CN110591827A - Method for producing gel-like detergent - Google Patents
Method for producing gel-like detergent Download PDFInfo
- Publication number
- CN110591827A CN110591827A CN201910739084.3A CN201910739084A CN110591827A CN 110591827 A CN110591827 A CN 110591827A CN 201910739084 A CN201910739084 A CN 201910739084A CN 110591827 A CN110591827 A CN 110591827A
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- Prior art keywords
- saturated
- carbon atoms
- rubber
- chem
- alkyl group
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- 239000003599 detergent Substances 0.000 title claims abstract description 86
- 238000004519 manufacturing process Methods 0.000 title abstract description 46
- 239000000203 mixture Substances 0.000 claims abstract description 113
- 239000003349 gelling agent Substances 0.000 claims abstract description 32
- 238000011049 filling Methods 0.000 claims abstract description 31
- 238000000465 moulding Methods 0.000 claims abstract description 24
- -1 amine salt Chemical class 0.000 claims description 69
- 125000004432 carbon atom Chemical group C* 0.000 claims description 47
- 229920006395 saturated elastomer Polymers 0.000 claims description 44
- 229910052700 potassium Inorganic materials 0.000 claims description 39
- 229910052708 sodium Inorganic materials 0.000 claims description 39
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims description 38
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 12
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 150000005846 sugar alcohols Polymers 0.000 claims description 10
- 229920002000 Xyloglucan Polymers 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 150000001734 carboxylic acid salts Chemical class 0.000 claims description 6
- 235000010418 carrageenan Nutrition 0.000 claims description 6
- 239000000679 carrageenan Substances 0.000 claims description 6
- 229920001525 carrageenan Polymers 0.000 claims description 6
- 229940113118 carrageenan Drugs 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 6
- 229920000161 Locust bean gum Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
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- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims description 2
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- 238000000034 method Methods 0.000 abstract description 37
- 230000008569 process Effects 0.000 abstract description 36
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- 238000001816 cooling Methods 0.000 abstract description 5
- 239000011734 sodium Substances 0.000 description 29
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
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- 238000003756 stirring Methods 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
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- 244000153158 Ammi visnaga Species 0.000 description 6
- 235000010585 Ammi visnaga Nutrition 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
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- IXOCGRPBILEGOX-UHFFFAOYSA-N 3-[3-(dodecanoylamino)propyl-dimethylazaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)CS([O-])(=O)=O IXOCGRPBILEGOX-UHFFFAOYSA-N 0.000 description 2
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- 240000004584 Tamarindus indica Species 0.000 description 1
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- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
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- 229960003237 betaine Drugs 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 description 1
- 229940043351 ethyl-p-hydroxybenzoate Drugs 0.000 description 1
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000008169 grapeseed oil Substances 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229960002969 oleic acid Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000724 poly(L-arginine) polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention aims to provide a method for producing a gel-like detergent with reduced man-hour and high productivity. The method for producing a gel-like detergent comprises a step of heating a gelling agent in water to 70-85 ℃ to dissolve the gelling agent, thereby obtaining a gelled aqueous solution; a process of adding the detergent composition to the gelled aqueous solution and dispersing the same to obtain a dissolved mixture; a process of filling the dissolved mixture into a rubber-like container for molding; a process of cooling and hardening the dissolved mixture filled in the rubber-like container at room temperature; a process for removing the rubbery vessel.
Description
The present application is a divisional application of chinese patent application 201380081777.9(PCT application No. PCT/JP2013/084366) having an application date of 2013, 12 and 20 months, and having an inventive name of "method for producing gel-like detergent".
Technical Field
The present invention relates to a method for producing a gel-like detergent.
Background
Generally, detergents are classified by appearance and are well known to be classified as solids, liquids and gels. Among these detergents, gel-like detergents have high commercial value and wide market prospects because they give a unique tactile sensation.
As a method for producing a gel-like detergent, there are known a method including: first, a process of mixing components such as a detergent composition and a gelling agent; then, a process of heating and stirring the mixture to obtain a gel-like substance; finally, the gel-like material is poured into a mold for molding and hardened.
For example, patent document 1 discloses a cleaning agent in the form of a gel-like semisolid prepared from an anionic surfactant, an amphoteric surfactant, and a gelling agent derived from a natural source, in which a casting mold is used as a mold for molding. However, since the gel-like detergent is a substance having a high moisture content and the gelling agent is easily mildewed and deteriorated, microorganisms such as bacteria are easily propagated, which makes it necessary to take time to clean the recycled casting mold. Further, since the desired gel-like cleansing agent has a different size, it is necessary to prepare a molding die having a desired size, which results in a very low production efficiency of the gel-like cleansing agent.
Patent document 2 discloses that a cylindrical container can be used as a mold for molding in a gel-like cleaning material prepared from a cleaning component and a polysaccharide, but does not disclose what kind of material the cylindrical container is made of.
Prior Art
Patent document
Patent document 1: japanese laid-open patent publication No. 2013-100305
Patent document 2: japanese laid-open patent publication No. 2013-147455
Disclosure of Invention
Technical problem to be solved by the invention
The present invention has been made in view of the above problems, and an object of the present invention is to provide a method for producing a gel-like detergent, which uses a rubber-like composition as a mold for molding, and which eliminates the need to clean the mold for molding, thereby reducing the number of man-hours and achieving high productivity.
Means for solving the problems
(1) One embodiment of the present invention provides a method for producing a gel-like detergent, including: a step (A) in which a gelling agent is dissolved by heating the gelling agent in water to 70-85 ℃ to obtain a gelled aqueous solution; a process (B) in which the detergent composition is dispersed after being added to the gelled aqueous solution, thereby obtaining a dissolved mixture; a process (C) of filling the dissolved mixture into a rubber-like container for molding; a step (D) in which the dissolved mixture filled in the rubber-like container is cooled and hardened at room temperature; a process (E) for removing the rubber-like container.
