CN110565267A - low-pollution environment-friendly preparation method of carbon felt - Google Patents

low-pollution environment-friendly preparation method of carbon felt Download PDF

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Publication number
CN110565267A
CN110565267A CN201910763843.XA CN201910763843A CN110565267A CN 110565267 A CN110565267 A CN 110565267A CN 201910763843 A CN201910763843 A CN 201910763843A CN 110565267 A CN110565267 A CN 110565267A
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CN
China
Prior art keywords
fiber
felt
polyacrylonitrile
fiber web
activated carbon
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Pending
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CN201910763843.XA
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Chinese (zh)
Inventor
高蓉连
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Datong Xincheng New Material Co Ltd
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Datong Xincheng New Material Co Ltd
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Priority to CN201910763843.XA priority Critical patent/CN110565267A/en
Publication of CN110565267A publication Critical patent/CN110565267A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/21Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F9/22Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282Addition polymers
    • D04H1/43Acrylonitrile series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • D04H1/488Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with bonding agents
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • D06C7/04Carbonising or oxidising

Abstract

the invention discloses a low-pollution environment-friendly preparation method of a carbon felt, which comprises the following steps: s1, loosening the compacted and intertwined polyacrylonitrile fiber raw material and removing impurities; s2, carding the spinning raw materials subjected to primary processing into a single fiber state, forming a net fiber thin layer, and then gathering into fiber strips; s3, adopting a laying mode, namely laying several layers of fiber webs to meet the requirements of uniformity, width, weight and strength of the non-woven fabric product; s4, repeatedly puncturing the fiber web by using a pre-needling machine, and reinforcing the fluffy fiber web; s5, repeatedly needling the pre-needled fiber web by using a main needle machine; and S6, bonding the fiber web by using viscose to form the polyacrylonitrile felt. The invention can ensure that the adsorption capacity of the activated carbon fiber felt is kept at a stable value, avoids resource waste and uneven quality in the production process, reduces the pollution to the environment, ensures the product quality in production and reduces the production cost.

Description

Low-pollution environment-friendly preparation method of carbon felt
Technical Field
The invention relates to the technical field of carbon felt production, in particular to a low-pollution environment-friendly preparation method of a carbon felt.
Background
the activated carbon fiber is activated carbon-containing fiber, and certain carbon-containing fiber (such as phenolic-based fiber, PAN-based fiber, viscose-based fiber, asphalt-based fiber and the like) is activated at high temperature (different activation temperatures of different activation methods), so that the surface of the carbon-containing fiber generates nanoscale pore diameters, the specific surface area is increased, the physicochemical characteristics of the carbon-containing fiber are changed, and the activated carbon fiber is a novel carbon adsorption material developed on the basis of the carbon fiber.
physical properties show that the surface of an object has attraction to the outside, the larger the surface is, the larger the adsorption force is, activated carbon fibers adsorb peripheral molecules and firmly adhere to micropores under the action of van der Waals force, the activated carbon fibers can be divided into 3 types of specific surface areas, namely, high specific surface area (Sr 1500m2/g), medium specific surface area (SBET =800 ~ m2/g) and low specific surface area (SBEr <800 m/g), the specific surface area of polyacrylonitrile-based activated carbon fibers is generally considered to be below 6335/g, at present, researches show that the strength of the performance of the activated carbon fibers is related to the surface area and the structure of the activated carbon fibers per se, but the existing activated carbon fibers cannot be prepared in a reasonable production process, the quality of activated carbon fibers cannot be guaranteed, the problem of environmental pollution caused by the increase of the quality of activated carbon fibers cannot be solved, and the pollution of activated carbon fibers cannot be easily solved, and the pollution of the activated carbon fibers cannot be caused by the problem that the quality of environmental pollution cannot be increased due to reasonable preparation of activated carbon fibers and the activated carbon fibers cannot be solved.
Disclosure of Invention
the invention aims to solve the defects in the prior art and provides an environment-friendly preparation method of a low-pollution carbon felt.
in order to achieve the purpose, the invention adopts the following technical scheme:
An environment-friendly preparation method of a low-pollution carbon felt comprises the following steps:
S1, loosening the compacted and intertwined polyacrylonitrile fiber raw material and removing impurities;
S2, carding the spinning raw materials subjected to primary processing into a single fiber state, forming a net fiber thin layer, and then gathering into fiber strips;
s3, adopting a laying mode, namely laying several layers of fiber webs to meet the requirements of uniformity, width, weight and strength of the non-woven fabric product;
S4, repeatedly puncturing the fiber web by using a pre-needling machine, and reinforcing the fluffy fiber web;
s5, repeatedly needling the pre-needled fiber web by using a main needle machine;
s6, bonding the fiber web by using viscose to form a polyacrylonitrile felt;
s7, removing natural impurities on the yarn or fabric, and sizing agent, auxiliary agent and contaminant attached in the spinning process by using a chemical reagent;
s8, dewatering the fiber web;
s9, converting protofilaments in the polyacrylonitrile fibers into a pyridine ring trapezoidal structure which is thermally stable and has a semiconductor resistance value;
And S10, activating the polyacrylonitrile fibers by using water vapor.
s11, measuring, checking and testing the performance in the inspection project;
and S12, forming the activated carbon fiber felt.
Preferably, the activated carbon fiber felt is made by a non-woven needle punching method.
preferably, the activated carbon fiber is made of fiber raw materials such as viscose, polyacrylonitrile, pitch, phenolic aldehyde and the like.
Preferably, the chemical agent is an activator.
The invention is characterized in that when producing active carbon fiber, polyacrylonitrile raw material is prepared, then the compressed and intertwined polyacrylonitrile fiber raw material is loosened and impurities are removed, the spinning raw material after primary processing is carded into single fiber state to form a net-shaped fiber thin layer, then the net-shaped fiber thin layer is assembled into fiber strips, several layers of fiber nets are overlapped by adopting an overlapping mode to meet the requirements of uniformity, width, weight and strength of a non-woven fabric product, after the polyacrylonitrile fiber nets are overlapped, the fiber nets are repeatedly punctured by a pre-needling machine to reinforce the fluffy fiber nets, in order to further enhance the connection stability, the pre-needled fiber nets are repeatedly needled by utilizing a main needling machine to stably connect the fiber nets, the fiber nets are bonded by utilizing viscose to form a polyacrylonitrile felt, natural impurities on the yarn or fabric are bonded by utilizing chemical reagents, and sizing agents attached in the spinning process, The auxiliary agent and the contaminant are removed, the chemical reagent is an activating agent, the activating agent is a kind of adjusting agent which can enhance the adsorption capacity of the mineral surface to the collecting agent in the flotation reagent, the chemical composition of the mineral surface is changed to eliminate the action of the inhibitor, so that the mineral surface can easily adsorb the collecting agent, the reaction speed component is increased along with the increase of the concentration of the activating agent, so that the specific surface area component of the activated carbon fiber is gradually increased, the first-degree capacity is enhanced, but the reaction is too violent after the concentration of the activating agent is increased to a certain degree, so that the formed micropores are destroyed, the adsorption capacity is reduced, then the fiber web is dehydrated, after the dehydration treatment is finished, the protofilaments in the polyacrylonitrile fiber are converted into a pyridine ring trapezoidal structure which is thermally stable and has a semiconductor resistance value, the polyacrylonitrile fiber is activated by using water vapor, and effective collision is generated among activated molecules in the activation process, finally forming an adsorption material, measuring, checking and testing the performance in the inspection items by a corresponding method, and finally forming the activated carbon fiber felt after a series of processes are finished. The invention can ensure that the adsorption capacity of the activated carbon fiber felt is kept at a stable value, avoids resource waste and uneven quality in the production process, reduces the pollution to the environment, ensures the product quality in production and reduces the production cost.
drawings
the accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the invention without limiting the invention. In the drawings:
FIG. 1 is a flow chart of an environment-friendly preparation method of a low-pollution carbon felt provided by the invention;
FIG. 2 is a diagram showing the state of the activation temperature of the method for preparing a low-pollution carbon felt in an environment-friendly manner according to the present invention;
FIG. 3 is a state diagram of the activation time of the low-pollution environment-friendly preparation method of carbon felt according to the present invention;
FIG. 4 is a state diagram of the activator metering fraction of the low-pollution environment-friendly carbon felt preparation method provided by the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
referring to fig. 1-4, a method for preparing a low-pollution carbon felt in an environment-friendly manner comprises the following steps:
s1, loosening the compacted and intertwined polyacrylonitrile fiber raw material and removing impurities, so that the transverse connection scale of the fibers is reduced, and conditions are created for further loosening to a single state;
S2, carding the spinning raw materials which are processed primarily into a single fiber state, forming a net fiber thin layer, then gathering into fiber strips, removing many impurities and defects from the fiber strips which are carded, fully mixing fibers with different qualities and colors, and straightening the fibers primarily and having directionality;
S3, adopting a laying mode, namely laying several layers of fiber webs to meet the requirements of uniformity, width, weight and strength of the non-woven fabric product;
S4, repeatedly puncturing the fiber web by using a pre-needling machine to reinforce the fluffy fiber web, wherein the pre-needling machine not only has the main structure of the needling machine, but also has a reasonable fiber web feeding mechanism, so that the fluffy fiber web can easily enter a needling area along with the guiding of the feeding mechanism;
S5, repeatedly needling the pre-needled fiber web by using a main needling machine, wherein the needle density of the main needling machine is much higher than that of the pre-needling machine, the needling frequency is high, and the needle stroke is generally less than 5 mm;
s6, bonding the fiber web by using viscose to form a polyacrylonitrile felt, wherein polyacrylonitrile is a chemical substance and is obtained by free radical polymerization of monomer acrylonitrile, and the polyacrylonitrile fiber has the advantages of weather resistance, sun resistance and the like, can keep 77% of the original strength after being placed outdoors for 18 months, and is resistant to chemical reagents, particularly inorganic acid, bleaching powder, hydrogen peroxide and common organic reagents;
S7, removing natural impurities on the yarn or fabric, and pulp, auxiliaries and contaminants attached to the yarn or fabric in the spinning process by using a chemical reagent, wherein the chemical reagent is an activating agent, the activating agent is a type of regulating agent which can enhance the adsorption capacity of the mineral surface to a collecting agent in a flotation reagent, and is used for eliminating the action of an inhibitor by changing the chemical composition of the mineral surface, so that the mineral surface is easy to adsorb the collecting agent, and common activating agents comprise water, alcohol, acid, alkali and the like;
S8, dewatering the fiber web, and mechanically separating the porous substance and the water or liquid contained in the accumulated particle layer to avoid the water and the liquid remaining in the fiber web;
s9, converting protofilaments in the polyacrylonitrile fibers into a pyridine ring trapezoidal structure which is thermally stable and has a semiconductor resistance value;
s10, performing activation treatment on polyacrylonitrile fibers by using water vapor, wherein collisions capable of generating chemical reactions are called effective collisions, molecules generating the effective collisions are called activated molecules, and the activation process is a process of adding a catalyst in the chemical reactions to increase the activated molecules in the whole chemical reactions and reduce the activation energy.
s11, measuring, checking and testing the performance in the inspection project, and determining whether the performance meets the standard or not and whether the quality of the activated carbon fiber felt can be determined or not through the measurement, the check and the test;
s12, forming an activated carbon fiber felt, wherein the activated carbon fiber felt is manufactured by a non-woven needling method, when a felting needle pierces a fiber web, a part of fibers are carried by a crochet hook on the felting needle to move in the fiber web, the fiber web is compressed, when the felting needle exits the fiber web, the crochet hook is in a forward direction, fiber bundles are separated from the crochet hook and are left in the fiber web to be entangled, and a non-woven fabric with certain thickness and strength is formed.
In the present invention: as shown in fig. 2, under the condition that other conditions are not changed, the activation temperature is only changed, the influence of the activation temperature on the adsorption performance and yield of the activated carbon fiber is observed, and as the activation temperature rises, the iodine adsorption value increases within a certain range, and then increases slowly to a certain extent, because the specific surface area gradually increases with the rise of the activation temperature, so that the adsorption capacity of the activated carbon fiber is enhanced, but the specific surface area decreases after increasing to a certain extent, because the reaction is too violent due to too high temperature, the formed micropores are destroyed, so that the specific surface area decreases, and therefore, the activation temperature is not higher, and the better.
in the present invention: as can be seen from fig. 3, the longer the activation time is, the better the adsorption performance of the activated carbon fiber is, and the lower the yield is, under the same conditions, because the activation time is prolonged, the activating agent and the carbon atoms continuously perform chemical reaction, and various generated byproducts continuously escape, leaving voids on the surface of the fiber, and it can also be seen that the iodine adsorption value is increased rapidly at first.
In the present invention: as can be seen from fig. 4: the reaction speed component is increased along with the increase of the concentration of the activating agent, so that the specific surface area component of the activated carbon fiber is gradually increased, and the first-time capacity is enhanced.
In summary, the following steps: the strength of the adsorption capacity of the activated carbon fiber is changed along with the change of the activation time, the activation temperature and the activation metering fraction.
In the invention: when the activated carbon fiber is produced, a polyacrylonitrile raw material is prepared, then the compressed and intertwined polyacrylonitrile fiber raw material is loosened and impurities are removed, the spinning raw material after primary processing is carded into a single fiber state to form a net-shaped fiber thin layer, the fiber thin layer is assembled into a fiber strip, a plurality of layers of fiber nets are overlapped in a stacking mode to meet the requirements of uniformity, width, weight and strength of a non-woven fabric product, after the polyacrylonitrile fiber nets are overlapped, the fiber nets are repeatedly punctured by a pre-needling machine to reinforce the fluffy fiber nets, in order to further enhance the connection stability, the fiber nets after pre-needling are repeatedly needled by a main needling machine to be stably connected, the fiber nets are bonded by viscose to form a polyacrylonitrile felt, chemical reagents are used for bonding natural impurities on the yarn or the fabric, and sizing agents attached to the fiber strips in the spinning process, The auxiliary agent and the contaminant are removed, the chemical reagent is an activating agent, the activating agent is a kind of adjusting agent which can enhance the adsorption capacity of the mineral surface to the collecting agent in the flotation reagent, the chemical composition of the mineral surface is changed to eliminate the action of the inhibitor, so that the mineral surface can easily adsorb the collecting agent, the reaction speed component is increased along with the increase of the concentration of the activating agent, so that the specific surface area component of the activated carbon fiber is gradually increased, the first-degree capacity is enhanced, but the reaction is too violent after the concentration of the activating agent is increased to a certain degree, so that the formed micropores are destroyed, the adsorption capacity is reduced, then the fiber web is dehydrated, after the dehydration treatment is finished, the protofilaments in the polyacrylonitrile fiber are converted into a pyridine ring trapezoidal structure which is thermally stable and has a semiconductor resistance value, the polyacrylonitrile fiber is activated by using water vapor, and effective collision is generated among activated molecules in the activation process, finally forming an adsorption material, measuring, checking and testing the performance in the inspection items by a corresponding method, and finally forming the activated carbon fiber felt after a series of processes are finished.
the above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (4)

1. The environment-friendly preparation method of the low-pollution carbon felt is characterized by comprising the following steps:
s1, loosening the compacted and intertwined polyacrylonitrile fiber raw material and removing impurities;
s2, carding the spinning raw materials subjected to primary processing into a single fiber state, forming a net fiber thin layer, and then gathering into fiber strips;
S3, adopting a laying mode, namely laying several layers of fiber webs to meet the requirements of uniformity, width, weight and strength of the non-woven fabric product;
s4, repeatedly puncturing the fiber web by using a pre-needling machine, and reinforcing the fluffy fiber web;
S5, repeatedly needling the pre-needled fiber web by using a main needle machine;
s6, bonding the fiber web by using viscose to form a polyacrylonitrile felt;
s7, removing natural impurities on the yarn or fabric, and sizing agent, auxiliary agent and contaminant attached in the spinning process by using a chemical reagent;
s8, dewatering the fiber web;
s9, converting protofilaments in the polyacrylonitrile fibers into a pyridine ring trapezoidal structure which is thermally stable and has a semiconductor resistance value;
S10, activating polyacrylonitrile fibers by using water vapor;
s11, measuring, checking and testing the performance in the inspection project;
and S12, forming the activated carbon fiber felt.
2. The method for preparing the carbon felt with low pollution in the environment-friendly way as claimed in claim 1, wherein the activated carbon fiber felt is prepared by a non-woven needle punching method.
3. The method for preparing the carbon felt with low pollution in the environment-friendly way as claimed in claim 1, wherein the activated carbon fiber is jointly made of fiber raw materials such as viscose, polyacrylonitrile, pitch, phenolic aldehyde and the like.
4. The method for preparing the carbon felt with low pollution in the environment-friendly way as claimed in claim 1, wherein the chemical agent is an activating agent.
CN201910763843.XA 2019-08-19 2019-08-19 low-pollution environment-friendly preparation method of carbon felt Pending CN110565267A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114538947A (en) * 2022-03-08 2022-05-27 苏州碳创新材料技术开发有限公司 Preparation method for roll-to-roll continuous production of carbon material substrate of gas diffusion layer

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CN1204622A (en) * 1998-06-20 1999-01-13 中山大学 Treatment of waste water containing dye using activated carbon fiber adsorption process
CN1303736A (en) * 2000-07-21 2001-07-18 中国科学院山西煤炭化学研究所 Fibrous carbon-based adsorption material and its preparation method
CN1354292A (en) * 2001-12-10 2002-06-19 梁继选 Continuous preparation method of active carbon fibre matting and cloth
CN101562076A (en) * 2008-04-16 2009-10-21 华昌星泰(北京)新材料有限公司 Preparation method of special activated carbon fiber cloth of super capacitor
WO2011127218A2 (en) * 2010-04-06 2011-10-13 Ndsu Research Foundation Liquid silane-based compositions and methods for producing silicon-based materials
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114538947A (en) * 2022-03-08 2022-05-27 苏州碳创新材料技术开发有限公司 Preparation method for roll-to-roll continuous production of carbon material substrate of gas diffusion layer

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