CN110643248A - 一种纳米乳胶漆及其制备方法 - Google Patents

一种纳米乳胶漆及其制备方法 Download PDF

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CN110643248A
CN110643248A CN201911039010.5A CN201911039010A CN110643248A CN 110643248 A CN110643248 A CN 110643248A CN 201911039010 A CN201911039010 A CN 201911039010A CN 110643248 A CN110643248 A CN 110643248A
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熊辉
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Abstract

本发明适用于建筑涂料领域,提供了一种纳米乳胶漆及其制备方法,该纳米乳胶漆由水、润湿剂、羟乙基纤维素、金红石钛白粉、煅烧高岭土、重钙粉、硅灰石粉、丙二醇、硅丙乳液、分散剂、防腐杀菌剂、消泡剂、流平剂、增稠剂、纳米二氧化硅、纳米二氧化钛和AMP‑95组成。纳米二氧化硅能够大幅度提高纳米乳胶漆的耐老化性和贮存稳定性,使其对紫外光、红外线和可见光都具有极强的反射性。纳米二氧化钛具有净化空气的作用,将其应用于纳米乳胶漆中能够减弱漆膜遭受紫外线的侵蚀,提升纳米乳胶漆的抗老化性能和耐擦洗性,从而提高纳米乳胶漆的品质。本发明提供的纳米乳胶漆具有良好的施工性、低温稳定性、耐沾污性、耐洗刷性和耐碱性。

