CN110511611A - A kind of aqueous tipping paper printing ink - Google Patents
A kind of aqueous tipping paper printing ink Download PDFInfo
- Publication number
- CN110511611A CN110511611A CN201910987056.3A CN201910987056A CN110511611A CN 110511611 A CN110511611 A CN 110511611A CN 201910987056 A CN201910987056 A CN 201910987056A CN 110511611 A CN110511611 A CN 110511611A
- Authority
- CN
- China
- Prior art keywords
- parts
- water
- aqueous
- tipping paper
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polyethylene Polymers 0.000 claims abstract description 39
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000004698 Polyethylene Substances 0.000 claims abstract description 33
- 229920000573 polyethylene Polymers 0.000 claims abstract description 33
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 27
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 27
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 27
- 150000001299 aldehydes Chemical class 0.000 claims abstract description 26
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000049 pigment Substances 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- 235000019441 ethanol Nutrition 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 11
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 claims abstract description 11
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 9
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 9
- 239000011976 maleic acid Substances 0.000 claims abstract description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 9
- HNGSNSWYGHQTEH-UHFFFAOYSA-N azane;2-[bis(2-hydroxyethyl)amino]ethanol Chemical compound N.OCCN(CCO)CCO HNGSNSWYGHQTEH-UHFFFAOYSA-N 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims description 10
- 235000019504 cigarettes Nutrition 0.000 claims description 10
- 239000004576 sand Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 150000008065 acid anhydrides Chemical class 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 239000000498 cooling water Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000012046 mixed solvent Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000013557 residual solvent Substances 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000001993 wax Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000000976 ink Substances 0.000 abstract 1
- 230000035943 smell Effects 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- 239000004925 Acrylic resin Substances 0.000 description 5
- 229920000178 Acrylic resin Polymers 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 125000005375 organosiloxane group Chemical group 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000007799 cork Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 229940043237 diethanolamine Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940031098 ethanolamine Drugs 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004176 ammonification Methods 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000009615 deamination Effects 0.000 description 1
- 238000006481 deamination reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of aqueous tipping paper printing inks, it is characterized by: according to parts by weight including following component, water-soluble polyethylene aldehyde contracting butyl ester 20-50 parts, rosin resin 0.1-15 parts water-soluble modified, 0.1-45 parts of pigment, 0.1-50 parts of filler, 0.1-1 parts of wax powder, 50-95 parts, 0.1-95 parts and 0.1-1 parts of dispersing agent of ethyl alcohol, the water-soluble modified rosin resin are made of water-soluble maleic acid, pentalyn and the triethanolamine ammonia that weight fraction ratio is 1:2:5:2.The present invention is small with smell, viscosity is low, the good advantage of stability.
Description
Technical field
The present invention relates to water-based ink technical fields, and in particular to a kind of aqueous tipping paper printing ink.
Background technique
Sight has all been invested water-based ink by many printing factories at present, and relevant enterprise and unit propose many thus
The technical solution factory of " cork paper printing ink ".Such as the patent No.: 200810233722.6, notification number: CN101429364 " tipping
Paper environment friendly bacteriostatic water color ink " (water-based acrylic resin)；The patent No.: 200910222386.X, notification number: CN
101718061A " preparation method of the cork paper of water-based ink " (water-based acrylic resin, aqueous acrylic modified rosin tree
Rouge)；Deng.But above-mentioned patent majority carries out ammonification Water-borne modification using acrylic compounds or acrylic acid modified resin.Due to acrylic acid
It is bad (blackhead, water wave) to lead to printing effect to pigment wetting poor dispersion for resin, while solidifying after deamination as acrylic compounds
Resin, the type resin are brittle resin, and ink film is harder and contraction is larger, and paper curling is obvious, in addition, taking a broad view of China's tipping paper
Water-based ink is printed, there is also following main problems at present for the application in terms of tipping paper paper:
(1) smell is larger.Tipping paper, which has product peculiar smell, to be distinctly claimed: must not have the peculiar smell for interfering cigarette, in water-based ink
Smell mostlys come from Ammonia substance used in resin ammonifying process, and smell sense organ is unfriendly.
