CN110591833A - Toilet cleaning agent and preparation method thereof - Google Patents
Toilet cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN110591833A CN110591833A CN201910953643.0A CN201910953643A CN110591833A CN 110591833 A CN110591833 A CN 110591833A CN 201910953643 A CN201910953643 A CN 201910953643A CN 110591833 A CN110591833 A CN 110591833A
- Authority
- CN
- China
- Prior art keywords
- toilet
- hypochlorite
- surfactant
- cleaning agent
- toilet cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title abstract description 13
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 54
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000000460 chlorine Substances 0.000 claims abstract description 44
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 44
- 239000002562 thickening agent Substances 0.000 claims abstract description 35
- 239000003381 stabilizer Substances 0.000 claims abstract description 32
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims description 28
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 20
- 239000003513 alkali Substances 0.000 claims description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 229920002125 Sokalan® Polymers 0.000 claims description 12
- 239000004115 Sodium Silicate Substances 0.000 claims description 11
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 11
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 11
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 10
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 10
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000011049 filling Methods 0.000 claims description 7
- 238000004806 packaging method and process Methods 0.000 claims description 7
- 238000005070 sampling Methods 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 claims description 4
- 229940075468 lauramidopropyl betaine Drugs 0.000 claims description 4
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 229940031728 cocamidopropylamine oxide Drugs 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 229940037001 sodium edetate Drugs 0.000 claims 1
- 235000011121 sodium hydroxide Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 24
- 238000004140 cleaning Methods 0.000 abstract description 19
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 241000894006 Bacteria Species 0.000 abstract description 5
- 230000001954 sterilising effect Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004061 bleaching Methods 0.000 abstract description 2
- 230000000249 desinfective effect Effects 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 27
- 239000007788 liquid Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 8
- -1 polyoxyethylene Polymers 0.000 description 7
- 230000008719 thickening Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 230000009471 action Effects 0.000 description 5
- 239000013022 formulation composition Substances 0.000 description 5
- 238000007689 inspection Methods 0.000 description 5
- 235000013599 spices Nutrition 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- JNGWKQJZIUZUPR-UHFFFAOYSA-N [3-(dodecanoylamino)propyl](hydroxy)dimethylammonium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)[O-] JNGWKQJZIUZUPR-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229940116335 lauramide Drugs 0.000 description 2
- 229940026210 lauramidopropylamine oxide Drugs 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- NKWSTMFSODPKIT-UHFFFAOYSA-N 2-hydroperoxy-4-hydroxy-1,3,5,2lambda5,4lambda5-trioxadiphosphepane 2,4-dioxide Chemical compound C1COP(=O)(OP(=O)(O1)O)OO NKWSTMFSODPKIT-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a toilet cleaning agent and a preparation method thereof, and relates to the technical field of daily chemical industry. The toilet cleaning agent comprises the following raw material components in percentage by weight: 0.2-4% of alkaline thickening agent, 0.1-40% of hypochlorite, 0.1-10% of effective chlorine stabilizer, 0.1-10% of surfactant, 0.1-5% of other components and the balance of deionized water. The toilet cleaning agent disclosed by the invention has the advantages that the alkaline thickening agent, the effective chlorine stabilizer and the hypochlorite are compounded to play a role in cleaning by strong chlorine bleaching of the hypochlorite, so that common organic dirt in a toilet can be effectively removed, common bacteria in the toilet can be killed, and the sterilization rate is as high as 99.999%. The product has good viscosity, improves the wall-hanging performance of the toilet cleaning product, has lasting wall hanging, breaks down stubborn dirt attached to the wall of the toilet, is convenient to use, and has the effects of sterilizing and removing peculiar smell. The toilet cleaning agent can also be used for cleaning, disinfecting and removing mildew on other hard surfaces. The preparation method is simple and suitable for industrial production.
Description
Technical Field
The invention relates to the technical field of daily-use chemical products, in particular to a toilet cleaning agent and a preparation method thereof.
