 cm; the weft density is 400 pieces/10 cm; the polyester fiber is modified by 3-aminopropyl bis (trimethylsiloxy) methylsilane modified porous graphene oxide; the weight ratio of the 3-aminopropyl bis (trimethylsiloxy) methylsilane to the porous graphene oxide is 1: 5; the addition amount of the modified graphene oxide is 6% of the total mass of the blend fiber.
In the step (2), the mass concentration of the protease solution is 0.1 wt%.
Example 3
Embodiment 3 provides a process for preparing a soft antistatic textile fabric, which at least comprises the following steps:
(1) preparing a primary blended fabric: the blended fabric comprises protein fibers and polyester fibers; the fabric is made into a primary blended fabric through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 20min at normal temperature, then heating to 40 ℃, standing and soaking for 15min, taking out, and washing with clear water to obtain the impregnated fabric;
(3) washing and drying: and (3) placing the impregnated fabric in a 90 ℃ water tank for soaking for 0.5h, taking out and drying, drying the blended fabric in vacuum at 70 ℃ for 6h, and storing after drying.
In the step (1), the weight ratio of the protein fibers to the polyester fibers is 1: 1.2; the fiber thickness is 80D, and the warp density is 300 pieces/10 cm; the weft density is 350 pieces/10 cm; the polyester fiber is modified by N- [3- [ tri (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine modified porous graphene oxide; the weight ratio of the N- [3- [ tri (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine to the porous graphene oxide is 1: 4; the addition amount of the modified graphene oxide is 5% of the total mass of the blend fiber.
In the step (2), the mass concentration of the protease solution is 0.08 wt%.
Example 4
Example 4 differs from example 3 in that the polyester fibers are unmodified.
Example 5
Example 5 is different from example 3 in that the polyester fiber is a porous graphene oxide modified polyester fiber.
Example 6
Example 6 is different from example 3 in that the polyester fiber is a graphene oxide modified polyester fiber.
Example 7
Example 7 is different from example 3 in that the polyester fiber is a modified porous graphene oxide-modified polyester fiber; the modified porous graphene oxide is octadecylamine-modified porous graphene oxide.
Example 8
Example 8 is different from example 3 in that, in the modified porous graphene oxide, the weight ratio of the aminosiloxane derivative to the porous graphene oxide is 1: 0.5.
example 9
Example 9 differs from example 3 in that the weight ratio of the aminosiloxane derivative to the porous graphene oxide in the modified porous graphene oxide is 1: 10.
example 10
The difference between the embodiment 10 and the embodiment 3 is that the addition amount of the modified porous graphene oxide is 0.5% of the total mass of the blended polyester fiber.
Example 11
Example 11 is different from example 3 in that the addition amount of the modified porous graphene oxide is 10% of the total mass of the blended polyester fiber.
Example 12
The difference between the embodiment 12 and the embodiment 3 is that the weight ratio of the protein fiber to the polyester fiber in the blended fabric is 1: 0.1.
example 13
Example 13 is different from example 3 in that the weight ratio of the protein fiber to the polyester fiber in the blended fabric is 1: 5.
example 14
Example 14 differs from example 3 in that the fiber thickness in the as-blended fabric was 10D.
Example 15
Example 15 differs from example 3 in that the fiber thickness in the as-blended fabric was 200D.
Example 16
Example 16 differs from example 3 in that the as-blended fabric has a medium orientation density of 100 threads/10 cm; the weft density was 150 pieces/10 cm.
Example 17
Example 17 differs from example 3 in that the as-blended fabric has a medium orientation density of 500 threads/10 cm; the weft density was 550 pieces/10 cm.
Example 18
Example 18 differs from example 3 in that the mass concentration of the protease solution in the impregnation solution was 0.01 wt%.
Example 19
Example 19 differs from example 3 in that the mass concentration of the protease solution in the immersion liquid was 0.3 wt%.
