CN110571445B - Metal fuel hydrogen power generation device - Google Patents
Metal fuel hydrogen power generation device Download PDFInfo
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- CN110571445B CN110571445B CN201910931011.4A CN201910931011A CN110571445B CN 110571445 B CN110571445 B CN 110571445B CN 201910931011 A CN201910931011 A CN 201910931011A CN 110571445 B CN110571445 B CN 110571445B
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- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 69
- 239000001257 hydrogen Substances 0.000 title claims abstract description 69
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 34
- 239000002184 metal Substances 0.000 title claims abstract description 34
- 238000010248 power generation Methods 0.000 title claims abstract description 32
- 239000000446 fuel Substances 0.000 title claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 239000012295 chemical reaction liquid Substances 0.000 claims description 17
- 239000011777 magnesium Substances 0.000 claims description 12
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 9
- 239000012670 alkaline solution Substances 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 230000007246 mechanism Effects 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000007769 metal material Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims 1
- 230000005611 electricity Effects 0.000 abstract description 13
- 230000007062 hydrolysis Effects 0.000 abstract description 13
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 13
- 238000000034 method Methods 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 10
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 230000033116 oxidation-reduction process Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000004506 ultrasonic cleaning Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910018626 Al(OH) Inorganic materials 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/30—Deferred-action cells
- H01M6/32—Deferred-action cells activated through external addition of electrolyte or of electrolyte components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
Abstract
The invention relates to the technical field of hydrogen electricity, in particular to a metal fuel hydrogen power generation device. Comprises an electrode plate, an electrode plug-in, a rotating shaft and a reaction tank; the electrode plate comprises a metal layer, a water film layer, a carbon layer and a nickel layer which are integrally connected in sequence in the form of a high polymer battery; the battery plug-in components are cylinders with a plurality of slots, and the slots are detachably connected with the electrode plates; the center of the battery plug-in is a rotating shaft, and the rotating shaft is connected with the controller, the motor and the transformer through circuits; a reaction cell is arranged below the battery plug-in unit. The device generates electricity by utilizing the potential difference generated in the metal oxidation-reduction process, collects hydrogen in the process and supplies the hydrogen to a fuel cell, a turbine engine, an internal combustion engine or a pressure power device, and realizes the maximum collection and utilization of energy in the hydrolysis process.
Description
Technical Field
The invention relates to the technical field of hydrogen electricity, in particular to a metal fuel hydrogen power generation device.
Background
Hydrogen energy is a secondary energy which is produced by other energy sources through a certain method, and unlike direct exploitation of coal, petroleum and natural gas, the hydrogen energy is almost completely produced by fossil fuels at present, and if engineering waste hydrogen can be recycled, about 1 billion cubic meters can be recycled every year, which is considerable.
To date, the utilization of hydrogen energy has been advanced. Various types of jet and rocket engines have been developed since the beginning of the development of liquid hydrogen engines in the united states in 1965. Space shuttles in the united states have successfully used liquid hydrogen as a fuel. China's Long Zheng No. 2 and No. 3 also use liquid hydrogen as fuel. Liquid hydrogen is used for replacing diesel oil, and the development of railway locomotives or general automobiles is also active. The hydrogen automobile runs by using hydrogen fuel and a hydrogen fuel cell, and is an important means for communicating a power system and a hydrogen energy system.
The biggest defects of the existing practical and commercial technology of hydrogen energy are the problem of energy efficiency and the dangers of reducing hydrogen production, storage, transportation and the like, so that research is carried out on hydrolysis hydrogen production, for example, chinese patent CN201810062022.9, namely a hydrolysis hydrogen production device applied to a fuel cell, discloses a hydrolysis device integrating hydrogen production, hydrogen storage and hydrogen use; or Chinese patent CN201910117543.4, and discloses an aluminum alloy capable of reducing hydrogen production cost, a preparation method and application thereof. The above patent of hydrolysis hydrogen production focuses on the use of hydrolysis method to prepare hydrogen, so that the energy obtained by further reaction of hydrogen is neglected, and the electric energy generated in the hydrolysis process is usually wasted and not fully utilized, which is a waste of energy obtained by hydrolysis hydrogen production method. Therefore, a new hydrogen energy power generation technology which is more economical and convenient is required.