Background
With the increasing living standard of people and the continuous development of social environment, the requirement of people on the environmental sanitation of the toilet is higher and higher. The toilet bowl has entered into thousands of households, and after long-time use, a layer of dirt, mainly oil stain, rust, urine alkali, sediment generated by hard water and the like, is formed on the glaze surface of the toilet bowl, is generally difficult to clean and easily generates peculiar smell. Currently, there are two types of toilet cleaning products on the market: a liquid toilet cleaner and a solid toilet cleaning block. The toilet cleaning block mainly adopts a slow release technology, active ingredients such as a cleaning agent, a binder, a bactericide, a pigment and the like are prepared into a solid matter, and the solid matter is put into a toilet water tank to be slowly dissolved so as to release the active ingredients and play a role in cleaning. The product is convenient to use, can effectively protect the closestool for a long time, but has limited detergency. The liquid toilet cleaner mainly relies on inorganic strong acid as an effective component, adopts a thickening technology to realize the wall-hanging effect in the using process, can effectively remove rust at the edge of a toilet bowl, urine alkali, sediments generated by hard water and other stains, and has certain degerming and bacteriostasis effects while removing scale. The product generally adopts strong acid as an effective component, is effective for cleaning the toilet bowl, but has larger irritation in the using process and certain potential safety hazard.
One prior art discloses a high-efficiency toilet cleaner and a preparation method thereof, and the toilet cleaner is prepared by adopting isomeric alcohol polyoxyethylene ether, oleylamine polyoxyethylene (2) ether, oxalic acid, hydroxy ethylene diphosphate, citric acid, hydrogen peroxide and the like as main components. The paint does not contain inorganic acid, has low corrosivity, is mild and environment-friendly, and has good wall-hanging effect. But has obvious disadvantages that the organic acid has limited removing force to the toilet dirt and the degerming effect of the product is poor. In addition, another prior art discloses a liquid pipe dredging liquid which uses hypochlorite, alkali metal hydroxide, sodium silicate, alkyl amine oxide, alkyl diphenyl oxide disulfonate, fatty acid soap, and the like as main components, and uses a surfactant to realize thickening, foaming, and decontamination. The product has certain viscosity, improves the wall-hanging performance of the dredging agent, and prolongs the action time of the dredging agent and the blocking substance. However, this patent uses the micelle concentration of the surfactant for thickening, and there is a case where the viscosity is unstable.
Disclosure of Invention
The invention aims to solve the technical problem of providing a toilet cleaning agent with stable viscosity, durable wall hanging and good disinfection and sterilization effects and a preparation method thereof, so as to solve at least one problem in the prior art.
In order to solve the above problems, the present invention proposes the following technical solutions:
in a first aspect, an embodiment of the invention provides a toilet cleaning agent, which comprises the following components in percentage by mass:
0.2-4% of an alkaline thickener;
0.1-40% hypochlorite;
0.1-10% of an available chlorine stabilizer;
0.1-10% of a surfactant;
0.1-5% of essence pigment;
the balance of deionized water;
wherein the alkaline thickener is a polyalkenyl ether crosslinked acrylic acid polymer;
the available chlorine content of the hypochlorite is more than 10%;
the effective chlorine stabilizer is one or more than one inorganic alkali;
the surfactant is one or more than one amphoteric surfactant.
The further technical scheme is that the coating comprises the following components in percentage by mass:
1-3.5% of an alkaline thickener;
10-35% hypochlorite;
0.5-7% of an effective chlorine stabilizer;
0.5-8% of a surfactant;
0.1-5% of essence pigment;
the balance being deionized water.
The further technical scheme is that the coating comprises the following components in percentage by mass:
1.5-2.5% of an alkaline thickener;
15-25% hypochlorite;
2-5% of an available chlorine stabilizer;
3-6% of a surfactant;
0.1-5% of essence pigment;
the balance being deionized water.