Description

一种纳米乳胶漆及其制备方法
技术领域
本发明属于建筑涂料领域,尤其涉及一种纳米乳胶漆及其制备方法。
背景技术
纳米乳胶漆是采用纳米级单体浆料、纳米乳液、纳米色浆、纳米杀菌剂、纳米多功能助剂等系列纳米材料,利用纳米仿生技术分散在涂料混合体系中的绿色环保型建筑涂料。纳米乳胶漆具有释放负离子、优化空气质量、无毒无味、健康环保、净化环境、清新空气、抗菌防霉、疏水耐污等性能,被广泛应用。
现有的纳米乳胶漆使用后,在长期低温的环境下容易发生强度降低,干裂的现象,在低温稳定性、耐刷洗性和施工性方面的性能还有待提升。
发明内容
本发明提供一种纳米乳胶漆及其制备方法,旨在解决现有的纳米乳胶漆的低温稳定性差的问题。
本发明是这样实现的,一种纳米乳胶漆,由以下质量百分含量的各组分组成:水20%~25%、润湿剂0.1%~0.5%、羟乙基纤维素0.1%~0.5%、金红石钛白粉7%~15%、煅烧高岭土5%~10%、重钙粉10%~15%、硅灰石粉3%~8%、丙二醇1%~2%、硅丙乳液30%~35%、分散剂0.5%~1%、防腐杀菌剂0.1%~0.3%、消泡剂0.1%~0.3%、流平剂0.1%~0.5%、增稠剂0.1%~0.5%、纳米二氧化硅1%~2%、纳米二氧化钛0.5%~2%、AMP-95 0.1%~0.5%。
更进一步地,所述润湿剂为PE-100。
更进一步地,所述羟乙基纤维素的粘度为10万~15万。
更进一步地,所述重钙粉的细度为300目~600目。
更进一步地,所述分散剂为5040分散剂。
更进一步地,所述增稠剂为聚丙烯酸酯增稠剂或聚氨酯增稠剂。
更进一步地,由以下质量百分含量的各组分组成:水23.5%、润湿剂0.1%、羟乙基纤维素0.3%、金红石钛白粉11.5%、煅烧高岭土6.5%、重钙粉14.5%、硅灰石粉5.5%、丙二醇1.5%、硅丙乳液32.5%、分散剂0.6%、防腐杀菌剂0.1%、消泡剂0.2%、流平剂0.3%、增稠剂0.3%、纳米二氧化硅1.4%、纳米二氧化钛1%、AMP-95 0.2%。
本发明还提供该纳米乳胶漆的制备方法,包括:
将各组分按相应的质量百分含量称量配料,向分散机中加入水,在不断搅拌下,依次加入润湿剂、丙二醇、分散剂、防腐杀菌剂、消泡剂、流平剂和AMP-95混合均匀,得到混合液体a;
提高分散机转速,在不断搅拌下,向混合液体a中加入金红石钛白粉、煅烧高岭土、重钙粉、硅灰石粉、纳米二氧化硅和纳米二氧化钛混合均匀,得到混合液体b;
降低分散机转速,在不断搅拌下,向混合液体b中加入硅丙乳液混合均匀,得到混合液体c;
向混合液体c中加入羟乙基纤维素和增稠剂达到指标粘度,得到所述纳米乳胶漆。
本发明提供的纳米乳胶漆,其中,润湿剂能够降低纳米乳胶漆与水界面间的表面张力,羟乙基纤维素能够提高纳米乳胶漆的表面粘度,改变纳米乳胶漆的流动性。金红石钛白粉、重钙粉和硅灰石粉能够提高纳米乳胶漆的遮盖力和消色力,煅烧高岭土能够提高纳米乳胶漆的消光效果。丙二醇能够改善纳米乳胶漆的抗冻性,使其经受多次冻融循环后,强度也不会显著降低。硅丙乳液具有很好的成膜特性,分散剂具有一定的空间位阻,由于静电效应作用,能够使各固相组分均匀分散在液相组分中。防腐杀菌剂能够防止纳米乳胶漆贮存在容器中时发生腐败或感染霉菌,避免降低品质。消泡剂能够消除纳米乳胶漆在生产和施工过程中产生的泡沫,提升涂膜时的光洁度。流平剂能够提高抗碱封底漆的机械稳定性和物理化学稳定性,增稠剂能够进一步提高纳米乳胶漆表面的粘度,防止其在贮存过程中发生沉淀。纳米二氧化硅能够大幅度提高纳米乳胶漆的耐老化性和贮存稳定性,使其对紫外光、红外线和可见光都具有极强的反射性。纳米二氧化钛由于具有纳米粒径,其比表面积大,光吸收性能好,光催化性能显著,还具有抗菌、杀菌、净化空气的作用,将其应用于纳米乳胶漆中能够减弱漆膜遭受紫外线的侵蚀,提高漆膜的色彩鲜艳度,提升纳米乳胶漆的抗老化性能和耐擦洗性,从而提高纳米乳胶漆的品质。AMP-95作为pH调节剂能够提升纳米乳胶漆中各组分的分散性,从而提升体系稳定性。本发明提供的纳米乳胶漆具有良好的施工性、低温稳定性、耐沾污性、耐洗刷性和耐碱性。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下通过实施例对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
