CN110499079A - Watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt and preparation method thereof - Google Patents

Watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt and preparation method thereof Download PDF

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Publication number
CN110499079A
CN110499079A CN201910771009.5A CN201910771009A CN110499079A CN 110499079 A CN110499079 A CN 110499079A CN 201910771009 A CN201910771009 A CN 201910771009A CN 110499079 A CN110499079 A CN 110499079A
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China
Prior art keywords
aqueous
water
resistance
iron oxide
oxide red
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Pending
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CN201910771009.5A
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Chinese (zh)
Inventor
任明华
唐永刚
叶鸿林
田多
杨成凯
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CHENGDU BAYDI NEW MATERIAL Co Ltd
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CHENGDU BAYDI NEW MATERIAL Co Ltd
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Priority to CN201910771009.5A priority Critical patent/CN110499079A/en
Publication of CN110499079A publication Critical patent/CN110499079A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C08K2003/2272—Ferric oxide (Fe2O3)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/327—Aluminium phosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/328—Phosphates of heavy metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention proposes a kind of watersoluble modified acrylic acid iron oxide red anti-corrosive primers of resistance to greasy dirt and preparation method thereof, including the following component according to mass fraction meter: aqueous acrylic emulsion 22.5-30%, water-base epoxy ester resin 3-10%, aqueous dispersion 0.25-0.5%, aqueous defoamer 0.2-0.4%, aqueous substrate wetting agents 0.1-0.4%, anti- flash rusting agent 0.4-0.8%, deionized water 5.3-10.1%, coalescing agent 3-6%, drier 0.2-0.4%, organobentonite 0.3-0.5%, fumed silica 0.3-0.5%, iron oxide red 10-15%, coarse whiting 27-32%, aqueous zinc phosphate 4-7%, sericite 3-5%, aqueous phosphate aluminium 3-4%, water-based thickener 0.2-0. 4%.Such product of the invention has that the greasy dirt of resistance to ground is good, reprocesses in oiliness and soaks that adhesive force is good, smooth surface wetting adhesive force is good on workpiece, thick film does not crack, the features such as thick film impact resistance buckling performance is excellent, freeze-thawing resistant stability is good, water-tolerant, antiseptic property is excellent, heat-resist, adhesive force is excellent；It can be widely used in the fields such as all kinds of large-scale steel structures, water-born paint for car chassis, automobile water compartment, train chassis paint, engineering machinery.

Description

Watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt and preparation method thereof
Technical field
The present invention relates to painting field, a kind of watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt and its system are particularly related to Preparation Method.
Background technique
Requirement with economic development its people to environmental quality, health is higher and higher, country to environmental requirement more Strictly, oil turns one of the main direction of development that water is generally acknowledged as coating industry, and water paint will welcome huge development machine It meets, while promoting the performance indexes for improving water paint, it is outstanding in smooth surface that everybody also encounters water soluble acrylic acid paint Its smooth surface, ground oily waste treatment are not thorough, and coating oil paint reprocesses the difficult wetting such as workpiece difficult the problem of adhering to.
For resistance to greasy dirt, the current common processing method of water paint is to add the auxiliary agent of resistance to greasy dirt, but the auxiliary agent of resistance to greasy dirt one Carry out price, dosage is small not to work, and dosage is big, and cost is expensive, while ineffective to seriously polluted surface, smooth surface, Poor adhesive force.
Summary of the invention
The present invention proposes a kind of watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt and preparation method thereof, can make antirust Paint is reprocessed in oiliness and soaks that adhesive force is good, smooth surface wetting adhesive force is good on workpiece, and thick film does not crack.
