CN105849246B - The manufacturing method of gel detergent - Google Patents
The manufacturing method of gel detergent Download PDFInfo
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- CN105849246B CN105849246B CN201380081777.9A CN201380081777A CN105849246B CN 105849246 B CN105849246 B CN 105849246B CN 201380081777 A CN201380081777 A CN 201380081777A CN 105849246 B CN105849246 B CN 105849246B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
Abstract
It is reduced the purpose of the present invention is to provide a kind of working hour number and the manufacturing method of gel detergent that production performance is high.The manufacturing method of gel detergent has following techniques, and gelating agent is heated to 70 DEG C or more 85 DEG C or less in water and is made it dissolve, to obtain the technique of gelation aqueous solution；Make its dispersion after adding cleaning agent component into gelation aqueous solution, to obtain the technique of dissolved mixture；Dissolved mixture is filled into the technique in the rubber-like container of forming；The technique that the dissolved mixture being filled into rubber-like container carries out hardening by cooling at room temperature；The technique for removing rubber-like container.
Description
Technical field
The present invention relates to a kind of manufacturing methods of gel cleaning material.
Background technique
In general, detergent is classified from the appearance, it is well known for being divided into solid, liquid and gel.
In these detergents, since gelatinous detergent can give a kind of unique touch feeling of people, so having very high business
Value and vast market prospect.
Manufacturing method as gel detergent, it is known that have include: firstly, by cleaning agent component, gelating agent
The technique that such ingredient is mixed；Then, it heats mixture and stirs the technique for obtaining spawn；Finally,
Spawn is poured into the manufacturing method for the technique hardened in the mold of forming.
For example, patent document 1 is a kind of by anionic surfactant, amphoteric surfactant and natural
In the detergent for the gelatinous semisolid shape that the agent that is gelled is prepared, use casting mould as the mold of forming.However,
Since gel detergent is a kind of substance that moisture amount is high and gelating agent is easy moldy metamorphism, bacterium etc.
Microorganism is easy breeding, this makes the casting mould for needing to spend time cleaning recycling.Further, since desired gel
Shape detergent it is of different sizes, therefore have to prepare in advance the mold of the forming of various desired sizes, so causing
Under the production efficiency of gel detergent becomes very low.
Although patent document 2 discloses a kind of gelatinous cleaning material being formulated by cleansing and polysaccharide
In, mold of the cylindrical container as forming can be used, but it does not disclose that the cylindrical container is by which type of
What material was constituted.
The prior art
Patent document
Patent document 1: special open 2013-100305 bulletin
Patent document 2: special open 2013-147455 bulletin
Summary of the invention
Technical problems to be solved by the inivention
The present invention is to complete in view of the above problems, and its purpose is to provide a kind of constituents by using rubber-like
As the mold of forming so that no longer need to clean the mold of forming, therefore working hour number be reduced and
The manufacturing method of the high gel detergent of production performance.
Solve the technological means of technical problem
(1) a kind of embodiment according to the present invention is to provide a kind of manufacturing method of gel detergent, has:
Technique (A) is that gelating agent is heated to 70 DEG C or more 85 DEG C or less in water to make it dissolve, so that it is water-soluble to obtain gelation
The technique of liquid；Technique (B) is to make its dispersion after adding cleaning agent component into gelation aqueous solution, to be dissolved
The technique of mixture afterwards；Technique (C) is the work being filled into dissolved mixture in the rubber-like container of forming
Skill；Technique (D) is that the dissolved mixture being filled into rubber-like container carries out hardening by cooling at room temperature
Technique；Technique (E) is the technique for removing rubber-like container.
(2) in the manufacturing method of the gel detergent documented by above-mentioned (1), the filling speed of technique (C) be can be
33g/ seconds or more, 50g/ seconds or less.
(3) in the manufacturing method of the gel detergent documented by above-mentioned (1) or (2), in technique (C) and technique
(D) between, further the described dissolved mixed of remnants can also be removed comprising aspirating from the opening portion of the rubber-like container
Close the technique (F) of object.
(4) in above-mentioned (1) into (3) in the manufacturing method of any one documented gel detergent, rubber-like is held
Device can also have protrusion, be located at the opposite side of opening portion.
(5) in above-mentioned (1) into (4) in the manufacturing method of any one documented gel detergent, detergent group
It can be at object containing the one or more kinds of substances selected from A group and/or B group as follows, gel
Agent can be containing the one or more kinds of substances selected from C group as follows.
(A group) anionic surfactant
(A -1) carboxylate
[changing 1]
R-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(A -2) polyoxyethylene alkyl ether carboxylate (carbon atom number of alkyl is 12~22, for saturation or unsaturation).
[changing 2]
R-O(CH2CH2O)nR1COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, and R1 indicates carbon
The saturated alkyl that atomicity is 1 or 2, M indicate Na, K or amine salt.
Sodium salt, sylvite or the amine salt of (A -3) N- acylamino acid
[changing 5]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, R2Indicate-
H ,-CH3Or-CH2CH2COOM, M indicate Na, K or amine salt.
(B group) amphoteric surfactant.
[changing 6]
R-NH-CH2-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–2)
[changing 7]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–3)
[changing 8]
R-NH-CH2CH2-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–4)
[changing 9]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
B–5
[changing 10]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–6)
[changing 11]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–7)
[changing 12]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–8)
[changing 13]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(C group) gelating agent
The water soluble polymer of (C -1) from plant or seaweed
Xyloglucan, guar gum, locust bean gum, agarose, carrageenan, gum arabic, sodium alginate, Portugal's sweet dew are poly-
Sugar, pectin；
(C -2) comes from water soluble polymer caused by microbe fermentation method
Xanthan gum, gellan gum, pulullan polysaccharide, Curdlan, Sodium Hyaluronate.
(6) in the manufacturing method of the gel detergent documented by above-mentioned (5), the carboxylate of (A -1) is also possible to contain
There is the carboxylate of fatty acid potassium salt.