Evaluation of Performance test
1. Softness test
The soft antistatic textile fabrics prepared in the examples 1-13 are cut into rectangular blocks of 6cm multiplied by 10cm, 6 samples are prepared for each group of examples for testing, wherein the long sides of 3 samples are parallel to the longitudinal direction of the fabric, the long sides of 3 samples are parallel to the transverse direction of the fabric, the samples are subjected to humidity conditioning for 24h under standard atmospheric conditions before testing, and no flaw point exists on the samples. The bending stiffness of the test piece was measured by using an electronic stiffness meter model LLY-01 manufactured by electronics instruments, Inc. of Laizhou. The test result is the sum of the mean value of the longitudinal test values and the mean value of the transverse test values. The test results are shown in table 1.
Table 1 softness test results of textile fabrics
2. Antistatic test
The test method is carried out according to the charge surface density method in GB/T12703-1991, textile static test method. The fabric charge was measured using an LFY-403A roller friction machine in combination with an LFY-403 fabric triboelectric charge tester (Faraday cage method), both of which were purchased from Shandong institute of textile science.
The cloth samples prepared in examples 1 to 11 were prepared according to the corresponding standards, with a size of 20cm x 20cm, and the samples were thrown into a friction drum, the instrument was started and run for 15min and stopped, the samples were taken out immediately (within 1 s) and placed into a faraday cage for charge measurement, and the readings on the charge measuring device were read and recorded. The antistatic properties were measured by the amount of charge obtained.
Calculating the formula: σ ═ CV/A, where σ is the charge areal density (μ C/m)2) C is total capacitance (F) of Faraday system, V is voltage reading value (V), A is test area (m) of sample2). The test results are shown in table 2.
Table 2 textile fabric charge areal density test results
3. Test for air permeability
Reference is made to the test standard GB/T5453-1997 determination of the air permeability of textile fabrics. The test results are shown in table 3.
TABLE 3 test results of textile fabric air permeability
As can be seen from tables 1-3, the soft antistatic textile fabric provided by the invention has excellent softness and antistatic performance. Meanwhile, the fabric has good air permeability and can be widely applied to the fields of clothes and home textiles.
Claims (10)
1. A preparation process of soft anti-static textile fabric is characterized by at least comprising the following steps,
(1) preparing a primary blended fabric: the blended fabric is prepared from protein fibers and polyester fibers through slivering, spinning and weaving;
(2) dipping the primary blended fabric: spreading the primary blended fabric, slowly adding a protease impregnation liquid, fully soaking for 10-30min at normal temperature, then heating to 20-50 ℃, standing and soaking for 10-15min, taking out and washing with clear water to obtain the impregnated primary blended fabric; the mass concentration of the protease solution is 0.05 wt% -0.1 wt%;
(3) washing and drying: soaking the soaked fabric in 70-90 deg.C water tank for 0.2-0.8 hr, taking out, vacuum drying the blended fabric at 60-80 deg.C for 4-6 hr, drying, and storing.
2. The preparation process of claim 1, wherein the polyester fiber is a modified polyester fiber obtained by modifying a polyester fiber with modified graphene oxide.
3. The process according to claim 2, wherein the modified graphene oxide is an aminosiloxane derivative-modified graphene oxide.
4. The process of claim 3, wherein the aminosiloxane derivative is a combination of one or more of N- [3- [ tris (2-methoxyethoxy) silyl ] propyl ] ethane-1, 2-diamine, 1, 3-bis (4-aminobutyl) tetramethyldisiloxane, 2-amino-1- (butyldimethylsiloxy) butane, 3-aminopropylbis (trimethylsiloxy) methylsilane.
5. The process according to claim 3, wherein the weight ratio between the aminosilicone derivative and the graphene oxide is 1: (2-5).
6. The preparation process of claim 2, wherein the addition amount of the modified graphene oxide is 2-6% of the total mass of the modified polyester fiber.
7. The process according to claim 1, wherein the weight ratio of the protein fibers to the polyester fibers is 1: (0.5-1.5).
8. The process of claim 1, wherein the fiber thickness of the as-blended fabric is 50-100D; the warp density is 250-350 pieces/10 cm; the weft density is 300-400 pieces/10 cm.