The further technical scheme is that the alkaline thickening agent is a polyalkenyl ether crosslinked acrylic polymer with the number average molecular weight of 600000-4000000.
The further technical scheme is that the alkaline thickening agent is a polyalkenyl ether cross-linked acrylic polymer with the number-average molecular weight of 650000-2500000.
The further technical proposal is that the hypochlorite is at least one of sodium hypochlorite, potassium hypochlorite or calcium hypochlorite.
The further technical proposal is that the effective chlorine stabilizer is at least one of sodium hydroxide, sodium carbonate, sodium bicarbonate, sodium ethylene diamine tetracetate and sodium metasilicate.
The further technical scheme is that the surfactant is at least one of cocamidopropyl amine oxide, lauramidopropyl amine oxide and lauramidopropyl betaine.
In a second aspect, the embodiments of the present invention also provide a method for preparing the toilet cleaning agent according to the first aspect, including the following steps:
(1) adding the alkaline thickening agent into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding an effective chlorine stabilizer into the solution in the step (1) and stirring until the effective chlorine stabilizer is fully dissolved;
(3) adding hypochlorite and a surfactant into the solution in the step (2) and stirring the mixture to obtain a uniform solution;
(4) adding the essence pigment into the solution in the step (3), and uniformly stirring until the essence pigment is fully dissolved;
(5) sampling and detecting, and filling and packaging after the product is qualified to obtain the toilet cleaning agent.
The further technical scheme is that the sequence of the steps (1) - (4) can be changed.
Compared with the prior art, the invention can achieve the following technical effects:
1) according to the invention, through the compound of the optimized alkaline thickening agent, the effective chlorine stabilizer, the hypochlorite and the surfactant, the synergistic effect of the components is realized, the thickening of a hypochlorite system is realized under the condition of strong alkali and strong oxidizing property, the strong chlorine bleaching cleaning effect of the hypochlorite is exerted, common organic dirt in a toilet can be effectively removed, common bacteria in the toilet are killed, and the sterilization rate is as high as 99.999%; the system has stable viscosity and can be hung on the wall for a long time, so that the action time of the toilet cleaning liquid and the colored mechanism on the toilet wall can be effectively prolonged, and the decontamination effect is improved; overcomes the defect of unstable thickening viscosity of a sodium hypochlorite system by independently using a surfactant.
2) The toilet cleaning agent provided by the invention has good stability: through high-temperature cycle test, the degradation rate of available chlorine can be controlled within 10%, and the organic matter and other stubborn dirt attached to the toilet wall can be effectively disintegrated, the hard surface of the toilet is not damaged, and the toilet has the effects of sterilization and disinfection. The toilet cleaning agent can also be used for cleaning, disinfecting and removing mildew on other hard surfaces.
3) The toilet cleaning agent provided by the embodiment of the invention is simple in preparation method and suitable for industrial production.
Detailed Description
The technical solutions in the examples will be clearly and completely described below. It is apparent that the embodiments to be described below are only a part of the embodiments of the present invention, and not all of them. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It will be understood that the terms "comprises" and/or "comprising," when used in this specification and the appended claims, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
It is also to be understood that the terminology used in the description of the embodiments of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the embodiments of the invention. As used in the description of embodiments of the present invention and the appended claims, the singular forms "a," "an," and "the" are intended to include the plural forms as well, unless the context clearly indicates otherwise.
The embodiment of the invention provides a toilet cleaning agent which comprises the following components in percentage by mass:
0.2-4% of an alkaline thickener;
0.1-40% hypochlorite;
0.1-10% of an available chlorine stabilizer;
0.1-10% of a surfactant;
0.1-5% of essence pigment;
the balance of deionized water;
wherein the alkaline thickener is a polyalkenyl ether crosslinked acrylic acid polymer;
the available chlorine content of the hypochlorite is more than 10%;
the effective chlorine stabilizer is one or more than one inorganic alkali;
the surfactant is one or more than one amphoteric surfactant.
