CN110511828B - Cleaning agent for intelligent cleaning robot and preparation method thereof - Google Patents
Cleaning agent for intelligent cleaning robot and preparation method thereof Download PDFInfo
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- CN110511828B CN110511828B CN201910839497.9A CN201910839497A CN110511828B CN 110511828 B CN110511828 B CN 110511828B CN 201910839497 A CN201910839497 A CN 201910839497A CN 110511828 B CN110511828 B CN 110511828B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a cleaning agent for an intelligent cleaning robot and a preparation method thereof. The organic acid is not contained in the application, and the application can still play the role of the organic acid when in use; the invention can reduce the reflection of light, so that the object can be imaged more clearly in the vision system of the cleaning robot.
Description
Technical Field
The invention relates to a cleaning agent for an intelligent cleaning robot and a preparation method thereof.
Background
The cleaning robot has very high popularity in Europe, America and Korean, is also applied in China in recent years, and is particularly used for cleaning outdoor glass of buildings. Because the building is high, the manual cleaning has great danger, and especially when the cleaning process encounters strong wind, the personal safety of cleaning personnel can be threatened, so that the cleaning robot used for cleaning outdoor buildings becomes the first choice of various large enterprises at present.
When the cleaning robot is used for cleaning, the surface information of a cleaned object is fed back to the visual positioning system, the visual positioning system performs cleaning operation according to the fed-back information, most of cleaning agents in the current market are products compounded by organic acid and surfactant, and the products are applied to the intelligent robot and have the following problems that 1) the cleaning robot possibly causes damage to the skin when being toppled and used due to the existence of the organic acid; the corrosion to equipment can be caused when the device is used; 2) the visual positioning system of the cleaning robot cannot obtain accurate information, and the cleaning efficiency of the cleaning robot is seriously influenced.
Because the intelligent cleaning robot belongs to new things in China, the intelligent cleaning robot is not compatible with the intelligent cleaning robot in the current market, does not corrode human bodies and equipment, and can improve the cleaning efficiency.
Disclosure of Invention
The invention provides a cleaning agent for an intelligent cleaning robot and a preparation method thereof, which solve the technical problems that 1) the cleaning agent does not contain organic acid and can not corrode human bodies and equipment; 2) the cleaning robot visual system obtains accurate information; 3) the cleaning quality and efficiency are improved.
In order to solve the technical problems, the invention adopts the following technical scheme:
the cleaning agent for the intelligent cleaning robot consists of a surfactant and water and contains a photoinitiator.
Preferably, the photoinitiator is one or two of radical polymerization photoinitiator, cationic polymerization photoinitiator, visible light initiator, aqueous photoinitiator and macromolecule photoinitiator in any proportion.
Preferably, the photoinitiator is a combination of a visible photoinitiator and a cationic polymerization photoinitiator.
Preferably, a defoaming agent is also contained.
The preparation method of the cleaning agent for the intelligent cleaning robot comprises the steps of adding a surfactant, water and a photoinitiator into a container, uniformly stirring, and adding a defoaming agent to obtain the cleaning agent for the intelligent cleaning robot;
the mass ratio of the surfactant to the water to the photoinitiator to the defoaming agent is 3-98.8: 1-96: 0.1-7: 0-2.
The invention has the following beneficial technical effects:
1. this application is through adding photoinitiator, can absorb partial ultraviolet light and visible light, when preventing that cleaning robot from wasing, because visible light reflection interference causes cleaning robot vision positioning system's visual error, and the information that cleaning robot obtained is inaccurate, and then influences cleaning efficiency and cleaning performance.
2. The cationic initiator is added, so that the addition of the organic acid can be omitted without influencing the using effect. When not in use, the product is stored in a light-proof environment or a light-proof container, and no organic acid is generated, so that the product does not corrode human bodies and equipment; when the cleaning solution is used outdoors and is not stored in a container, no light exists, and no super-strong protonic acid exists, and when the cleaning solution is sprayed for use, the cleaning solution is exposed to the sunlight, the cationic initiator generates decomposition reaction under the irradiation of light, and finally generates the super-strong protonic acid, also called as Bronsted acid, which can play the role of organic acid in the cleaning agent, so the cleaning effect is basically not influenced.
3. Because the cleaner contains surfactant active and water, consequently when using, can produce a large amount of bubbles, and the existence of bubble is unfavorable for the wetting by the washing thing, and because the existence of air in the bubble, can form the one deck air on the surface by the washing thing and isolate, it is unclear to lead to the surface by the washing thing to develop the picture in cleaning robot's visual system, and then influenced the cleaning efficiency, after the defoaming agent is added to this application, can obviously reduce the existence of bubble, reduce the isolated of air, it is clear to make the surface of washing thing develop the picture in cleaning robot's visual system, improve the cleaning efficiency.
Drawings
FIG. 1 is a photograph taken by means of a transmission electron microscope in example 3.
FIG. 2 is a photograph taken by means of a transmission electron microscope in example 4.
FIG. 3 is a transmission electron micrograph using comparative example 1.
Detailed Description
The present invention is further illustrated by the following specific examples.
Example 1
The cleaning agent for the intelligent cleaning robot consists of a surfactant and water and contains a photoinitiator.
The surfactant is a composition of AEO-9 and op-10 according to a mass ratio of 5: 1; the photoinitiator was diphenyl titanyl fluoride metallocene (Irgacure 784).
The preparation method of the cleaning agent for the intelligent cleaning robot comprises the steps of adding a surfactant, water and a photoinitiator into a container, and uniformly stirring to obtain the cleaning agent for the intelligent cleaning robot;
the mass ratio of the surfactant to the water to the photoinitiator was 7:92.5: 0.5.
Example 2
The cleaning agent for the intelligent cleaning robot consists of a surfactant and water and contains a photoinitiator.
The surfactant is a composition of AEO-9 and op-10 according to a mass ratio of 5: 1; the photoinitiator is a diaryliodonium salt.
The preparation method of the cleaning agent for the intelligent cleaning robot comprises the steps of adding a surfactant, water and a photoinitiator into a container, and uniformly stirring to obtain the cleaning agent for the intelligent cleaning robot;
the mass ratio of the surfactant to the water to the photoinitiator was 7:92.5: 0.5.
Example 3
The cleaning agent for the intelligent cleaning robot consists of a surfactant and water and contains a photoinitiator.
The surfactant is a composition of AEO-9 and op-10 according to a mass ratio of 5: 1; the photoinitiator is a composition of diphenyl titanium fluoride metallocene (Irgacure 784) and diaryl iodonium salt according to a mass ratio of 1: 1.
The preparation method of the cleaning agent for the intelligent cleaning robot comprises the steps of adding a surfactant, water and a photoinitiator into a container, and uniformly stirring to obtain the cleaning agent for the intelligent cleaning robot;
the mass ratio of the surfactant to the water to the photoinitiator was 7:92.5: 0.5.
Example 4
The cleaning agent for the intelligent cleaning robot consists of a surfactant and water, and contains a photoinitiator; also contains defoaming agent.
The surfactant is a composition of AEO-9 and op-10 according to a mass ratio of 5: 1; the photoinitiator is a composition of diphenyl titanium fluoride metallocene (Irgacure 784) and diaryl iodonium salt according to a mass ratio of 1: 1.
The preparation method of the cleaning agent for the intelligent cleaning robot comprises the steps of adding a surfactant, water and a photoinitiator into a container, uniformly stirring, and adding a defoaming agent to obtain the cleaning agent for the intelligent cleaning robot; the antifoaming agent is purchased from Beijing Xinmeiya chemical industry Co., Ltd; model number is SA 362.
The mass ratio of the surfactant to the water to the photoinitiator to the defoamer is 7:92.4:0.5: 0.1.
Example 5
The cleaning agent for the intelligent cleaning robot consists of a surfactant and water and contains a photoinitiator.
The photoinitiator is 2-hydroxy-2-methyl-1-phenyl acetone.
The surfactant is peregal.