(7) in the manufacturing method of the gel detergent documented by above-mentioned (5), the polyoxyethylene alkyl ether carboxylic of (A -2)
Hydrochlorate (carbon atom number of alkyl is 12~22, for saturation or unsaturated) can be containing (A-2-1) as described below or
The salt of person (A-2-2).
(A-2-1) polyoxyethylene alkyl ether acetate
[changing 3]
R-O(CH2CH2O)nCH2COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, and M indicates Na, K
Or amine salt.
(A-2-2) polyoxyethylene alkyl ether propionate
[changing 4]
R-O(CH2CH2O)nCH2CH2COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, and M indicates Na, K
Or amine salt.
(8) in the manufacturing method of the gel detergent documented by any one of above-mentioned (1) to (7), gel is clear
Clean dose may further contain one or more kinds of unitary or polyalcohol.
(9) in the manufacturing method of the gel detergent documented by any one of above-mentioned (1) to (8), at technique (B)
In, make its dispersion after cleaning agent component being added into gelation aqueous solution, is then de-gassed after obtaining dissolution
Mixture technique (G).
(10) in the manufacturing method of the gel detergent documented by above-mentioned (8), in technique (B), can also include,
Make its dispersion after adding fatty acid potassium salt into gelation aqueous solution, is then de-gassed to obtain the technique (H) of adjustment object；
Make its dispersion with after the cleaning agent component other than the addition fatty acid potassium salt into adjustment object, is then de-gassed to obtain institute
State the technique (I) of dissolved mixture.
Invention effect
It is capable of providing a kind of manufacture for the gel detergent that working hour number is reduced and production performance is high through the invention
Method.
Detailed description of the invention
Fig. 1 shows be the manufacture for illustrating gel detergent involved in first embodiment for carrying out the present invention
The flow chart of the technique of method.
What Fig. 2 was indicated is the manufacture for illustrating gel detergent involved in second embodiment for carrying out the present invention
The flow chart of the technique of method.
What Fig. 3 was indicated is the manufacture for illustrating gel detergent involved in third embodiment for carrying out the present invention
The flow chart of the technique of method.
What Fig. 4 was indicated is the manufacture for illustrating gel detergent involved in the 4th embodiment for carrying out the present invention
The flow chart of the technique of method.
What Fig. 5 was indicated is the schematic cross sectional view of an example of the fluid reservoir of manufacturing method for carrying out the present invention.
What Fig. 6 was indicated is the schematic cross section of an example of the vacuum plant of manufacturing method for carrying out the present invention
Figure.
What Fig. 7 A was indicated is the technique being filled into dissolved mixture of the invention in the rubber-like container of forming
View.
What Fig. 7 B was indicated is the expanded view of fill process.
What Fig. 7 C was indicated is manufacturing method for carrying out the present invention, and dissolved mixture is filled into the rubber of forming
The sectional view of one example of the filling device in gluey container.
Fig. 8 shows be manufacturing method for carrying out the present invention, be filled into molten in the rubber-like container of forming
The schematic diagram of an example of device that mixture after solution is cooled down and hardened.
What Fig. 9 was indicated is the view for removing the technique of rubber-like container of the invention.
Specific embodiment
Hereinafter, referring to attached drawing to the preferred embodiment of the manufacturing method for implementing gel detergent of the invention (hereinafter,
Referred to as embodiment) it is described in detail.In addition, being assigned to identical element identical in the explanation of entire embodiment
Appended drawing reference.
In the manufacturing method of the present invention, cleaning agent component is can to contain a kind in A group and/or B group
Or substance of more than two kinds.
The anionic surfactant of (A group) is (A -1) carboxylate, and (A -2) polyoxyethylene alkyl ether carboxylate is (in alkyl
Carbon atom number be 12~22, saturation or unsaturated) either (A -3) N- acylamino acid sodium salt, sylvite or amine salt.
As (A -1) carboxylate, preferably with substance represented by following chemical formula.
[changing 1]
R-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(A -1) not have as long as fatty acid used in carboxylate can usually expect substance obtained from preparing with cleaning
Special standby limitation, alkyl can be saturation, unsaturation with 8~22 carbon atoms, the fatty acid of straight chain or branch or
Natural oil.It is saturation, unsaturation with 8~22 carbon atoms as alkyl, the fatty acid of linear chain or branched chain, such as can be with
It enumerates: capric acid, lauric acid, myristic acid, palmitinic acid, stearic acid, arachic acid, behenic acid, oleic acid, linoleic acid, flax
Acid, erucic acid, different palmitinic acid, isostearic acid and neodecanoic acid.As natural oil, such as can lift, coconut oil, palm oil, palm
Benevolence oil, cottonseed oil, apricot kernel oil, avocado oil, olive oil, grape seed oil and corn oil.
In addition, alkaline reagent used in salt as carboxylate can be enumerated, sodium hydroxide, potassium hydroxide, sodium carbonate,
The inorganic bases such as potassium carbonate, the organic base of the L- pR60 of basic amino acid, monoethanolamine, diethanol amine, triethanolamine etc. are more
Ethanol amine, aminomethyl propanol, aminoethyl propylene glycol, aminomethyl propylene glycol, diisopropanolamine (DIPA), the triisopropanolamine, list of first hydramine
The alkylamine of isopropanolamine etc..From the viewpoint of low-temperature stability, preferred potassium hydroxide, triethanolamine, further preferred hydrogen
Potassium oxide.
Moreover, in these carboxylates, the fatty acid potassium for having referred to as potash soap base that can be enumerated as preferred example
Salt.Fatty acid potassium salt be it is a kind of carry out heating boiling being added after potassium hydroxide into natural oil to manufactured substance,
As its main component, potassium laurate, potassium myristate etc. can be contained, and include inevitable caused by manufacturing method
Unreacted grease, decomposition and glycerol for generating etc..
It is excellent as (A -2) polyoxyethylene alkyl ether carboxylate (carbon atom number of alkyl is 12~22, saturation or unsaturated)
Choosing is with substance represented by following chemical formula.