(2) In the method for producing a gel-like cleansing agent according to the above (1), the filling rate in the step (C) may be 33 g/sec or more and 50 g/sec or less.
(3) The method for producing a gel-like detergent according to the above (1) or (2), further comprising a step (F) of removing the remaining dissolved mixture by suction from an opening of the rubber-like container between the step (C) and the step (D).
(4) In the method for producing a gel-like cleansing agent according to any one of the above (1) to (3), the rubber-like container may further have a protrusion portion located on the opposite side of the opening portion.
(5) In the method for producing a gel-like detergent according to any one of the above (1) to (4), the detergent composition may contain one or two or more selected from the group a and/or the group B shown below, and the gelling agent may contain one or two or more selected from the group C shown below.
(group A) anionic surfactant
(A-1) Carboxylic acid salt
[ CHEM 1 ]
R-COOM
In the formula, R represents saturated or unsaturated alkyl with 12-22 carbon atoms, and M represents Na, K or amine salt;
(A-2) a polyoxyethylene alkyl ether carboxylate (in which the alkyl group has 12 to 22 carbon atoms and is saturated or unsaturated).
[ CHEM 2 ]
R-O(CH2CH20)nR1COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, R1 represents a saturated alkyl group having 1 or 2 carbon atoms, and M represents Na, K or an amine salt.
(A-3) sodium salt, potassium salt or amine salt of N-acylamino acid
[ CHEM 5 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and R2represents-H, -CH3or-CH2CH2COOM, M represents Na, K or an amine salt.
(group B) amphoteric surfactants.
[ CHEM 6 ]
R-NH-CH2-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–2)
[ CHEM 7 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–3)
[ CHEM 8 ]
R-NH-CH2CH2-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–4)
[ CHEM 9 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
B–5
[ CHEM 10 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–6)
[ CHEM 11 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–7)
[ CHEM 12 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–8)
[ CHEM 13 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(group C) gelling agent
(C-1) Water-soluble Polymer derived from plant or seaweed
Xyloglucan, guar gum, locust bean gum, agarose, carrageenan, gum arabic, sodium alginate, glucomannan, pectin;
(C-2) Water-soluble Polymer derived from fermentation with microorganism
Xanthan gum, gellan gum, pullulan polysaccharide, curdlan, sodium hyaluronate.
(6) In the method for producing a gel-like detergent according to the above (5), the carboxylic acid salt of (A-1) may be a carboxylic acid salt containing a fatty acid potassium salt.
(7) In the method for producing a gel-like detergent according to the above (5), the polyoxyethylene alkyl ether carboxylate (saturated or unsaturated alkyl group having 12 to 22 carbon atoms) of the (A-2) may be a salt containing the following (A-2-1) or (A-2-2).
(A-2-1) polyoxyethylene alkyl ether acetate
[ CHEM 3 ]
R-O(CH2CH2O)nCH2COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and M represents Na, K or an amine salt.
(A-2-2) Polyoxyethylene alkyl ether propionate
[ CHEM 4 ]
R-O(CH2CH20)nCH2CH2COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and M represents Na, K or an amine salt.
(8) The method for producing a gel-like cleansing agent according to any one of the above (1) to (7), wherein the gel-like cleansing agent further contains one or more kinds of monohydric or polyhydric alcohols.
(9) In the method for producing a gel-like detergent according to any one of the above (1) to (8), in the step (B), the detergent composition may be added to the gelling aqueous solution, dispersed, and then degassed to obtain a dissolved mixture.
(10) The method for producing a gel-like detergent according to item (8) above, wherein the step (B) may further comprise a step (H) of adding a fatty acid potassium salt to the gelling aqueous solution, dispersing the resulting dispersion, and degassing the dispersion to obtain a conditioned product; and a process (I) in which a detergent composition other than the potassium salt of a fatty acid is added to the conditioning product, dispersed, and then degassed to obtain the dissolved mixture.
Effects of the invention
The invention provides a method for producing a gel-like detergent with reduced man-hour and high productivity.
Drawings
Fig. 1 is a flowchart illustrating a process for carrying out a method for producing a gel-like detergent according to a first embodiment of the present invention.
Fig. 2 is a flowchart illustrating a process for carrying out a method for producing a gel-like cleansing agent according to a second embodiment of the present invention.
Fig. 3 is a flowchart illustrating a process for carrying out a method for producing a gel-like cleansing agent according to a third embodiment of the present invention.
Fig. 4 is a flowchart illustrating a process for carrying out a method for producing a gel-like cleansing agent according to a fourth embodiment of the present invention.
FIG. 5 is a schematic cross-sectional view of one example of a fluid reservoir tank for use in practicing the manufacturing method of the present invention.
Fig. 6 is a schematic cross-sectional view showing an example of a vacuum apparatus for carrying out the manufacturing method of the present invention.
FIG. 7A is a view showing a process of filling the dissolved mixture of the present invention into a rubber-like container for molding.
Fig. 7B is an enlarged view of the filling process.
FIG. 7C is a sectional view showing an example of a filling apparatus for filling a rubber-like container for molding with the dissolved mixture, for carrying out the production process of the present invention.
FIG. 8 is a schematic view showing an example of an apparatus for cooling and hardening a dissolved mixture filled in a rubber-like container for molding, for carrying out the production method of the present invention.
Fig. 9 is a view showing a process for removing the rubber-like container of the present invention.
Detailed Description
Hereinafter, preferred embodiments (hereinafter, referred to as embodiments) for carrying out the method for producing a gel-like cleansing agent according to the present invention will be described in detail with reference to the drawings. In the description of the embodiments, the same elements will be denoted by the same reference numerals.