And adding the surfactant, water and the photoinitiator into the container, and uniformly stirring to obtain the cleaning agent for the intelligent cleaning robot.
Example 6
The cleaning agent for the intelligent cleaning robot consists of a surfactant and water and contains a photoinitiator.
The surfactant is a composition of fatty alcohol-polyoxyethylene ether sodium sulfate, sodium dodecyl benzene sulfonate, AES and AEO-9 according to a mass ratio of 5:3:2: 1;
the photoinitiator is a composition of 2-hydroxy-2-methyl-1- [4- (2-hydroxyethoxy) phenyl ] -1-acetone, benzoin dimethyl ether, bis (pentafluorophenyl) titanocene and 2, 4-dihydroxy benzophenone in a mass ratio of 3:2:4: 1.
The defoaming agent is dimethyl silicone oil.
The preparation method of the cleaning agent for the intelligent cleaning robot comprises the steps of adding a surfactant, water and a photoinitiator into a container, uniformly stirring, and adding a defoaming agent to obtain the cleaning agent for the intelligent cleaning robot;
the mass ratio of the surfactant to the water to the photoinitiator to the defoamer is 15:81:2: 2.
The beneficial effects of the present invention are further illustrated below in conjunction with experimental data:
experiment one
1. Experimental materials
1, materials and methods:
1.1 test site: certain analysis center of cigarette platform
1.2 test detection: a reflectance with a wavelength of 200 to 850 nm;
1.3 subjects: examples 1 to 4 and comparative example 1 (the other preparation methods are the same as in example 1 except that no photoinitiator was added);
1.4 Experimental Equipment: a USB4000 spectrometer;
1.5 experimental design: examples 1 to 4 and comparative example 1 (which were identical to example 1 except that no photoinitiator was added) were applied uniformly to the glass plate and measured.
The experiment has the same experimental conditions except different experimental treatments.
2 results and analysis
TABLE 1 Effect of the treatments on glass reflectance
As can be seen from a comparison of the data in Table 1 for examples 1 to 4 and comparative example 1, the present application can reduce the light by adding a photoinitiator
Is reflected.
Experiment two
1, materials and methods:
1.1 test site: a certain analysis center of the smoke bench;
1.2 test detection: microscopic views of the same slide were taken with different treatments;
1.3 subjects: example 3, example 4 and comparative 2 (all other preparation methods are identical to example 3 except that no photoinitiator is added);
1.4 design of test: one side of the slide was evenly coated with example 3 and the other side was left untreated and placed under a microscope for observation
Imaging; wiping off the example 3, uniformly coating the example 4 on the coating position of the example 3, and placing the coating under a microscope for square imaging; example 4 was wiped off, and comparative 2 (identical to example 3 except that no photoinitiator was added) was applied uniformly to the application site of example 4 and imaged under a microscope.
The experiment has the same experimental conditions except different experimental treatments.
2 results and analysis
It can be seen from the experiment that comparative 1 without photoinitiator addition has a significant reflection, whereas the application is smeared with almost no reflection, and the image smeared with the application is clearer compared to the image of comparative 1 (except without photoinitiator addition, the other preparation methods are consistent with example 3); the image of example 4, with both photoinitiator and defoamer added, is clearer.
Experiment three
1. Experimental materials
1, materials and methods:
1.1 test site: the economic and technical development area of the cigarette end city is the Wanke city.
1.2 test detection: speed of cleaning robot applying glass and acceptance of the experiment by property personnel
The acceptance is divided into: satisfaction, basic satisfaction, goodness, and worse.
1.3 test materials: examples 1 to 4 and comparative example 1 (preparation method other than without addition of photoinitiator and example 1 homogeneity)
So);
1.4 design of test: randomly grouping selected 5 buildings side by side, which correspond to examples 1 to 4 and comparative example 1 (except that no photoinitiator is added, other preparation methods are consistent with example 1); the selected floor heights are all 30 floors.
The cleaning robot selected in the experiment is provided by automatic science and technology limited of Haitelin of tobacco terrace;
the experiment has the same experimental conditions except different experimental treatments; .
