CN110607107A - Environment-friendly jasmine flower painting pigment and production method thereof - Google Patents
Environment-friendly jasmine flower painting pigment and production method thereof Download PDFInfo
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- CN110607107A CN110607107A CN201910993101.6A CN201910993101A CN110607107A CN 110607107 A CN110607107 A CN 110607107A CN 201910993101 A CN201910993101 A CN 201910993101A CN 110607107 A CN110607107 A CN 110607107A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/02—Starch; Degradation products thereof, e.g. dextrin
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention relates to the technical field of pigment production processes, in particular to an environment-friendly jasmine flower painting pigment and a production method thereof, wherein the environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight: 5-10 parts of jasmine flower powder; 25-35 parts of polyacrylic acid emulsion; 10-15 parts of pigment powder; 5-7 parts of locust bean gum; 0.5-1 part of graphene; 25-35 parts of potato starch; 3-5 parts of glycerol; 1-1.5 parts of ethylparaben; 1-1.5 parts of maltodextrin; 0.5-1.0 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.1-0.2 part of stabilizer; 35-45 parts of distilled water. The jasmine flower painting pigment prepared by the invention does not contain harmful substances, is safe and environment-friendly, has strong tinting strength, is resistant to high temperature and humid environments, has good mildew resistance, is not easy to fall off and change color when being illuminated, and has a jasmine flower fragrance.
Description
Technical Field
The invention relates to the technical field of pigment production processes, in particular to an environment-friendly jasmine flower painting pigment and a production method thereof.
Background
The pigment is a powdery substance for coloring which is insoluble in a medium such as water, oil, resin or organic solvent, but can be uniformly dispersed in the medium to color the medium, and has a certain hiding power. Pigments are commonly used materials in art design and are in many kinds. Since ancient times, the source of pigments has been classified mainly into pigments of mineral origin, pigments of vegetable or animal origin and pigments of modern chemical synthesis. The colorful pigment creates colorful color world and art, and is the most precious cultural treasure up to now. The pigment is colored fine particle powdery substance, and can be divided into inorganic pigment and organic pigment from chemical composition, wherein the inorganic pigment mainly comprises metal oxide, chromate, carbonate, sulfate, sulfide and the like, and can also be divided into metal pigment, white covering pigment, coloring pigment, antirust pigment and the like, and the pigment is the pigment with the largest application amount and the widest application range in the coating industry; they can be classified into natural pigments and synthetic pigments from raw material sources.
The pigment is a commonly used art product and can be divided into traditional Chinese painting pigment, oil painting pigment and gouache pigment; the art pigment basically requires that the finer the particles, the brighter the color, and the longer the color, the better the color will not change (the better the stability). Some organic pigments and synthetic pigments contain formaldehyde, have certain toxicity, are inconvenient to use in practice, and are particularly dangerous when used by children; and the existing pigments are relatively complex in manufacturing work, so that the production efficiency of the pigments is relatively low, and the actual use requirements cannot be met. The common pigments in the current market have the defects that most of the pigments are made of chemical raw materials, the pigments are not healthy and environment-friendly enough, the colors are not natural enough, the existing painting pigments have the problems of large dry-wet color difference and unsmooth painting, and the aging problems of yellowing of a coating film and the like can occur when works are stored for a long time under the action of air, water and ultraviolet lamps; meanwhile, the problems of mildew and the like easily occur due to improper storage, the common pigment on the market does not have special smell such as fragrance, and the made picture works have visual perception and no olfactory perception.
Disclosure of Invention
The invention aims to provide an environment-friendly jasmine flower painting pigment and a production method thereof, aiming at the defects of art painting pigments in the prior art. The jasmine flower painting pigment prepared by the method does not contain harmful substances, is safe and environment-friendly, has strong tinting strength, high temperature and humidity resistance and good mildew resistance, is not easy to fall off and change color when being illuminated, and has a jasmine flower fragrance.
In order to achieve the purpose, the invention adopts the following technical scheme:
the environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight:
5-10 parts of jasmine flower powder; 25-35 parts of polyacrylic acid emulsion; 10-15 parts of pigment powder; 5-7 parts of locust bean gum; 0.5-1 part of graphene; 25-35 parts of potato starch; 3-5 parts of glycerol; 1-1.5 parts of ethylparaben; 1-1.5 parts of maltodextrin; 0.5-1.0 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.1-0.2 part of stabilizer; 35-45 parts of distilled water.