In the production method of the present invention, the detergent composition may contain 1 or 2 or more kinds selected from group a and/or group B.
The anionic surfactant (group A) is (A-1) a carboxylate, (A-2) a polyoxyethylene alkyl ether carboxylate (saturated or unsaturated with 12 to 22 carbon atoms in the alkyl group), or (A-3) a sodium salt, potassium salt or amine salt of an N-acylamino acid.
The (A-1) carboxylic acid salt is preferably represented by the following chemical formula.
[ CHEM 1 ]
R-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
The fatty acid used in the carboxylate (A-1) is not particularly limited as long as it is generally a fatty acid that can be formulated with a detergent, and the alkyl group may be a saturated, unsaturated, straight-chain or branched fatty acid having 8 to 22 carbon atoms or a natural oil. Examples of the alkyl group are saturated, unsaturated, straight-chain or branched fatty acids having 8 to 22 carbon atoms, and include: capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, eicosanoic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, isopalmitic acid, isostearic acid and neodecanoic acid. As the natural oils and fats, for example, coconut oil, palm kernel oil, cottonseed oil, almond oil, avocado oil, olive oil, grape seed oil and corn oil can be cited.
Examples of the basic agent used as the salt of the carboxylic acid salt include inorganic bases such as sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate, organic bases such as L-polyarginine, monoethanolamine, diethanolamine and triethanolamine as basic amino acids, and alkylamines such as ethanolamine, aminomethylpropanol, aminoethylpropanediol, aminomethylpropanediol, diisopropanolamine, triisopropanolamine and monoisopropanolamine as polyalcohol amines. From the viewpoint of low-temperature stability, potassium hydroxide and triethanolamine are preferable, and potassium hydroxide is more preferable.
Among these carboxylates, a potassium salt of a fatty acid called a potassium soap group is cited as a preferable example. The potassium salt of a fatty acid is obtained by adding potassium hydroxide to a natural oil or fat and then cooking the mixture by heating, and may contain, as a main component, potassium laurate, potassium myristate, and the like, and may include unreacted oils and fats inevitably produced by the production method, glycerin produced by decomposition, and the like.
The (A-2) polyoxyethylene alkyl ether carboxylate (in which the alkyl group has 12 to 22 carbon atoms and is saturated or unsaturated) is preferably represented by the following chemical formula.
[ CHEM 2 ]
R-O(CH2CH2O)nR1COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and R1Represents a saturated alkyl group having 1 or 2 carbon atoms, and M represents Na, K or an amine salt.
The polyoxyethylene alkyl ether carboxylate (a-2) is typically produced by addition polymerization of 4 to 5 moles of ethylene oxide to lauryl alcohol and then reaction of the resultant with monochloroacetic acid.
Among the polyoxyethylene alkyl ether carboxylates (A-2), polyoxyethylene alkyl ether acetates (A-2-1) represented by the following chemical formula are preferable from the viewpoint of suppressing irritation to the skin.
[ CHEM 3 ]
R-O(CH2CH2O)nCH2COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and M represents Na, K or an amine salt.
Further, in the (a-2) polyoxyethylene alkyl ether carboxylate, it is preferable to use a mixture of sodium laurate and sodium myristate which have stability in hard water. From the viewpoint of exhibiting detergency, a polyoxyethylene alkyl ether propionate (A-2-2) represented by the following chemical formula (wherein the number of carbon atoms in the alkyl group is 12 to 22, and the alkyl group is saturated or unsaturated) is preferable.
[ CHEM 4 ]
R-O(CH2CH20)nCH2CN2COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and M represents Na, K or an amine salt.
Specific examples of (a-2-2) include sodium polyoxyethylene lauryl ether acetate (n ═ 4, R ═ C)12M ═ Na), NEO-HITENOL ECL-30S (first Industrial pharmaceutical Co., Ltd.), BEAULIGHT LCA (Sanyo chemical Co., Ltd.)) ENABIKORU EC-30 (Shiwang corporation), and the like.
The sodium salt, potassium salt or amine salt of the (A-3) N-acylamino acid is preferably represented by the following chemical formula.
[ CHEM 5 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and R2represents-H, -CH3or-CH2CH2COOM, M represents Na, K or an amine salt.
The sodium salt, potassium salt or amine salt of (A-3) N-acylamino acid is preferable because it has mild detergency and is less irritating to the skin.
The amphoteric surfactants of group (B) include (B-1) to (B-8) represented by the following chemical formulae.
(B-1)
[ CHEM 6 ]
R-NH-CN2-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-2)
[ CHEM 7 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-3)
[ CHEM 8 ]
R-NH-CH2CH2-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-4)
[ CHEM 9 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–5)
[ CHEM 10 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–6)
[ CHEM 11 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–7)
[ CHEM 12 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B–8)
[ CHEM 13 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
The gel-like cleansing agent preferably contains a zwitterionic surfactant having a hydroxyl group because it can interact with a water-soluble natural polymer and can contribute to gelation. Further, from the viewpoint of low irritation to the skin, stability in hard water, and excellent foaming power, alkylamidopropylbetaines shown in (B-6) are preferable. From the viewpoint of excellent detergency and foamability, and low irritation to the eye, 2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazoline betaine is preferable.
The gelling agent may contain one or more than 2 kinds selected from group C shown below.
(group C) gelling agent
(C-1) Water-soluble Polymer derived from plant or seaweed
Xyloglucan, guar gum, locust bean gum, agarose, carrageenan, gum arabic, sodium alginate, glucomannan, pectin.
(C-2) Water-soluble Polymer derived from fermentation with microorganism
Xanthan gum, gellan gum, pullulan polysaccharide, curdlan, sodium hyaluronate.
