CN110591116A - Modified emulsifier for environment-friendly asphalt for micro-surfacing - Google Patents

Modified emulsifier for environment-friendly asphalt for micro-surfacing Download PDF

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Publication number
CN110591116A
CN110591116A CN201810602190.2A CN201810602190A CN110591116A CN 110591116 A CN110591116 A CN 110591116A CN 201810602190 A CN201810602190 A CN 201810602190A CN 110591116 A CN110591116 A CN 110591116A
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China
Prior art keywords
parts
environment
micro
surfacing
modified
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Withdrawn
Application number
CN201810602190.2A
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Chinese (zh)
Inventor
田纹绮
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Individual
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Individual
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Priority to CN201810602190.2A priority Critical patent/CN110591116A/en
Publication of CN110591116A publication Critical patent/CN110591116A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/028—Polyamidoamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2395/00—Bituminous materials, e.g. asphalt, tar or pitch
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2409/06—Copolymers with styrene
    • C08J2409/08—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2411/00—Characterised by the use of homopolymers or copolymers of chloroprene
    • C08J2411/02—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2479/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
    • C08J2479/02—Polyamines

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Polyamides (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The invention discloses a modified emulsifier for micro-surfacing environment-friendly asphalt, which solves the problems of short storage time, strong smell and environmental pollution of the emulsifier in China in the prior art. The invention comprises the following components in parts by weight: 3-5 parts of cationic styrene-butadiene latex, 1.5-2.5 parts of neoprene latex, 2.5-3 parts of oleyl propylene diamine, 1.8-2.2 parts of industrial hydrochloric acid, 1.6-2.0 parts of Mqk-1m and 1.5-2.5 parts of PAMAM. The invention has the advantages of good emulsification effect, good stability and the like, can greatly prolong the storage time, and has very remarkable effect.

Description

Modified emulsifier for environment-friendly asphalt for micro-surfacing
Technical Field
The invention relates to an emulsifier, in particular to a modified emulsifier of environment-friendly asphalt for micro surfacing.
Background
Micro-surfacing is a more advanced preventative maintenance method developed on the basis of slurry seals. The working principle is that stone chips or sand, filler (cement, lime, fly ash, stone powder, etc.), polymer modified emulsified asphalt, additive and water are mixed according to a certain proportion to form a flowing mixture, and then the mixture is uniformly spread on the road surface to form a sealing layer. The micro-surfacing has the characteristics of economy, energy conservation, environmental protection and safety, so that the micro-surfacing becomes an effective preventive maintenance mode and is widely applied to the road surface maintenance of the highway in China.
The emulsified asphalt has the advantages of energy and asphalt saving, environmental protection, safety, wide application, convenient use, ideal road effect and the like. Emulsified asphalt is the best binder for micro surfacing. At present, the production base of emulsified asphalt in China is distributed all over the country. The road maintenance industry has been developing to make the demand of high-performance emulsified asphalt increase greatly.
The development of high concentration, high stability and ultrafine particle of the emulsified asphalt puts higher requirements on the used emulsifier. The domestic emulsifier is developed to a certain extent, but the emulsifier still has the defects of few varieties, unstable quality, low solid content, short storage time, strong smell and environmental pollution.
Disclosure of Invention
The invention aims to solve the problems of short storage time, strong smell and environmental pollution of the emulsifier in China in the prior art; provides a modified emulsifier for environment-friendly asphalt for micro-surfacing, which solves the problems.
In order to achieve the purpose, the technical scheme of the invention is as follows:
a modified emulsifier for environment-friendly asphalt for micro-surfacing comprises the following components in parts by weight:
3-5 parts of cationic styrene-butadiene latex, 1.5-2.5 parts of neoprene latex, 2.5-3 parts of oleyl propylene diamine, 1.8-2.2 parts of industrial hydrochloric acid, 1.6-2.0 parts of Mqk-1m and 1.5-2.5 parts of PAMAM.
Because the emulsifying effect of a single emulsifier is not ideal, better effect can be achieved if other emulsifiers or auxiliary agents are added. The invention screens out the components which are matched with each other through long-term productive technology research and experiments, and the components are compounded with each other, so that the construction requirement is met, the production cost of the emulsified asphalt can be effectively reduced, and the effect is obvious.
Moreover, all the components of the invention are environment-friendly materials, have no smell or little smell, do not influence the environment after being used, and have excellent environment-friendly effect. Moreover, the emulsifier prepared by the invention has good emulsifying effect and good stability, can greatly prolong the storage time and has very remarkable effect.
Further, the concentration of the industrial hydrochloric acid is 30-40%.
Further, the PAMAM is modified hyperbranched polyamide-amine.
Furthermore, the specific preparation process of the modified hyperbranched polyamide-amine is as follows:
(1) synthesizing AB by Michael addition reaction of diethylenetriamine and methyl acrylate2The mass ratio of the diethylenetriamine to the methyl acrylate is 1: 1-1.2;
(2)AB2the type monomer is subjected to self melt polycondensation reaction to synthesize hyperbranched polyamide-amine;
(3) carrying out amidation reaction on hyperbranched polyamide-amine and oleic acid, wherein the ratio of the amount of a substance of primary amine to the amount of a substance of oleic acid in the hyperbranched polyamide-amine is 1: 1-1.2.
Preferably, the invention comprises the following components in parts by weight:
4.2 parts of cationic styrene-butadiene latex, 1.8 parts of neoprene latex, 2.7 parts of oleyl propylene diamine, 2.1 parts of industrial hydrochloric acid, 1.6 parts of Mqk-1m and 2.2 parts of PAMAM.
Compared with the prior art, the invention has the following advantages and beneficial effects:
1. according to the invention, through the mutual compounding of the components, the construction requirements are met, the production cost of the emulsified asphalt can be effectively reduced, and the effect is obvious;
2. the components of the invention are environment-friendly materials, have no smell or little smell, do not influence the environment after being used, and have excellent environment-friendly effect;
3. the emulsifier prepared by the invention has good emulsifying effect and good stability, can greatly prolong the storage time and has very obvious effect.
Detailed Description
The present invention will be described in further detail with reference to examples, but the embodiments of the present invention are not limited thereto.
Example 1
A modified emulsifier for environment-friendly asphalt for micro-surfacing comprises the following components in parts by weight:
3-5 parts of cationic styrene-butadiene latex, 1.5-2.5 parts of neoprene latex, 2.5-3 parts of oleyl propylene diamine, 1.8-2.2 parts of industrial hydrochloric acid, 1.6-2.0 parts of Mqk-1m and 1.5-2.5 parts of PAMAM.
The concrete proportions of the components in the embodiment are as follows: 4.2 parts of cationic styrene-butadiene latex, 1.8 parts of neoprene latex, 2.7 parts of oleyl propylene diamine, 2.1 parts of industrial hydrochloric acid, 1.6 parts of Mqk-1m and 2.2 parts of PAMAM.
The specific preparation method of the modified emulsifier in the embodiment is as follows:
(1) dissolving 1.6-2.0 parts of Mqk-1m and 2.5-3 parts of oleyl propylene diamine in 1.8-2.2 parts of industrial hydrochloric acid to obtain a first mixed solution for later use;
(2) 3-5 parts of cationic styrene-butadiene latex and 1.5-2.5 parts of neoprene latex are uniformly mixed to obtain a second mixed solution for later use;
(3) and mixing the mixed solution I, the mixed solution II and the PAMAM, and uniformly stirring to obtain a finished product.
Example 2
The difference between this embodiment and embodiment 1 is that the composition of each substance is optimized in this embodiment, and the specific settings are as follows:
the concentration of the industrial hydrochloric acid is 30-40%.
The PAMAM is modified hyperbranched polyamide-amine. The specific preparation process of the modified hyperbranched polyamide-amine comprises the following steps:
(1) synthesizing AB by Michael addition reaction of diethylenetriamine and methyl acrylate2The mass ratio of the diethylenetriamine to the methyl acrylate is 1: 1-1.2;
(2)AB2the type monomer is subjected to self melt polycondensation reaction to synthesize hyperbranched polyamide-amine;
(3) carrying out amidation reaction on hyperbranched polyamide-amine and oleic acid, wherein the ratio of the amount of a substance of primary amine to the amount of a substance of oleic acid in the hyperbranched polyamide-amine is 1: 1-1.2.
The above-mentioned embodiments are only preferred embodiments of the present invention, and do not limit the scope of the present invention, but all the modifications made by the principles of the present invention and the non-inventive efforts based on the above-mentioned embodiments shall fall within the scope of the present invention.