(2) paper distortion is excessive.It is slim paper, water since tipping paper printing is 31-37g/m2 with body paper quantification range
The aqueous paper that will lead to of ink print feels like jelly to the absorption of moisture, causes the deformation of paper more serious.
(3) rate of drying is too slow.The rate of drying of water-based ink is excessively slow, influences print speed printing speed and following process, it is also possible to
It is that intaglio plate phenomena such as photographic fog and scumming occurs.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of aqueous tipping paper printing ink, have
Smell is small, viscosity is low, the good advantage of stability.
To achieve the above object, the present invention provides the following technical scheme that a kind of aqueous tipping paper printing ink, according to parts by weight
Number includes following component, 20-50 parts of water-soluble polyethylene aldehyde contracting butyl ester, rosin resin 0.1-15 parts water-soluble modified, pigment
0.1-45 parts, 0.1-50 parts of filler, 0.1-1 parts of wax powder, 50-95 parts of ethyl alcohol, 0.1-95 parts of water and 0.1-1 parts of dispersing agent, institute
State water-soluble maleic acid, pentalyn and three that water-soluble modified rosin resin is 1:2:5:2 by weight fraction ratio
Ethanol amine ammonia is constituted.
Preferably, the concentration of the water-soluble polyethylene aldehyde contracting butyl ester is 30%, the water-soluble polyethylene aldehyde contracting butyl ester choosing
Viscosity is taken to be less than the water-soluble polyethylene aldehyde contracting butyl ester of 500MPa.s.
Preferably, the pigment chooses one of inorganic white, carbon black or other organic color pigments or a variety of.
Preferably, the dispersing agent chooses organosiloxane.
Preferably, the wax powder chooses water-borne wax, and the water-borne wax can choose polyethylene wax or/and polypropylene wax.
It is a further object to provide a kind of cigarette tipping papers printed by aqueous tipping paper printing ink.
It is a further object to provide a kind of preparation methods of aqueous tipping paper printing ink, include the following steps:
(a) under stirring conditions, investment second alcohol and water obtains mixed solvent, and pigment, dispersing agent, filler, wax powder is then added,
And wetting and dispersing is stirred, dispersion speed of agitator degree turns/min in 500-1000;Time is 10-30min；
(b) water-soluble polyethylene aldehyde contracting butyl ester, water-soluble modified rosin resin and residual solvent are put into after step (a),
It is uniformly dispersed under agitation, obtains dispersed material, dispersion speed of agitator degree turns/min in 500-1000;Time is 30-
40min；
(c) dispersed material is ground, filters, can be obtained aqueous tipping paper printing ink, the time is sanded according to ink fineness and
Fixed, for general control at 1-3 hours, sand grinding process need to open cooling water, and temperature of charge will be lower than 50 DEG C；
(d) the aqueous tipping paper printing ink for obtaining step (c) carries out fineness test, and is filtered, and then guarantees, detects, enters
Library.
8, the preparation method of aqueous tipping paper printing ink according to claim 7, it is characterised in that: the frosted is in stick
It is carried out on pin-type sand mill.
9, the preparation method of aqueous tipping paper printing ink according to claim 7, it is characterised in that: the step (d)
In filtering choose 200 mesh filter bag, be filtered in bag filter.
Preferably, the filter bag of 200 mesh is chosen in the filtering in the step (d), is filtered in bag filter.
Preferably, the preparation method of the pentalyn, includes the following steps:
100 parts of rosin are chosen, 150 DEG C of -160 DEG C of meltings of heating are added formaldehyde 12-30 parts, stir under conditions of 90-100 DEG C
2-2.5 hours, 5-15 parts of 2,3 pyrazine diacid acid anhydride were added in 180-200 DEG C of reaction 1.5-2H, 80 parts of pentaerythrite and oxygen is added
Change magnesium 2-2.2 parts, is warming up to 270-280 DEG C, vacuumizes 1 hour.
In conclusion the invention has the following advantages:
1, the aqueous tipping paper printing ink of the present invention is environmentally protective using the mixed solution of water and ethyl alcohol as solvent, reduction VOC emission,
Can save the cost, save the energy；
It 2, is polyvinyl butyral after solidification using resin based on aqueous polyethylene butyral, opposite water soluble acrylic acid
It is for brittle acrylic resin after resin solidification, printed matter surface layer of the present invention ink film is soft, and printed matter is not curled, without pungent
Property unfriendly smell, meet cigarette tipping paper cigarette and peculiar smell control require；
3, the present invention by maleic acid and pentalyn and triethanolamine, not only may be used in water by aminating reaction, gained resin
To use water to dissolve, and relative usage ammonium hydroxide, monoethanolamine or diethanol amine and maleic acid and pentaerythrite modified rosin are anti-
The watersoluble modified rosin resin ratio of gained after answering, smell is small, and stability is good；
4, unlike water-base resin used in traditional water-based ink, the present invention directly uses complete aqueous polyethanol butyral
(it is special, in the present invention, be with Chengdu dragon at synthesis provided by new high-tech material Co., Ltd full water-solubility modifying it is aqueous
Polyvinyl butyral) it is raw material (specific application number: CN201810800361 Publication No. CN109180842A), it can be complete
Use water as solvent, the phenomenon that precipitation without resin.And standard aqueous tipping paper printing ink is water soluble acrylic acid with resin
Resin, be it is water-soluble to acrylic resin grafted amino group, except acrylic resin smell itself greatly in addition to, grafting amino printing
When release the bad smells such as ammonia.The present invention all can do solvent not only save the cost using water simultaneously, also more environmentally-friendly
Emission reduction, while the peculiar smell required without tipping paper；
5, aqueous polyethylene butyral of the invention is that viscosity is less than 500MPa.s, and viscosity is low, can promote ink resin and contain
Amount, printing effect and smell have very big improvement；
6, the use of wax powder of the invention can be improved the wearability for printing formed ink layer, it is ensured that printed matter does not fade, together
When can improve the heat resistance of printed matter, effectively prevent the high temperature adhesion of tipping paper Cigarette；
7, the present invention is by selection, adjustment and the optimization for resin as above, pigment, solvent and auxiliary material, but also by as above former
Expect the not only viscosity with good stability and lower of aqueous tipping paper printing ink prepared by (particularly preferably raw material), but also
Smell is low, and printed matter is not curled, meets the intaglio printing requirement of cigarette tipping paper.
Specific embodiment
Embodiment 1:
A kind of aqueous tipping paper printing ink includes following component according to parts by weight, 20 parts of water-soluble polyethylene aldehyde contracting butyl ester, water-soluble
Property 0.1 part of modified rosin resin, 0.1 part of pigment, 0.1 part of filler, 0.1 part of wax powder, 50 parts of ethyl alcohol, 0.1 part of water and dispersing agent
0.1 part, water-soluble maleic acid, the rosin pentaerythrite that the water-soluble modified rosin resin is 1:2:5:2 by weight fraction ratio
Ester and triethanolamine ammonia are constituted.
The preparation method of the pentalyn, includes the following steps:
100 parts of rosin are chosen, 150 DEG C of -160 DEG C of meltings of heating are added 12 parts of formaldehyde, stir 2- under conditions of 90-100 DEG C
2.5 hours, 5 parts of 2,3 pyrazine diacid acid anhydride were added in 180-200 DEG C of reaction 1.5-2H, 80 parts of pentaerythrite and magnesia 2 is added
Part, it is warming up to 270-280 DEG C, is vacuumized 1 hour.
The concentration of the water-soluble polyethylene aldehyde contracting butyl ester is 30%, and the water-soluble polyethylene aldehyde contracting butyl ester chooses viscosity
Water-soluble polyethylene aldehyde contracting butyl ester less than 500MPa.s.
The pigment chooses one of inorganic white, carbon black or other organic color pigments or a variety of.
The dispersing agent chooses organosiloxane.
The wax powder chooses water-borne wax, and the water-borne wax can choose polyethylene wax or/and polypropylene wax.
A kind of cigarette tipping paper being prepared by above-mentioned aqueous tipping paper printing ink.