From the viewpoint of low irritation to the skin, the gel-like detergent preferably has a pH of 8 or more and 11 or less in terms of a 1 wt% aqueous solution, and therefore the gelling agent is preferably alkali-resistant, salt-resistant, and heat-resistant. Among them, xyloglucan, guar gum, carrageenan and locust bean gum derived from tamarind gum are water-soluble polymers of gums having salt resistance and heat resistance, and they are derived from plants, and therefore they are preferable from the viewpoint of environmental protection.
The amount of the gelling agent is preferably 0.1 wt% to 10 wt%, more preferably 1 wt% to 5 wt%, based on the total weight of the gel-like cleansing agent. When the amount of the gelling agent is less than 1% by weight, solidification to form a gel is difficult, while when the amount of the gelling agent exceeds 10% by weight, excessive solidification occurs, whereby the foamability of the gel-like cleansing agent is impaired, foaming is not easily generated during use, and detergency cannot be exerted.
A1 wt% aqueous solution of a gelling agent having a viscosity of 5 to 9000 mPas, more preferably 1000 to 8000 mPas, and still more preferably 2000 to 6000 mPas is preferably used. When the viscosity is less than 5 mPas or exceeds 9000 mPas, handling becomes difficult.
The gel-like detergent preferably contains one or more types of monohydric alcohol or polyhydric alcohol from the viewpoint of improving foamability, foam quality, and moisture retention of the skin, and also from the viewpoint of thickening by interaction with a gelling agent such as a water-soluble polymer.
Specific examples of the monohydric alcohol or polyhydric alcohol include monohydric alcohols such as ethanol, propanol and isopropanol; polyhydric alcohols such as isoprene glycol, propylene glycol, dipropylene glycol, 1, 2-hexanediol, pentanediol, polyethylene glycol (molecular weight of 400 to 7000), polypropylene glycol (molecular weight of 400), diglycerin, 1, 3-butanediol, glycerol, and inositol; sucrose, lactose, xylitol, maltitol, mannitol, maltose, sorbitol, fructose, trehalose, erythritol, raffinose, lactitol, syrup and the like.
The amount of the monohydric alcohol or the polyhydric alcohol is preferably 2 wt% or more and 50 wt% or less, and more preferably 10 wt% or more and 40 wt% or less, based on the total weight of the gel-like cleanser, from the viewpoint of thickening properties and foaming properties. The amount of the saccharide or sugar alcohol is preferably 0.5 wt% to 50 wt%, more preferably 3 wt% to 30 wt%, based on the total weight of the gel-like detergent.
Fig. 1 is a flowchart illustrating a process for carrying out a method for producing a gel-like detergent according to a first embodiment of the present invention. The first embodiment of the present invention is carried out by the process (a) of heating a gelling agent in water to 70 ℃ to 85 ℃ inclusive to dissolve the gelling agent, thereby obtaining a gelled aqueous solution (step S1); a process (B) of adding the detergent composition to the gelling aqueous solution and then dispersing the mixture to obtain a dissolved mixture (step S2); then, a process (C) of stirring the dissolved mixture and filling it into a rubber-like container for molding (step S3); a step (D) of cooling and hardening the dissolved mixture filled in the rubber-like container at room temperature (step S4); and (E) a step of removing the rubber-like container (step S5).
In step S1, the gelling agent is dissolved in water by heating at 70 to 85 ℃, thereby obtaining a gelling aqueous solution. The gelling aqueous solution is obtained by heating at 70 ℃ to 85 ℃ for a predetermined time (for example, 15 minutes to 3 hours) to swell the gelling agent, and mixing or dissolving the gelling agent in water. FIG. 5 is a schematic cross-sectional view of one example of a fluid reservoir tank for use in practicing the manufacturing method of the present invention. For example, a gelling agent and water are added to a liquid storage tank 10 having a heater 11 as shown in fig. 5. Then, the stirring device 12 having a stirring blade or the like in the stock solution tank 10 is operated to stir the gelled aqueous solution 13 in the stock solution tank, thereby uniformly mixing the gelled aqueous solution. If the heating temperature is less than 70 ℃, the gelling agent may be incompletely dissolved, while if the heating temperature exceeds 85 ℃, the gelling agent may be denatured.
When a monohydric or polyhydric alcohol is added to the gel-like cleansing agent, in step S1, the monohydric or polyhydric alcohol is added, and the gelling agent and water are heated and dissolved together at 70 ℃ to 85 ℃ to obtain a gelled aqueous solution.
In step S2, the detergent composition is added to the gelling aqueous solution and dispersed to obtain a dissolved mixture. In order to uniformly disperse the detergent composition in the gelling aqueous solution, it is preferable to heat and disperse the detergent composition for a predetermined time (for example, 1 hour to 2 hours). The heating temperature may be appropriately set according to the melting point of the gelling agent and the detergent composition. In general, the heating temperature is preferably not lower than the melting point of the highest melting temperature of the raw material, and is preferably 65 ℃ or higher and not higher than 85 ℃ in order to prevent the gelling agent from being denatured while dissolving the raw material.