实施例一
本发明实施例提供的一种纳米乳胶漆,由以下质量百分含量的各组分组成:水23.5%、润湿剂0.1%、羟乙基纤维素0.3%、金红石钛白粉11.5%、煅烧高岭土6.5%、重钙粉14.5%、硅灰石粉5.5%、丙二醇1.5%、硅丙乳液32.5%、分散剂0.6%、防腐杀菌剂0.1%、消泡剂0.2%、流平剂0.3%、增稠剂0.3%、纳米二氧化硅1.4%、纳米二氧化钛1%、AMP-95 0.2%。
其中,润湿剂为PE-100,羟乙基纤维素的粘度为10万,重钙粉的细度为400目,分散剂为5040分散剂,增稠剂为聚丙烯酸酯增稠剂。
实施例二
本发明实施例提供的一种纳米乳胶漆,由以下质量百分含量的各组分组成:水21%、润湿剂0.5%、羟乙基纤维素0.2%、金红石钛白粉15%、煅烧高岭土6%、重钙粉15%、硅灰石粉4%、丙二醇2%、硅丙乳液31%、分散剂1%、防腐杀菌剂0.2%、消泡剂0.3%、流平剂0.2%、增稠剂0.5%、纳米二氧化硅1%、纳米二氧化钛2%、AMP-95 0.1%。
其中,润湿剂为PE-100,羟乙基纤维素的粘度为15万,重钙粉的细度为300目,分散剂为5040分散剂,增稠剂为聚丙烯酸酯增稠剂。
实施例三
本发明实施例提供的一种纳米乳胶漆,由以下质量百分含量的各组分组成:水25%、润湿剂0.1%、羟乙基纤维素0.4%、金红石钛白粉7%、煅烧高岭土9%、重钙粉10%、硅灰石粉8%、丙二醇1%、硅丙乳液35%、分散剂0.5%、防腐杀菌剂0.3%、消泡剂0.1%、流平剂0.5%、增稠剂0.1%、纳米二氧化硅2%、纳米二氧化钛0.5%、AMP-95 0.5%。
其中,润湿剂为PE-100,羟乙基纤维素的粘度为10万,重钙粉的细度为500目,分散剂为5040分散剂,增稠剂为聚氨酯增稠剂。
实施例四
本发明实施例提供的一种纳米乳胶漆,由以下质量百分含量的各组分组成:水23%、润湿剂0.3%、羟乙基纤维素0.3%、金红石钛白粉11%、煅烧高岭土7%、重钙粉14%、硅灰石粉5%、丙二醇1.5%、硅丙乳液33%、分散剂0.8%、防腐杀菌剂0.2%、消泡剂0.3%、流平剂0.4%、增稠剂0.3%、纳米二氧化硅1.6%、纳米二氧化钛1%、AMP-95 0.3%。
其中,润湿剂为PE-100,羟乙基纤维素的粘度为15万,重钙粉的细度为600目,分散剂为5040分散剂,增稠剂为聚氨酯增稠剂。
本发明实施例一至四的纳米乳胶漆的制备方法均为:
将各组分按相应的质量百分含量称量配料,向分散机中加入水,控制分散机的转速为500r/min~600r/min,在不断搅拌下,依次加入润湿剂、丙二醇、分散剂、防腐杀菌剂、消泡剂、流平剂和AMP-95混合均匀,得到混合液体a;
控制分散机的转速为1200r/min~1500r/min,在不断搅拌下,向混合液体a中加入金红石钛白粉、煅烧高岭土、重钙粉、硅灰石粉、纳米二氧化硅和纳米二氧化钛混合均匀,得到混合液体b;
控制分散机的转速为500r/min~700r/min,在不断搅拌下,向混合液体b中加入硅丙乳液混合均匀,得到混合液体c;
向混合液体c中加入羟乙基纤维素和增稠剂达到指标粘度,得到所述纳米乳胶漆。
将本发明实施例一至四的纳米乳胶漆进行检测,得到的检测结果如下表所示。
Figure BDA0002252340170000061
由上表可知,本发明实施例一至四的纳米乳胶漆具有良好的稳定性、施工性、低温稳定性、耐沾污性、耐洗刷性、耐碱性和涂层耐温变性,各项检测均符合检测依据的合格标准。
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。