The technical scheme of the present invention is realized as follows: a kind of watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt, It is characterized in that: including the following component according to mass fraction meter: aqueous acrylic emulsion 22.5-30%, water-base epoxy ester resin 3-10%, aqueous dispersion 0.25-0.5%, aqueous defoamer 0.2-0.4%, aqueous substrate wetting agents 0.1-0.4%, anti-sudden strain of a muscle Become rusty agent 0.4-0.8%, deionized water 5.3-10.1%, coalescing agent 3-6%, drier 0.2-0.4%, organobentonite 0.3-0.5%, fumed silica 0.3-0.5%, iron oxide red 10-15%, coarse whiting 27-32%, aqueous zinc phosphate 4-7%, Sericite 3-5%, aqueous phosphate aluminium 3-4%, water-based thickener 0.2-0.4%.
Preferably, the water-base epoxy ester resin includes the water-base epoxy ester resin of different oil content；That is water-base epoxy ester In resin between oil-containing or fatty acid amount 30-70%.
The preparation method of the watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt, the water-base epoxy ester need to have been carried out preferentially Full dispersion, preparation method includes the following steps:
Water-base epoxy ester is added in production cylinder A step a., is slowly added into neutralization while stirring using 400-600 revs/min Agent, drier, deionized water, using 600-800 revs/min of high speed dispersion, until water-base epoxy ester resin is completely dissolved, fineness < 5um is stand-by；
Step b. is by aqueous acrylic emulsion, aqueous dispersion, aqueous substrate wetting agents, aqueous defoamer, coalescing agent It is added in production cylinder, is stirred 5 minutes using 300-500 revs/min；
Step c. using 300-600 revs/min while stirring be added organobentonite, aqueous phosphate aluminium, fumed silica, Sericite, iron oxide red, coarse whiting, aqueous zinc phosphate, using 600-800 revs/min stirring 10-15 minutes；
Fineness is ground to 50 microns using horizontal sand mill by step d.；
Step e. is slowly added into anti-flash rusting agent using 800-1000 revs/min while stirring, production cylinder is added in water-based thickener In, continue stirring 5 minutes.
Compared with the prior art, the advantages of the present invention are as follows: such product is with the greasy dirt of resistance to ground is good, reprocesses work in oiliness Soak that adhesive force is good, smooth surface wetting adhesive force is good on part, thick film does not crack, and thick film impact resistance buckling performance is excellent, resistance to jelly Melt the features such as good stability, water-tolerant, antiseptic property are excellent, heat-resist, adhesive force is excellent；It can be widely used in all kinds of Large Steels The fields such as structure, water-born paint for car chassis, automobile water compartment, train chassis paint, engineering machinery.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without creative efforts belongs to the model that the present invention protects It encloses.
Embodiment:
One, the watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt
Raw material is as follows:
Aqueous acrylic emulsion (06,140,000 China)
Water-base epoxy ester resin (GS-5000B Changzhou Guang Shu)
Coalescing agent (ethylene glycol monobutyl ether, propylene glycol monobutyl ether, dipropylene, butyl, poly- second two Alcohol, diethylene glycol dimethyl ether, n-butanol etc. are one or more)
Neutralizer (N, N- dimethylethanolamine, triethylamine, ammonium hydroxide, tetramethyl ammonium hydroxide, AMP-95 etc. it is one of with On)
Deionized water (self-control)
Aqueous dispersion (ZWD1 ring fine jade chemical industry)
Aqueous defoamer (BYK-024 BYK)
Anti- flash rusting agent (ten pine of the Jiangsu ZH-55)
Drier (6206 is profound new)
Organobentonite (DE Hai Mingsi)
Fumed silica (972 Degussa)
Iron oxide red (190D span new century)
Coarse whiting (the 1250 rich chemical industry of mesh Henan barium)
Sericite (800 mesh Baofeng)
Aqueous phosphate aluminium (YR-1 has Rong Huagong)
Aqueous zinc phosphate (YR-2 has Rong Huagong)
Water-based thickener (MT-105A Hai Mingsi)
Aqueous substrate wetting agents (452W is first created)