In order to prevent the mixing of bubbles generated by the addition of the detergent composition and to improve the transparency of the gel-like detergent, it is preferable to degas the dissolved mixture using a vacuum vessel. Fig. 2 is a flowchart illustrating a process for carrying out the method for producing a gel-like detergent according to the second embodiment of the present invention, which is a process (B) for obtaining a dissolved mixture by adding a detergent composition to a gelled aqueous solution and then dispersing the same, and a process (G) for obtaining a dissolved mixture by adding a detergent composition to a gelled aqueous solution and then dispersing the same, and degassing the same (step S2-1). Fig. 6 is a schematic cross-sectional view showing an example of a vacuum apparatus for carrying out the manufacturing method of the present invention. In step S2-1, the gelled aqueous solution and the detergent composition are charged into the vacuum tank 21, the above substances are heated and stirred in the vacuum apparatus 20 by operating the stirring device 22 of the vacuum apparatus having a stirring blade or the like and the jacket 24 having a heating device in the vacuum apparatus 20, the pressure in the vacuum tank 21 is reduced or brought into a vacuum state by operating the vacuum pump 23, the dissolved mixture is uniformly mixed, and bubbles are removed. In order to remove the deposits on the inner wall surface of the vacuum vessel 21 or the residues in the lower part of the vacuum vessel 21, the stirring device 22 of the vacuum apparatus is preferably an anchor stirrer equipped with a scraper 25. In order to mix the dissolved mixture having high viscosity, it is preferable that the stirring device 22 of the vacuum device is a device capable of obtaining a peripheral speed of 5 m/sec to 25 m/sec. From the viewpoint of efficiency of bubble removal, it is preferable that the degree of vacuum in the vacuum apparatus 20 is 15kpa (abs) or less and 75kpa (abs) or less. In the case where the detergent composition is dispersed after being added to the gelling aqueous solution, and the process for obtaining the dissolved mixture and the degassing process are simultaneously performed in the vacuum apparatus 20, the treatment time is preferably 1 hour to 1.5 hours in order to prevent the water content in the dissolved mixture from decreasing, and the process is preferably performed in stages during heating.
Fig. 3 is a flowchart illustrating a process for carrying out a method for producing a gel-like detergent according to a third embodiment of the present invention, and the process (B) for obtaining a dissolved mixture by adding a detergent composition to a gelled aqueous solution and dispersing and degassing the mixture includes a process (H) for obtaining a preparation by adding a potassium salt of a fatty acid to the gelled aqueous solution and dispersing and degassing the mixture (step S2-2), and a process (I) for obtaining a dissolved mixture by adding a detergent composition other than the potassium salt of a fatty acid to the preparation and dispersing and degassing the mixture (step S2-3). In the case where the gel-like detergent contains a potassium salt of a fatty acid, since it is difficult to remove air bubbles, it is preferable to perform the steps S2-2 and S2-3 to perform degassing twice when obtaining a mixture after dissolution from the aqueous gelation solution.
The gelled detergent of the present invention may contain other components, for example, preservatives (ethyl p-hydroxybenzoate, butyl p-hydroxybenzoate, etc.), powders (pigments, dyes, resins, etc.), perfumes, moisturizers, physiologically active ingredients, salts, solvents, pearlizing agents, neutralizers, pH adjusters, enzymes, etc., as appropriate, in addition to the gelling agent and the detergent composition, within a range not detrimental to the object of the present invention. From the viewpoint of dispersibility of each component, those components are preferably compatible with a dissolved mixture in which the detergent composition is not sufficiently dissolved in the gelling aqueous solution, and for example, when a gold foil is contained in the gel-like detergent, the gold foil dispersed in an alcohol solvent is added to the dissolved mixture and mixed to be dispersed.
In step S3, the dissolved mixture is stirred and filled into a rubber-like container for molding. FIG. 7A is a view showing a process of filling the dissolved mixture of the present invention into a rubber-like container for molding. Fig. 7B is an enlarged view of the filling process.
A plurality of notches 2, an injection portion 3, and a removal portion 4 are provided at equal intervals on the outer peripheral portion of the turntable 1 of the filling device 40. When the rubber-like container 41 is in the attached state, the turntable 1 intermittently rotates. A rubber-like container 41 is attached to the notch 2 located in front of the injection portion 3. In the injection section 3, when the turntable 1 is stopped, the injector 3a is lowered to be in close contact with the upper portion of the rubber-like container 41, and a predetermined amount of the dissolved mixture is filled in the rubber-like container 41. Further, when the injector 3a is raised in the above-mentioned filled state, since the dissolved mixture overflows from the rubber-like container, the injector 3a is raised after the opening 41a is bound with the binding material 41c by the binding device 3b provided on the outer peripheral portion of the rotary table 1. Further, the rubber-like container 41 filled with the dissolved mixture therein is rotated and removed from the notch portion in the removing portion 4.
As shown in fig. 7B, the rubber-like container 41 has an opening 41a for filling the dissolved mixture and an expandable expansion portion 41B formed in a substantially spherical or elliptical shape. The material of the rubber-like container 41 may be, for example, natural latex or synthetic latex, and is not particularly limited as long as it is a material used in a usual case. Since the rubber-like container 41 has a colored or transferable pattern on the inside thereof, the color can be maintained inGelThe outside of the detergent-like body is colored or patterned. The filling amount of the mixture after dissolution is not particularly limited, and for example, the filling amount may be set to 100g so that the rubber-like container swells to form a substantially spherical shape having a diameter of 5 cm.
Fig. 4 is a flowchart illustrating a process for carrying out a method for producing a gel-like cleansing agent according to a fourth embodiment of the present invention. Between the process (C) and the process (D), it is further preferable to include a process (F) of removing the remaining dissolved mixture by suction from the opening of the rubber-like container (step S3-2). When step S3-2 is performed, for example, it is preferable that the removing unit 4 of the filling device 40 is provided with a suction device 4a for sucking and removing the remaining dissolved mixture flowing out of the rubber-like container 41 from the opening 41a of the rubber-like container. The suction pump 4b of the suction device 4a sucks the gas in the suction nozzle 4c to recover the remaining dissolved mixture, and at the same time, the rubber-like container 41 can be removed from the notch 2 by the suction pressure.