Claims (8)

1.一种纳米乳胶漆,其特征在于,由以下质量百分含量的各组分组成:水20%~25%、润湿剂0.1%~0.5%、羟乙基纤维素0.1%~0.5%、金红石钛白粉7%~15%、煅烧高岭土5%~10%、重钙粉10%~15%、硅灰石粉3%~8%、丙二醇1%~2%、硅丙乳液30%~35%、分散剂0.5%~1%、防腐杀菌剂0.1%~0.3%、消泡剂0.1%~0.3%、流平剂0.1%~0.5%、增稠剂0.1%~0.5%、纳米二氧化硅1%~2%、纳米二氧化钛0.5%~2%、AMP-950.1%~0.5%。
2.如权利要求1所述的纳米乳胶漆,其特征在于,所述润湿剂为PE-100。
3.如权利要求1所述的纳米乳胶漆,其特征在于,所述羟乙基纤维素的粘度为10万~15万。
4.如权利要求1所述的纳米乳胶漆,其特征在于,所述重钙粉的细度为300目~600目。
5.如权利要求1所述的纳米乳胶漆,其特征在于,所述分散剂为5040分散剂。
6.如权利要求1所述的纳米乳胶漆,其特征在于,所述增稠剂为聚丙烯酸酯增稠剂或聚氨酯增稠剂。
7.如权利要求1~6任一项所述的纳米乳胶漆,其特征在于,由以下质量百分含量的各组分组成:水23.5%、润湿剂0.1%、羟乙基纤维素0.3%、金红石钛白粉11.5%、煅烧高岭土6.5%、重钙粉14.5%、硅灰石粉5.5%、丙二醇1.5%、硅丙乳液32.5%、分散剂0.6%、防腐杀菌剂0.1%、消泡剂0.2%、流平剂0.3%、增稠剂0.3%、纳米二氧化硅1.4%、纳米二氧化钛1%、AMP-95 0.2%。
8.权利要求1所述的纳米乳胶漆的制备方法,其特征在于,包括:
将各组分按相应的质量百分含量称量配料,向分散机中加入水,在不断搅拌下,依次加入润湿剂、丙二醇、分散剂、防腐杀菌剂、消泡剂、流平剂和AMP-95混合均匀,得到混合液体a;
提高分散机转速,在不断搅拌下,向混合液体a中加入金红石钛白粉、煅烧高岭土、重钙粉、硅灰石粉、纳米二氧化硅和纳米二氧化钛混合均匀,得到混合液体b;
降低分散机转速,在不断搅拌下,向混合液体b中加入硅丙乳液混合均匀,得到混合液体c;
向混合液体c中加入羟乙基纤维素和增稠剂达到指标粘度,得到所述纳米乳胶漆。
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111534184A (zh) * 2020-06-05 2020-08-14 郑希超 一种抗污环保乳胶漆及其制备方法
CN111704839A (zh) * 2020-07-16 2020-09-25 江门市锦富百年建材有限公司 一种多功能涂料
CN112608684A (zh) * 2020-12-10 2021-04-06 西洞庭凯兴建材有限公司 一种室内装修用抗菌无害乳胶漆的加工方法
CN113817367A (zh) * 2021-11-08 2021-12-21 南京红枫环保材料有限公司 一种环保纳米乳胶漆涂料制备方法及系统
CN114213973A (zh) * 2021-12-09 2022-03-22 河南三棵树新材料科技有限公司 一种柔光耐擦内墙乳胶漆及其制备方法
CN115232526A (zh) * 2021-05-06 2022-10-25 湖南国彩新材料有限公司 一种纳米改性路桥防护涂料及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1431266A (zh) * 2003-01-20 2003-07-23 湖南大学 多功能纳米建筑外墙涂料及其制备方法
CN1923913A (zh) * 2005-11-02 2007-03-07 中科纳米涂料技术(苏州)有限公司 自清洁纳米复合环保型乳胶漆及其制备方法
CN101338164A (zh) * 2008-08-18 2009-01-07 中山市三和气雾有限公司 电脑调色基础漆
CN103468081A (zh) * 2013-08-14 2013-12-25 青岛益群漆业集团有限公司 纳米罩光自洁涂料
CN107760136A (zh) * 2017-11-21 2018-03-06 清远市思晴新材料科技有限公司 一种纳米改性硅丙耐侯性外墙负离子涂料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1431266A (zh) * 2003-01-20 2003-07-23 湖南大学 多功能纳米建筑外墙涂料及其制备方法
CN1923913A (zh) * 2005-11-02 2007-03-07 中科纳米涂料技术(苏州)有限公司 自清洁纳米复合环保型乳胶漆及其制备方法
CN101338164A (zh) * 2008-08-18 2009-01-07 中山市三和气雾有限公司 电脑调色基础漆
CN103468081A (zh) * 2013-08-14 2013-12-25 青岛益群漆业集团有限公司 纳米罩光自洁涂料
CN107760136A (zh) * 2017-11-21 2018-03-06 清远市思晴新材料科技有限公司 一种纳米改性硅丙耐侯性外墙负离子涂料及其制备方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111534184A (zh) * 2020-06-05 2020-08-14 郑希超 一种抗污环保乳胶漆及其制备方法
CN111704839A (zh) * 2020-07-16 2020-09-25 江门市锦富百年建材有限公司 一种多功能涂料
CN112608684A (zh) * 2020-12-10 2021-04-06 西洞庭凯兴建材有限公司 一种室内装修用抗菌无害乳胶漆的加工方法
CN115232526A (zh) * 2021-05-06 2022-10-25 湖南国彩新材料有限公司 一种纳米改性路桥防护涂料及其制备方法
CN113817367A (zh) * 2021-11-08 2021-12-21 南京红枫环保材料有限公司 一种环保纳米乳胶漆涂料制备方法及系统
CN114213973A (zh) * 2021-12-09 2022-03-22 河南三棵树新材料科技有限公司 一种柔光耐擦内墙乳胶漆及其制备方法

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