CN1106468A - Nickel-saving heat-resisting steel - Google Patents
Nickel-saving heat-resisting steel Download PDFInfo
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- CN1106468A CN1106468A CN 94100956 CN94100956A CN1106468A CN 1106468 A CN1106468 A CN 1106468A CN 94100956 CN94100956 CN 94100956 CN 94100956 A CN94100956 A CN 94100956A CN 1106468 A CN1106468 A CN 1106468A
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- steel
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Abstract
The utility model is a saving nickel heat resistant steel which contains the rare earth etc. The steel is mainly characterized that through the addition of a few rare earth and other microelements, the utility model contains fewer nickels and total alloy content, which is much more economic. The steel is provided with higher high temperature strength, better oxidation resistance and smaller age brittleness inclination in the range of 650DEG C to1000DEG C. The steel is smelted in an electric furnace or a non-vacuum induction melting furnace and can be made into various deformation materials and castings. The utility model suits for the various furnace components and other heat resistant components in the range of 650DEG C to1000DEG C.
Description
The invention belongs to a kind of rare earth and other the micro-chromium-nickel austenite high temperature steel of containing in the steel alloy.Be applicable to the various heat-resistant components in making 650-1000 ℃.
In 650-1000 ℃ of temperature range, adopt 1Cr18Ni9Ti both at home and abroad in a large number, steel grades such as Cr25Ni13, Cr20Ni14Si2, its nickel content is higher, and price is more expensive.In order to save nickel, the domestic chromium manganese nitrogen type (as Cr21Mn12Si2N) of also having carried out, the research of iron aluminium manganese type high temperature steel such as (Mn30A19 types), but because it is higher to contain manganese in the steel, antioxidant property is relatively poor, and after long-time high-temperature aging and the use, the fragility tendency is also more serious, influence the result of use of steel, limited its use range.Clear 59-16954, clear 61-183449, clear 58-141891, clear 59-162256 and GB1525243, the US3969109 etc. of the open special permission communique report of Japan also introduce the high temperature steel that contains rare earth in the present prior art abroad, though these high temperature steel can satisfy some service requirementss at high temperature, but its most of nickel content is all higher, certainly will cost an arm and a leg, the manganese content that has is higher, unfavorable to high-temperature oxidation resistant, the N content that has is higher, the difficult control of smelting technology, these all make it be restricted in promoting the use of.
The purpose of this invention is to provide a kind ofly in 650-1000 ℃ of scope, the joint nickel heat-resisting steel of higher high temperature strength, good high-temperature oxidation-resistance and less timeliness fragility tendency is arranged.
In order to achieve the above object, the concrete chemical ingredients (weight %) of high temperature steel of the present invention is C 0.26～0.40%; Si 1.0～3.0%; Mn 1.0～2.8%; Cr 18～22%; Ni 2.0～4.8%; N 0.15～0.28%; RE 0.001～0.20%; Mg 0.0005～0.10%; Zr≤0.2%; All the other are Fe.In steel of the present invention, adopt carbon, nitrogen and minor amount of nickel as austenizer, to form austenitic matrix.Carbon is the intensive austenite former in steel of the present invention, adds higher carbon in steel, to enlarge and stable austenite, reduces nickel content.Because carbide dispersion-strengthened has improved the high temperature creep tension strength at break of steel, and can suppress the formation of σ phase, reduce the timeliness fragility tendency of steel simultaneously.
Guaranteeing steel formation austenitic matrix and having under the situation of enough stability, nickel is controlled at 2.0～4.8% lower contents levels, still can obtain the performance suitable, thereby make steel reach the purpose of joint nickel, also guarantee steel fundamental strength requirement at high temperature with High Nickel Steel.Utilize carbon, nitrogen, rare earth composite alloying further to improve the hot strength of steel in addition.Chromium, silicon are the main alloy element that steel of the present invention guarantees to have enough oxidation-resistances, but consider the comprehensive mechanical performance, chromium is controlled at 18～22%, silicon is controlled in 1～3% the scope, the rare earth element that wherein in steel, adds trace, increased the adhesivity of oxide film, the oxidation-resistance of steel of the present invention is obviously improved, reached 1000 ℃ with interior service requirements.In steel of the present invention, contain higher carbon, element silicon, guaranteed the flowability of molten steel, make the castability of steel of the present invention also fine.Add trace element magnesium, zirconium in the steel, can purify crystal boundary, strengthen crystal boundary, improve hot strength; After adding magnesium, can also crystal grain thinning, improve the thermoplasticity of steel, improve lumber recovery.The casting performance of steel of the present invention is also fine with making.