FIG. 7C is a sectional view showing an example of a filling apparatus for filling a rubber-like container for molding with the dissolved mixture, for carrying out the production process of the present invention. The filling device 40 is a device that raises or lowers the injectors 3a each by means of a cylindrical cam. A plunger 5 is slidably attached to a center portion of the injector 3a, the injector 3a is vertically moved by an injector drive cam 7, and the plunger 5 is vertically moved by a plunger drive cam 6. When the turntable 1 is stopped, the injector 3a is driven by the injector drive cam 7 to descend and contact the upper surface of the turntable 1, and then the plunger 5 is pushed downward by the plunger drive cam 6. On the upper part of the filling device 40, a liquid reservoir 8 of the filling device is installed, and the inside thereof is filled with the dissolved mixture to be filled. In the stage where the plunger 5 is moved up, the dissolved mixture flows from the reservoir tank 8 of the filling device with stirring function into the injector 3a through the pipe 9, and is filled into the rubber-like container 41 by the downward movement of the plunger 5. The cam shaft 47 to which each cam is attached is driven by the motor 42 via the chain 43, and the turntable 1 is driven by the motor 42 and rotated via the chain 44, the intermittent drive unit 45, and the chain 46.
From the viewpoint of filling properties, it is preferable to cool the dissolved mixture to 60 ℃ to 65 ℃. When the temperature is lower than 60 ℃, the dissolved mixture is easily hardened, and the filling property into the rubber-like container is deteriorated, while when the temperature exceeds 65 ℃, the viscosity of the dissolved mixture is lowered, and the weight of the gel-like detergent may be uneven during filling. In the process (C) of filling the dissolved mixture into a rubber-like container for molding, the filling rate is preferably 33 g/sec or more and 50 g/sec or less. When the filling rate is less than 33 g/sec, the mixture after dissolution is easily hardened, while when the filling rate is more than 50 g/sec, air may be mixed into the rubber-like container 41.
In step S4, the dissolved mixture filled in the rubber-like container 41 is cooled and hardened at room temperature. FIG. 8 is a schematic view showing an example of an apparatus for cooling and hardening a dissolved mixture filled in a rubber-like container for molding, for carrying out the production method of the present invention. The dissolved mixture filled in the rubber-like container 41 is stored in the holder 51 with the bundled mouth portion 41a facing downward, placed in the storage box 50, and left to stand at room temperature. By setting the time required for cooling and hardening to a time of about 1 day to 2 days, the mixture dissolved in the rubber-like container 41 is hardened to the center to form a gel-like detergent.
In step S5, the rubber-like container is removed. FIG. 9 is a view showing a process (E) for removing the rubber-like container of the present invention. The rubber-like container 41 is broken by a sharp-pointed instrument 61 such as a needle to remove the rubber-like container 41, and the gel-like detergent 62 is taken out from the rubber-like container 41. Since the rubber-like container 41 is formed into a substantially elliptical spherical shape by being swollen by filling the gel-like detergent 62, the surface of the rubber-like container 41 can be broken by making a small hole, and thus the breakage easily occurs.
As shown in fig. 7B, the rubber-like container 41 preferably has a protrusion 41d on the side opposite to the opening 41 a. In step S5, when the rubber-like container 41 is broken, the broken rubber film instantaneously contracts, and therefore the external shape of the gel-like detergent 62 may be damaged. However, when the rubber-like container 41 has the protrusions 41d, the rubber film can be smoothly contracted as compared with a rubber-like container without the protrusions 41d, and therefore the rubber-like container 41 can be broken without breaking the outer shape of the gel-like detergent 62.
Examples
The present invention will be described in more detail below with reference to examples. However, the present invention is not limited to the following examples. Percentages, ratios, and weight portions recited in the specification, examples, and claims of this invention are by weight, and unless otherwise indicated are exemplary values. In addition, examples 1-6 were prepared according to the flow chart of the manufacturing process shown in fig. 1.
[ example 1 ]
(1) Refined water 67.9%
(2) 10.0 percent of glycerin
(3) Dipropylene glycol 7.0%
(4) 2.5 percent of 1, 2-hexanediol
(5) Xyloglucan (registered trademark: GLYLOID 6C,/DSP GOKYO food and chemical Co., Ltd.) 0.8%
(6) Xanthan gum 0.2%
(7) Lauric acid 5.9%
(8) Myristic acid 2.2%
(9) Palmitic acid 1.0%
(10) Stearic acid 0.4%
(11) Oleic acid 0.6%
(12) 1.5 percent of sodium hydroxide
The total content is 100.0 percent
Method for producing
The components (5), (6) are wetted in the mixture of the components (2), (3) and dispersed, and then they are added to the component (1), heated to 85 ℃, and stirred to be dissolved (step S1). Then, the components (7) to (12) are added thereto, mixed and dissolved, and stirred to obtain a uniform dissolved mixture (step S2). Then, the dissolved mixture was kept at 65 to 80 ℃, and the dissolved mixture was stirred and filled into a rubber-like container for molding (step S3), and then the dissolved mixture filled into the rubber-like container was allowed to stand at room temperature (step S4), and then the rubber-like container was removed with a toothpick (step S5), thereby obtaining a gel-like detergent.