Claims (5)

1. The modified emulsifier for the environment-friendly asphalt for micro surfacing is characterized by comprising the following components in parts by weight:
3-5 parts of cationic styrene-butadiene latex, 1.5-2.5 parts of neoprene latex, 2.5-3 parts of oleyl propylene diamine, 1.8-2.2 parts of industrial hydrochloric acid, 1.6-2.0 parts of Mqk-1m and 1.5-2.5 parts of PAMAM.
2. The modified emulsifier for environment-friendly micro-surfacing asphalt according to claim 1, wherein the concentration of the industrial hydrochloric acid is 30-40%.
3. The modified emulsifier for environment-friendly asphalt for micro-surfacing according to claim 1, wherein the PAMAM is modified hyperbranched polyamidoamine.
4. The modified emulsifier for the environment-friendly asphalt for micro-surfacing according to claim 3, wherein the modified hyperbranched polyamidoamine is prepared by the following steps:
(1) synthesizing AB by Michael addition reaction of diethylenetriamine and methyl acrylate2The mass ratio of the diethylenetriamine to the methyl acrylate is 1: 1-1.2;
(2)AB2the type monomer is subjected to self melt polycondensation reaction to synthesize hyperbranched polyamide-amine;
(3) carrying out amidation reaction on hyperbranched polyamide-amine and oleic acid, wherein the ratio of the amount of a substance of primary amine to the amount of a substance of oleic acid in the hyperbranched polyamide-amine is 1: 1-1.2.
5. The modified emulsifier for the environment-friendly asphalt for micro-surfacing according to any one of claims 1 to 4, which is characterized by comprising the following components in parts by weight:
4.2 parts of cationic styrene-butadiene latex, 1.8 parts of neoprene latex, 2.7 parts of oleyl propylene diamine, 2.1 parts of industrial hydrochloric acid, 1.6 parts of Mqk-1m and 2.2 parts of PAMAM.
CN201810602190.2A 2018-06-12 2018-06-12 Modified emulsifier for environment-friendly asphalt for micro-surfacing Withdrawn CN110591116A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810602190.2A CN110591116A (en) 2018-06-12 2018-06-12 Modified emulsifier for environment-friendly asphalt for micro-surfacing

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810602190.2A CN110591116A (en) 2018-06-12 2018-06-12 Modified emulsifier for environment-friendly asphalt for micro-surfacing

Publications (1)

Publication Number Publication Date
CN110591116A true CN110591116A (en) 2019-12-20

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ID=68848838

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CN201810602190.2A Withdrawn CN110591116A (en) 2018-06-12 2018-06-12 Modified emulsifier for environment-friendly asphalt for micro-surfacing

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CN (1) CN110591116A (en)

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Application publication date: 20191220

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