CN110592932A - Preparation method of flame-retardant coated fabric - Google Patents

Preparation method of flame-retardant coated fabric Download PDF

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Publication number
CN110592932A
CN110592932A CN201910787659.9A CN201910787659A CN110592932A CN 110592932 A CN110592932 A CN 110592932A CN 201910787659 A CN201910787659 A CN 201910787659A CN 110592932 A CN110592932 A CN 110592932A
Authority
CN
China
Prior art keywords
aluminum hydroxide
base cloth
fabric
soaking barrel
base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910787659.9A
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Chinese (zh)
Inventor
朱小华
许生军
朱鑫丽
奚香楠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Textile Polytron Technologies Inc
Original Assignee
Zhejiang Textile Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Textile Polytron Technologies Inc filed Critical Zhejiang Textile Polytron Technologies Inc
Priority to CN201910787659.9A priority Critical patent/CN110592932A/en
Publication of CN110592932A publication Critical patent/CN110592932A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30Flame or heat resistance, fire retardancy properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention belongs to the field of coated fabrics, in particular to a preparation method of flame-retardant coated fabric, which aims at solving the problems that the existing coated fabric has relatively poor flame-retardant performance on a base fabric, has large use limitation and is easy to cause poor coating firmness and stability of the coated fabric in the coating process, and provides the following scheme, which comprises the following steps: grinding aluminum hydroxide into powder particles by using a grinder, then putting the aluminum hydroxide into a soaking barrel, then pouring distilled water into the soaking barrel to form an aluminum hydroxide aqueous solution, S2: the base cloth woven by the blended yarn of 60% terylene and 40% spandex is put into a soaking barrel, the reinforcing layer, the base cloth and the scratch-resistant layer are respectively soaked in an aqueous solution of aluminum hydroxide, and then the reinforcing layer, the base cloth and the scratch-resistant layer are pressed by a press machine, so that the flame retardance can be effectively improved, the use limitation is greatly reduced, and the wear resistance and the stability of the coated cloth can be improved.