Preferably, in other embodiments, the invention provides a toilet cleaning agent, which comprises the following components in percentage by mass:
1-3.5% of an alkaline thickener;
10-35% hypochlorite;
0.5-7% of an effective chlorine stabilizer;
0.5-8% of a surfactant;
0.1-5% of essence pigment;
the balance being deionized water.
More preferably, in other embodiments, the invention provides a toilet cleaning agent, which comprises the following components in percentage by mass:
1.5-2.5% of an alkaline thickener;
15-25% hypochlorite;
2-5% of an available chlorine stabilizer;
3-6% of a surfactant;
0.1-5% of essence pigment;
the balance being deionized water.
In a specific embodiment, the alkaline thickener is a polyalkenyl ether crosslinked acrylic acid polymer with the number average molecular weight of 600000-4000000.
Preferably, the alkaline thickening agent is a polyalkenyl ether crosslinked acrylic acid polymer with the number average molecular weight of 650000-2500000.
The embodiment realizes thickening under a hypochlorite system under the strong alkali and strong oxidizing property condition by preferably selecting the alkaline thickening agent with a specific molecular weight range, has stable viscosity and durable wall hanging, can effectively prolong the action time of the toilet cleaning liquid and the colored mechanism on the toilet wall, and improves the decontamination effect of the product.
In specific embodiments, the hypochlorite is at least one of sodium hypochlorite, potassium hypochlorite, or calcium hypochlorite.
Preferably, the hypochlorite is sodium hypochlorite having an available chlorine content of 10%.
In specific implementation, the available chlorine stabilizer is at least one of sodium hydroxide, sodium carbonate, sodium bicarbonate, sodium ethylene diamine tetracetate and sodium metasilicate.
In specific implementation, the surfactant is at least one of cocamidopropyl amine oxide, lauramidopropyl amine oxide and lauramidopropyl betaine.
It is understood that the essence and the pigment in the embodiment of the invention are all general components of daily chemical detergent products, and the variety is not particularly limited.
The raw materials used in the examples of the invention are all common products sold in the market.
Examples 1 to 3
The toilet cleaning agents of the embodiments 1 to 3 are respectively prepared according to the formula content shown in the table 1, and the preparation method comprises the following steps:
(1) adding the basic thickener of the poly alkenyl ether crosslinked acrylic acid polymer into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding the effective chlorine stabilizer liquid alkali and sodium carbonate into the solution, and stirring until the effective chlorine stabilizer liquid alkali and the sodium carbonate are fully dissolved;
(3) adding sodium hypochlorite, sodium ethylene diamine tetracetate and surfactant cocoamidopropyl amine oxide into the solution, and stirring to obtain a uniform solution;
(4) adding essence, spice and pigment into the solution, and stirring to dissolve completely;
(5) sampling and detecting, and filling and packaging after the inspection is qualified to obtain the toilet cleaning agent.
TABLE 1 formulation composition of toilet cleaner of examples 1-3
Examples 4 to 6
According to the formula contents shown in Table 2, toilet cleaning agents of examples 4-6 were prepared respectively. The preparation method comprises the following steps:
(1) adding the basic thickener of the poly alkenyl ether crosslinked acrylic acid polymer into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding the effective chlorine stabilizer liquid alkali and sodium metasilicate into the solution, and stirring until the effective chlorine stabilizer liquid alkali and the sodium metasilicate are fully dissolved;
(3) adding sodium hypochlorite and a surfactant lauramide propyl amine oxide into the solution, and stirring to obtain a uniform solution;
(4) adding essence, spice and pigment into the solution, and stirring to dissolve completely;
(5) sampling and detecting, and filling and packaging after the inspection is qualified to obtain the toilet cleaning agent.