[changing 2]
R-O(CH2CH2O)nR1COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, R1Indicate carbon
The saturated alkyl that atomicity is 1 or 2, M indicate Na, K or amine salt.
About (A -2) polyoxyethylene alkyl ether carboxylate, representative polyoxyethylene alkyl ether carboxylate is to make 4~5 to rub
Your ethylene oxide and laruyl alcohol addition polymerization, then make the substance of its generation that reacts with chloroacetic acid.
In (A -2) polyoxyethylene alkyl ether carboxylate, in terms of inhibiting to the irritation of skin, preferably with following chemistry
(A-2-1) polyoxyethylene alkyl ether acetate represented by formula.
[changing 3]
R-O(CH2CH2O)nCH2COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, and M indicates Na, K
Or amine salt.
In addition, with the lauric acid of stability in (A -2) polyoxyethylene alkyl ether carboxylate, it is preferable to use in hard water
The mixture of sodium and Sodium myristate.From the viewpoint of playing soil release performance, preferably with (A-2-represented by following chemical formula
2) polyoxyethylene alkyl ether propionate (carbon atom number of alkyl is 12~22, saturation or unsaturated).
[changing 4]
R-O(CH2CH2O)nCH2CH2COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, and M indicates Na, K
Or amine salt.
As the specific example of (A-2-2), polyoxyethylene lauryl ether sodium acetate (n=4, R=C can be enumerated12, M=
Na), NEO-HITENOL ECL-30S (Di-ichi Kogyo Seiyaku Co., Ltd.), BEAULIGHT LCA (Sanyo's chemical conversion industry strain formula
Commercial firm), ENAJIKORU EC-30 (Lion Corporation) etc..
As the sodium salt, sylvite or amine salt of (A -3) N- acylamino acid, preferably with substance represented by following chemical formula.
[changing 5]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, R2Indicate-
H ,-CH3Or-CH2CH2COOM, M indicate Na, K or amine salt.
Since the sodium salt, sylvite or amine salt of (A -3) N- acylamino acid are the substances with mild dirt-removing power, to skin
The irritation of skin is small, it is advantageous to.
(B -1)~(B -8) as the amphoteric surfactant of (B group), represented by can enumerating by following chemical formulas.
(B–1)
[changing 6]
R-NH-CH2-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–2)
[changing 7]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–3)
[changing 8]
R-NH-CH2CH2-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–4)
[changing 9]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–5)
[changing 10]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–6)
[changing 11]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–7)
[changing 12]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
(B–8)
[changing 13]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt.
It is preferred that containing the zwitterionic surfactant with hydroxyl in gel detergent, this is because it can be with water
The interaction of soluble natural macromolecule, can aid in gelation.In addition, it is low from the irritation to skin, have in hard water
Stability and with excellent foaming power from the viewpoint of, preferred alkylamide propyl-betaine shown in (B -6).From excellent
Different detergency and foaming power, and the low irritant viewpoint consideration to eyes, preferably 2- alkyl-N- carboxymethyl-N- ethoxy
Imidazolinium betaine.
Gelling agent can be containing the one kind or substance of more than two kinds selected from C group as shown below.
(C group) gelating agent
The water soluble polymer of (C -1) from plant or seaweed
Xyloglucan, guar gum, locust bean gum, agarose, carrageenan, gum arabic, sodium alginate, Portugal's sweet dew are poly-
Sugar, pectin.
(C -2) comes from water soluble polymer caused by microbe fermentation method
Xanthan gum, gellan gum, pulullan polysaccharide, Curdlan, Sodium Hyaluronate.
Consider from the low irritant viewpoint to skin, is preferably converted with the aqueous solution of 1 weight %, the pH of gel detergent
Value is 8 or more 11 hereinafter, being alkali resistance, salt tolerance, the substance of heat resistance it is advantageous to gelating agent.Wherein, due to coming from sieve
Xyloglucan, guar gum, carrageenan, the misdescription of shop sign in the form of a streamer glue be with salt tolerance, the water soluble polymer of the glue class of heat resistance,
And they come from plant, so they are preferred from the viewpoint of environmental protection.
The use level of gelling agent is calculated on the basis of all total weights of gel detergent, preferably its 0.1 weight
10 weight % of % or more is measured hereinafter, further preferably 1 weight % or more, 5 weight % or less.When the use level of gelling agent is small
When 1 weight %, it is difficult to solidization forms gel, on the other hand, if the use level of gelling agent is more than 10 weight %,
It will lead to excessive solid, so that the bubble of gel detergent is weakened, do not allow to be also easy to produce foam when in use, and
Detergency can not be played.
It is preferable to use viscosity be 5mPas or more 9000mPas hereinafter, further preferably viscosity be 1000mPas with
Upper 8000mPas is hereinafter, still more preferably viscosity is the 1 of 2000mPas or more 6000mPas gelling agent below
The aqueous solution of weight %.When viscosity is lower than 5mPas or more than 9000mPas, processing is become difficult.
As gel detergent, from improving foaming characteristic, foam quality and to the moisture retention of skin, by with water solubility
From the perspective of tackifying shown by the interaction of the gelating agent of macromolecule etc., one or more are preferably comprised
The substance of monohydric alcohol or polyalcohol.
It as monohydric alcohol or the specific example of polyalcohol, can enumerate, ethyl alcohol, propyl alcohol, these monohydric alcohols of isopropanol；It is different
Pentanediol, propylene glycol, dipropylene glycol, 1.2- hexylene glycol, pentanediol, polyethylene glycol (molecular weight is 400 or more 7000 or less) gather
Propylene glycol (molecular weight 400), diglycerol, 1,3-BDO, glycerol, the polyalcohol of inositol etc.；Sucrose, lactose, xylitol, wheat
Bud sugar alcohol, mannitol, maltose, D-sorbite, fructose, trehalose, erythrite, gossypose, lactitol, misdescription, misdescription, sugar
The carbohydrate or glycitols of slurry etc..