Description

Preparation method of flame-retardant coated fabric
Technical Field
The invention relates to the technical field of coated fabrics, in particular to a preparation method of flame-retardant coated fabric.
Background
The coated fabric is mainly characterized in that a layer of material with special functions is coated on the basis of the fabric by adopting a special process, so that the fabric is added with special functions. And is also referred to as a functional coating facing. The coated fabric has three types of PVC coating, PU coating and semi-PU coating according to different coating materials, and mercerized leather, matte, anti-genuine leather, wrinkled leather and the like according to different coating processes. Classified according to functions and characteristics, the paint is color glue, PVC, silver, calendering, flame retardant, PA moisture permeable, PU moisture permeable and transparent, and the like.
In the prior art, the flame retardant property of the coated fabric on the base fabric is relatively poor, the use limitation is large, and the wear resistance and stability of the coated fabric are poor easily in the coating process, so a preparation method of the flame retardant coated fabric is provided for solving the problems.
Disclosure of Invention
Based on the technical problems that the flame retardant property of the coated fabric on the base fabric is relatively poor, the use limitation is large, and the coating firmness and stability of the coated fabric are poor easily in the coating process in the background technology, the invention provides a preparation method of the flame retardant coated fabric.
The invention provides a preparation method of flame-retardant coated fabric, which comprises the following steps:
s1: grinding aluminum hydroxide into powdery particles by using a grinder, then putting the aluminum hydroxide into a soaking barrel, and then pouring distilled water into the soaking barrel to form an aluminum hydroxide aqueous solution;
s2: putting base cloth woven by 60% of terylene and 40% of spandex blended yarn into a soaking barrel, and then stirring the base cloth by using a stirrer for 50 minutes;
s3: taking out the soaked base cloth from the soaking barrel, and drying the base cloth by using a dryer;
s4: putting the dried base cloth on an ironing machine, and removing wrinkles of the base cloth by using the ironing machine;
s5: putting the reinforcing layer and the base cloth into a press machine, and setting the pressure of the press machine to be 20 KPa;
s6: the scratch-resistant layer, the base fabric, and the reinforcing layer were put into a press, and the pressure value of the press was set to 20 KPa.
Preferably, in S1, after the aluminum hydroxide is ground into powder, the aluminum hydroxide is screened by a 200-mesh screen, and the ratio of the aluminum hydroxide to the distilled water is 3: 100.
preferably, in S2, the rotation speed of the stirrer is 50r/min-250r/min, and after each rotation period is finished, the stirrer is kept standing for 5min-9 min.
Preferably, in the step S3, the temperature of the dryer is 45 ℃, the wind speed is 5m/S, and the cloth moving speed of the dryer is 10/min.
Preferably, in S3, after the base fabric is dried by the dryer, the base fabric is placed on a widening machine to perform preliminary leveling on the fabric.
Preferably, in S4, the temperature set by the ironing machine is 130 degrees celsius, and the pressure set by the ironing machine is 30 KPa.
Preferably, in S5, the reinforcing layer selects nitrile rubber as a base material, nitrile is placed in the water solution of aluminum hydroxide in the soaking barrel, the nitrile rubber is stirred by a stirrer and then dried by a dryer, the nitrile rubber is put into a hot melting machine, the temperature in the hot melting machine is set to 120 ℃, the molten nitrile rubber is poured into an extruder, and the nitrile is extruded into a piece of nitrile cloth with a thickness of 3 mm.
Preferably, in S6, the anti-scratch layer is made of ultra-high strength fibers, the ultra-high strength fibers are placed in a soaking barrel and fused with an aqueous solution of aluminum hydroxide, and then 1% of an anti-aging agent is poured into the soaking barrel.
The invention has the beneficial effects that:
sequentially placing a base cloth, a reinforcing layer and an anti-scratching layer into a soaking barrel respectively to enable aqueous solution of aluminum hydroxide to be attached to the base cloth, the reinforcing layer and the anti-scratching layer, drying the base cloth by using a dryer, transversely flattening the base cloth by using a widening machine, placing the base cloth on an ironing machine, flattening the base cloth by using the ironing machine, placing butadiene rubber as a base material for the reinforcing layer, placing the butadiene rubber into the soaking barrel to be located in the aqueous solution of the aluminum hydroxide, stirring the butadiene rubber by using a stirrer, drying by using the dryer, placing the butadiene rubber into a hot melting machine, setting the temperature in the hot melting machine to be 120 ℃, pouring the butadiene rubber after hot melting into an extruder, extruding the butadiene rubber into the butadiene rubber with the thickness of 3mm, extruding the anti-scratching layer by using ultrahigh-strength fibers as the base material, placing the ultrahigh-strength fibers into the soaking barrel to be fused with the aqueous solution of the aluminum hydroxide, and then pouring 1% of anti-aging agent into the soaking barrel, and finally respectively pressing the reinforcing layer and the anti-scratch layer with the two sides of the base fabric.