Disclosure of Invention
The technical problem to be solved by the invention is that the existing hydrolysis hydrogen production technology mainly aims at preparing hydrogen by using a hydrolysis method, obtaining energy through further reaction of the hydrogen, neglecting electric energy generated in the hydrolysis process, and wasting the part of the electric energy which is often wasted and not fully utilized, thereby being a great waste of energy obtained by the hydrolysis hydrogen production method.
In order to solve the problems, a metal fuel hydrogen power generation device is provided, which generates power by utilizing the potential difference generated in the metal oxidation reduction process, collects hydrogen in the process and supplies the hydrogen to a fuel cell, a turbine engine, an internal combustion engine or a pressure power device, and realizes the maximum collection and utilization of energy in the hydrolysis process.
In order to achieve the purpose, the invention is realized by the following technical scheme: a metal fuel hydrogen power generation device is a device which mainly collects oxidation-reduction electric energy generated in the process of generating hydrogen by reacting metal alloy with alkaline solution and is used for power generation, and meanwhile, the generated hydrogen can be collected and reused by a fuel cell, a turbine engine, an internal combustion engine or a pressure power device and the like. Wherein, the voltage generated by the reaction of several metals with alkaline solution (solvent can be water, salt water, sea water) under the same conditions is as follows (according to the average generated 0.04A current meter):
Li≥3.04V，Mg＝2.37V，Al≥1.66V，Zn≥0.76V，Fe≥0.44V，H≥0V，Hg≥-0.24V，Cu≥0.34V，Ag≥1.69V。
from the above data, it can be seen that Mg or Al alloys are ideal metal fuels in terms of magnitude of voltage produced, cost. The reaction equation is as follows:
Mg+2H 2 O—>Mg(OH) 2 +H 2 ↑
Al+3H 2 O—>Al(OH) 3 +3/2H 2 ↑
the specific voltage and current values can be adjusted by adjusting the size and quantity of the metal of the electrode plate, the concentration of the alkaline solution, the area of the contact surface and the contact period.
The structure of the device comprises an electrode plate, an electrode plug-in unit, a rotating shaft and a reaction tank; the electrode plate comprises a metal layer, a water film layer, a carbon layer and a nickel layer which are integrally connected in sequence in the form of a high polymer battery (namely, all the layers are sequentially overlapped and combined), so that combined power generation and replacement by mistake and leakage are facilitated; the battery plug-in components are cylinders with a plurality of slots, and the slots are detachably connected with the electrode plates; the center of the battery plug-in is a rotating shaft, and the rotating shaft is connected with the switch, the motor and the transformer through a circuit; a reaction cell is arranged below the battery plug-in unit.
Further, the electrode plates were sized as follows: 5cm long by 10cm wide; thickness of each layer: 0.2cm of metal, 0.4cm of water film, 0.3cm of carbon and 1cm of nickel.
Further, the metal layer is made of magnesium, magnesium alloy or aluminum, aluminum alloy.
Further, the metal layer is made of a magnesium alloy, wherein the ratio of the components is Mg to Al to Li to Ni = 99-61.
Furthermore, 1008 slots are uniformly arranged on the battery plug-in. The number of the plug-in components can ensure that the power generation device has stronger cruising ability and is not wasted due to overlarge electric quantity and excessive hydrogen productivity.
Further, the rotating shaft is connected with a lifting mechanism, so that the whole battery plug-in is lifted to a height separated from liquid in the reaction tank, and the reaction is stopped; such as, but not limited to, hydraulic rams, tripods, etc.
Furthermore, the reaction tank is respectively connected with a water inlet pipe and a water outlet pipe, the water outlet pipe is connected with a water pump, the waste water mixed with reactants in the reaction tank is pumped out by the water pump, and new reaction liquid is supplemented into the reaction tank by the water inlet pipe, so that continuous power generation is realized; meanwhile, the extracted waste water can be connected with a filtering device to filter out reaction products for fireproof materials and the like.
Furthermore, an outer cover is arranged above the reaction tank, the electrode plate, the electrode plug-in and the rotating shaft are all sealed in the outer cover, a safety valve and an air outlet pipeline are connected to the outer cover, and the air outlet pipeline is connected with the fuel cell, the hydrogen engine and/or the hydrogen boiler. The hydrogen generated by the chemical reaction can be collected and utilized to carry out secondary power generation.