About the use level of monohydric alcohol or polyalcohol, from the viewpoint of tackifying and foaming characteristic, with gel detergent
All total weights on the basis of calculate, use level is preferably 2 weight % or more, 50 weight % hereinafter, further preferably 10 weights
Measure % or more 40 weight % or less.About the use level of carbohydrate or glycitols, it is with all total weights of gel detergent
Benchmark, use level is preferably 0.5 weight % or more, 50 weight % hereinafter, further preferably 3 weight % or more, 30 weights
Measure % or less.
Fig. 1 shows be the manufacture for illustrating gel detergent involved in first embodiment for carrying out the present invention
The flow chart of the technique of method.First embodiment of the invention is by process implementing below, that is, gelating agent exists
It is heated to 70 DEG C or more 85 DEG C or less in water to make it dissolve, to obtain the technique (A) (step S1) of gelation aqueous solution；So
Afterwards, make its dispersion after adding cleaning agent component in gelation aqueous solution, to obtain the technique of dissolved mixture
(B) (step S2)；Then, the mixture after stirring and dissolving, and fill it into the technique in the rubber-like container of forming
(C) (step S3)；Then, the dissolved mixture filled in rubber-like container is placed in hardening by cooling under conditions of room temperature
Technique (D) (step S4)；Then, the technique (E) (step S5) of rubber-like container is removed.
In step sl, gelating agent is carried out to 70 DEG C or more 85 DEG C heating below in water to make it dissolve, to obtain
Obtain gelation aqueous solution.Gelation aqueous solution is under the conditions of 70 DEG C or more 85 DEG C below, according to preset time (example
Such as, 3 hours 15 minutes or more or less) it carries out heating and expands gelating agent, and pass through the institute that mixes or be dissolved in the water with water
It obtains.What Fig. 5 was indicated is the schematic cross sectional view of an example of the fluid reservoir of manufacturing method for carrying out the present invention.Example
Such as, gelating agent and water are added in the fluid reservoir 10 for having heater 11 as shown in Figure 5.Then, pass through operation
The agitating device 12 for having stirring blade etc. in fluid reservoir 10, is stirred, so that gelation is water-soluble in fluid reservoir
Liquid 13 is uniformly mixed.When heating temperature being not up to 70 DEG C the case where, it is likely that cause the dissolution of gelating agent incomplete, separately
On the one hand, if heating temperature is more than 85 DEG C, there is the possibility being denaturalized in gelating agent if.
In addition, in step sl, adding unitary when making in gel detergent containing the case where unitary or polyalcohol
Or polyalcohol, and gelating agent and water are carried out heating under the conditions of 70 DEG C or more 85 DEG C are below together keeps them molten
Solution is to obtain gelation aqueous solution.
In step s 2, keep its dispersion dissolved to obtain after cleaning agent component is added into gelation aqueous solution
Mixture.In order to be generally uniformly dispersed in cleaning agent component in gelation aqueous solution, preferably in preset time (example
Such as, 2 hours 1 hour or more or less) in heated, and dispersed.Heating temperature can be according to gelling agent and cleaning
The fusing point of agent constituent carries out setting appropriate.Under normal circumstances, preferably heating temperature highest possessed by raw material melting is warm
It is more than the fusing point of degree, in order to which dissolution of raw material can either be made gelating agent can be prevented to be denaturalized again, preferable temperature be 65 DEG C with
Upper high 85 DEG C or less.
Being mixed into because of bubble caused by addition cleaning agent component in order to prevent, and improve the transparent of gel detergent
Property is, it is preferable to use dissolved mixture is de-gassed by vacuum tank.What Fig. 2 was indicated is to illustrate for carrying out the present invention the
The flow chart of the technique of the manufacturing method of gel detergent involved in two embodiments is into gelation aqueous solution
Make its dispersion after addition cleaning agent component, to obtain in the technique (B) of dissolved mixture, to gelation aqueous solution
Make its dispersion after middle addition cleaning agent component, and be de-gassed, to obtain technique (the G) (step of dissolved mixture
Rapid S2-1).What Fig. 6 was indicated is the schematic cross section of an example of the vacuum plant of manufacturing method for carrying out the present invention
Figure.In step S2-1, gelation aqueous solution and cleaning agent component are attached in vacuum kettle 21, by operating vacuum plant 20
In the vacuum plant for having stirring blade etc. agitating device 22 and have the sheath 24 of heating device, above-mentioned substance
It is heated and stirs in vacuum plant 20, by operated vacuum pumps 23, the pressure in vacuum kettle 21 can reduce or become vacuum
State, dissolved mixture is mixed uniformly, and bubble is removed.It is attached in inner wall surface in order to remove vacuum kettle 21
The retentate of 21 lower part of object or vacuum kettle, the agitating device 22 of vacuum plant be preferably an anchor formula equipped with scraping 25
Blender.In order to mix the high dissolved mixture of vicidity, the agitating device 22 of preferably vacuum plant, which is one, to be obtained
Obtain the device of 5 meter per seconds or more, 25 meter per seconds peripheral speed below.In addition, from the viewpoint of the efficiency for removing bubble, it is excellent
Choosing makes vacuum degree 15KPa (abs) the following 75KPa (abs) in vacuum plant 20 below.It is added when into gelation aqueous solution
Make its dispersion after cleaning agent component, the technique and degasification technique for obtaining dissolved mixture are same in vacuum plant 20
When the case where Shi Jinhang, the moisture in dissolved mixture is reduced in order to prevent, and the processing time is preferably 1 hour or more 1.5
Hour hereinafter, in addition, when heated, the preferably interim mode carried out.
What Fig. 3 was indicated is the manufacture for illustrating gel detergent involved in third embodiment for carrying out the present invention
The flow chart of the technique of method makes its dispersion after adding cleaning agent component into gelation aqueous solution, to be dissolved
In the technique (B) of mixture afterwards, which includes so that its dispersion is gone forward side by side after adding fatty acid potassium salt into gelation aqueous solution
Row degassing obtains the technique (H) (step S2-2) of adjustment object, and adds into adjustment object described clear other than fatty acid potassium salt
So that it is dispersed and is de-gassed after clean dose of constituent, obtains the technique (I) (step S2-3) of dissolved mixture.Work as gel
When the case where containing fatty acid potassium salt in detergent, since the removing of bubble is relatively difficult, so being obtained from gelation aqueous solution
When obtaining dissolved mixture, step S2-2 and step S2-3 is preferably implemented, is deaerated twice.