A kind of preparation method of aqueous tipping paper printing ink,
Include the following steps:
(a) under stirring conditions, investment second alcohol and water obtains mixed solvent, and pigment, dispersing agent, filler, wax powder is then added,
And wetting and dispersing is stirred, dispersion speed of agitator degree turns/min in 500-1000;Time is 10-30min；
(b) water-soluble polyethylene aldehyde contracting butyl ester, water-soluble modified rosin resin and residual solvent are put into after step (a),
It is uniformly dispersed under agitation, obtains dispersed material, dispersion speed of agitator degree turns/min in 500-1000;Time is 30-
40min；
(c) dispersed material is ground, filters, can be obtained aqueous tipping paper printing ink, the time is sanded according to ink fineness and
Fixed, for general control at 1-3 hours, sand grinding process need to open cooling water, and temperature of charge will be lower than 50 DEG C；
(d) the aqueous tipping paper printing ink for obtaining step (c) carries out fineness test, and is filtered, and then guarantees, detects, enters
Library.
Above-mentioned frosted carries out on stick pin-type sand mill.Grinding temperature in preparation process will be controlled at 50 DEG C hereinafter, mistake
High-temperature, will lead to resin reaction and mobility is deteriorated
The filter bag of 200 mesh is chosen in filtering in above-mentioned steps (d), is filtered in bag filter.
Embodiment 2:
A kind of aqueous tipping paper printing ink includes following component according to parts by weight, 35 parts of water-soluble polyethylene aldehyde contracting butyl ester, water-soluble
7 parts of modified rosin resin of property, 23 parts of pigment, 25 parts of filler, 0.5 part of wax powder, 80 parts of ethyl alcohol, 43 parts of water and 0.5 part of dispersing agent,
The water-soluble modified rosin resin by weight fraction ratio be the water-soluble maleic acid of 1:2:5:2, pentalyn and
Triethanolamine ammonia is constituted.
The preparation method of the pentalyn, includes the following steps:
100 parts of rosin are chosen, 150 DEG C of -160 DEG C of meltings of heating are added 24 parts of formaldehyde, stir 2- under conditions of 90-100 DEG C
2.5 hours, 10 parts of 2,3 pyrazine diacid acid anhydride were added in 180-200 DEG C of reaction 1.5-2H, 80 parts of pentaerythrite and magnesia is added
2.1 parts, it is warming up to 270-280 DEG C, is vacuumized 1 hour.
The concentration of the water-soluble polyethylene aldehyde contracting butyl ester is 30%, and the water-soluble polyethylene aldehyde contracting butyl ester chooses viscosity
Water-soluble polyethylene aldehyde contracting butyl ester less than 500MPa.s.
The pigment chooses one of inorganic white, carbon black or other organic color pigments or a variety of.
The dispersing agent chooses organosiloxane.
The wax powder chooses water-borne wax, and the water-borne wax can choose polyethylene wax or/and polypropylene wax.
A kind of cigarette tipping paper being prepared by above-mentioned aqueous tipping paper printing ink.
A kind of preparation method of aqueous tipping paper printing ink,
Include the following steps:
(a) under stirring conditions, investment second alcohol and water obtains mixed solvent, and pigment, dispersing agent, filler, wax powder is then added,
And wetting and dispersing is stirred, dispersion speed of agitator degree turns/min in 500-1000;Time is 10-30min；
(b) water-soluble polyethylene aldehyde contracting butyl ester, water-soluble modified rosin resin and residual solvent are put into after step (a),
It is uniformly dispersed under agitation, obtains dispersed material, dispersion speed of agitator degree turns/min in 500-1000;Time is 30-
40min；
(c) dispersed material is ground, filters, can be obtained aqueous tipping paper printing ink, the time is sanded according to ink fineness and
Fixed, for general control at 1-3 hours, sand grinding process need to open cooling water, and temperature of charge will be lower than 50 DEG C；
(d) the aqueous tipping paper printing ink for obtaining step (c) carries out fineness test, and is filtered, and then guarantees, detects, enters
Library.
Above-mentioned frosted carries out on stick pin-type sand mill.Grinding temperature in preparation process will be controlled at 50 DEG C hereinafter, mistake
High-temperature, will lead to resin reaction and mobility is deteriorated
The filter bag of 200 mesh is chosen in filtering in above-mentioned steps (d), is filtered in bag filter.
Embodiment 3:
A kind of aqueous tipping paper printing ink includes following component according to parts by weight, 50 parts of water-soluble polyethylene aldehyde contracting butyl ester, water-soluble
15 parts of modified rosin resin of property, 45 parts of pigment, 50 parts of filler, 1 part of wax powder, alcohol 95 part, 95 parts of water and 1 part of dispersing agent, institute
State water-soluble maleic acid, pentalyn and three that water-soluble modified rosin resin is 1:2:5:2 by weight fraction ratio
Ethanol amine ammonia is constituted.
The preparation method of the pentalyn, includes the following steps:
100 parts of rosin are chosen, 150 DEG C of -160 DEG C of meltings of heating are added 30 parts of formaldehyde, stir 2- under conditions of 90-100 DEG C
2.5 hours, 15 parts of 2,3 pyrazine diacid acid anhydride were added in 180-200 DEG C of reaction 1.5-2H, 80 parts of pentaerythrite and magnesia is added
2.2 parts, it is warming up to 270-280 DEG C, is vacuumized 1 hour.
The concentration of the water-soluble polyethylene aldehyde contracting butyl ester is 30%, and the water-soluble polyethylene aldehyde contracting butyl ester chooses viscosity
Water-soluble polyethylene aldehyde contracting butyl ester less than 500MPa.s.
The pigment chooses one of inorganic white, carbon black or other organic color pigments or a variety of.
The dispersing agent chooses organosiloxane.
The wax powder chooses water-borne wax, and the water-borne wax can choose polyethylene wax or/and polypropylene wax.
A kind of cigarette tipping paper being prepared by above-mentioned aqueous tipping paper printing ink.
A kind of preparation method of aqueous tipping paper printing ink,
Include the following steps:
(a) under stirring conditions, investment second alcohol and water obtains mixed solvent, and pigment, dispersing agent, filler, wax powder is then added,
And wetting and dispersing is stirred, dispersion speed of agitator degree turns/min in 500-1000;Time is 10-30min；
(b) water-soluble polyethylene aldehyde contracting butyl ester, water-soluble modified rosin resin and residual solvent are put into after step (a),
It is uniformly dispersed under agitation, obtains dispersed material, dispersion speed of agitator degree turns/min in 500-1000;Time is 30-
40min；
(c) dispersed material is ground, filters, can be obtained aqueous tipping paper printing ink, the time is sanded according to ink fineness and
Fixed, for general control at 1-3 hours, sand grinding process need to open cooling water, and temperature of charge will be lower than 50 DEG C；
(d) the aqueous tipping paper printing ink for obtaining step (c) carries out fineness test, and is filtered, and then guarantees, detects, enters
Library.
Above-mentioned frosted carries out on stick pin-type sand mill.Grinding temperature in preparation process will be controlled at 50 DEG C hereinafter, mistake
High-temperature, will lead to resin reaction and mobility is deteriorated
The filter bag of 200 mesh is chosen in filtering in above-mentioned steps (d), is filtered in bag filter.
Test experiments:
Comparative example 1: the difference from example 2 is that using ammonium hydroxide, monoethanolamine or diethanol amine and maleic acid and pentaerythrite
Modified rosin
Table 1 is the performance table of embodiment 1-3
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| Smell | And free from extraneous odour | And free from extraneous odour | And free from extraneous odour | With biggish peculiar smell |
| Whether tipping paper is observed under conditions of 80 DEG C Occur itself to be adhered and whether tension changes | No itself to be adhered phenomenon, no-station pole canopy becomes Change situation | It is no itself to be adhered phenomenon, no-station pole canopy Situation of change | It is no itself to be adhered phenomenon, no-station pole canopy Situation of change | / |
The foregoing is merely presently preferred embodiments of the present invention, is not intended to restrict the invention, it is all design concept of the invention it
Interior, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of aqueous tipping paper printing ink, it is characterised in that: according to parts by weight include following component, the contracting of water-soluble polyethylene aldehyde
20-50 parts of butyl ester, rosin resin 0.1-15 parts water-soluble modified, 0.1-45 parts of pigment, 0.1-50 parts of filler, 0.1-1 parts of wax powder,
50-95 parts of ethyl alcohol, 0.1-95 parts of water and 0.1-1 parts of dispersing agent, the water-soluble modified rosin resin are by weight fraction ratio
Water-soluble maleic acid, pentalyn and the triethanolamine ammonia of 1:2:5:2 is constituted.
