CN101643340A - Stabilizer for CA mortar - Google Patents
Stabilizer for CA mortar Download PDFInfo
- Publication number
- CN101643340A CN101643340A CN200910099082A CN200910099082A CN101643340A CN 101643340 A CN101643340 A CN 101643340A CN 200910099082 A CN200910099082 A CN 200910099082A CN 200910099082 A CN200910099082 A CN 200910099082A CN 101643340 A CN101643340 A CN 101643340A
- Authority
- CN
- China
- Prior art keywords
- mortar
- water
- stablizer
- polymer latex
- cationic emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 42
- 239000003381 stabilizer Substances 0.000 title abstract 2
- 239000004816 latex Substances 0.000 claims abstract description 15
- 229920000126 latex Polymers 0.000 claims abstract description 15
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 12
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 12
- 125000002091 cationic group Chemical group 0.000 claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 5
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 claims description 4
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 244000068988 Glycine max Species 0.000 claims description 2
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 claims description 2
- MQNJWAJFPXDDBC-UHFFFAOYSA-M [Cl-].C(C1=CC=CC=C1)N.C(CCCCCCCCCCCCCCC)[N+](CC1=CC=CC=C1)(C)C Chemical compound [Cl-].C(C1=CC=CC=C1)N.C(CCCCCCCCCCCCCCC)[N+](CC1=CC=CC=C1)(C)C MQNJWAJFPXDDBC-UHFFFAOYSA-M 0.000 claims description 2
- OCBHHZMJRVXXQK-UHFFFAOYSA-M benzyl-dimethyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 OCBHHZMJRVXXQK-UHFFFAOYSA-M 0.000 claims description 2
- BJQDLJHOLXWQFM-UHFFFAOYSA-N dimethyl(1-phenyltridecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC([NH+](C)C)C1=CC=CC=C1 BJQDLJHOLXWQFM-UHFFFAOYSA-N 0.000 claims description 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical group CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 239000004568 cement Substances 0.000 abstract description 11
- 239000010426 asphalt Substances 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000013530 defoamer Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000010412 perfusion Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
A stabilizer for CA mortar belongs to the technical field of manufacturing of auxiliary materials for cement asphalt mortar, and comprises water-soluble polymer monomers, polymer latex, cationic emulsifier, water and the like, wherein the components in percentage by weight are as follows: 1.2-1.5% of water-soluble polymer monomer, 8-10% of polymer latex, 1-1.3% of cationic emulsifier and the balance of water, wherein the total weight percentage of the components is 100%; the addition amount of the additive in the CA mortar is 2-6% of the weight of the CA mortar. The formula is reasonable in design, the stability of the CA mortar can be effectively improved, and the technical performance of the CA mortar is improved.
Description
Technical field
The present invention relates to a kind of CA mortar stablizer, belong to the manufacturing technology field of cement asphalt mortar with subsidiary material.
Background technology
Cement asphalt mortar (being called for short the CA mortar) is the key components of plate-type slag-free orbit in inter-city high-speed rail, city high speed light rail, the city underground etc., mainly is made up of cement, bitumen emulsion, fine aggregate etc.Perfusion CA mortar in the space that the plate-type slag-free orbit construction is reserved between pre-track plate and concrete bed the time has rigidity and elastic filling bed course concurrently with what form homogeneous, can play the dual function of adjusting the track geometry precision and absorbing the vibratory impulse energy.Because the consistency in the existing CA mortar between each component is poor, cause the poor stability of system, layering has easily influenced intensity and other performances of CA screed after the sclerosis.Therefore, the consistency of improving between each component of CA mortar is a key that promotes CA mortar technical feature.
Summary of the invention
It is reasonable to the purpose of this invention is to provide a kind of formulating of recipe, can effectively improve the stability of CA mortar, improves the CA mortar stablizer of CA mortar technical feature.
The present invention is a kind of CA mortar stablizer, it is characterized in that comprising the water-soluble polymers monomer, polymer latex, cationic emulsifier, water etc., the composition of each component is respectively by weight percentage: water-soluble polymers monomer 1.2～1.5%, polymer latex 8～10%, cationic emulsifier 1～1.3%, all the other are water, the weight percent summation of each component is 100%.
Described water-soluble polymers monomer can be polyacrylamide.
Described polymer latex can be SBR latex.
Described cationic emulsifier can be lauryl amine, tetradecylamine, hexadecylamine, dodecyl dimethyl benzyl ammonia chloride, tetradecyl benzyl dimethyl ammonium chloride, hexadecyldimethyl benzyl ammonium benzyl ammonia chloride, the soybean oleyl amine, the mixture of any one or more of coconut oleyl amine etc.To promote the emulsification of polymer latex.
Described CA mortar can be 2～6% of CA mortar weight with the add-on of stablizer in the CA mortar.
The mechanism of modification of CA mortar of the present invention is mainly: polymkeric substance (water-soluble polymers monomer, polymer latex) homodisperse in bitumen emulsion, cement gel, thereby make hydration more become perfect, formed the network that runs through mutually with pitch, cement gel, increased the cohesive force between them, improve the intensity and the stability of CA mortar, reduced the material separation degree of CA mortar.
Embodiment
Below will have the composition of CA mortar material Comparative Examples and 12 embodiment each components of the present invention now and detect after the basic mechanical design feature contrast be listed as follows, to further specify excellent properties of the present invention.
The present invention is not limited to following embodiment, when practical application, can require and use occasion according to different performance, selects the different proportionings among the following embodiment, or the different proportionings except that following each embodiment, but does not all limit the scope of the invention in any form.
CA mortar of the present invention with the preparation method of stablizer is: water-soluble polymers monomer, cationic emulsifier are joined in 65～80 ℃ the water, stir, can obtain product of the present invention with polymer latex by emulsifying device processing.
The CA mortar material that embodiment 1 (prior art Comparative Examples) selects for use for the present invention: get cement, fine aggregate, aluminium powder, defoamer, AE agent, swelling agent, bitumen emulsion, mixed with polymers emulsion, water mixing stirring, the shared weight part of each raw material is: 100 parts of cement, 220 parts of fine aggregates, 0.025 part of aluminium powder, 0.55 part of defoamer, 0.015 part of AE agent, 10 parts of swelling agents, 180 parts of bitumen emulsions, 25 parts in water.
The add-on of stablizer among the embodiment 2～10 in the CA mortar material is 20 parts.
Table 1: the difference of water-soluble polymers monomer, polymer latex, cationic emulsifier proportioning is to the technical feature influence of CA mortar in the stablizer.
Product of the present invention as can be seen from Table 1 can effectively reduce the material separation degree of CA mortar, the early strength of raising CA mortar.
Water-soluble polymers monomer, polymer latex, cationic emulsifier proportioning are 1.5%: 9.0%: 1.1% among the embodiment 11～13.
Table 2: the difference of stablizer add-on is to the technical feature influence of CA mortar
As can be seen from Table 2, the optimal addn of product of the present invention is 20～25 parts (100 parts of cement, 220 parts of fine aggregates, 180 parts of bitumen emulsions).
In the various embodiments described above, cement is the ordinary Portland cement of strength grade 42.5R.Fine aggregate is clean, hard, does not contain detrimental impurity river sands such as earth and organic matter, and maximum particle diameter is less than 2.5mm, and fineness modulus is 1.4～2.2, moisture ≯ 1%.Aluminium powder is thin phosphorus sprills, 250 orders.Defoamer is the waterborne organic silicon defoamer.The AE agent is a MNC-AE type water reducing type air entrapment agent.Swelling agent is a UEA type cement expansive material.Bitumen emulsion is the common cation bitumen emulsion.
Claims (5)
1, a kind of CA mortar stablizer, it is characterized in that comprising the water-soluble polymers monomer, polymer latex, cationic emulsifier, water, the composition of each component is respectively by weight percentage: water-soluble polymers monomer 1.2～1.5%, polymer latex 8～10%, cationic emulsifier 1～1.3%, all the other are water, the weight percent summation of each component is 100%.
2, by the described a kind of CA mortar stablizer of claim 1, it is characterized in that described water-soluble polymers monomer is a polyacrylamide.
3, by the described a kind of CA mortar stablizer of claim 1, it is characterized in that described polymer latex is a SBR latex.
4, by the described a kind of CA mortar stablizer of claim 1, it is characterized in that described cationic emulsifier is a lauryl amine, tetradecylamine, hexadecylamine, dodecyl dimethyl benzyl ammonia chloride, tetradecyl benzyl dimethyl ammonium chloride, hexadecyldimethyl benzyl ammonium benzyl ammonia chloride, the soybean oleyl amine, the mixture of any one or more of coconut oleyl amine.
5, by the described a kind of CA mortar stablizer of claim 1, it is characterized in that described CA mortar is 2～6% of a CA mortar weight with the add-on of stablizer in the CA mortar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910099082A CN101643340A (en) | 2009-06-04 | 2009-06-04 | Stabilizer for CA mortar |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910099082A CN101643340A (en) | 2009-06-04 | 2009-06-04 | Stabilizer for CA mortar |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101643340A true CN101643340A (en) | 2010-02-10 |
Family
ID=41655429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910099082A Pending CN101643340A (en) | 2009-06-04 | 2009-06-04 | Stabilizer for CA mortar |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101643340A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103360002A (en) * | 2013-07-10 | 2013-10-23 | 杨林江 | Cement asphalt mortar |
| CN103804930A (en) * | 2012-11-07 | 2014-05-21 | 中国石油化工股份有限公司 | Modified emulsified asphalt and preparation method thereof |
| CN105837081A (en) * | 2016-03-24 | 2016-08-10 | 湖州新奥克化工有限公司 | Environment-friendly stabilizer for CA mortar and preparation method thereof |
| CN106673487A (en) * | 2016-11-18 | 2017-05-17 | 绍兴职业技术学院 | Pervious mortar stabilizer for sponge city and preparation method of pervious mortar stabilizer |
-
2009
- 2009-06-04 CN CN200910099082A patent/CN101643340A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103804930A (en) * | 2012-11-07 | 2014-05-21 | 中国石油化工股份有限公司 | Modified emulsified asphalt and preparation method thereof |
| CN103804930B (en) * | 2012-11-07 | 2016-03-02 | 中国石油化工股份有限公司 | A kind of modified emulsifying asphalt and preparation method thereof |
| CN103360002A (en) * | 2013-07-10 | 2013-10-23 | 杨林江 | Cement asphalt mortar |
| CN105837081A (en) * | 2016-03-24 | 2016-08-10 | 湖州新奥克化工有限公司 | Environment-friendly stabilizer for CA mortar and preparation method thereof |
| CN105837081B (en) * | 2016-03-24 | 2018-06-26 | 南通优元美术图案设计有限公司 | A kind of environment-friendly type CA mortar stabilizers and preparation method thereof |
| CN106673487A (en) * | 2016-11-18 | 2017-05-17 | 绍兴职业技术学院 | Pervious mortar stabilizer for sponge city and preparation method of pervious mortar stabilizer |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20100210 |