CN110527570A - The production method and its production system of high-stability coal water slurry fuel - Google Patents

The production method and its production system of high-stability coal water slurry fuel Download PDF

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Publication number
CN110527570A
CN110527570A CN201910940016.3A CN201910940016A CN110527570A CN 110527570 A CN110527570 A CN 110527570A CN 201910940016 A CN201910940016 A CN 201910940016A CN 110527570 A CN110527570 A CN 110527570A
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China
Prior art keywords
tank
slurry
grinding machine
dispersing agent
finished pulp
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Inventor
樊凤升
侯鑫
杨成
陈凤存
李瑞国
李光磊
吴春娟
孙云国
金福
闫蕾
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Qingdao Trier Technology Co.,Ltd.
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Qingdao Tellier Environmental Protection Group Co Ltd
Qingdao Anpaier Clean Energy Technology Co Ltd
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Priority to CN201910940016.3A priority Critical patent/CN110527570A/en
Publication of CN110527570A publication Critical patent/CN110527570A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/326Coal-water suspensions

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The present invention proposes the production method and its production system of a kind of high-stability coal water slurry fuel, belongs to water-coal-slurry production technical field, and the water-coal-slurry product that production obtains has preferable grain size distribution, and stability and mobility are more preferable.The production method includes the steps of determining that the total dosage of dispersing agent and the total dosage of stabilizer;Whole feed coals, water, part dispersing agent and partially stabilized dose are added in grinding machine from the arrival end of grinding machine and ground;Remaining dispersing agent is added from the outlet end of grinding machine to from the slurry that the outlet end of grinding machine is flowed out, and obtains primary slurry;Primary slurry is collected, stir and refined filtration after, be delivered in agitator tank;Remaining stabilizer is added to being mixed evenly in agitator tank with the slurry in agitator tank, second level slurry is obtained;Second level slurry pipeline steel to homogeneous tank is subjected to homogeneous curing, finished pulp is sent into finished pulp storage tank from the bottom of finished pulp storage tank and is stored.

Description

The production method and its production system of high-stability coal water slurry fuel
Technical field
The invention belongs to water-coal-slurry production technical field more particularly to a kind of production methods of high-stability coal water slurry fuel And its production system.
Background technique
Coal water slurry fuel be by coal, water, a small amount of additive through being processed into have certain particle size distribution and it is good The fluid of rheological behavior, the quality of water-coal-slurry is mainly by coal quality, additive types and dosage, coal powder size gradation and grinding method The influence of (dry grinding and wet-milling).Wherein, additive types and dosage are determined according to coal quality, and coal powder size gradation is ground The influence of the storehouse quantity of method, mill types and grinding machine.Thus, when coal quality, additive types, grinding method and mill types are true After fixed, really influence water-coal-slurry quality is the adding manner of additive and the subsequent treatment process of slurry.
Additive used in water-coal-slurry mainly includes dispersing agent and stabilizer, in traditional slurries production technology, Dispersing agent is usually mill entrance to be added together with clear water, coal, and stabilizer is then to be directly added in strong stirring tank and slurry Body is mixed.However, the dosage of dispersing agent is to test determination according to coal paste-forming properties, it can from dispersing agent Analysis on action mechanism Know, dispersing agent be added at one time can be substantially reduced coal, aqueous mixtures viscosity, increase mobility, but from the mechanism of action of grinding machine Analysis reduces the chance for obtaining optimal granularity gradation, and then influence it is found that this will increase to touch pounds chance and reduce grinder meeting The stability of water-coal-slurry.It is actually a kind of remedial measure to water coal slurry stability that stabilizer is added in strong stirring tank, The effect of stabilizer is that water-coal-slurry is made to be more likely to be changed into thixotroping body, so as to improve the stability of water-coal-slurry, but is added steady Determining agent but cannot fundamentally solve the problems, such as that water-coal-slurry is easily settled, and water-coal-slurry is still deposited after storing for a long time in finished pulp storage tank In serious deposited phenomenon, even if precipitation capacity is still in the case where mechanical stirring device is arranged in the tank deck of finished pulp storage tank It is larger, it need to frequently carry out clear tank.
Thus, the stability of coal water slurry fuel how is improved, is a current technical problem urgently to be solved.
Summary of the invention
The present invention for the above technical issues, proposes the production method and its production of a kind of high-stability coal water slurry fuel System, the water-coal-slurry product that production obtains have preferable grain size distribution, and stability and mobility are more preferable.
In order to achieve the above object, the technical solution adopted by the present invention are as follows:
The present invention provides a kind of production methods of high-stability coal water slurry fuel, include the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) whole feed coals, water, part dispersing agent and partially stabilized dose are added in grinding machine from the arrival end of grinding machine and are carried out Grinding;
(3) remaining dispersing agent is added from the outlet end of grinding machine to from the slurry that the outlet end of grinding machine is flowed out, is obtained Primary slurry;
(4) primary slurry is collected, stir and refined filtration after, be delivered in agitator tank;
(5) remaining stabilizer is added to being mixed evenly in agitator tank with the slurry in agitator tank, obtains second level Slurry;
(6) second level slurry pipeline steel to homogeneous tank is subjected to homogeneous curing, obtains finished pulp, by finished pulp from finished pulp storage tank Bottom be sent into finished pulp storage tank stored.
Preferably, the additive amount for the dispersing agent being added in the grinding machine is that the dispersing agent is always used in step (2) Amount 60%~95%, be added the stabilizer in the grinding machine additive amount be the total dosage of the stabilizer 10%~ 30%.
Preferably, the dispersing agent includes one of naphthalene sulfonate, lignosulfonates and sulfonated humic acid or more Kind.
Preferably, the stabilizer includes ferrous sulfate, dimethyl carbonate, sodium carboxymethylcellulose and polyacrylamide One of or it is a variety of.
The present invention also provides a kind of production system of high-stability coal water slurry fuel, the production system uses above-mentioned The production method of high-stability coal water slurry fuel described in one technical solution;The production system includes: coal dust surge bunker, water Tank, dispersing agent tank, stabilizer tank, grinding machine, collection stock tank, pulp filter, agitator tank, homogeneous tank and finished pulp storage tank;The coal dust is slow The arrival end that storehouse is connected to the grinding machine by coal dust charging gear is rushed, the water pot is connected to the grinding machine by water delivery pipe Arrival end, the collection stock tank is set to below the outlet end of the grinding machine, the collection stock tank, pulp filter, agitator tank and homogeneous Tank is sequentially connected by fluid-conveying pipe, and the homogeneous tank is connected to the finished pulp tank bottom by finished pulp delivery pipe; Between the dispersing agent tank and the arrival end of grinding machine and between the dispersing agent tank and the outlet end of grinding machine, it is connected separately with Dispersing agent delivery pipe;Between the stabilizer tank and the arrival end of the grinding machine and between the stabilizer tank and agitator tank, It is connected separately with stabilizer delivery pipe.
Preferably, the finished pulp delivery pipe includes sequentially connected straight pipe and ring pipe section, the straight pipe connection In the homogeneous tank, the ring pipe section is sheathed on outside the finished pulp storage tank, and the ring pipe section is equipped with described in multiple be connected to The finished pulp delivery port of finished pulp tank bottom side wall, each finished pulp delivery port are equipped with control valve, it is multiple it is described at Product slurry delivery port is distributed in the ring pipe section.
Preferably, the grinding machine is double storehouses grinding machine.
Preferably, the coal dust charging gear includes the vibration feed for the discharge outlet for being set to the coal dust surge bunker Machine, and it is set to the weighing belt below the vibrating feeder outlet end, the feed end of the weighing belt is given with the vibration Material machine outlet end is correspondingly arranged, and the discharge end of the weighing belt and the arrival end of the grinding machine are correspondingly arranged.
Preferably, being parallel with slurry conveying shunt valve between the fluid-conveying pipe of the pulp filter two sides connection.
Preferably, the water delivery pipe, dispersing agent delivery pipe and stabilizer delivery pipe are respectively arranged with metering pump;Even Be connected to it is described collection stock tank fluid-conveying pipe on, on the fluid-conveying pipe between the agitator tank and homogeneous tank and it is described at Product are starched in delivery pipe, and slurry delivery pump is respectively arranged with.
Compared with prior art, the advantages and positive effects of the present invention are:
1, the production method of high-stability coal water slurry fuel provided by the invention, by dispersing agent and stabilizer addition side The adjustment of formula, the mode that cooperation finished pulp is sent into from the bottom of finished pulp storage tank, in coal, dispersing agent and stabilizer types and use Under conditions of amount, mill types are all the same, the mobility and stability of the water-coal-slurry product of acquisition are more preferable, and production cost is more It is low;
2, in the production method of high-stability coal water slurry fuel provided by the invention, dispersing agent by grinding machine arrival end and go out Two sections of additions are divided at mouth end, compared to the adding manner that dispersing agent in traditional handicraft is all added by mill entrance end, dispersing agent point Two sections of adding manner can be such that the dispersing agent entered in grinding machine reduces, and on the one hand control the flowing velocity of slurry, increase slurry Residence time of the body in grinding machine, milling time is extended, on the other hand since viscosity increases, can reduce to touch and pound chance and increase Add grinder meeting, creates conditions to obtain optimal granularity gradation, and remaining dispersing agent is added from the outlet end of grinding machine, can subtract The viscosity of small slurry, the mobility for increasing slurry, to guarantee that the viscosity of slurry and mobility reach requirement;
3, in the production method of high-stability coal water slurry fuel provided by the invention, stabilizer is from mill entrance end and stirring Two positions of tank are added, and are all added compared to stabilizer in traditional handicraft to the adding manner in agitator tank, in mill entrance Partially stabilized dose of end addition, can properly increase the slurry viscosity in grinding machine, create advantageous item to extend slurry milling time Part, and the remaining stabilizer being added at agitator tank, can further increase stabilizer and uniformly divide in water-coal-slurry coal particle The effect of cloth is prepared for the slurry curing of next step homogeneous tank;
4, in the production method of high-stability coal water slurry fuel, finished pulp is sent into finished pulp storage from the bottom of finished pulp storage tank In tank, the unstable agglomerated particle of finished pulp tank bottom can be made to restore normal condition again, it is heavy to greatly reduce tank bottom Shallow lake amount is conducive to the stabilization for keeping coal water slurry fuel, extends the clear tank period, saved clear tank expense, moreover, storing up in finished pulp Tank top saves equipment investment and maintenance cost without installing mechanical stirring device additional;Meanwhile finished pulp is from finished pulp storage tank Bottom is sent into, and the outlet pressure of the screw pump of conveying progressively reaches most with the raising of liquid level in finished pulp storage tank from zero Greatly, it is conducive to extend the service life of screw pump, finished pulp delivery pipe in existing coal water slurry fuel production system is solved and connects In finished pulp tank top and the short problem of bring service life of screw pump.
Detailed description of the invention
Fig. 1 is the schematic diagram of the production system of high-stability coal water slurry fuel provided by the embodiment of the present invention;
Fig. 2 be the embodiment of the present invention provided by high-stability coal water slurry fuel production system in finished pulp delivery pipe with The connection schematic diagram of finished pulp tank bottom;
Fig. 3 is the cross-sectional view of the line A-A along Fig. 2;
In above each figure: 1, coal dust surge bunker;2, coal dust charging gear;21, vibrating feeder;22, weighing belt;3, it grinds Machine;4, water pot;5, dispersing agent tank;6, stabilizer tank;7, collect stock tank;8, pulp filter;9, agitator tank;10, homogeneous tank;11, finished product Starch storage tank;12, water delivery pipe;13, dispersing agent delivery pipe;14, stabilizer delivery pipe;15, fluid-conveying pipe;16, finished pulp is defeated Send pipe;161, straight pipe;162, ring pipe section;163, finished pulp delivery port;164, control valve;17, slurry conveys shunt valve;18, Metering pump;19, slurry delivery pump.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The embodiment of the invention provides a kind of production methods of high-stability coal water slurry fuel, include the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) by whole feed coals, water, part dispersing agent and partially stabilized dose from the arrival end of grinding machine 3 be added grinding machine 3 in into Row grinding;
(3) remaining dispersing agent is added from the outlet end of grinding machine 3 to from the slurry that the outlet end of grinding machine 3 is flowed out, is obtained To primary slurry;
(4) primary slurry is collected, stir and refined filtration after, be delivered in agitator tank 9;
(5) remaining stabilizer is added to being mixed evenly in agitator tank 9 with the slurry in agitator tank 9, obtains two Grade slurry;
(6) second level slurry pipeline steel to homogeneous tank 10 is subjected to homogeneous curing, obtains finished pulp, finished pulp is stored up from finished pulp The bottom of tank 11 is sent into finished pulp storage tank 11 and is stored.
Compared to the conventional production methods of coal water slurry fuel, the production method of above-mentioned high-stability coal water slurry fuel by pair The adjustment of dispersing agent and stabilizer adding manner, the mode be sent into from the bottom of finished pulp storage tank 11 of cooperation finished pulp, coal, Under conditions of dispersing agent and stabilizer types and dosage, 3 type of grinding machine are all the same, the mobility of the water-coal-slurry product of acquisition and steady It is qualitative more preferable, and production cost is lower.In the production method of above-mentioned high-stability coal water slurry fuel, dispersing agent is entered by grinding machine 3 Two sections of additions are divided in mouthful end and outlet end, compared to the adding manner that dispersing agent in traditional handicraft is all added by mill entrance end, Dispersing agent is divided to two sections of adding manner that the dispersing agent entered in grinding machine 3 can be made to reduce, and on the one hand controls the flowing speed of slurry Degree increases residence time of the slurry in grinding machine 3, extends milling time, on the other hand since viscosity increases, can reduce and touch It pounds chance and increases grinder meeting, create conditions to obtain optimal granularity gradation, and remaining dispersing agent is from the outlet end of grinding machine 3 It is added, the viscosity of slurry can be reduced, increase the mobility of slurry, to guarantee that the viscosity of slurry and mobility reach requirement. Meanwhile in the production method of above-mentioned high-stability coal water slurry fuel, stabilizer is from 9 two positions of 3 arrival end of grinding machine and agitator tank It is added, is all added compared to stabilizer in traditional handicraft to the adding manner in agitator tank, in the portion that 3 arrival end of grinding machine is added Divide stabilizer, the slurry viscosity in grinding machine 3 can be properly increased, create favorable conditions to extend slurry milling time, and is stirring Mix at tank the 9 remaining stabilizers being added, can further increase stabilizer to coal particle the equally distributed effect in water-coal-slurry, It prepares for the slurry curing of next step homogeneous tank 10.In addition, in the production method of above-mentioned high-stability coal water slurry fuel, finished product Slurry is sent into finished pulp storage tank 11 from the bottom of finished pulp storage tank 11, can make the unstable reunion of 11 bottom of finished pulp storage tank Grain restores normal condition again, greatly reduces tank bottom precipitation capacity, is conducive to the stabilization for keeping coal water slurry fuel, extends clear The tank period has saved clear tank expense, moreover, saving equipment without installing mechanical stirring device additional at the top of finished pulp storage tank 11 Investment and maintenance cost.Meanwhile in the production method of above-mentioned high-stability coal water slurry fuel, finished pulp is from finished pulp storage tank 11 Bottom is sent into, if liquid level is zero in tank, the initial pressure of the screw pump of conveying is also zero, as finished pulp constantly enters, Tank level gradually rises, and the outlet pressure of screw pump is also gradually increased therewith, when liquid level rises to vertex in tank, screw pump Pressure reach maximum, it is seen that the outlet pressure of screw pump is to progressively reach from zero maximum, is conducive to extend making for screw pump With the service life, solve that finished pulp is sent at the top of finished pulp storage tank 11 in traditional handicraft and bring service life of screw pump is short Problem.
In the production method of above-mentioned high-stability coal water slurry fuel, it should be noted that in step (3), remaining dispersion Agent is specially to be added from the outlet mesh inner end of 3 outlet end of grinding machine.In step (5), remaining stabilizer is specially from stirring The top of tank 9 is added.In step (6), the bottom of finished pulp storage tank 11 is connected with multiple finished pulp delivery ports 163, and finished pulp is defeated When sending, a finished pulp delivery port 163 can be opened, can also open multiple finished pulp delivery ports 163, and periodically transformation open at Product starch delivery port 163, comprehensively to be disturbed using the finished pulp of conveying to 11 bottom of finished pulp storage tank.
In a preferred embodiment, in step (2), the additive amount that the dispersing agent in grinding machine 3 is added is the total dosage of dispersing agent 60%~95%, be added grinding machine 3 in stabilizer additive amount be the total dosage of stabilizer 10%~30%.This preferred implementation Example defines the additive amount preferred scope in the dispersing agent and stabilizer that are added in grinding machine 3, and dispersing agent and stabilizer control are upper It states in preferred scope, the mating reaction of the two can be played, be conducive to the mobility, stability and the synthesis that improve coal water slurry fuel Quality.
In a preferred embodiment, dispersing agent includes one of naphthalene sulfonate, lignosulfonates and sulfonated humic acid Or it is a variety of.The specific type of dispersing agent is listed in this preferred embodiment, it is of course possible to be used to prepare the selected of coal water slurry fuel Dispersant is not limited to above-mentioned cited several, but using the dispersing agent of mentioned kind, can prepare stabilization Property and the better coal water slurry fuel of mobility.
In a preferred embodiment, stabilizer includes ferrous sulfate, dimethyl carbonate, sodium carboxymethylcellulose and polypropylene One of amide is a variety of.The specific type of stabilizer is listed in this preferred embodiment, it is of course possible to be used to prepare water coal The selected stabilizer type of slurry fuel be not limited to it is above-mentioned cited several, can but using the stabilizer of mentioned kind Prepare stability and the better coal water slurry fuel of mobility.
In order to become apparent from the production method for introducing high-stability coal water slurry fuel provided by the embodiment of the present invention in detail, It is described below in conjunction with specific embodiment.In following embodiment, dispersing agent is that the lignosulfonates that concentration is 10% are molten Liquid, stabilizer are the carboxymethylcellulose sodium solution that concentration is 1.5%.In following embodiment, the feed coal of use, dispersing agent, Stabilizer type and adding proportion are all the same.
Embodiment 1
The production method of high-stability coal water slurry fuel, includes the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) by whole feed coals, water, the dispersing agent for accounting for the total dosage 60% of dispersing agent and the steady of the total dosage 10% of stabilizer is accounted for Determine agent to be ground out of the arrival end of grinding machine 3 addition grinding machine 3;
(3) dispersing agent of residue 40% is added from the outlet end of grinding machine 3 to the slurry flowed out from the outlet end of grinding machine 3 In, obtain primary slurry;
(4) to step (3) obtain primary slurry be collected, stir and refined filtration after, be delivered in agitator tank 9;
(5) stabilizer of residue 90% is added to being mixed evenly in agitator tank 9 with the slurry in agitator tank 9, is obtained To second level slurry;
(6) the second level slurry pipeline steel for obtaining step (5) to homogeneous tank 10 carries out homogeneous curing, obtains finished pulp, will be at Product slurry is sent into finished pulp storage tank 11 from the bottom of finished pulp storage tank 11 and is stored.
Embodiment 2
The production method of high-stability coal water slurry fuel, includes the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) by whole feed coals, water, the dispersing agent for accounting for the total dosage 70% of dispersing agent and the steady of the total dosage 15% of stabilizer is accounted for Determine agent to be ground out of the arrival end of grinding machine 3 addition grinding machine 3;
(3) dispersing agent of residue 30% is added from the outlet end of grinding machine 3 to the slurry flowed out from the outlet end of grinding machine 3 In, obtain primary slurry;
(4) to step (3) obtain primary slurry be collected, stir and refined filtration after, be delivered in agitator tank 9;
(5) stabilizer of residue 85% is added to being mixed evenly in agitator tank 9 with the slurry in agitator tank 9, is obtained To second level slurry;
(6) the second level slurry pipeline steel for obtaining step (5) to homogeneous tank 10 carries out homogeneous curing, obtains finished pulp, will be at Product slurry is sent into finished pulp storage tank 11 from the bottom of finished pulp storage tank 11 and is stored.
Embodiment 3
The production method of high-stability coal water slurry fuel, includes the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) by whole feed coals, water, the dispersing agent for accounting for the total dosage 77% of dispersing agent and the steady of the total dosage 20% of stabilizer is accounted for Determine agent to be ground out of the arrival end of grinding machine 3 addition grinding machine 3;
(3) dispersing agent of residue 23% is added from the outlet end of grinding machine 3 to the slurry flowed out from the outlet end of grinding machine 3 In, obtain primary slurry;
(4) to step (3) obtain primary slurry be collected, stir and refined filtration after, be delivered in agitator tank 9;
(5) stabilizer of residue 80% is added to being mixed evenly in agitator tank 9 with the slurry in agitator tank 9, is obtained To second level slurry;
(6) the second level slurry pipeline steel for obtaining step (5) to homogeneous tank 10 carries out homogeneous curing, obtains finished pulp, will be at Product slurry is sent into finished pulp storage tank 11 from the bottom of finished pulp storage tank 11 and is stored.
Embodiment 4
The production method of high-stability coal water slurry fuel, includes the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) by whole feed coals, water, the dispersing agent for accounting for the total dosage 85% of dispersing agent and the steady of the total dosage 25% of stabilizer is accounted for Determine agent to be ground out of the arrival end of grinding machine 3 addition grinding machine 3;
(3) dispersing agent of residue 15% is added from the outlet end of grinding machine 3 to the slurry flowed out from the outlet end of grinding machine 3 In, obtain primary slurry;
(4) to step (3) obtain primary slurry be collected, stir and refined filtration after, be delivered in agitator tank 9;
(5) stabilizer of residue 75% is added to being mixed evenly in agitator tank 9 with the slurry in agitator tank 9, is obtained To second level slurry;
(6) the second level slurry pipeline steel for obtaining step (5) to homogeneous tank 10 carries out homogeneous curing, obtains finished pulp, will be at Product slurry is sent into finished pulp storage tank 11 from the bottom of finished pulp storage tank 11 and is stored.
Embodiment 5
The production method of high-stability coal water slurry fuel, includes the following steps:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, the total dosage of dispersing agent and stabilization are determined The total dosage of agent;
(2) by whole feed coals, water, the dispersing agent for accounting for the total dosage 95% of dispersing agent and the steady of the total dosage 30% of stabilizer is accounted for Determine agent to be ground out of the arrival end of grinding machine 3 addition grinding machine 3;
(3) dispersing agent of residue 5% is added from the outlet end of grinding machine 3 to from the slurry that the outlet end of grinding machine 3 is flowed out, Obtain primary slurry;
(4) to step (3) obtain primary slurry be collected, stir and refined filtration after, be delivered in agitator tank 9;
(5) stabilizer of residue 70% is added to being mixed evenly in agitator tank 9 with the slurry in agitator tank 9, is obtained To second level slurry;
(6) the second level slurry pipeline steel for obtaining step (5) to homogeneous tank 10 carries out homogeneous curing, obtains finished pulp, will be at Product slurry is sent into finished pulp storage tank 11 from the bottom of finished pulp storage tank 11 and is stored.
Performance inspection is carried out to embodiment 1-5 and using the coal water slurry fuel that traditional coal-water-slurry biofuel production process prepares It surveys, testing result is as shown in the table:
1 coal water slurry fuel performance comparison table of table
Seen from table 1, compared to conventional method, the water coal obtained using production method provided in an embodiment of the present invention production Slurry fuel has optimal grain size distribution, and stability is more preferable.
As shown in Figure 1, the embodiment of the invention also provides a kind of high-stability coal water slurry combustions with aforementioned production method The production system of material, comprising: coal dust surge bunker 1, water pot 4, dispersing agent tank 5, stabilizer tank 6, grinding machine 3, collection stock tank 7, pulp filter 8, agitator tank 9, homogeneous tank 10 and finished pulp storage tank 11;Coal dust surge bunker 1 is connected to entering for grinding machine 3 by coal dust charging gear 2 Mouth end, water pot 4 are connected to the arrival end of grinding machine 3 by water delivery pipe 12, and collection stock tank 7 is set to below the outlet end of grinding machine 3, collection Stock tank 7, pulp filter 8, agitator tank 9 and homogeneous tank 10 are sequentially connected by fluid-conveying pipe 15, and homogeneous tank 10 is defeated by finished pulp Pipe 16 is sent to be connected to 11 bottom of finished pulp storage tank;Between dispersing agent tank 5 and the arrival end of grinding machine 3 and dispersing agent tank 5 and grinding machine Between 3 outlet end, it is connected separately with dispersing agent delivery pipe 13;Between stabilizer tank 6 and the arrival end of grinding machine 3, and stablize Between agent tank 6 and agitator tank 9, it is connected separately with stabilizer delivery pipe 14.
In the production system of above-mentioned high-stability coal water slurry fuel, coal dust surge bunker 1 is for containing the coal dust being crushed, coal Powder charging gear 2 is for coal dust to be delivered in grinding machine 3.As shown in Figure 1, coal dust charging gear 2 includes setting in the present embodiment In the vibrating feeder 21 of the discharge outlet of coal dust surge bunker 1, and it is set to the belt below 21 outlet end of vibrating feeder Scale 22, feed end and 21 outlet end of vibrating feeder of weighing belt 22 are correspondingly arranged, the discharge end of weighing belt 22 and entering for grinding machine 3 Mouth end is correspondingly arranged.The coal dust fallen from 1 discharge outlet of coal dust surge bunker can be shaken and be dissipated by the vibrating feeder 21 of setting, Coal dust adhesion is avoided, the additive amount of coal dust can accurately be controlled by the weighing belt 22 of setting, to improve the quality of production.
Water pot 4 is for containing water, and water delivery pipe 12 is for water to be delivered in grinding machine 3.It should be noted that such as Fig. 1 institute Show, water delivery pipe 12 is provided with metering pump 18, in order to accurately control the conveying capacity of water.
Dispersing agent tank 5 passes through dispersion for containing dispersing agent, the arrival end and outlet end of dispersing agent tank 5 and grinding machine 3 respectively Agent delivery pipe 13 is connected, dispersing agent can be made be divided to two sections of additions by the arrival end and outlet end of grinding machine 3, and dispersing agent is divided to two sections to add Entering mode can be such that the dispersing agent entered in grinding machine 3 reduces, and on the one hand control the flowing velocity of slurry, increase slurry in grinding machine Residence time in 3 extends milling time, on the other hand since viscosity increases, can reduce to touch and pound chance and increase grinding Chance creates conditions to obtain optimal granularity gradation, and remaining dispersing agent is added from the outlet end of grinding machine 3, can reduce slurry The viscosity of body, the mobility for increasing slurry, to guarantee that the viscosity of slurry and mobility reach requirement.It should be noted that such as Shown in Fig. 1, dispersing agent delivery pipe 13 is provided with metering pump 18, in order to accurately control the additive amount of dispersing agent.
Stabilizer tank 6 passes through stabilization for containing stabilizer, the arrival end and agitator tank 9 of stabilizer tank 6 and grinding machine 3 respectively Agent delivery pipe 14 is connected, and stabilizer can be made to be added from 9 two positions of 3 arrival end of grinding machine and agitator tank, added in 3 arrival end of grinding machine Partially stabilized dose entered can properly increase the slurry viscosity in grinding machine 3, create favorable conditions to extend slurry milling time, And the remaining stabilizer being added at agitator tank 9, it can further increase stabilizer and coal particle is uniformly distributed in water-coal-slurry Effect, for next step homogeneous tank 10 slurry curing prepare.It should be noted that as shown in Figure 1, stabilizer delivery pipe 14 It is provided with metering pump 18, in order to accurately control the additive amount of stabilizer.
Grinding machine 3 is used to carry out mixed grinding to coal dust, water, dispersing agent and stabilizer, in order to improve grinding effect, grinding machine 3 Preferably double storehouse grinding machines.When using double storehouse grinding machines, dispersing agent is divided to two sections of additions by the arrival end and outlet end of grinding machine 3, mainly It is so that a storehouse is transformed into grinding state from the past state of pounding of touching, while extending the milling time in two storehouses.
For the primary slurry flowed out from the outlet end of grinding machine 3 to be collected and stirred, pulp filter 8 is used for collection stock tank 7 Refined filtration is carried out to primary slurry, agitator tank 9 is used to carry out strong stirring to the stabilizer added from agitator tank 9 and primary slurry To obtain second level slurry, homogeneous tank 10 is used to carry out second level slurry homogeneous curing to obtain finished pulp, collects stock tank 7, pulp filter 8, agitator tank 9 and homogeneous tank 10 are sequentially connected by fluid-conveying pipe 15 to carry out the conveying of slurry.It should be noted that as schemed Shown in 1, it is connected on the fluid-conveying pipe 15 of collection stock tank 7, on the fluid-conveying pipe 15 between agitator tank 9 and homogeneous tank 10, Slurry delivery pump 19 is respectively arranged with to provide slurry conveying power (the slurry delivery pump between collection stock tank 7 and agitator tank 9 19 also referred to as unloading pump, the slurry delivery pumps 19 between agitator tank 9 and homogeneous tank 10 are also referred to as pump for mortar transmission), moreover, slurry Delivery pump 19 also has certain shear action to slurry, is conducive to the stabilization of slurry.
Due to pulp filter 8 need periodic cleaning with prevent obstruction, guarantee refined filtration efficiency, thus, in order to avoid because cleaning filter It starches device 8 and causes to stop production, as a preference, as shown in Figure 1, in parallel between the fluid-conveying pipe 15 of 8 two sides of pulp filter connection There is slurry to convey shunt valve 17.When needing to clear up pulp filter 8, then it is connected to slurry conveying shunt valve 17, makes slurry by collection stock tank 7 It is fed directly in agitator tank 9, to guarantee normal production.
Finished pulp storage tank 11 is used to store the finished pulp of preparation with spare, and finished pulp passes through finished pulp delivery pipe 16 from homogeneous Tank 10 is delivered to finished pulp storage tank 11, and finished pulp delivery pipe 16 is connected to 11 bottom of finished pulp storage tank, makes finished pulp from finished pulp The bottom of storage tank 11 is sent into finished pulp storage tank 11, and the unstable agglomerated particle of 11 bottom of finished pulp storage tank can be made extensive again Multiple normal condition, greatly reduces tank bottom precipitation capacity, is conducive to the stabilization for keeping coal water slurry fuel, extends the clear tank period, saves About clear tank expense, moreover, saving equipment investment and maintenance without installing mechanical stirring device additional at the top of finished pulp storage tank 11 Expense.It should be noted that as shown in Figure 1, be provided with slurry delivery pump 19 in finished pulp delivery pipe 16 to provide conveying power, Slurry delivery pump 19 herein is also referred to as slurry supply pump.When finished pulp delivery pipe 16 is connected to finished pulp 11 bottom of storage tank, finished pulp It is sent into from the bottom of finished pulp storage tank 11, when use screw pump is as slurry supply pump, if liquid level is zero in tank, at the beginning of screw pump Beginning pressure is also zero, and as finished pulp constantly enters, tank level is gradually risen, and the outlet pressure of screw pump also gradually increases therewith Greatly, when liquid level rises to vertex in tank, the pressure of screw pump reaches maximum, it is seen that the outlet pressure of screw pump be from zero gradually Reach maximum, be conducive to extend the service life of screw pump, it is defeated to solve finished pulp in existing coal water slurry fuel production system Pipe is sent to be connected to finished pulp tank top and the short problem of bring service life of screw pump.
Further, in order to improve finished pulp from 11 bottom of finished pulp storage tank be sent into when to the disturbance in finished pulp storage tank 11 Effect, as shown in Figures 2 and 3, finished pulp delivery pipe 16 include sequentially connected straight pipe 161 and ring pipe section 162, straight pipe 161 are connected to homogeneous tank 10, and ring pipe section 162 is sheathed on outside finished pulp storage tank 11, and ring pipe section 162 is connected to finished product equipped with multiple The finished pulp delivery port 163 of 11 bottom sidewall of storage tank is starched, each finished pulp delivery port 163 is equipped with control valve 164, multiple finished products Slurry delivery port 163 is distributed in ring pipe section 162.It can control the opening and closing of each finished pulp delivery port 163, by control valve 164 with control Manufactured goods slurry is sent into finished pulp storage tank 11 from different finished pulp delivery port 163, so as to 11 bottom of finished pulp storage tank not The finished pulp delivery port 163 for being disturbed with position, and being opened by periodic replacement, it is ensured that 11 bottom of finished pulp storage tank Comprehensively disturbed.In addition, it should be noted that, irregular air blast stirring can be used in finished pulp storage tank 11, with synthesis Disturbance effect of the product slurry conveying to finished pulp storage tank 11.

Claims (10)

1. the production method of high-stability coal water slurry fuel, which comprises the steps of:
(1) according to the total dosage of feed coal and the paste-forming properties test data of feed coal, determine that the total dosage of dispersing agent and stabilizer are total Dosage;
(2) whole feed coals, water, part dispersing agent and partially stabilized dose are added in grinding machine from the arrival end of grinding machine and are ground Mill;
(3) remaining dispersing agent is added from the outlet end of grinding machine to from the slurry that the outlet end of grinding machine is flowed out, obtains primary Slurry;
(4) primary slurry is collected, stir and refined filtration after, be delivered in agitator tank;
(5) remaining stabilizer is added to being mixed evenly in agitator tank with the slurry in agitator tank, obtains second level slurry;
(6) second level slurry pipeline steel to homogeneous tank is subjected to homogeneous curing, obtains finished pulp, by finished pulp from the bottom of finished pulp storage tank Portion is sent into finished pulp storage tank and is stored.
2. the production method of high-stability coal water slurry fuel according to claim 1, it is characterised in that: in step (2), add The additive amount for entering the dispersing agent in the grinding machine is the 60%~95% of the total dosage of the dispersing agent, is added in the grinding machine The stabilizer additive amount be the total dosage of the stabilizer 10%~30%.
3. the production method of high-stability coal water slurry fuel according to claim 1 or 2, it is characterised in that: the dispersion Agent includes one of naphthalene sulfonate, lignosulfonates and sulfonated humic acid or a variety of.
4. the production method of high-stability coal water slurry fuel according to claim 1 or 2, it is characterised in that: the stabilization Agent includes one of ferrous sulfate, dimethyl carbonate, sodium carboxymethylcellulose and polyacrylamide or a variety of.
5. the production system of high-stability coal water slurry fuel, it is characterised in that: the production system is any with claim 1-4 The production method of high-stability coal water slurry fuel described in;The production system includes: coal dust surge bunker, water pot, dispersing agent Tank, stabilizer tank, grinding machine, collection stock tank, pulp filter, agitator tank, homogeneous tank and finished pulp storage tank;The coal dust surge bunker passes through coal Powder charging gear is connected to the arrival end of the grinding machine, and the water pot is connected to the arrival end of the grinding machine by water delivery pipe, The collection stock tank is set to below the outlet end of the grinding machine, and the collection stock tank, pulp filter, agitator tank and homogeneous tank pass through slurry Delivery pipe is sequentially connected, and the homogeneous tank is connected to the finished pulp tank bottom by finished pulp delivery pipe;The dispersing agent Between tank and the arrival end of grinding machine and between the dispersing agent tank and the outlet end of grinding machine, it is connected separately with dispersing agent conveying Pipe;Between the stabilizer tank and the arrival end of the grinding machine and between the stabilizer tank and agitator tank, it is connected separately with Stabilizer delivery pipe.
6. the production system of high-stability coal water slurry fuel according to claim 4, it is characterised in that: the finished pulp is defeated Sending pipe includes sequentially connected straight pipe and ring pipe section, and the straight pipe is connected to the homogeneous tank, and the ring pipe section is sheathed on Outside the finished pulp storage tank, the ring pipe section is equipped with multiple finished pulp conveyings for being connected to the finished pulp tank bottom side wall Mouthful, each finished pulp delivery port is equipped with control valve, and multiple finished pulp delivery ports are distributed in the ring pipe section.
7. the production system of high-stability coal water slurry fuel according to claim 5, it is characterised in that: the grinding machine is double Storehouse grinding machine.
8. the production system of high-stability coal water slurry fuel according to claim 5, it is characterised in that: the coal dust feed Device includes the vibrating feeder for being set to the discharge outlet of the coal dust surge bunker, and is set to the vibrating feeder and goes out Weighing belt below mouth end, the feed end of the weighing belt are correspondingly arranged with the vibrating feeder outlet end, the weighing belt The arrival end of discharge end and the grinding machine be correspondingly arranged.
9. the production system of high-stability coal water slurry fuel according to claim 4, it is characterised in that: the pulp filter two Slurry conveying shunt valve is parallel between the fluid-conveying pipe of side connection.
10. the production system of high-stability coal water slurry fuel according to claim 4, it is characterised in that: the water conveying Pipe, dispersing agent delivery pipe and stabilizer delivery pipe are respectively arranged with metering pump;It is connected to the fluid-conveying pipe of the collection stock tank On, on the fluid-conveying pipe between the agitator tank and homogeneous tank and in the finished pulp delivery pipe, it is respectively arranged with slurry Material conveying pump.
CN201910940016.3A 2019-09-30 2019-09-30 The production method and its production system of high-stability coal water slurry fuel Pending CN110527570A (en)

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Publication number Priority date Publication date Assignee Title
CN101691927A (en) * 2009-09-23 2010-04-07 郑州洪威高新能源工程技术有限公司 Water coal slurry device and production process thereof
CN101691926A (en) * 2009-09-23 2010-04-07 郑州洪威高新能源工程技术有限公司 Container moving type water-coal-slurry device and production process thereof
CN101899338A (en) * 2010-07-28 2010-12-01 江阴市中立机械工业有限公司 Coal-water slurry slurrying system and method for coal chemical industry
CN103540375A (en) * 2013-10-21 2014-01-29 青岛开源集团有限公司 Preparation process of coal water slurry
CN108822907A (en) * 2018-06-25 2018-11-16 合肥金同维低温科技有限公司 A method of textile printing and dyeing wastewater is handled using slurries production technology

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101691927A (en) * 2009-09-23 2010-04-07 郑州洪威高新能源工程技术有限公司 Water coal slurry device and production process thereof
CN101691926A (en) * 2009-09-23 2010-04-07 郑州洪威高新能源工程技术有限公司 Container moving type water-coal-slurry device and production process thereof
CN101899338A (en) * 2010-07-28 2010-12-01 江阴市中立机械工业有限公司 Coal-water slurry slurrying system and method for coal chemical industry
CN103540375A (en) * 2013-10-21 2014-01-29 青岛开源集团有限公司 Preparation process of coal water slurry
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