In gelation detergent of the invention, other than containing gelating agent and cleaning agent component, this is not being damaged
Other compositions can also be contained in the range of the purpose of invention, for example, preservative (P-hydroxybenzoic acid second can be mated properly into
Ester, butyl p-hydroxybenzoate etc.), pulvis (pigment, dyestuff, resin etc.), fragrance, moisturizer, physiologically active ingredient, salt,
Solvent, pearling agent, neutralizer, pH adjusting agent, the ingredients such as enzyme.From the viewpoint of the dispersibility of each ingredient, preferred these ingredients
It can be with the substance that detergent composition is matched without the dissolved mixture sufficiently dissolved in gelation aqueous solution, example
Such as, when making in gel detergent containing the case where goldleaf, the goldleaf being scattered in spirit solvent is added to dissolved
Mixing is carried out in mixture makes its dispersion.
In step S3, mixture after stirring and dissolving, and fill it into the rubber-like container of forming.Fig. 7 A is indicated
Be the view that dissolved mixture of the invention is filled into the technique in the rubber-like container of forming.What Fig. 7 B was indicated
It is the expanded view of fill process.
On the outer peripheral portion of the turntable 1 of filling device 40, there are multiple notch sections 2 with spaced set, be additionally provided with
Injection unit 3, removal portion 4.When rubber-like container 41 is in mounted state, turntable 1 carries out intermittent rotary.It is being located at note
Enter the notch section 2 before portion 3 and rubber-like container 41 is installed.In injection unit 3, when turntable 1 is in stop phase, note
Enter device 3a decline, the top close proximity with rubber-like container 41, and after filling a certain amount of dissolution into rubber-like container 41
Mixture.Further, when increase injector 3a, since dissolved mixture can be from rubber-like
It is overflowed in container, so by the binding apparatus 3b for the peripheral part for being set to turntable 1, using binding material 41c by opening portion
Increase injector 3a after 41a binding.Further, the rubber-like container 41 that inside is filled with dissolved mixture is revolved
Turn, is removed in removal portion 4 from notch section.
As shown in Figure 7 B, rubber-like container 41 has the opening portion 41a for filling dissolved mixture, and is generally formed into
The spherical or elliptical enlarged portion 41b that can be expanded.About the material of rubber-like container 41, such as it can be genuine milk
Glue or synthetic latex etc., as long as substance used under normal conditions is then not particularly limited.Due in rubber-like container
41 inside has coloring or the pattern that can transfer, so can beRubberThe outside of shape detergent applies coloring or figure
Case.In addition, although the loading of dissolved mixture is not particularly limited, for example, loading 100g can be made, this
Sample, rubber-like container expand the approximately spherical shape to form that diameter is 5cm.
What Fig. 4 was indicated is the manufacture for illustrating gel detergent involved in the 4th embodiment for carrying out the present invention
The flow chart of the technique of method.It further preferably include from the opening portion of rubber-like container between technique (C) and technique (D)
Suction removes the technique (F) (step S3-2) of the remaining dissolved mixture.When the case where implementation steps S3-2, example
Such as, the remaining dissolved mixture that will preferably betray from rubber-like container 41 in the setting of the removal portion 4 of filling device 40
The suction unit 4a removed from the opening portion 41a of rubber-like container suction.The suction pump 4b of suction unit 4a passes through sucking suction
Gas in mouth 4c, so that remaining dissolved mixture is recycled, meanwhile, it can be by rubber-like container 41 by the suction pressure
It is removed from notch section 2.
What Fig. 7 C was indicated is manufacturing method for carrying out the present invention, and dissolved mixture is filled into the rubber of forming
The sectional view of one example of the filling device in gluey container.Filling device 40 is one respectively to make injector by cylindrical cam
3a is increased or reduced device.It is slidably mounted with plunger 5 in the central part of injector 3a, injector 3a passes through injector
7 oscilaltion of cam is driven, plunger 5 passes through 6 oscilaltion of plunger actuation cam.When turntable 1 stops, injector 3a is infused
Enter device driving cam 7 driving and decline, is contacted with the upper surface of turntable 1, then, under plunger 5 is pushed to by plunger actuation cam 6
Side.On the top of filling device 40, the fluid reservoir 8 of filling device is installed, it is internal full of the dissolved mixing that should be filled
Object.Plunger 5 rise stage in, dissolved mixture from agitating function filling device fluid reservoir 8 via pipe
Road 9 flows into injector 3a, is filled into rubber-like container 41 by the decline of plunger 5.It attached the camshaft of each cam
47 are driven by motor 42 by chain 43, and turntable 1 is driven by engine 42, passes through chain 44,45 and of intermittent driving unit
Chain 46 and rotate.
From the viewpoint of fillibility, dissolved mixture is preferably cooled to 60 DEG C or more 65 DEG C or less.Work as temperature
When lower than 60 DEG C, dissolved mixture is easy to happen hardening, causes the fillibility into rubber-like container to be deteriorated, another party
Face, when temperature is more than 65 DEG C, the viscosity of dissolved mixture declines, when filling, it is possible to lead to gel detergent
Weight is uneven.In addition, in the technique (C) in the rubber-like container that dissolved mixture is filled into forming, preferably
Filling speed be 33g/ seconds or more, 50g/ seconds or less.When filling speed is lower than 33g/ seconds, dissolved mixture is easy hair
Stiffization, on the other hand, when filling speed is higher than 50g/ seconds, it is possible to air be caused to be mixed into rubber-like container 41.
In step s 4, the dissolved mixture being filled into rubber-like container 41 carries out cold at room temperature
But it and hardens.Fig. 8 shows be manufacturing method for carrying out the present invention, be filled into molten in the rubber-like container of forming
The schematic diagram of an example of device that mixture after solution is cooled down and hardened.The dissolution being filled into rubber-like container 41
Mixture afterwards, the oral area 41a being tied is incorporated on fixator 51 in a manner of downward, and is placed on containing box
In 50, stand at room temperature.By the way that the time required for hardening by cooling is set as 2 days 1 day or more degree below,
So that the dissolved mixture being filled into rubber-like container 41 to form gel cleaning up to centre hardens
Agent.
In step s 5, rubber-like container is removed.What Fig. 9 was indicated is the technique for removing rubber-like container of the invention
(E) view.Rupture rubber-like container 41 by the utensil 61 with sharp portion of needle etc., to remove rubber-like container
41, to take out gel detergent 62 from rubber-like container 41.Because rubber-like container 41 is clear by gel filled shape
It to expand, is shaped generally as elliptical spherical for clean dose 62, it is possible to which rubber-like container 41 is destroyed in the hole by generating very little
Surface, ruptured to become easy.
As shown in Figure 7 B, preferred rubber shape container 41 has protrusion 41d in the opposite side of opening portion 41a.In step
It is clear it is possible to damage gel because the rubber membrane moment split shrinks when rubber-like container 41 ruptures in S5
Clean dose 62 of outer shape.However, the rubber-like when having protrusion 41d on rubber-like container 41, with no protrusion 41d
Container is compared, and rubber membrane can smoothly be shunk, therefore the outer shape of gel detergent 62 is enabled to not to be destroyed
In the case where rubber-like container 41 can rupture.
Embodiment
Hereinafter, by embodiment, the present invention will be described in more detail.But the present invention is not by embodiment below
The invention limited.In the detailed description of specification of the invention, embodiment and claims documented percentage,
Ratio and weight portion are all weight basis, unless otherwise stated, it is a schematical value.In addition, embodiment 1~
6 are prepared according to the flow chart of manufacturing process shown in Fig. 1.
[embodiment 1]
(1) Purified Water 67.9%
(2) glycerol 10.0%
(3) dipropylene glycol 7.0%
(4) 1,2- hexylene glycol 2.5%
(5) xyloglucan (registered trademark: GLYLOID 6C ,/DSP GOKYO food chemistry Co., Ltd) 0.8%
0.8%
(6) xanthan gum 0.2%
(7) lauric acid 5.9%
(8) myristic acid 2.2%
(9) palmitinic acid 1.0%
(10) stearic acid 0.4%
(11) oleic acid 0.6%
(12) sodium hydroxide 1.5%
Amount to 100.0%
Preparation method
Ingredient (5), (6) are soaked in the mixture of ingredient (2), (3) and disperse them, are then added them into
In ingredient (1), 85 DEG C are heated to, and being stirred makes them dissolve (step S1).Then, thereto be added ingredient (7)~
(12) it mixed, dissolved, be stirred to obtain uniform dissolved mixture (step S2).It then, will be after dissolution
Mixture be maintained at 65 DEG C~80 DEG C, the mixture after stirring and dissolving, and filling it into the rubber-like container of forming
(step S3), the dissolved mixture being then filled into rubber-like container stand (step S4) at room temperature,
Then, rubber-like container (step S5) is removed with toothpick, to obtain gel detergent.
[embodiment 2]
(1) Purified Water 48.4%
(2) sorbierite 10.0%
(3) propylene glycol 10.0%
(4) 1,2- hexylene glycol 2.5%
(5) xyloglucan (registered trademark: GLYLOID 6C) 1.0%
(6) xanthan gum 0.5%
(7) lauric acid 5.9%
(8) myristic acid 2.2%
(9) palmitinic acid 1.0%
(10) stearic acid 0.3%
(11) oleic acid 0.6%
(12) potassium hydroxide 2.60%
(13) dodecanamide propyl hydroxy sulfo lycine (SOFTAZOLINE LSB//Chuan Yan fine chemicals Co., Ltd)
15.0%
Amount to 100.0%
Preparation method
Ingredient (5), (6) are soaked in the mixture of ingredient (2)~(4) and disperse them, are then added them into
To in ingredient (1), 85 DEG C are heated to, and being stirred makes them dissolve (step S1).Then, thereto be added ingredient (7)~
(12) it is mixed, after being then heated to 75 DEG C~85 DEG C dissolutions, is stirred after ingredient (13) are added, so that it is equal to obtain mixing
Even dissolved mixture (step S2).Then, dissolved mixture is maintained at 75 DEG C~80 DEG C, after stirring and dissolving
Mixture, and fill it into the rubber-like container of forming (step S3), it is then filled into molten in rubber-like container
Mixture after solution stands (step S4) at room temperature, then, removes rubber-like container (step S5) with toothpick, thus
Obtain gel detergent.
[embodiment 3]
(1) Purified Water 48.0%
(2) dipropylene glycol 7.0%
(3) 1,2- hexylene glycol 2.5%
(4) xanthan gum 0.5%
(5) carrageenan 2.0%
(6) the coco-nut oil fatty acid amido propyl betaine aqueous solution (east OBAZORIN CAB30/ nation chemical industry strain formula meeting
Society) 40.0%
Amount to 100.0%
Preparation method
Ingredient (4), (5) are soaked in the mixture of ingredient (2), (3) and disperse them, are then added them into
In ingredient (1), 85 DEG C are heated to, and being stirred makes them dissolve (step S1).Then, ingredient (6) are added thereto to carry out
Mixing, and stir to obtain uniformly mixed dissolved mixture (step S2).Then, dissolved mixture is kept
In 68 DEG C~80 DEG C, mixture after stirring and dissolving, and fill it into the rubber-like container of forming (step S3), then
The dissolved mixture being filled into rubber-like container stands (step S4) at room temperature, then, is removed with toothpick
Rubber-like container (step S5) is removed, to obtain gel detergent.