According to the environment-friendly jasmine flower painting pigment, the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve. The jasmine flower powder added into the pigment can endow the pigment jasmine flower with the fragrance, and has the effect of removing peculiar smell.
In the environment-friendly jasmine flower painting pigment, the pigment powder is natural plant pigment, and comprises one or more of indigo blue, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, roselle red, plant carbon black or cherokee rose brown.
In the environment-friendly jasmine flower painting pigment, the stabilizer is disodium stannous citrate.
The production method of the environment-friendly jasmine flower painting pigment comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1-1.5 hours at 70-75 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 5-10min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 3-5 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
The polyacrylic acid emulsion used in the invention is milky viscous liquid which is easy to dissolve in water, and the solid content of the polyacrylic acid emulsion is 38-40%. The locust bean gum, also called locust bean gum, is a plant seed gum prepared from locust tree seeds produced in Mediterranean sea, is white or yellowish powder of macromolecular polysaccharide polymer formed by combining galactose and mannose units through glycosidic bond, and can be dispersed in cold water to partially dissolve to form sol, and completely dissolve at 80 deg.C. Locust bean gum interacts with agar, carrageenan and xanthan gum, which can form a complex in solution to enhance the gel effect. The food industry uses predominantly locust bean gum, which has the ability to bind large amounts of water, for dairy products and frozen desserts. Is usually compounded with other thickeners to be used as a thickener, a water holding agent, an adhesive, an emulsifier, a gelling agent and the like.
Graphene (Graphene) used in the invention is a two-dimensional carbon nanomaterial with a hexagonal honeycomb lattice formed by sp hybridized orbits of carbon atoms, is one of materials with the highest known strength, has good toughness and can be bent, has excellent optical, electrical and mechanical properties, and has an important application prospect in the aspects of materials science, micro-nano processing, energy, biomedicine, drug delivery and the like. The graphene is used as a raw material to prepare the pigment, so that the conductive performance and the antistatic performance of a product can be improved, the painting is not easy to adsorb dust, and the performance indexes of the pigment, such as friction resistance, hardness, adhesive force and the like, can be improved.
Ethylparaben, also known as ethylparaben, having a molecular formula C9H10O3Colorless crystals or white crystalline powder, slight flavor, slightly astringent. Parabens are one of the commonly used preservatives, which inhibit the activity of the respiratory and delivery enzyme systems of microbial cells and destroy the cell membrane machinery of the microbes, thus having a wide range of antibacterial effects against molds, yeasts and bacteria. The ethylparaben is a substance with strong bactericidal property, the phenol coefficient is 8.0, the toxicity is extremely low, the ethylparaben has no stimulation to human skin, the antibacterial ability of the ethylparaben is stronger than that of sorbic acid and benzoic acid, and the antibacterial effect is influenced by phThe influence of the value is small, and the effect is good in the range of ph value 4-8. The ethylparaben is added during the preparation of the pigment, so that the antibacterial performance of the pigment can be improved, and the pigment can resist a humid environment and is not easy to mildew and deteriorate.
The 5-chloro-2-methyl-4-isothiazoline-3-ketone is a high-activity bactericide, the minimum inhibitory concentration of the bactericide on a plurality of microorganisms is below 10mg/l, the bactericide has extremely strong killing and inhibiting effects on bacteria, mould, yeast and algae, and the bactericide is effective at low concentration. The product has good safety, low toxicity classification, biodegradability, no teratogenic and mutagenic reaction, is easily biodegraded into nontoxic and pollution-free substances after being diluted to use concentration, and is relatively stable in acidic and oxidative environments; the additive can prevent the putrefaction and deterioration of the pigment, improve the antiseptic property of the pigment and make the coating film have the capability of resisting the attack of mould.
The disodium stannous citrate is a food additive, has the functions of resisting oxidation, preventing corrosion and protecting color, and maintains the color quality and flavor of food. The invention adopts the disodium stannous citrate as one of the raw materials, can increase the stability of the mixture, slow down the reaction, keep the chemical balance, reduce the surface tension, prevent the effects of light, thermal decomposition or oxidative decomposition and the like.
The invention has the beneficial effects that:
1. the environment-friendly jasmine flower painting pigment and the production method thereof have the advantages that the used raw materials are safe and environment-friendly, the formaldehyde is not contained, and no toxic or harmful gas is generated in the using process. The prepared painting pigment has excellent performance, good texture, no toxicity and no pollution, and the total content of benzene, toluene, ethylbenzene and xylene, free formaldehyde, the content of Volatile Organic Compounds (VOC) and the content of migratable heavy metals in the pigment all meet the requirement of environmental protection.
2. According to the invention, the jasmine flower powder is used as the raw material to prepare the painting pigment, so that the prepared pigment has light jasmine flower fragrance, and the effect of removing peculiar smell is achieved to a certain extent.
3. According to the invention, ethylparaben and 5-chloro-2-methyl-4-isothiazolin-3-one are added during the preparation of the pigment, so that the antibacterial and mildew-proof performance of the prepared pigment can be greatly improved, and the prepared pigment is resistant to a humid environment and is not easy to breed mildew in the humid environment after being used for drawing.
4. The environment-friendly jasmine flower painting pigment prepared by the invention has bright color, strong tinting strength, high temperature and humidity resistance, is not easy to fall off and change color when being illuminated by light, has better durability, is not embrittled and yellowed, has better high color retention, and is natural in color and not easy to mildew during storage.
5. The environment-friendly jasmine flower painting pigment prepared by the invention does not contain substances harmful to human bodies, such as toxic heavy metals or formaldehyde, is safe and environment-friendly, and has stable quality, strong tinting strength, bright color, good stability and convenient painting use; meets the requirements of people on safety and painting effect, and is suitable for industrial production.
Detailed Description
Example 1
The environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight:
5 parts of jasmine flower powder; 25 parts of polyacrylic acid emulsion; 10 parts of pigment powder; 5 parts of locust bean gum; 0.5 part of graphene; 25 parts of potato starch; 3 parts of glycerol; 1 part of ethylparaben; 1 part of maltodextrin; 0.5 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.1 part of stabilizer disodium stannous citrate; 35 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is lemon yellow.
The production method of the environment-friendly jasmine flower painting pigment comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1.5 hours at 70 ℃, then heating to 90 ℃ for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 5min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 3 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
Example 2
The environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight:
7 parts of jasmine flower powder; 30 parts of polyacrylic acid emulsion; 12 parts of pigment powder; 6 parts of locust bean gum; 0.7 part of graphene; 30 parts of potato starch; 4 parts of glycerol; 1.2 parts of ethylparaben; 1.3 parts of maltodextrin; 0.8 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.15 part of stabilizer disodium stannous citrate; 40 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is alkannin.
The production method of the environment-friendly jasmine flower painting pigment comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1.2 hours at 72 ℃, then heating to 90 ℃ for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 8min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 4 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
Example 3
The environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight:
10 parts of jasmine flower powder; 35 parts of polyacrylic acid emulsion; 15 parts of pigment powder; 7 parts of locust bean gum; 1 part of graphene; 35 parts of potato starch; 5 parts of glycerol; 1.5 parts of ethylparaben; 1.5 parts of maltodextrin; 1.0 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.2 part of stabilizer disodium stannous citrate; 45 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is one of indigo, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, roselle red, plant carbon black or cherokee rose brown.
The production method of the environment-friendly jasmine flower painting pigment comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1 hour at 75 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 10min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 5 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
Example 4
The environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight:
9 parts of jasmine flower powder; 32 parts of polyacrylic acid emulsion; 12 parts of pigment powder; 6 parts of locust bean gum; 0.6 part of graphene; 31 parts of potato starch; 4 parts of glycerol; 1.3 parts of ethylparaben; 1.4 parts of maltodextrin; 0.8 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.16 part of stabilizer disodium stannous citrate; 41 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is prepared from alkannin and capsanthin.
The production method of the environment-friendly jasmine flower painting pigment comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1 hour at 70-75 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 5-10min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 5 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
Example 5
The environment-friendly jasmine flower painting pigment comprises the following raw materials in parts by weight:
6 parts of jasmine flower powder; 28 parts of polyacrylic acid emulsion; 11 parts of pigment powder; 6 parts of locust bean gum; 0.6 part of graphene; 30 parts of potato starch; 4 parts of glycerol; 1.2 parts of ethylparaben; 1 part of maltodextrin; 0.6 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.12 part of stabilizer disodium stannous citrate; 39 parts of distilled water; the jasmine flower powder is obtained by drying fresh jasmine flowers, carrying out superfine grinding and sieving with a 800-mesh sieve; the pigment powder is natural plant pigment, including one or more of indigo blue, gardenia blue, lemon yellow, curcumin, seabuckthorn yellow, alkannin, beet red, capsanthin, hibiscus sabdariffa red, plant carbon black or cherokee rose brown.
The production method of the environment-friendly jasmine flower painting pigment comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1.5 hours at 70-75 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 5-10min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 4 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
Performance testing
The environment-friendly jasmine flower painting pigment prepared in the embodiment 2 of the invention is subjected to performance test, and the results are shown in the following table 1.
As can be seen from the above table 1, the environment-friendly jasmine flower painting pigment prepared by the invention is fine and smooth, and has good light resistance and heat resistance, and good cold resistance and mildew resistance.
Claims (5)
1. The environment-friendly jasmine flower painting pigment is characterized by comprising the following raw materials in parts by weight:
5-10 parts of jasmine flower powder; 25-35 parts of polyacrylic acid emulsion; 10-15 parts of pigment powder; 5-7 parts of locust bean gum; 0.5-1 part of graphene; 25-35 parts of potato starch; 3-5 parts of glycerol; 1-1.5 parts of ethylparaben; 1-1.5 parts of maltodextrin; 0.5-1.0 part of 5-chloro-2-methyl-4-isothiazolin-3-one; 0.1-0.2 part of stabilizer; 35-45 parts of distilled water.
2. The environment-friendly jasmine flower drawing pigment according to claim 1, wherein the jasmine flower powder is obtained by drying fresh jasmine flowers, micronizing, and sieving with 800-mesh sieve.
3. The environment-friendly jasmine painting pigment as claimed in claim 1, wherein the pigment powder is natural plant pigment including one or more of indigo blue, gardenia blue, lemon yellow, curcumin, sea buckthorn yellow, alkannin, beet red, capsanthin, hibiscus sabdariffa red, plant carbon black or cherokee rose brown.
4. The environment-friendly jasmine painting pigment according to claim 1, wherein the stabilizer is disodium stannous citrate.
5. The environment-friendly jasmine painting pigment according to claim 1, wherein the production method comprises the following steps:
(1) adding locust bean gum and maltodextrin into water according to parts by weight, stirring and swelling for 1-1.5 hours at 70-75 ℃, then heating to 90 ℃, and heating for 30 minutes to obtain viscous liquid;
(2) standing the obtained viscous liquid to normal temperature, adding polyacrylic acid emulsion, pigment powder, potato starch, graphene and ethylparaben, stirring for 5-10min, then sequentially adding jasmine flower powder, 5-chloro-2-methyl-4-isothiazoline-3-ketone, stabilizer and glycerol under the stirring condition, and mixing and stirring uniformly to obtain a crude slurry;
(3) and adding the coarse slurry into a hopper of a three-roller grinder, and grinding for 3-5 times by the three-roller grinder to obtain the environment-friendly jasmine flower painting pigment.
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CN112745724A (en) * | 2020-12-30 | 2021-05-04 | 上海持凡文化传播有限公司 | Environment-friendly durable wall painting propylene pigment and preparation method thereof |
CN115386266A (en) * | 2022-10-17 | 2022-11-25 | 湖南师范大学 | Environment-friendly odor-free art painting pigment and preparation method thereof |
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CN109401396A (en) * | 2018-11-05 | 2019-03-01 | 陈琼燕 | Metope drawing pigment with jasmin and preparation method thereof |
CN109401500A (en) * | 2018-11-05 | 2019-03-01 | 陈琼燕 | A kind of drawing acrylic paints of the pollen containing jasmine and preparation method thereof |
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Patent Citations (3)
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CN107325668A (en) * | 2017-07-24 | 2017-11-07 | 宁波墨西科技有限公司 | Acrylic paints of graphene-containing and preparation method thereof |
CN109401396A (en) * | 2018-11-05 | 2019-03-01 | 陈琼燕 | Metope drawing pigment with jasmin and preparation method thereof |
CN109401500A (en) * | 2018-11-05 | 2019-03-01 | 陈琼燕 | A kind of drawing acrylic paints of the pollen containing jasmine and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112745724A (en) * | 2020-12-30 | 2021-05-04 | 上海持凡文化传播有限公司 | Environment-friendly durable wall painting propylene pigment and preparation method thereof |
CN115386266A (en) * | 2022-10-17 | 2022-11-25 | 湖南师范大学 | Environment-friendly odor-free art painting pigment and preparation method thereof |
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