9. A process according to any one of claims 1 to 8 for the preparation of a soft antistatic textile fabric.
10. Use of a soft antistatic textile fabric as claimed in claim 9 in the field of apparel and home textiles.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111334922A (en) * | 2020-04-13 | 2020-06-26 | 曹维维 | Antibacterial modal composite fabric and preparation method thereof |
| CN112680952A (en) * | 2020-12-22 | 2021-04-20 | 江苏翔鹰纺织科技有限公司 | Preparation process of soft anti-static textile fabric |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103898645A (en) * | 2012-12-30 | 2014-07-02 | 汤丽娟 | Production method of worsted shell fabric containing polyolefin elastic fibers |
| CN105231566A (en) * | 2015-10-27 | 2016-01-13 | 江苏云蝠服饰股份有限公司 | Anti-static fabric |
| CN106037099A (en) * | 2016-06-03 | 2016-10-26 | 江阴市悦达印染有限公司 | Manufacturing method of carding woolen fabric |
| CN106480707A (en) * | 2015-08-29 | 2017-03-08 | 江苏阳光集团有限公司 | The production method of the woolen fabric with health care |
| CN107149815A (en) * | 2017-04-14 | 2017-09-12 | 南通强生石墨烯科技有限公司 | A kind of antimicrobial filtering core |
| CN107747160A (en) * | 2017-09-30 | 2018-03-02 | 宿迁市神龙家纺有限公司 | A kind of antistatic wool felt and its production technology |
| CN108794999A (en) * | 2018-05-02 | 2018-11-13 | 陕西金瑞烯科技发展有限公司 | A kind of preparation method of graphene terylene composite material master batch and fiber |
| CN109943902A (en) * | 2019-03-14 | 2019-06-28 | 福建省银河服饰有限公司 | A kind of modified polyester fiber and preparation method |
| CN110093680A (en) * | 2019-06-04 | 2019-08-06 | 福建省银河服饰有限公司 | A kind of graphene/cage modle polysilsesquioxane modified polyester fiber and preparation method |
-
2019
- 2019-08-23 CN CN201910784787.8A patent/CN110656502A/en not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103898645A (en) * | 2012-12-30 | 2014-07-02 | 汤丽娟 | Production method of worsted shell fabric containing polyolefin elastic fibers |
| CN106480707A (en) * | 2015-08-29 | 2017-03-08 | 江苏阳光集团有限公司 | The production method of the woolen fabric with health care |
| CN105231566A (en) * | 2015-10-27 | 2016-01-13 | 江苏云蝠服饰股份有限公司 | Anti-static fabric |
| CN106037099A (en) * | 2016-06-03 | 2016-10-26 | 江阴市悦达印染有限公司 | Manufacturing method of carding woolen fabric |
| CN107149815A (en) * | 2017-04-14 | 2017-09-12 | 南通强生石墨烯科技有限公司 | A kind of antimicrobial filtering core |
| CN107747160A (en) * | 2017-09-30 | 2018-03-02 | 宿迁市神龙家纺有限公司 | A kind of antistatic wool felt and its production technology |
| CN108794999A (en) * | 2018-05-02 | 2018-11-13 | 陕西金瑞烯科技发展有限公司 | A kind of preparation method of graphene terylene composite material master batch and fiber |
| CN109943902A (en) * | 2019-03-14 | 2019-06-28 | 福建省银河服饰有限公司 | A kind of modified polyester fiber and preparation method |
| CN110093680A (en) * | 2019-06-04 | 2019-08-06 | 福建省银河服饰有限公司 | A kind of graphene/cage modle polysilsesquioxane modified polyester fiber and preparation method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111334922A (en) * | 2020-04-13 | 2020-06-26 | 曹维维 | Antibacterial modal composite fabric and preparation method thereof |
| CN111334922B (en) * | 2020-04-13 | 2022-01-11 | 葫芦岛斯达威体育用品有限公司 | Antibacterial modal composite fabric and preparation method thereof |
| CN112680952A (en) * | 2020-12-22 | 2021-04-20 | 江苏翔鹰纺织科技有限公司 | Preparation process of soft anti-static textile fabric |
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