According to the invention, the reinforcing layer, the base cloth and the anti-scratching layer are respectively soaked in the aqueous solution of aluminum hydroxide, and then the reinforcing layer, the base cloth and the anti-scratching layer are pressed by a press machine, so that the flame retardance can be effectively improved, the use limitation is greatly reduced, and the wear resistance and the stability of the coated cloth can be improved.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples.
Examples
The embodiment provides a preparation method of flame-retardant coated fabric, which comprises the following steps:
s1: grinding aluminum hydroxide into powdery particles by using a grinder, then putting the aluminum hydroxide into a soaking barrel, and then pouring distilled water into the soaking barrel to form an aluminum hydroxide aqueous solution;
s2: putting base cloth woven by 60% of terylene and 40% of spandex blended yarn into a soaking barrel, and then stirring the base cloth by using a stirrer for 50 minutes;
s3: taking out the soaked base cloth from the soaking barrel, and drying the base cloth by using a dryer;
s4: putting the dried base cloth on an ironing machine, and removing wrinkles of the base cloth by using the ironing machine;
s5: putting the reinforcing layer and the base cloth into a press machine, and setting the pressure of the press machine to be 20 KPa;
s6: the scratch-resistant layer, the base fabric, and the reinforcing layer were put into a press, and the pressure value of the press was set to 20 KPa.
In this embodiment, in S1, after aluminum hydroxide is ground into powder, a 200-mesh screen is used to screen the aluminum hydroxide, and the ratio of aluminum hydroxide to distilled water is 3: 100.
in the embodiment, in S2, the rotation speed of the stirrer is 50r/min-250r/min, and after each rotation period is finished, the stirrer is kept stand for 5min-9 min.
In this embodiment, in S3, the temperature of the dryer is 45 degrees celsius, the wind speed is 5m/S, and the cloth moving speed of the dryer is 10/min.
In this embodiment, in S3, after the base fabric is dried by the dryer, the base fabric is placed on the widening machine, and the fabric is preliminarily flattened.
In this embodiment, in S4, the temperature set by the ironing machine is 130 degrees celsius, and the pressure set by the ironing machine is 30 KPa.
In this embodiment, in S5, the reinforcing layer is made of butadiene rubber, butadiene rubber is placed in the water solution of aluminum hydroxide in the soaking barrel, the butadiene rubber is stirred by the stirrer, then dried by the dryer, the butadiene rubber is put into the hot melting machine, the temperature in the hot melting machine is set to 120 ℃, then the heated butadiene rubber is poured into the extruder, and the butadiene rubber is extruded into a piece of butadiene cloth with a thickness of 3 mm.
In this embodiment, in S6, the anti-scratch layer uses the ultra-high strength fiber as a base material, the ultra-high strength fiber is put into a soaking bucket and fused with an aqueous solution of aluminum hydroxide, and then 1% of the anti-aging agent is poured into the soaking bucket.
In the embodiment, a base cloth, a reinforcing layer and an anti-scratching layer are sequentially placed in a soaking barrel respectively, so that aqueous solution of aluminum hydroxide is attached to the base cloth, the reinforcing layer and the anti-scratching layer, then the base cloth is dried by a dryer, then the base cloth is transversely flattened by a widening machine, then the base cloth is placed on an ironing machine and is leveled by the ironing machine, butadiene acrylonitrile rubber is selected as a base material for the reinforcing layer, butadiene acrylonitrile is placed in the soaking barrel and is located in the aqueous solution of the aluminum hydroxide, a stirrer is used for stirring the butadiene acrylonitrile rubber, then the drying machine is used for drying, the butadiene acrylonitrile rubber is put in the hot melting machine, the temperature in the hot melting machine is set to be 120 ℃, then the butadiene acrylonitrile rubber after hot melting is poured into an extruder, the butadiene acrylonitrile rubber with the thickness of 3mm is extruded out of the butadiene acrylonitrile, the anti-scratching layer is made of ultra-high strength fiber, the ultra-high strength fiber is placed in the soaking barrel and is fused with the aqueous solution of the aluminum hydroxide, and then 1% of anti-aging agent is poured into the soaking barrel, and finally the reinforcing layer and the anti-scratch layer are respectively pressed with the two sides of the base cloth, so that the flame retardance can be effectively improved, the use limitation is greatly reduced, and the wear resistance and the stability of the coated cloth can be improved.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (8)