TABLE 2 formulation composition of toilet cleaner of examples 4-6
Examples 7 to 9
According to the formula contents in the table 3, the toilet cleaning agents of the embodiments 7-9 are respectively prepared, and the preparation method comprises the following steps:
(1) adding the basic thickener of the poly alkenyl ether crosslinked acrylic acid polymer into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding the effective chlorine stabilizer liquid alkali and sodium metasilicate into the solution, and stirring until the effective chlorine stabilizer liquid alkali and the sodium metasilicate are fully dissolved;
(3) adding sodium hypochlorite and a surfactant lauramidopropyl betaine into the solution, and stirring to obtain a uniform solution;
(4) adding essence, spice and pigment into the solution, and stirring to dissolve completely;
(5) sampling and detecting, and filling and packaging after the inspection is qualified to obtain the toilet cleaning agent.
TABLE 3 formulation composition of toilet cleaner of examples 7-9
Examples 10 to 12
According to the formula contents in the table 4, toilet cleaning agents in the examples 10 to 12 are respectively prepared, and the preparation method comprises the following steps:
(1) adding the basic thickener of the poly alkenyl ether crosslinked acrylic acid polymer into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding sodium carbonate and sodium metasilicate serving as effective chlorine stabilizers into the solution, and stirring until the effective chlorine stabilizers are fully dissolved;
(3) adding sodium hypochlorite and a surfactant, namely cocoamidopropyl amine oxide, into the solution, and stirring the mixture to obtain a uniform solution;
(4) adding essence, spice and pigment into the solution, and stirring to dissolve completely;
(5) sampling and detecting, and filling and packaging after the inspection is qualified to obtain the toilet cleaning agent.
TABLE 4 formulation composition of toilet cleaner of examples 10-12
Examples 13 to 15
According to the formula contents in the table 5, toilet cleaning agents in the examples 13-15 are respectively prepared, and the preparation method comprises the following steps:
(1) adding the basic thickener of the poly alkenyl ether crosslinked acrylic acid polymer into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding sodium hypochlorite and a surfactant lauramide propyl amine oxide into the solution, and stirring to obtain a uniform solution;
(3) adding the effective chlorine stabilizer liquid alkali and sodium metasilicate into the solution, and stirring until the effective chlorine stabilizer liquid alkali and the sodium metasilicate are fully dissolved;
(4) adding essence, spice and pigment into the solution, and stirring to dissolve completely;
(5) sampling and detecting, and filling and packaging after the inspection is qualified to obtain the toilet cleaning agent.
TABLE 5 formulation composition of toilet cleaner of examples 13-15
Comparative example 1
A toilet cleaner substantially the same as in example 4 except that: the number average molecular weight of the acrylic acid homopolymer used as the alkaline thickener was 3000.
Comparative example 2
A toilet cleaner substantially the same as in example 4 except that: the number average molecular weight of the alkaline thickener acrylic acid homopolymer was 450000.
Comparative example 3
A toilet cleaner substantially the same as in example 4 except that: the thickener used is hydroxyethyl cellulose.
Comparative example 4
A toilet cleaner substantially the same as in example 4 except that: the thickener used was dodecyl dimethyl amine oxide.
Experiment of effect application
The toilet cleaning agents provided by the embodiments 1-15 and the comparative examples 1-4 of the invention are selected to be tested for detergency, bactericidal effect and stability, and the test method is as follows:
1. detergency measuring and evaluating method
Manufacturing and cleaning dirt: mixing hydrogenated lanolin and calcium stearate with 95% alcohol, heating to boiling state, directly coating on the surface of ceramic tile, and air drying at room temperature until the alcohol is completely volatilized. Then the ceramic tile is put into an oven with the temperature of 160 ℃ for aging for 1 hour, and is taken out and placed at room temperature for one day. The substrate was scrubbed twice back and forth with a scrub resistance meter and then rinsed with tap water to evaluate the effect before and after cleaning.