[embodiment 4]
(1) Purified Water 58.5%
(2) dipropylene glycol 7.0%
(3) 1,2- hexylene glycol 2.5%
(4) carrageenan 2.0%
(5) polyoxyethylene lauryl ether sodium acetate (NEO-HITENOL ECL-30S/ Di-ichi Kogyo Seiyaku Co., Ltd.)
30.0%
Amount to 100.0%
Preparation method
Ingredient (4) is soaked in the mixture of ingredient (2), (3) and disperses them, then adds them into ingredient
(1) in, 85 DEG C are heated to, and being stirred makes them dissolve (step S1).Then, ingredient (6) are added thereto to be mixed,
85 DEG C are heated to, and is stirred to obtain uniformly mixed dissolved mixture (step S2).It then, will be dissolved
Mixture is maintained at 60 DEG C~75 DEG C, the mixture after stirring and dissolving, and fills it into (step in the rubber-like container of forming
Rapid S3), the dissolved mixture being then filled into rubber-like container stands (step S4) at room temperature, so
Afterwards, rubber-like container (step S5) is removed with toothpick, to obtain gel detergent.
[embodiment 5]
(1) Purified Water 59.5%
(2) 1,2- hexylene glycol 2.5%
(3) xyloglucan (registered trademark: GLYLOID 6C) 0.7%
(4) xanthan gum 0.3%
(5) potash soap base (100%) 12.0%
(6) dodecanamide propyl hydroxy sulfo lycine (SOFTAZOLINE LSB/ Chuan Yan fine chemicals Co., Ltd)
15.0%
(7) glycerol 10.0%
(8) appropriate citric acid
(9) appropriate sodium citrate
Amount to 100.0%
Preparation method
Ingredient (3), (4) are soaked in ingredient (2) and disperse them, then adds them into ingredient (1), adds
Heat is to 85 DEG C, and being stirred makes them dissolve (step S1).Then, ingredient (5), (6) are sequentially added, is heated to 65 DEG C~85
DEG C, it is stirred during heating, after mentioned component dissolution, ingredient (7)~(9) is added thereto, pH value adjustment is arrived
10.0 so that obtain uniform dissolved mixture (step S2).Then, the mixture after stirring and dissolving, and fill it into
In the rubber-like container of forming (step S3), the dissolved mixture in rubber-like container is then filled into room temperature
Under the conditions of stand (step S4), then, with toothpick remove rubber-like container (step S5), to obtain gel detergent.
[embodiment 6]
(1) Purified Water 36.5%
(2) dipropylene glycol 10.0%
(3) 1,2- hexylene glycol 2.5%
(4) xanthan gum 0.5%
(5) locust bean gum 0.5%
(6) the coco-nut oil fatty acid amido propyl betaine aqueous solution (east OBAZORIN CAB30/ nation chemical industry strain formula meeting
Society) 50.0%
Amount to 100.0%
Preparation method
Ingredient (4), (5) are soaked in the mixture of ingredient (2), (3) and disperse them, are then added them into
In ingredient (1), 85 DEG C are heated to, and being stirred makes them dissolve (step S1).Then, ingredient (6) are added thereto to carry out
After mixing, 70 DEG C~85 DEG C are heated to, and is stirred to obtain uniformly mixed dissolved mixture (step S2).So
Afterwards, the mixture after stirring and dissolving, and fill it into the rubber-like container of forming (step S3), then it is filled into rubber
Dissolved mixture in gluey container stands (step S4) at room temperature, then, removes rubber-like with toothpick and holds
Device (step S5), to obtain gel detergent.
More than, using embodiment, the present invention is described, but technical scope of the invention be not limited to it is above-mentioned
Range documented by embodiment.It will be apparent to one skilled in the art that can apply to above embodiment each
Kind changes or modifications.In addition, according to the range of the record of claims it is readily apparent that the application various changes or improvement
Embodiment be also included in the technical scope of the present invention.
Description of symbols
1 turntable
2 notch sections
3 injection units
3a injector
3b binding apparatus
4 removal portions
4a suction unit
4b suction pump
4c suction nozzle with battery unit
5 plungers
6 plunger actuation cams
7 injectors drive cam
The fluid reservoir of 8 filling devices
9 pipelines
10 fluid reservoirs
11 heaters
12 agitating devices
13 gelation aqueous solutions
20 vacuum plants
21 vacuum kettles
The agitating device of 22 vacuum plants
23 vacuum pumps
24 sheaths
25 scrapings
40 filling devices
41 rubber-like containers
The opening portion 41a
41b enlarged portion
41c binding material
41d protrusion
42 engines
43,44,46 chain
45 intermittent drive devices
47 camshafts
50 containing boxs
51 fixators
61 utensils with point
62 gel detergents
Claims (6)
1. a kind of manufacturing method of gel detergent, it is characterised in that have following techniques,
Technique (A) is that gelating agent is heated to 70 DEG C or more 85 DEG C or less in water to make it dissolve, to obtain gelation
The technique of aqueous solution；
Technique (B), be into the gelation aqueous solution add cleaning agent component after make its dispersion, be then de-gassed from
And the technique for obtaining dissolved mixture；
Technique (C) was by the dissolved mixture with 33g/ seconds or more, and filling speed below is filled into tool within 50g/ seconds
Have opening portion, enlarged portion, protrusion forming rubber-like container in technique, wherein the opening portion is for filling institute
Dissolved mixture is stated, the enlarged portion is expanded because filling the dissolved mixture, and the protruding part is in described
The opposite side of opening portion；
Technique (F) is the technique for removing the remaining dissolved mixture from the suction of the opening portion of rubber-like container；
Technique (D), be the dissolved mixture that is filled into the rubber-like container at room temperature into
The technique of row hardening by cooling；
Technique (E) is the technique for removing the rubber-like container.