Furthermore, the outer cover is provided with a spray nozzle, the spray nozzle is connected with a water pump and a reaction liquid storage tank through a pipeline, reaction liquid is sprayed to a battery plate on the electrode plug-in unit for reaction, and redundant reaction liquid and reaction products enter a reaction tank.
Furthermore, the power generation device is also provided with a controller, and the controller is connected with a sensor and switches of all the components in the power generation device to control the operation of the whole device. Such as but not limited to pressure sensor, pH meter, current meter, voltmeter, etc., and each component switch refers to a switch of the rotating shaft, a switch of the lifting mechanism, a switch of the safety valve, a switch of the water inlet pipe, a valve of the water outlet pipe, a switch of the water pump, etc.
Further, the motor is arranged on the frame and rotates through the belt driving rotating shaft, a plurality of ultrasonic generators are arranged below the reaction tank, the ultrasonic generators are started after the system runs for a period of time, the electrode plates are subjected to ultrasonic cleaning, hydroxide and garbage generated on the surfaces are removed, and the inner metal plates are leaked to ensure the continuation of the reaction, so that continuous power generation can be realized. And each time of cleaning is about 30s, other electrode plates still generate electricity while cleaning, and the use is not influenced.
The invention has the beneficial effects that:
(1) The electric energy generated in the process of potential difference ionization for producing hydrogen by using oxidation-reduction reaction does not need to be supplemented with an input power supply, and the electric energy ionization device can be used in regions without electric energy and has a wide application range.
(2) And electricity and hydrogen are obtained while the reaction is carried out, so that the cost is low and the efficiency is high.
(3) The reaction product produced by the reaction can be reused as a fireproof material, soap, detergent and the like through certain treatment.
(4) In the hydrogen production process, carbon dioxide can be absorbed to purify air and improve the atmospheric environment.
(5) In the hydrogen production process, hydroxide and garbage generated on the surface are removed through ultrasonic cleaning, so that the reaction can be continuously and continuously carried out, and continuous power generation is realized.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the embodiments or the prior art descriptions will be briefly described below. It is clear that the drawings in the following description are examples of embodiments of the invention, and that for a person skilled in the art, other drawings can be derived from them without inventive effort.
FIG. 1 is a schematic diagram of the electrode plate structure of the present invention;
FIG. 2 is a schematic view of the overall structure of the present invention;
FIG. 3 is a schematic view of the internal structure of embodiment 7 of the present invention;
in the figure, an electrode plate 1, a metal layer 11, a water film layer 12, a carbon layer 13, a nickel layer 14, an electrode insert 2, a rotating shaft 3, a reaction tank 4, a water inlet pipe 41, a water outlet pipe 42, a water pump 43, an outer cover 5, a safety valve 51, an air outlet pipeline 52, a controller 6 and an ultrasonic generator 7.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention. It is to be understood that the embodiments described are only a few embodiments of the present invention, and not all embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1:
a metal fuel hydrogen power generation device comprises an electrode plate 1, an electrode plug-in 2, a rotating shaft 3 and a reaction tank 4; the electrode plate 1 comprises a metal layer 11, a water film layer 12, a carbon layer 13 and a nickel layer 14 which are sequentially and integrally connected in the form of a high polymer battery (namely, the layers are sequentially overlapped and combined), so that combined power generation and staggered replacement are facilitated; wherein the metal layer is used as a cathode and is used for providing a metal material for reaction, and the water film layer is made of a water absorbing materialThe material is prepared for providing alkaline solution for reaction, the carbon layer is used as a positive electrode, the size of the electrode plate can be reduced, the power generation efficiency is improved, and the nickel layer can effectively conduct generated electricity; the battery plug-in 2 is a cylinder with a plurality of slots, the slots are detachably connected with the electrode plates, individual reacted electrode plates can be replaced at any time, and the operation of the whole device cannot be influenced; the center of the battery plug-in is a rotating shaft 3, and the rotating shaft 3 is connected with a switch, a motor and a transformer through a circuit; the pivot can control electrode plug-in components rotatory to control the plate electrode quantity of contact with the reaction liquid in the unit interval, thereby can control the generated energy, in addition, the experiment finds that, the plate electrode after with the contact of reaction liquid, still can continuously generate electricity in certain time after with the separation of reaction liquid, so also can save the cost through adjusting the rotational speed, the life of extension plate electrode, on the other hand, can be through the rotation of pivot, with the product (Mg (OH) after the panel reaction 2 Or Al (OH) 3 ) The solar cell plate is separated from the solar cell plate under the action of gravity and centrifugal force and finally falls into the reaction tank, so that the influence of the adhesion of reactants on the power generation efficiency is avoided; the reaction tank 4 is arranged below the battery plug-in unit, the reaction tank 4 can be connected with or provide reaction liquid, alkaline solution reacting with the battery plate phase is in the reaction tank, and products after reaction also fall into the reaction tank in the rotating process so as to be processed in a centralized mode.
The dimensions of the electrode plates are as follows: 5cm long by 10cm wide; thickness of each layer: 0.2cm of metal, 0.4cm of water film, 0.3cm of carbon and 1cm of nickel.
The metal layer is made of a magnesium alloy, wherein the ratio of the components is Mg to Al to Li to Ni = 99.
1008 slots are uniformly arranged on the battery plug-in 2. The number of the plug-in components can ensure that the power generation device has stronger cruising ability and is not wasted due to overlarge electric quantity and excessive hydrogen productivity. In this case, 2,318v × 40,32a =93,461 watts of electricity, which is sufficient for use.
The rotating shaft 3 is connected with a lifting mechanism, so that the whole battery plug-in is lifted to a height separated from liquid in the reaction tank, and the reaction is stopped; such as, but not limited to, hydraulic rams, tripods, etc.
The reaction tank is respectively connected with a water inlet pipe 41 and a water outlet pipe 42, the water outlet pipe is connected with a water pump 43, the waste water of mixed reactants in the reaction tank is pumped out by the water pump, and new reaction liquid is supplemented into the reaction tank through the water inlet pipe, so that continuous power generation is realized; meanwhile, the extracted waste water can be connected with a filtering device to filter out reaction products for fireproof materials and the like.
An outer cover 5 is arranged above the reaction tank, the electrode plate 1, the electrode plug-in 2 and the rotating shaft 3 are all sealed in the outer cover, a safety valve 51 and an air outlet pipeline 52 are connected on the outer cover, and the air outlet pipeline is connected with a fuel cell, a hydrogen engine and/or a hydrogen boiler. The hydrogen generated by the chemical reaction can be collected and utilized to carry out secondary power generation.
The power generation device is also provided with a controller 6, and the controller is connected with a sensor and switches of all the components arranged in the power generation device to control the operation of the whole device. The sensors include, but are not limited to, pressure sensors, pH meters, current meters, voltage meters, and the like, and the switches of the components refer to switches of the rotating shaft, switches of the lifting mechanism, switches of the safety valve, valves of the water inlet pipe and the water outlet pipe, switches of the water pump, and the like.
Example 2:
the metal layer is made of a magnesium alloy, wherein the ratio of the components is Mg to Al to Li to Ni = 84.5.
The rest is the same as in example 1.
Example 3:
the metal layer is made of a magnesium alloy, wherein the ratio of the components is Mg to Al to Li to Ni = 72.7.
The rest is the same as in example 1.
Example 4:
the metal layer is made of a magnesium alloy, wherein the ratio of the components is Mg to Al to Li to Ni = 61.3.
The rest is the same as in example 1.
Example 5:
the metal layer is made of aluminum or aluminum.
The rest of the process was the same as in example 1.
Example 6:
and the outer cover 5 is provided with a spray nozzle which is connected with a water pump and a reaction liquid storage tank through a pipeline and sprays reaction liquid to a battery plate on the electrode plug-in unit for reaction, and redundant reaction liquid and reaction products enter a reaction tank.
The rest of the examples are the same as any of examples 1 to 5.
Example 7:
as shown in figure 3, the motor is arranged on the frame, the rotating shaft is driven to rotate through the belt, meanwhile, a plurality of ultrasonic generators 7 are arranged below the reaction tank, the ultrasonic generators are started after the system runs for a period of time, the electrode plates are ultrasonically cleaned, hydroxide and garbage generated on the surfaces are removed, and the metal plates in the reaction tank are leaked out to ensure the continuous reaction, so that the continuous power generation can be realized. And each time of cleaning is about 30s, other electrode plates still generate electricity while cleaning, and the use is not influenced.