The detergency effect evaluation method comprises the following steps: a total of 10 human volunteers (age 22-55 years) were selected, and the cleaned tiles were subjected to sensory evaluation and evaluated for detergency effect by scoring at 5 degrees: 10 minutes, the cleaning effect is very clean; 8 minutes, the cleaning effect is cleaner; 6 minutes, the cleaning effect is general; 4 minutes, the cleaning effect is poor; 0 min, no cleaning effect. Scores of 10 volunteers were summarized as detergency evaluation results.
2. Quantitative bactericidal kill test
The quantitative bacteria killing test of the toilet cleaning agent is tested according to the requirements in the Disinfection technical Specification of the Ministry of health. The test strains are common bacteria such as Escherichia coli and Staphylococcus aureus. The killing rate of the toilet cleaner on bacteria is tested under the following conditions: the concentration of the test solution is the original solution, and the action time is 2 min.
3. Stability test
And (3) testing the high-temperature stability: 1) respectively placing the samples prepared in examples 1-15 and comparative examples 1-4 in an incubator at (54 +/-2) DEG C for 7 days, and taking out the samples to return to room temperature to measure the content of available chlorine and the change of viscosity; 2) the samples prepared in the examples and the comparative examples were placed in an incubator at (37. + -. 2 ℃ C.) for 30 days, and the content of available chlorine was measured after being taken out and returned to room temperature. And judging the stability of the sample according to the change condition of the effective chlorine content.
The results of the detergency, bactericidal effect and stability tests are shown in table 6.
Table 6 test results of the effect application experiment
From the results in Table 6, it is understood that the thickeners used in comparative examples 1 to 4 are toilet cleaner systems of acrylic acid homopolymer, hydroxyethyl cellulose, and dodecyl dimethyl amine oxide having too low or too high number average molecular weight, low viscosity, rapid decrease in available chlorine at high temperature, poor stability, no storage stability, and general detergency.
The toilet cleaning agent provided by the embodiments 1 to 15 of the invention has a detergency of above 86% and a good sterilization effect, and by preferably selecting an acrylic acid homopolymer with a specific molecular weight range as an alkaline thickener, the thickening is realized under a hypochlorite system under the strong alkaline and strong oxidizing property condition, the viscosity is maintained stable, so that the viscosity change is small, the degradation of effective chlorine is controlled within 10% in a high-temperature period stability test at 54 ℃ and 32 ℃, and the toilet cleaning agent is wall-hung persistently, can effectively prolong the action time of the toilet cleaning agent and colored organic matters on a toilet wall, breaks stubborn dirt such as organic matters adhered to the toilet wall, improves the decontamination effect of a product, does not damage the hard surface of the toilet, and has the sterilization and disinfection effects.
In the above embodiments, the descriptions of the respective embodiments have respective emphasis, and for parts that are not described in detail in a certain embodiment, reference may be made to related descriptions of other embodiments.
While the invention has been described with reference to specific embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (10)
1. The toilet cleaning agent is characterized by comprising the following components in percentage by mass:
0.2-4% of an alkaline thickener;
0.1-40% hypochlorite;
0.1-10% of an available chlorine stabilizer;
0.1-10% of a surfactant;
0.1-5% of essence pigment;
the balance of deionized water;
wherein the alkaline thickener is a polyalkenyl ether crosslinked acrylic acid polymer;
the available chlorine content of the hypochlorite is more than 10%;
the effective chlorine stabilizer is one or more than one inorganic alkali;
the surfactant is one or more than one amphoteric surfactant.
2. The toilet cleaning agent according to claim 1, comprising the following components in percentage by mass:
1-3.5% of an alkaline thickener;
10-35% hypochlorite;
0.5-7% of an effective chlorine stabilizer;
0.5-8% of a surfactant;
0.1-5% of essence pigment;
the balance being deionized water.