2 results and analysis
The speed of the cleaning robot applying the glass and the results of the customer satisfaction evaluation test are shown in Table 2
As can be seen from the comparison of the experimental data in the table 2, the cleaning efficiency of the cleaning robot can be obviously improved, the cleaning effect is good, and the cleaning robot can be used together with the cleaning robot; and the comparison 1 of the photoinitiator and the defoaming agent which are not added shows that the cleaning speed is low, the cleaning effect is poor, and the effect is unsatisfactory when the cleaning agent is used together with a cleaning robot.
Claims (4)
1. The cleaning agent for the intelligent cleaning robot is characterized by comprising a surfactant, water and a photoinitiator;
the surfactant is a composition of AEO-9 and op-10 according to a mass ratio of 5: 1; the photoinitiator is a composition of diphenyl titanium fluoride metallocene Irgacure 784 and diaryl iodonium salt according to a mass ratio of 1: 1;
the mass ratio of the surfactant to the water to the photoinitiator was 7:92.5: 0.5.
2. The preparation method of the cleaning agent for the intelligent cleaning robot as claimed in claim 1, wherein the cleaning agent for the intelligent cleaning robot is obtained by adding the surfactant, the water and the photoinitiator into a container and uniformly stirring.
3. The cleaning agent for the intelligent cleaning robot is characterized by comprising a surfactant, water, a photoinitiator and a defoaming agent;
the surfactant is a composition of AEO-9 and op-10 according to a mass ratio of 5: 1; the photoinitiator is a composition of diphenyl titanium fluoride metallocene Irgacure 784 and diaryl iodonium salt according to a mass ratio of 1: 1;
the mass ratio of the surfactant to the water to the photoinitiator to the defoamer is 7:92.4:0.5: 0.1.
4. The method for preparing a cleaning agent for an intelligent cleaning robot as claimed in claim 3, wherein the cleaning agent is a mixture of water and an organic solvent,
adding a surfactant, water and a photoinitiator into a container, uniformly stirring, and adding a defoaming agent to obtain the cleaning agent for the intelligent cleaning robot.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910270206 | 2019-04-04 | ||
| CN2019102702069 | 2019-04-04 |
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| CN110511828A CN110511828A (en) | 2019-11-29 |
| CN110511828B true CN110511828B (en) | 2021-06-15 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104342302A (en) * | 2014-10-26 | 2015-02-11 | 青岛克立克信息技术有限公司 | Long-acting and traceless cleaning agent |
| CN107446723A (en) * | 2017-09-29 | 2017-12-08 | 成都意町工业产品设计有限公司 | A kind of cleaning robot glass cleaner |
| CN107541358A (en) * | 2017-09-29 | 2018-01-05 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent with fast cleaning function |
| CN107686780A (en) * | 2017-09-29 | 2018-02-13 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent |
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- 2019-09-06 CN CN201910839497.9A patent/CN110511828B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104342302A (en) * | 2014-10-26 | 2015-02-11 | 青岛克立克信息技术有限公司 | Long-acting and traceless cleaning agent |
| CN107446723A (en) * | 2017-09-29 | 2017-12-08 | 成都意町工业产品设计有限公司 | A kind of cleaning robot glass cleaner |
| CN107541358A (en) * | 2017-09-29 | 2018-01-05 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent with fast cleaning function |
| CN107686780A (en) * | 2017-09-29 | 2018-02-13 | 成都意町工业产品设计有限公司 | A kind of cleaning robot cleaning agent |
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| CN110511828A (en) | 2019-11-29 |
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Effective date of registration: 20220104 Address after: 264006 106, building 5, municipal entrepreneurship Park, No. 163, Jinshajiang Road, economic and Technological Development Zone, Yantai City, Shandong Province Patentee after: Yantai Xuanwei Intelligent Technology Co.,Ltd. Address before: 264006 room 618, Kexin building, 212 Changjiang Road, Yantai Development Zone, Shandong Province Patentee before: HUAZHI (YANTAI) INTELLIGENT TECHNOLOGY Co.,Ltd. |
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