2. the manufacturing method of gel detergent according to claim 1, which is characterized in that
The cleaning agent component be containing from selected in A group and/or B group as follows it is one or two kinds of more than
Substance,
The gelating agent be containing the one or more kinds of substances selected from C group as follows,
(A group) anionic surfactant
(A -1) carboxylate,
[changing 1]
R-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(A -2) polyoxyethylene alkyl ether carboxylate, wherein the carbon atom number of alkyl is 12~22, for saturation or unsaturation；
[changing 2]
R-O(CH2CH2O)nR1COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, n average out to 1~20, R1Indicate carbon atom number
For 1 or 2 saturated alkyl, M indicates Na, K or amine salt；
Sodium salt, sylvite or the amine salt of (A -3) N- acylamino acid；
[changing 5]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, R2Expression-H ,-CH3Or-CH2CH2COOM, M
Indicate Na, K or amine salt；
B group: amphoteric surfactant；
(B–1)
[changing 6]
R-NH-CH2-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–2)
[changing 7]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–3)
[changing 8]
R-NH-CH2CH2-COOM
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–4)
[changing 9]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–5)
[changing 10]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–6)
[changing 11]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–7)
[changing 12]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(B–8)
[changing 13]
In formula, R indicates the saturation or unsaturated alkyl that carbon atom number is 12~22, and M indicates Na, K or amine salt；
(C group) gelating agent
The water soluble polymer of (C -1) from plant
Wherein, (C -1) is selected from xyloglucan, guar gum, locust bean gum, agarose, angle fork from the water soluble polymer of plant
Dish glue, gum arabic, sodium alginate, glucomannans, pectin；
(C -2) comes from water soluble polymer caused by microbe fermentation method
Wherein, (C -2) comes from water soluble polymer caused by microbe fermentation method and is selected from xanthan gum, gellan gum, Propiram
Polysaccharide, Curdlan, Sodium Hyaluronate.
3. the manufacturing method of gel detergent according to claim 2, which is characterized in that
The carboxylate of (A -1) is the carboxylate containing fatty acid potassium salt.
4. the manufacturing method of gel detergent according to claim 2, which is characterized in that
Salt of the polyoxyethylene alkyl ether carboxylate of (A-2) containing (A-2-1) or (A-2-2) as described below,
In, the carbon atom number of alkyl is 12~22, for saturation or unsaturated,
(A-2-1) polyoxyethylene alkyl ether acetate
[changing 3]
R-O(CH2CH2O)nCH2COOM
In formula, R indicate carbon atom number be 12~22 saturation or unsaturated alkyl, n average out to 1~20, M indicate Na, K or
Amine salt；
(A-2-2) polyoxyethylene alkyl ether propionate
[changing 4]
R-O(CH2CH2O)nCH2CH2COOM
In formula, R indicate carbon atom number be 12~22 saturation or unsaturated alkyl, n average out to 1~20, M indicate Na, K or
Amine salt.
5. the manufacturing method of gel detergent according to claim 1, which is characterized in that
The gel detergent further contains one or more kinds of monohydric alcohols or polyalcohol.
6. the manufacturing method of gel detergent according to claim 4, which is characterized in that
In the technique (B), further include,
Make its dispersion after adding fatty acid potassium salt into the gelation aqueous solution, is then de-gassed to obtain adjustment object
Technique (H)；With
Make its dispersion after adding the cleaning agent component other than the fatty acid potassium salt into the adjustment object, then carries out
Degassing is to obtain the technique (I) of the dissolved mixture.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910739084.3A CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
| CN201910738879.2A CN110499221A (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2013/084366 WO2015092939A1 (en) | 2013-12-20 | 2013-12-20 | Method for producing gel detergent |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910739084.3A Division CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
| CN201910738879.2A Division CN110499221A (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105849246A CN105849246A (en) | 2016-08-10 |
| CN105849246B true CN105849246B (en) | 2019-08-16 |
Family
ID=53402331
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910738879.2A Pending CN110499221A (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
| CN201380081777.9A Active CN105849246B (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
| CN201910739084.3A Pending CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910738879.2A Pending CN110499221A (en) | 2013-12-20 | 2013-12-20 | The manufacturing method of gel detergent |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910739084.3A Pending CN110591827A (en) | 2013-12-20 | 2013-12-20 | Method for producing gel-like detergent |
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| EP (1) | EP3085762B1 (en) |
| JP (1) | JP6322214B2 (en) |
| KR (1) | KR102072833B1 (en) |
| CN (3) | CN110499221A (en) |
| ES (1) | ES2881233T3 (en) |
| WO (1) | WO2015092939A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014139307A (en) * | 2012-12-22 | 2014-07-31 | Neige Corporation:Kk | Method for producing gelled detergent |
| WO2018189587A1 (en) | 2017-04-14 | 2018-10-18 | Capsugel Belgium Nv | Process for making pullulan |
| CN110678170A (en) | 2017-04-14 | 2020-01-10 | 比利时胶囊公司 | Pullulan polysaccharide capsule |
| CN113430077A (en) * | 2021-08-04 | 2021-09-24 | 王盛龙 | Enzyme-containing laundry gel ball and preparation method thereof |
| DE102022203707A1 (en) * | 2022-04-13 | 2023-10-19 | Henkel Ag & Co. Kgaa | Process for producing a detergent portion unit |
| KR102571190B1 (en) * | 2022-12-16 | 2023-08-28 | 권명주 | Cleansing balm composition and manufacturing method thereof |
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- 2013-12-20 CN CN201380081777.9A patent/CN105849246B/en active Active
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| JP2013100305A (en) * | 2011-12-28 | 2013-05-23 | Neige Corporation:Kk | Gel and semi-solid detergent |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN110499221A (en) | 2019-11-26 |
| ES2881233T3 (en) | 2021-11-29 |
| WO2015092939A1 (en) | 2015-06-25 |
| JPWO2015092939A1 (en) | 2017-03-16 |
| JP6322214B2 (en) | 2018-05-09 |
| EP3085762B1 (en) | 2021-06-16 |
| KR20160100303A (en) | 2016-08-23 |
| CN110591827A (en) | 2019-12-20 |
| KR102072833B1 (en) | 2020-02-03 |
| EP3085762A1 (en) | 2016-10-26 |
| EP3085762A4 (en) | 2017-08-02 |
| CN105849246A (en) | 2016-08-10 |
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