3. The toilet cleaning agent according to claim 1, comprising the following components in percentage by mass:
1.5-2.5% of an alkaline thickener;
15-25% hypochlorite;
2-5% of an available chlorine stabilizer;
3-6% of a surfactant;
0.1-5% of essence pigment;
the balance being deionized water.
4. The toilet cleaner according to any one of claims 1 to 3, wherein the alkaline thickener is a polyalkenyl ether crosslinked acrylic acid polymer having a number average molecular weight of 600000 to 4000000.
5. The toilet cleaner according to claim 4, wherein the alkaline thickener is a polyalkenyl ether crosslinked acrylic acid polymer having a number average molecular weight of 650000-2500000.
6. A toilet cleaner according to any one of claims 1 to 3, wherein the hypochlorite is at least one of sodium hypochlorite, potassium hypochlorite or calcium hypochlorite.
7. A toilet cleaner according to any one of claims 1 to 3, wherein the available chlorine stabilizer is at least one of sodium hydroxide, soda ash, sodium bicarbonate, sodium edetate and sodium metasilicate.
8. A toilet cleaner according to any one of claims 1 to 3, wherein the surfactant is at least one of cocamidopropyl amine oxide, lauramidopropyl betaine.
9. A process for preparing a toilet cleaner according to any one of claims 1 to 8, comprising the steps of:
(1) adding the alkaline thickening agent into deionized water according to a certain proportion, and uniformly stirring and dispersing;
(2) adding an effective chlorine stabilizer into the solution in the step (1) and stirring until the effective chlorine stabilizer is fully dissolved;
(3) adding hypochlorite and a surfactant into the solution in the step (2) and stirring the mixture to obtain a uniform solution;
(4) adding the essence pigment into the solution in the step (3), and uniformly stirring until the essence pigment is fully dissolved;
(5) sampling and detecting, and filling and packaging after the product is qualified to obtain the toilet cleaning agent.
10. The method of preparing a toilet cleaner according to claim 9, wherein the sequence of steps (1) - (4) is interchangeable.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111349527A (en) * | 2020-04-15 | 2020-06-30 | 广州立白企业集团有限公司 | Mildew-removing gel and preparation method thereof |
| CN112877147A (en) * | 2021-02-19 | 2021-06-01 | 上海康臣生物科技有限公司 | Chlorine-containing alkaline foam cleaning agent |
| CN113197218A (en) * | 2021-03-30 | 2021-08-03 | 天圣制药集团股份有限公司 | Disinfectant and preparation method thereof |
| CN114766505A (en) * | 2022-05-25 | 2022-07-22 | 南京中敖日化科技有限公司 | Stable disinfection gel and preparation method thereof |
| CN118291214A (en) * | 2024-03-19 | 2024-07-05 | 柔京姬(深圳)家化科技有限公司 | Toilet cleaner composition without brushing |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0373864A2 (en) * | 1988-12-15 | 1990-06-20 | The Procter & Gamble Company | Stable thickened aqueous bleach compositions |
-
2019
- 2019-10-09 CN CN201910953643.0A patent/CN110591833B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0373864A2 (en) * | 1988-12-15 | 1990-06-20 | The Procter & Gamble Company | Stable thickened aqueous bleach compositions |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111349527A (en) * | 2020-04-15 | 2020-06-30 | 广州立白企业集团有限公司 | Mildew-removing gel and preparation method thereof |
| CN112877147A (en) * | 2021-02-19 | 2021-06-01 | 上海康臣生物科技有限公司 | Chlorine-containing alkaline foam cleaning agent |
| CN113197218A (en) * | 2021-03-30 | 2021-08-03 | 天圣制药集团股份有限公司 | Disinfectant and preparation method thereof |
| CN114766505A (en) * | 2022-05-25 | 2022-07-22 | 南京中敖日化科技有限公司 | Stable disinfection gel and preparation method thereof |
| CN118291214A (en) * | 2024-03-19 | 2024-07-05 | 柔京姬(深圳)家化科技有限公司 | Toilet cleaner composition without brushing |
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