2. a kind of aqueous tipping paper printing ink according to claim 1, it is characterised in that: the water-soluble polyethylene aldehyde contracting fourth
The concentration of ester is 30%, and the water-soluble polyethylene aldehyde contracting butyl ester chooses water-soluble polyethylene aldehyde of the viscosity less than 500MPa.s and contracts
Butyl ester.
3. a kind of aqueous tipping paper printing ink according to claim 1, it is characterised in that: the pigment chooses inorganic white, charcoal
One of black or other organic color pigments are a variety of.
4. a kind of aqueous tipping paper printing ink according to claim 1, it is characterised in that: the dispersing agent chooses organosilicon oxygen
Alkane.
5. a kind of aqueous tipping paper printing ink according to claim 1, it is characterised in that: the wax powder chooses water-borne wax, institute
Polyethylene wax or/and polypropylene wax can be chosen by stating water-borne wax.
6. a kind of cigarette tipping paper, it is characterised in that: the aqueous tipping paper printing ink as described in claim 1-5 prints to obtain.
7. a kind of preparation method of aqueous tipping paper printing ink as claimed in claims 1-5, it is characterised in that: including walking as follows
It is rapid:
(a) under stirring conditions, investment second alcohol and water obtains mixed solvent, and pigment, dispersing agent, filler, wax powder is then added,
And wetting and dispersing is stirred, dispersion speed of agitator degree turns/min in 500-1000;Time is 10-30min；
(b) water-soluble polyethylene aldehyde contracting butyl ester, water-soluble modified rosin resin and residual solvent are put into after step (a),
It is uniformly dispersed under agitation, obtains dispersed material, dispersion speed of agitator degree turns/min in 500-1000;Time is 30-
40min；
(c) dispersed material is ground, filters, can be obtained aqueous tipping paper printing ink, the time is sanded according to ink fineness and
Fixed, for general control at 1-3 hours, sand grinding process need to open cooling water, and temperature of charge will be lower than 50 DEG C；
(d) the aqueous tipping paper printing ink for obtaining step (c) carries out fineness test, and is filtered, and then guarantees, detects, enters
Library.
8. the preparation method of aqueous tipping paper printing ink according to claim 7, it is characterised in that: the frosted is in stick pin type
It is carried out on sand mill.
9. the preparation method of aqueous tipping paper printing ink according to claim 7, it is characterised in that: in the step (d)
The filter bag of 200 mesh is chosen in filtering, is filtered in bag filter.
10. a kind of aqueous tipping paper printing ink according to claim 1, it is characterised in that: the pentalyn
Preparation method includes the following steps:
100 parts of rosin are chosen, 150 DEG C of -160 DEG C of meltings of heating are added formaldehyde 12-30 parts, stir under conditions of 90-100 DEG C
2-2.5 hours, 5-15 parts of 2,3 pyrazine diacid acid anhydride were added in 180-200 DEG C of reaction 1.5-2H, 80 parts of pentaerythrite and oxygen is added
Change magnesium 2-2.2 parts, is warming up to 270-280 DEG C, vacuumizes 1 hour.
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| CN111923622A (en) * | 2020-08-26 | 2020-11-13 | 增和包装股份有限公司 | Gold stamping tipping paper and preparation method thereof |
| CN112646411A (en) * | 2020-12-30 | 2021-04-13 | 浙江特美新材料股份有限公司 | Method for preparing water-based environment-friendly ink composition for tipping paper and preparation method thereof |
| CN113234358A (en) * | 2021-06-07 | 2021-08-10 | 江苏唐彩新材料科技股份有限公司 | Water-based flexo printing temperature-variable anti-counterfeiting ink and preparation method thereof |
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Application publication date: 20191129 |