Steel of the present invention can adopt electric furnace or non-vacuum induction furnace to smelt, because the casting performance of steel of the present invention is good, can adopt sand mold to be cast into the parts of different shape, also can adopt rotational casting to become tubing; Can forge, the rolling various distortion materials etc. that are processed into.Foundry goods can as cast condition be delivered goods, and the distortion material carries out solution heat treatment.
Steel of the present invention is compared with the prior art steel and is had good hot strength and antioxidant property, and its comparing result sees Table 1.Show that by contrast compare with existing chromium-nickel austenite steel, the nickel content in the steel of the present invention obviously reduces, so both economical; And hot strength and oxidation-resistance have have all met or exceeded the level of compared steel.Steel of the present invention is compared with the chromium manganese nitrogen type steel, and manganese content is lower in the invar, has significantly improved the oxidation-resistance of steel, and total alloy content is low in the steel, and has less timeliness fragility tendency.Steel of the present invention also has smelting simultaneously, cast molding is easy, and production technique simply is easy to advantages such as grasp.
Embodiment
According to above-mentioned chemical ingredients scope, on induction furnace, smelted three stoves steel of the present invention and 1Cr20Ni14Si2, each stove of 4Cr25Ni13 compared steel, its concrete Chemical Composition sees Table 2.Be cast into steel ingot and as-cast specimen behind the smelting steel respectively, steel ingot forges into bar, and then respectively service check has been carried out in forging and as-cast specimen.Steel of the present invention is owing to after having added trace elements such as rare earth, magnesium, improved antioxidant property.Table 3 is 1000 ℃ of oxidation weight gain test-results.Table 4 has been enumerated the Mechanics Performance Testing comparing result of steel of the present invention and compared steel.
The performance comparison of table 1 steel of the present invention and prior art steel grade
(as-forged condition, solution treatment)
1000 ℃ of oxidation weight gain tests of table 3 comparing result (g/m
2H)
The Mechanics Performance Testing comparing result of table 4 embodiment
Claims (2)
1, the joint nickel heat-resisting steel that contains rare earth and other trace elements that uses under a kind of 650-1000 of being adapted at ℃ temperature is characterized in that the Chemical Composition content of high temperature steel is (weight %): C 0.26～0.40%; Si 1.0～3%; Mn 1-2.8%; Cr 18.0～22%; Ni 2.0～4.8%; N 0.15～0.28%; RE 0.001～0.2%; Mg 0.0005～0.10%; All the other are iron.
2, high temperature steel according to claim 1 is characterized in that in the chemical ingredients of steel Zr≤0.2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94100956 CN1032599C (en) | 1994-02-02 | 1994-02-02 | Nickel-saving heat-resisting steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94100956 CN1032599C (en) | 1994-02-02 | 1994-02-02 | Nickel-saving heat-resisting steel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1106468A true CN1106468A (en) | 1995-08-09 |
| CN1032599C CN1032599C (en) | 1996-08-21 |
Family
ID=5029956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94100956 Expired - Fee Related CN1032599C (en) | 1994-02-02 | 1994-02-02 | Nickel-saving heat-resisting steel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1032599C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100406608C (en) * | 2005-04-18 | 2008-07-30 | 张光华 | Ultra-strong refractory steel |
| CN104651737A (en) * | 2013-11-20 | 2015-05-27 | 兴化市金牛机械铸造有限公司 | Nickel-saving heat-resistant steel |
| CN106521326A (en) * | 2016-12-19 | 2017-03-22 | 苏州金威特工具有限公司 | Shear-steel |
-
1994
- 1994-02-02 CN CN 94100956 patent/CN1032599C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100406608C (en) * | 2005-04-18 | 2008-07-30 | 张光华 | Ultra-strong refractory steel |
| CN104651737A (en) * | 2013-11-20 | 2015-05-27 | 兴化市金牛机械铸造有限公司 | Nickel-saving heat-resistant steel |
| CN106521326A (en) * | 2016-12-19 | 2017-03-22 | 苏州金威特工具有限公司 | Shear-steel |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1032599C (en) | 1996-08-21 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |