CN110527383A - A kind of fungi-proofing interior wall coating of water mildow-proof - Google Patents
A kind of fungi-proofing interior wall coating of water mildow-proof Download PDFInfo
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- CN110527383A CN110527383A CN201910850122.2A CN201910850122A CN110527383A CN 110527383 A CN110527383 A CN 110527383A CN 201910850122 A CN201910850122 A CN 201910850122A CN 110527383 A CN110527383 A CN 110527383A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses a kind of fungi-proofing interior wall coating of water mildow-proof, belongs to architectural decoration material field.Including following raw material according to the mass fraction: 16-20 parts of lyate ion water, 0.2-0.5 parts of cellulose, 0.35-0.49 parts of dispersing agent, 3.5-5.6 parts of coalescing agent, 0.07-0.21 parts of defoaming agent, 31-36 parts of pigments and fillers, 38-42 parts of water-based acrylic resin, 0.2-0.4 parts of multifunctional assistant, 0.07-0.28 parts of moistening flatting agent, 0.07-0.31 parts of antimildew disinfectant, 0.1-0.7 parts of thickener, anti-graffiti auxiliary agent 0.2-0.6 parts, the sum of above constituent mass percentage composition is 100%.The present invention is with nanometer modified aqueous acrylic resin (lotion) for base-material, and using ionized water as solvent, a variety of auxiliary agents and filler are deployed, and adds one or more kinds of antimildew disinfectants, effectively prevent the mouldy raw bacterium of wall.
Description
Technical field
The present invention relates to water paint field, especially a kind of fungi-proofing interior wall coating of water mildow-proof.
Background technique
In southern big city, most of building constructions are compact, cause that sunlight can not be seen within doors, and not
Ventilation, so that moist within doors, wall is mouldy, grows many bacteriums, and permanent inhabitation is very big to the body harm of people, causes a series of
Disease；Most of interior wall coatings and have without the function of sterilizing dampproof in the market, are also only limitted to a kind of sterilization or moisture-proof, and
Two kinds of compound compatibilities are not added in a kind of coating.
Summary of the invention
In order to solve the above technical problems, the invention proposes a kind of fungi-proofing interior wall coating of water mildow-proof and preparation method,
The present invention is used cooperatively using different kinds material, and same material is used in compounding, and water-resistant coating is preferable, has resistance to marking pen
Property, antigraffiti effect；Antimildew disinfectant is used in compounding, and reaches killing and inhibiting effect to various bacteriums, fungi and mould；
Technical solution of the present invention is as follows:
A kind of fungi-proofing interior wall coating of water mildow-proof, it is made of following weight proportion raw material: 16-20 parts of lyate ion water,
0.2-0.5 parts of cellulose, 0.35-0.49 parts of dispersing agent, 3.5-5.6 parts of coalescing agent, 0.07-0.21 parts of defoaming agent, pigments and fillers
It is 31-36 parts, 38-42 parts of water-based acrylic resin, 0.2-0.4 parts of multifunctional assistant, 0.07-0.28 parts of moistening flatting agent, mould proof
0.07-0.31 parts of fungicide, 0.1-0.7 parts of thickener, anti-graffiti auxiliary agent 0.2-0.6 parts, the above constituent mass percentage composition it
Be 100%.
Preferably, affiliated cellulose is water dissolvable carboxylic propyl methocel, and carboxylic propyl methocel is as mashing
When thickener, provide a better shear viscosity environment, gloss, air-tightness and the water resistant after improving interior wall coating film forming
Property；
Preferably, the dispersing agent is at least one of ammonium polyacrylate salt dispersing agent or sodium polycarboxylate salt, is reduced
Relative viscosity and thixotropy improve levelability；
Preferably, the coalescing agent is one kind or compounding of alcohol ester 12 or ethylene glycol monobutyl ether, has been used in compounding
Intermolecular stress is eliminated on effect ground, can be formed a film at 3 DEG C or more.
Preferably, the defoaming agent is one kind or compounding of polysiloxane copolymer or polyacrylate, and compounding makes
With intermolecular surface tension can be effectively reduced；
Preferably, the abrasion resistance of coating can be increased to 1 by original more than 1000 times by the pigments and fillers nanometer titanium dioxide
Wan Duoci, and there is antifouling, sterilization, deodorization and other effects；The gloss and anti-settling ability of product can be improved in the powdered whiting；
Several compoundings of barium sulfate or talcum powder；
Preferably, the water-based acrylic resin is by nano-material modified acrylic resin；
Preferably, the multifunctional assistant is that 2-amino-2-methyl-1-propanol is producing to adjust the pH value of product
It is provided in product manufacturing process and stablizes internal environment, and there is wetting, levelling and other effects；
Preferably, the moistening flatting agent is one kind or compounding of dimethyl silicone polymer or acetylenic glycols ethoxy base class, two
Surface tension, can be reduced to minimum segment by being used in compounding for kind moistening flatting agent in the molecule, provide preferable ground wetting
And levelling effect；
Preferably, the antimildew disinfectant is poly- 2-methyl-4-isothiazolin-3-one or 1,2- benzisothiazole -3-
One kind or compounding of ketone, poly- 2-methyl-4-isothiazolin-3-one or 1 He, 2- benzisothiazole-3-ketone are directed to difference respectively
Bacterium, fungi and the mould of type have killing and inhibiting effect；
Preferably, the thickener is non-ionic thickening leveling agent, and product is made to have good dispersion viscosity；
Preferably, the anti-graffiti auxiliary agent is the dimethyl silicone polymer of hydroxy functional groups, has resistance to marking pen, prevents
Antigraffiti effect.
A kind of preparation method of the fungi-proofing interior wall coating of water mildow-proof includes the steps that next coming in order carry out:
(1) 16-20 parts of lyate ion water are added in dispersion cylinder, 0.2-0.5 parts of celluloses is added under stirring, fill
Divide dissolution；Revolving speed is adjusted to 500-700r/min, sequentially adds 0.35-0.49 parts of dispersing agents, 3.5-5.6 parts of coalescing agents, 0.07-
0.21 part of defoaming agent stirs 2-4min；
(2) nanometer titanium dioxide, powdered whiting, barium sulfate or talcum powder are mixed in a certain ratio uniformly, it is 31-36 parts total
Pigments and fillers are slowly added in dispersion cylinder, high speed dispersion to fineness qualification；
(3) 38-42 parts of water-based acrylic resins are added in dispersion cylinder, add 0.2-0.4 parts of multifunctional assistants, adjusted molten
Liquid PH is 8-8.5；
(4) be successively slowly added to 0.07-0.28 parts of moistening flatting agents, 0.07-0.31 parts 0.2-0.6 parts of antimildew disinfectant it is anti-
Scribble auxiliary agent, adds 0.1-0.7 parts of thickeners, is adjusted to appropriate viscosity, after mixing evenly, filters and packages.
The present invention is a kind of fungi-proofing interior wall coating of water mildow-proof and preparation method, and the present invention is cooperated using different kinds material
It uses, same material is used in compounding, and water-resistant coating is preferable, has resistance to marking pen, antigraffiti effect；Antimildew disinfectant is answered
With use, reach the killing and inhibiting effect to various bacteriums, fungi and mould；Solve the mouldy raw bacterium of wall under wet environment
Problem provides a comfortable environment to user.
Specific embodiment
The content of present invention is described in detail with reference to embodiments, disclosed is only several specific implementations of invention
Example, but the present invention is not limited to this, the changes that any person skilled in the art can think of should all fall into guarantor of the invention
Protect range.
Embodiment 1
A kind of fungi-proofing interior wall coating of water mildow-proof is made: 16-20 parts of lyate ion water, fine of following weight proportion raw material
0.2-0.5 parts of element of dimension, 0.35-0.49 parts of dispersing agent, 3.5-5.6 parts of coalescing agent, 0.07-0.21 parts of defoaming agent, pigments and fillers 31-
36 parts, 38-42 parts of water-based acrylic resin, 0.2-0.4 parts of multifunctional assistant, 0.07-0.28 parts of moistening flatting agent, antimycotic antiseptic
0.07-0.31 parts of agent, 0.1-0.7 parts of thickener, anti-graffiti auxiliary agent 0.2-0.6 parts, the sum of above constituent mass percentage composition is
100%.
Further, affiliated cellulose is water dissolvable carboxylic propyl methocel；
Further, the dispersing agent is at least one of ammonium polyacrylate salt dispersing agent or sodium polycarboxylate salt.
Further, the coalescing agent is one kind or compounding of alcohol ester 12 or ethylene glycol monobutyl ether；
Further, the defoaming agent is one kind or compounding of polysiloxane copolymer or polyacrylate.
Further, the pigments and fillers are several compoundings of nanometer titanium dioxide, powdered whiting, barium sulfate or talcum powder；
Further, the water-based acrylic resin is by nano-material modified acrylic resin.
Further, the multifunctional assistant is 2-amino-2-methyl-1-propanol；
Further, the moistening flatting agent is one kind or compounding of dimethyl silicone polymer or acetylenic glycols ethoxy base class.
Further, the antimildew disinfectant is poly- 2-methyl-4-isothiazolin-3-one or 1,2- benzisothiazole-
One kind or compounding of 3- ketone；
The thickener is non-ionic thickening leveling agent.
The anti-graffiti auxiliary agent is the dimethyl silicone polymer of hydroxy functional groups.
(1) 17.9 parts of lyate ion water are added in dispersion cylinder, open dispersion machine, revolving speed is adjusted to 400r/min and is added 0.2
Part cellulose after completely dissolution to cellulose sequentially adds 0.4 part of dispersing agent, 4.2 parts of coalescing agents, 0.14 part of defoaming agent, stirs
3min is mixed, is stirred；
(2) revolving speed is adjusted to 800r/min, sequentially adds 15 parts of nanometer titanium dioxides, 13 parts of powdered whitings, 7 parts of sulfuric acid
Dispersing speed after filler is added, is adjusted to 2100r/min by barium, and high speed dispersion to fineness is less than or equal to 60 μm, executes step
(3)；
(3) revolving speed is reduced to 1100r/min, and 41 parts of water-based acrylic resins are added in dispersion cylinder, are added more than 0.32 part
Function additive adjusts solution PH；
(4) it is successively slowly added to 0.12 part of moistening flatting agent, 0.21 part of antimildew disinfectant, 0.31 part of anti-graffiti auxiliary agent, is stirred
3min adds 0.2 part of thickener, adjusts viscosity, and stirring 30min to liquid is uniformly mixed, filters and packages.
Implementation column 2
(1) 19.8 parts of lyate ion water are added in dispersion cylinder, open dispersion machine, revolving speed is adjusted to 400r/min and is added 0.2
Part cellulose after completely dissolution to cellulose sequentially adds 0.4 part of dispersing agent, 1.0 parts of coalescing agents, 0.14 part of defoaming agent, stirs
3min is mixed, is stirred；
(2) revolving speed is adjusted to 800r/min, sequentially adds 12 parts of nanometer titanium dioxides, 15 parts of powdered whitings, 9 parts of sulfuric acid
Dispersing speed after filler is added, is adjusted to 2100r/min by barium, and high speed dispersion to fineness is less than or equal to 60 μm, executes step
(3)；
(3) revolving speed is reduced to 1100r/min, and 38 parts of water-based acrylic resins are added in dispersion cylinder, are added more than 0.32 part
Function additive adjusts solution PH；
(4) 0.21 part of moistening flatting agent, 3.2 parts of coalescing agents, 0.21 part 0.31 part of antimildew disinfectant are successively slowly added to
Anti-graffiti auxiliary agent stirs 3min, adds 0.21 part of thickener, adjusts viscosity, and stirring 30min to liquid is uniformly mixed, bag filter
Dress.
Disclosed above is only several specific embodiments of the invention, but the present invention is not limited to this, any this field
Technical staff can think changes and improvements should all fall into protection scope of the present invention.
Claims (8)
1. a kind of fungi-proofing interior wall coating of water mildow-proof, it is characterised in that: it is made of following weight proportion raw material: lyate ion water
16-20 parts, 0.2-0.5 parts of cellulose, 0.35-0.49 parts of dispersing agent, 3.5-5.6 parts of coalescing agent, defoaming agent 0.07-0.21
Part, 31-36 parts of pigments and fillers, 38-42 parts of water-based acrylic resin, 0.2-0.4 parts of multifunctional assistant, moistening flatting agent 0.07-
0.28 part, 0.07-0.31 parts of antimildew disinfectant, 0.1-0.7 parts of thickener, anti-graffiti auxiliary agent 0.2-0.6 parts, the above constituent mass
The sum of percentage composition is 100%.
2. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, it is characterised in that:
Affiliated cellulose is water dissolvable carboxylic propyl methocel；
The dispersing agent is at least one of ammonium polyacrylate salt dispersing agent or sodium polycarboxylate salt.
3. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, it is characterised in that:
The coalescing agent is one kind or compounding of alcohol ester 12 or ethylene glycol monobutyl ether；
The defoaming agent is one kind or compounding of polysiloxane copolymer or polyacrylate.
4. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, it is characterised in that:
The pigments and fillers are several compoundings of nanometer titanium dioxide, powdered whiting, barium sulfate or talcum powder；
The water-based acrylic resin is by nano-material modified acrylic resin.
5. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, it is characterised in that:
The multifunctional assistant is 2-amino-2-methyl-1-propanol；
The moistening flatting agent is one kind or compounding of dimethyl silicone polymer or acetylenic glycols ethoxy base class.
6. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, it is characterised in that:
The antimildew disinfectant is one kind or multiple of poly- 2-methyl-4-isothiazolin-3-one or 1,2-benzisothiazolin-3-one
Match；
The thickener is non-ionic thickening leveling agent.
7. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, it is characterised in that:
The anti-graffiti auxiliary agent is the dimethyl silicone polymer of hydroxy functional groups.
8. the fungi-proofing interior wall coating of a kind of water mildow-proof according to claim 1, which is characterized in that a kind of water mildow-proof
The preparation method of fungi-proofing interior wall coating includes the steps that next coming in order carry out:
(1) 16-20 parts of lyate ion water are added in dispersion cylinder, 0.2-0.5 parts of celluloses is added under stirring, it is sufficiently molten
Solution；Revolving speed is adjusted to 500-700r/min, sequentially adds 0.35-0.49 parts of dispersing agents, 3.5-5.6 parts of coalescing agents, 0.07-0.21
Part defoaming agent, stirs 2-4min；
(2) nanometer titanium dioxide, powdered whiting, barium sulfate or talcum powder are mixed in a certain ratio uniformly, total 31-36 parts of face is filled out
Material is slowly added in dispersion cylinder, high speed dispersion to fineness qualification；
(3) 38-42 parts of water-based acrylic resins are added in dispersion cylinder, add 0.2-0.4 parts of multifunctional assistants, adjust solution PH
For 8-8.5；
(4) be successively slowly added to 0.07-0.28 parts of moistening flatting agents, 0.07-0.31 parts 0.2-0.6 parts of antimildew disinfectant it is anti-graffiti
Auxiliary agent adds 0.1-0.7 parts of thickeners, is adjusted to appropriate viscosity, after mixing evenly, filters and packages.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910850122.2A CN110527383A (en) | 2019-09-10 | 2019-09-10 | A kind of fungi-proofing interior wall coating of water mildow-proof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910850122.2A CN110527383A (en) | 2019-09-10 | 2019-09-10 | A kind of fungi-proofing interior wall coating of water mildow-proof |
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| CN201910850122.2A Pending CN110527383A (en) | 2019-09-10 | 2019-09-10 | A kind of fungi-proofing interior wall coating of water mildow-proof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112126298A (en) * | 2020-09-23 | 2020-12-25 | 长沙三思新材料科技有限公司 | Water-based acrylic resin coating with intelligent mildew-proof function and preparation method thereof |
| CN112812630A (en) * | 2020-12-21 | 2021-05-18 | 广东嘉宝莉科技材料有限公司 | Water-based matte anti-doodling interior wall coating |
| CN113736297A (en) * | 2021-09-02 | 2021-12-03 | 亚士创能科技(上海)股份有限公司 | Mildew-proof auxiliary agent and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112126298A (en) * | 2020-09-23 | 2020-12-25 | 长沙三思新材料科技有限公司 | Water-based acrylic resin coating with intelligent mildew-proof function and preparation method thereof |
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| CN113736297A (en) * | 2021-09-02 | 2021-12-03 | 亚士创能科技(上海)股份有限公司 | Mildew-proof auxiliary agent and preparation method and application thereof |
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Application publication date: 20191203 |