The rest is the same as any of examples 1 to 6.
The operation principle of the device is as follows:
under the drive of the rotating shaft, the electrode plug-in unit inserted with the electrode plate rotates, the water film layer absorbs the reaction liquid and starts to react, so that the electrode plate can be prevented from being too quickly oxidized in the reaction liquid all the time and cannot stably generate electricity, and meanwhile, the ultrasonic cleaning device is also arranged, hydroxide and garbage generated on the surface can be timely removed, and continuous power generation is realized. And then the reaction liquid is supplemented and the power generation is continuously carried out through the circulating water inlet and outlet of the reaction tank, and by-products obtained by the reaction are effectively removed, recycled and reused through circulation. During the operation, the rotation speed, the total amount and the concentration of the reaction liquid can be controlled by the controller to adjust the electricity generation amount, the hydrogen generation amount and the pressure in the reactor. Wherein the generated electricity is proportionally increased according to the size and the quantity of the seeds, the rotating speed of the electrode plate, the quantity of the electrolytic solution and the PH concentration
The hydrogen generated when the electrode plate is used is stored in a storage container and can be used for producing secondary electricity.
Claims (9)
1. A metal fuel hydrogen power generation device, characterized in that: comprises an electrode plate, an electrode plug-in, a rotating shaft and a reaction tank; the electrode plate comprises a metal layer, a water film layer, a carbon layer and a nickel layer which are integrally connected in sequence in the form of a high polymer battery; the electrode plug-in is a cylinder with a plurality of slots, and the slots are detachably connected with the electrode plate; the center of the electrode plug-in is a rotating shaft, and the rotating shaft is connected with the controller, the motor and the transformer through circuits; a reaction tank is arranged below the electrode plug-in unit;
the metal layer is made of magnesium or magnesium alloy or aluminum alloy;
the metal layer is used as a negative electrode and used for providing a metal material for reaction, the water film layer is made of a water absorption material and used for providing an alkaline solution for reaction, and the carbon layer is used as a positive electrode.
2. The metal-fueled hydrogen power plant according to claim 1, wherein: the dimensions of the electrode plates were as follows: 5cm long by 10cm wide; the thickness of each layer is 0.2cm of metal, 0.4cm of water film, 0.3cm of carbon and 1cm of nickel.
3. The metal-fueled hydrogen power plant according to claim 1, wherein: the metal layer is made of a magnesium alloy, wherein the ratio of Mg to Al to Li to Ni =99 to 61.
4. The metal-fueled hydrogen power plant according to claim 1, wherein: 1008 slots are uniformly arranged on the electrode plug-in unit.
5. The metal-fueled hydrogen power plant according to claim 1, wherein: the rotating shaft is connected with the lifting mechanism.
6. The metal-fueled hydrogen power plant according to claim 1, wherein: the reaction tank is respectively connected with a water inlet pipe and a water outlet pipe, and the water outlet pipe is connected with a water pump; the upper part of the reaction tank is provided with an outer cover, the electrode plate, the electrode plug-in and the rotating shaft are all sealed in the outer cover, the outer cover is connected with a safety valve and an air outlet pipeline, and the air outlet pipeline is connected with the fuel cell, the hydrogen engine and/or the hydrogen boiler.
7. The metal-fueled hydrogen power plant according to claim 6, wherein: the outer cover is provided with a spray nozzle which is connected with a water pump and a reaction liquid storage tank through pipelines.
8. The metal-fueled hydrogen power plant according to claim 1, wherein: a plurality of ultrasonic generators are arranged below the reaction tank.
9. The metal-fueled hydrogen power generation device according to any one of claims 1 to 8, wherein: the power generation device is also provided with a controller, and the controller is connected with a sensor and switches of all the components arranged in the power generation device.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003045461A (en) * | 2001-08-03 | 2003-02-14 | Sony Corp | Motor device and fuel cell |
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| JP2003045461A (en) * | 2001-08-03 | 2003-02-14 | Sony Corp | Motor device and fuel cell |
| DE102009049084B3 (en) * | 2009-10-07 | 2011-06-09 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Electrochemical reactor useful for power supply of a system, comprises a galvanic cell, which has a metal anode and an inert cathode for operation of the galvanic cell and an aqueous solution as an electrolyte, and a fuel cell |
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