[ example 2 ]
(1) Refined water 48.4%
(2) Sorbitol 10.0%
(3) 10.0 percent of propylene glycol
(4) 2.5 percent of 1, 2-hexanediol
(5) Xyloglucan (registered trade name: GLYLOID 6C) 1.0%
(6) Xanthan gum 0.5%
(7) Lauric acid 5.9%
(8) Myristic acid 2.2%
(9) Palmitic acid 1.0%
(10) Stearic acid 0.3%
(11) Oleic acid 0.6%
(12) 2.60 percent of potassium hydroxide
(13) Lauramidopropylhydroxysultaine (SOFTAAZOLINE LSB// Chuanjian Fine Chemicals Co., Ltd.) 15.0%
The total content is 100.0 percent
Method for producing
The components (5) and (6) are wetted in the mixture of the components (2) to (4) and dispersed, and then they are added to the component (1), heated to 85 ℃, and stirred to be dissolved (step S1). Then, the components (7) to (12) are added thereto and mixed, and then dissolved by heating to 75 to 85 ℃, and then the component (13) is added thereto and stirred to obtain a uniformly mixed and dissolved mixture (step S2). Then, the dissolved mixture was kept at 75 to 80 ℃, and the dissolved mixture was stirred and filled into a rubber-like container for molding (step S3), and then the dissolved mixture filled into the rubber-like container was allowed to stand at room temperature (step S4), and then the rubber-like container was removed with a toothpick (step S5), thereby obtaining a gel-like detergent.
[ example 3 ]
(1) 48.0 percent of refined water
(2) Dipropylene glycol 7.0%
(3) 2.5 percent of 1, 2-hexanediol
(4) Xanthan gum 0.5%
(5) 2.0 percent of carrageenan
(6) Coconut oil fatty acid amide propyl betaine aqueous solution (OBAZORIN CAB 30/Toho chemical industry Co., Ltd.) 40.0%
The total content is 100.0 percent
Method for producing
The components (4), (5) are wetted in the mixture of the components (2), (3) and dispersed, and then they are added to the component (1), heated to 85 ℃, and stirred to be dissolved (step S1). Then, the component (6) was added thereto, mixed, and stirred to obtain a uniformly mixed dissolved mixture (step S2). Then, the dissolved mixture was kept at 68 to 80 ℃, and the dissolved mixture was stirred and filled into a rubber-like container for molding (step S3), and then the dissolved mixture filled into the rubber-like container was allowed to stand at room temperature (step S4), and then the rubber-like container was removed with a toothpick (step S5), thereby obtaining a gel-like detergent.
[ example 4 ]
(1) 58.5 percent of refined water
(2) Dipropylene glycol 7.0%
(3) 2.5 percent of 1, 2-hexanediol
(4) 2.0 percent of carrageenan
(5) Sodium polyoxyethylene lauryl ether acetate (NEO-HITENOL ECL-30S/first Industrial pharmaceutical Co., Ltd.) 30.0%
The total content is 100.0 percent
Method for producing
Component (4) is wetted in the mixture of components (2), (3) and dispersed, and then they are added to component (1), heated to 85 ℃, and stirred to dissolve them (step S1). Then, the component (6) was added thereto, mixed, heated to 85 ℃, and stirred to obtain a uniformly mixed dissolved mixture (step S2). Then, the dissolved mixture was kept at 60 to 75 ℃, and the dissolved mixture was stirred and filled into a rubber-like container for molding (step S3), and then the dissolved mixture filled into the rubber-like container was allowed to stand at room temperature (step S4), and then the rubber-like container was removed with a toothpick (step S5), thereby obtaining a gel-like detergent.
[ example 5 ]
(1) Refined water 59.5%
(2) 2.5 percent of 1, 2-hexanediol
(3) Xyloglucan (registered trade name: GLYLOID 6C) 0.7%
(4) Xanthan gum 0.3%
(5) Potassium soap base (100%) 12.0%
(6) Lauramidopropylhydroxysultaine (SOFTAZOINE LSB/Chuanjian Fine Chemicals Co., Ltd.) 15.0%
(7) 10.0 percent of glycerin
(8) Proper amount of citric acid
(9) Proper amount of sodium citrate
The total content is 100.0 percent
Method for producing
The components (3), (4) are wetted in the component (2) and dispersed, and then they are added to the component (1), heated to 85 ℃, and stirred to be dissolved (step S1). Then, the components (5) and (6) are added in this order, heated to 65 to 85 ℃ and stirred during the heating to dissolve the above components, and then the components (7) to (9) are added thereto to adjust the PH to 10.0 to obtain a uniform dissolved mixture (step S2). Then, the dissolved mixture was stirred and filled into a rubber-like container for molding (step S3), and then the dissolved mixture filled into the rubber-like container was allowed to stand at room temperature (step S4), and then the rubber-like container was removed with a toothpick (step S5), thereby obtaining a gel-like detergent.
[ example 6 ]
(1) Refined water 36.5%
(2) 10.0 percent of dipropylene glycol
(3) 2.5 percent of 1, 2-hexanediol
(4) Xanthan gum 0.5%
(5) 0.5 percent of locust bean gum
(6) Coconut oil fatty acid amide propyl betaine aqueous solution (OBAZORIN CAB 30/Toho chemical industry Co., Ltd.) 50.0%
The total content is 100.0 percent
Method for producing
The components (4), (5) are wetted in the mixture of the components (2), (3) and dispersed, and then they are added to the component (1), heated to 85 ℃, and stirred to be dissolved (step S1). Then, the component (6) is added thereto and mixed, and then heated to 70 to 85 ℃, and stirred to obtain a uniformly mixed and dissolved mixture (step S2). Then, the dissolved mixture was stirred and filled into a rubber-like container for molding (step S3), and then the dissolved mixture filled into the rubber-like container was allowed to stand at room temperature (step S4), and then the rubber-like container was removed with a toothpick (step S5), thereby obtaining a gel-like detergent.
The present invention has been described above with reference to the embodiments, but the technical scope of the present invention is not limited to the scope described in the above embodiments. It will be apparent to those skilled in the art that various changes or modifications can be made to the above embodiments. It is apparent from the scope of the claims that the embodiments to which various changes and modifications are applied are also included in the technical scope of the present invention.