1. The preparation method of the flame-retardant coated fabric is characterized by comprising the following steps of:
s1: grinding aluminum hydroxide into powdery particles by using a grinder, then putting the aluminum hydroxide into a soaking barrel, and then pouring distilled water into the soaking barrel to form an aluminum hydroxide aqueous solution;
s2: putting base cloth woven by 60% of terylene and 40% of spandex blended yarn into a soaking barrel, and then stirring the base cloth by using a stirrer for 50 minutes;
s3: taking out the soaked base cloth from the soaking barrel, and drying the base cloth by using a dryer;
s4: putting the dried base cloth on an ironing machine, and removing wrinkles of the base cloth by using the ironing machine;
s5: putting the reinforcing layer and the base cloth into a press machine, and setting the pressure of the press machine to be 20 KPa;
s6: the scratch-resistant layer, the base fabric, and the reinforcing layer were put into a press, and the pressure value of the press was set to 20 KPa.
2. The method as claimed in claim 1, wherein in S1, after grinding the aluminum hydroxide into powder, the aluminum hydroxide is screened by a 200-mesh screen, and the ratio of the aluminum hydroxide to the distilled water is 3: 100.
3. the method for preparing a flame-retardant coated fabric according to claim 1, wherein in S2, the rotation speed of the stirrer is 50r/min-250r/min, and the fabric is left for 5min-9min after each rotation period is finished.
4. The method as claimed in claim 1, wherein in the step S3, the temperature of the dryer is 45 ℃, the wind speed is 5m/S, and the traveling speed of the dryer is 10/min.
5. The method of claim 1, wherein in step S3, after the base fabric is dried by the dryer, the base fabric is placed on a stretching machine to perform a preliminary leveling process.
6. The method as claimed in claim 1, wherein the ironing machine set temperature is 130 degrees celsius and the ironing machine set pressure value is 30KPa in S4.
7. The method as claimed in claim 1, wherein in S5, the reinforcing layer is made of butadiene acrylonitrile rubber, butadiene acrylonitrile is put into the water solution of aluminum hydroxide in the soaking barrel, the butadiene acrylonitrile rubber is stirred by a stirrer, then the butadiene acrylonitrile rubber is dried by a dryer, the butadiene acrylonitrile rubber is put into a hot melting machine, the temperature in the hot melting machine is set to 120 ℃, then the butadiene acrylonitrile rubber after hot melting is poured into an extruder, and the butadiene acrylonitrile rubber is extruded into butadiene acrylonitrile cloth with the thickness of 3 mm.
8. The method of claim 1, wherein in the step S6, the ultra-high strength fiber is used as a base material for the scratch-resistant layer, the ultra-high strength fiber is placed in a soaking tank and fused with an aqueous solution of aluminum hydroxide, and then 1% of an anti-aging agent is poured into the soaking tank.
CN201910787659.9A 2019-08-26 2019-08-26 Preparation method of flame-retardant coated fabric Pending CN110592932A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111716764A (en) * 2020-06-24 2020-09-29 安徽大盘特种装备车辆有限公司 Method for winding glass fibers of CNG (compressed natural gas) cylinder
CN116219735A (en) * 2023-04-23 2023-06-06 国纳之星(上海)纳米科技发展有限公司 Flame-retardant heat-preservation plant fiber environment-friendly material and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4769275A (en) * 1986-02-15 1988-09-06 Kawasaki Jukogyo Kabushiki Kaisha Coated cloth
CN101654864A (en) * 2009-09-25 2010-02-24 厦门大学 Fire-retardant polypropylene non-woven fabric and preparation method thereof
CN102416735A (en) * 2011-09-02 2012-04-18 福建省百凯经编实业有限公司 Hierarchical coating ultraviolet-resistant composite fabric
CN103343454A (en) * 2013-07-16 2013-10-09 徐州亿盈纺织科技有限公司 Flame-retardant textile fabric and manufacturing method thereof
CN103397512A (en) * 2013-07-31 2013-11-20 徐州市华晟纺织有限公司 Production method of inorganic flame retardant fabric

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4769275A (en) * 1986-02-15 1988-09-06 Kawasaki Jukogyo Kabushiki Kaisha Coated cloth
CN101654864A (en) * 2009-09-25 2010-02-24 厦门大学 Fire-retardant polypropylene non-woven fabric and preparation method thereof
CN102416735A (en) * 2011-09-02 2012-04-18 福建省百凯经编实业有限公司 Hierarchical coating ultraviolet-resistant composite fabric
CN103343454A (en) * 2013-07-16 2013-10-09 徐州亿盈纺织科技有限公司 Flame-retardant textile fabric and manufacturing method thereof
CN103397512A (en) * 2013-07-31 2013-11-20 徐州市华晟纺织有限公司 Production method of inorganic flame retardant fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111716764A (en) * 2020-06-24 2020-09-29 安徽大盘特种装备车辆有限公司 Method for winding glass fibers of CNG (compressed natural gas) cylinder
CN116219735A (en) * 2023-04-23 2023-06-06 国纳之星(上海)纳米科技发展有限公司 Flame-retardant heat-preservation plant fiber environment-friendly material and preparation method thereof

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Application publication date: 20191220