Description of the reference numerals
1 rotating table
2 notch part
3 injection part
3a injector
3b binding device
4 removing part
4a suction device
4b suction pump
4c suction nozzle
5 plunger piston
6 plunger driving cam
7 injector drive cam
Liquid storage tank of 8 filling device
9 pipeline
10 liquid storage tank
11 heater
12 stirring device
13 gelled aqueous solution
20 vacuum device
21 vacuum kettle
22 stirring device of vacuum device
23 vacuum pump
24 sheath
25 scraper
40 filling device
41 rubber-like container
41a opening part
41b expansion part
41c binding material
41d projection part
42 engine
43. 44, 46 chain
45 intermittent driving device
47 camshaft
50 containing box
51 fixer
61 utensil with tip
62 gel-like detergent
Claims (6)
1. A rubber-like container for molding a dissolved mixture into a gel-like detergent, which is made of natural latex or synthetic latex, comprising: an opening portion for filling the dissolved mixture, and an expanding portion which can be expanded into a substantially spherical or substantially ellipsoidal shape by filling the dissolved mixture.
2. A rubber-like container according to claim 1, wherein said container has a projection on a side opposite to said opening.
3. A rubber-like container according to claim 1 or 2, wherein the opening portion is bound with a binding material.
4. A rubber-like container according to any one of claims 1 to 3, wherein the dissolved mixture to be formed into a gel-like detergent contains a gelling agent and a detergent composition.
5. A rubber-like container according to claim 4, wherein said gelling agent is 1 or 2 or more gelling agents selected from the group consisting of xyloglucan, guar gum, carrageenan and locust bean gum.
6. A rubber-like container according to claim 4 or 5, wherein said detergent composition is a detergent composition containing 1 or 2 or more kinds of surfactants selected from the group consisting of the following group A anionic surfactants and/or the following group B zwitterionic surfactants, and a monohydric or polyhydric alcohol:
(group A) anionic surfactant:
(A-1) a carboxylic acid salt represented by the following formula:
[ CHEM 1 ]
R-COOM
In the formula, R represents saturated or unsaturated alkyl with 12-22 carbon atoms, and M represents Na, K or amine salt;
(A-2) a polyoxyethylene alkyl ether carboxylate represented by the following formula:
[ CHEM 2 ]
R-O(CH2CH2O)nR1COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, n is 1 to 20 on average, and R1Represents a saturated alkyl group having 1 or 2 carbon atoms, and M represents Na, K or an amine salt;
(A-3) an N-acylamino acid salt represented by the following formula:
[ CHEM 3 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and R is2represents-H, -CH3or-CH2CH2COOM, M represents Na, K or an amine salt;
(group B) zwitterionic surfactant:
(B-1) a zwitterionic surfactant represented by the following formula:
[ CHEM 4 ]
R-NH-CH2-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-2) a zwitterionic surfactant represented by the following formula:
[ CHEM 5 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt;
(B-3) a zwitterionic surfactant represented by the following formula:
[ CHEM 6 ]
R-NH-CH2CH2-COOM
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt;
(B-4) a zwitterionic surfactant represented by the following formula:
[ CHEM 7 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-5) a zwitterionic surfactant represented by the following formula:
[ CHEM 8 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-6) a zwitterionic surfactant represented by the following formula:
[ CHEM 9 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
(B-7) a zwitterionic surfactant represented by the following formula:
[ CHEM 10 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt;
(B-8) a zwitterionic surfactant represented by the following formula:
[ CHEM 11 ]
Wherein R represents a saturated or unsaturated alkyl group having 12 to 22 carbon atoms, and M represents Na, K or an amine salt.
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| CN201910739084.3A CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
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| Application Number | Priority Date | Filing Date | Title |
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| PCT/JP2013/084366 WO2015092939A1 (en) | 2013-12-20 | 2013-12-20 | Method for producing gel detergent |
| CN201910739084.3A CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
| CN201380081777.9A CN105849246B (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
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| CN201910739084.3A Pending CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
| CN201380081777.9A Active CN105849246B (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
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| JP (1) | JP6322214B2 (en) |
| KR (1) | KR102072833B1 (en) |
| CN (3) | CN110499221A (en) |
| ES (1) | ES2881233T3 (en) |
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| JP2014139307A (en) * | 2012-12-22 | 2014-07-31 | Neige Corporation:Kk | Method for producing gelled detergent |
| AU2018251256B2 (en) | 2017-04-14 | 2023-10-05 | Capsugel Belgium Nv | Pullulan capsules |
| JP7222911B2 (en) | 2017-04-14 | 2023-02-15 | カプスゲル・ベルギウム・ナムローゼ・フェンノートシャップ | How to make pullulan |
| CN113430077A (en) * | 2021-08-04 | 2021-09-24 | 王盛龙 | Enzyme-containing laundry gel ball and preparation method thereof |
| DE102022203707A1 (en) * | 2022-04-13 | 2023-10-19 | Henkel Ag & Co. Kgaa | Process for producing a detergent portion unit |
| KR102571190B1 (en) * | 2022-12-16 | 2023-08-28 | 권명주 | Cleansing balm composition and manufacturing method thereof |
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Also Published As
| Publication number | Publication date |
|---|---|
| KR102072833B1 (en) | 2020-02-03 |
| JP6322214B2 (en) | 2018-05-09 |
| WO2015092939A1 (en) | 2015-06-25 |
| ES2881233T3 (en) | 2021-11-29 |
| JPWO2015092939A1 (en) | 2017-03-16 |
| CN110499221A (en) | 2019-11-26 |
| EP3085762B1 (en) | 2021-06-16 |
| EP3085762A1 (en) | 2016-10-26 |
| CN105849246A (en) | 2016-08-10 |
| EP3085762A4 (en) | 2017-08-02 |
| CN105849246B (en) | 2019-08-16 |
| KR20160100303A (en) | 2016-08-23 |
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