Table 1: the 4 watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt formula of embodiment 1- embodiment
Raw material Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Aqueous acrylic emulsion 22.5 25.5 30 30
Water-base epoxy ester resin 8 6 3 10
Aqueous dispersion 0.25 0.3 0.5 0.5
Aqueous defoamer 0.2 0.4 0.3 0.2
Aqueous substrate wetting agents 0.4 0.2 0.2 0.1
Anti- flash rusting agent 0.4 0.6 0.8 0.8
Deionized water 10.1 5.6 7.1 5.3
Coalescing agent 3 4 6 6
Drier 0.4 0.3 0.2 0.2
Organobentonite 0.5 0.4 0.3 0.3
Fumed silica 0.4 0.5 0.3 0.3
Iron oxide red 15 12 10 10
Coarse whiting 27 32 27 29
Aqueous zinc phosphate 4 4 7 5
Sericite 3 5 3 3
Aqueous phosphate aluminium 4 3 4 4
Water-based thickener 0.4 0.2 0.3 0.3
It is total 100 100 100 100
:
Technique
1, water-base epoxy ester resin is added to produce in cylinder and is added with stirring neutralizer, drier, goes for 400-600 rev/min Ionized water is stirred 20 minutes using 800-1000 revs/min；
2, aqueous acrylic emulsion, aqueous dispersion, aqueous substrate wetting agents, aqueous defoamer, coalescing agent are added Produce cylinder in, using 400-600 revs/min stirring 5-10 minutes；
3, organobentonite, aqueous phosphate aluminium, fumed silica, thin,tough silk cloud are added while stirring using 400-600 revs/min Mother, iron oxide red, coarse whiting, aqueous zinc phosphate, using 600-800 revs/min stirring 10-15 minutes；
4, fineness is ground to 50 microns using horizontal sand mill；
5, using 600-800 revs/min be slowly added into while stirring anti-flash rusting agent, water-based thickener be added production cylinder in, after Continuous stirring 5-10 minutes.
Dry plate is realized:
The deionized water of the watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt made addition 0-5% is carried out dilute It releases, spray viscosity is adjusted to 30-40S (T-4 glasss), is sprayed using 2.0-2.5 bore spray gun, ground uses tinplate Piece, direct spraying after polishing, the dry plate thickness control of physical performance detection is at 15-25 microns, under room temperature from after doing 48 hours The dry plate thickness control of detection, pattern detection detects under the conditions of 50-60 microns, 23 ± 2 DEG C from after doing 7 days.
Properties test foundation: dry to execute according to GB/T1728 standard, hardness is executed according to GB/T1730 standard, attached To put forth effort to execute according to GB/T1720 standard, impact is executed according to GB/T1732 standard, and flexibility is executed according to GB/T1731 standard, Water resistance is executed according to GB/T1733 standard, and resistance to gasoline is executed according to GB/T1734 standard, heat resistance is according to GB/T1735 standard It executes, salt spray resistance is executed according to GB/T1771 standard.
Table 2: 4 dry plate the performance test results of embodiment 1- embodiment
It can be seen that paint film rate of drying all very fastly than data by watch 2, but comprehensive properties cost (its center Heart index is resistance to oil stains and smooth surface adhesive force) from the point of view of, embodiment 2 is optimal.Paint film in the early stage resistance to dripping property test completely without It is abnormal, water resistance test reach 720 hours it is without exception, salt spray resistance can reach 500 hours non-corrodings.Production cost is moderate, Can be widely applied oil pollution be difficult to again all kinds of large-scale steel structures cleared up, water-born paint for car chassis, automobile water compartment, train chassis paint, The fields such as engineering machinery.
The water-base epoxy ester resin and aqueous acrylic emulsion painting that the present invention cleverly uses matching good, balance resistance to Greasy dirt performance and paint stemness, while the introducing of epoxy-ester substantially increases the salt spray resistance chemical-resistance freeze-thawing resistant stabilization of paint film Newly, make it have that the greasy dirt of resistance to ground is good, reprocesses in oiliness and soaks that adhesive force is good, smooth surface wetting adhesive force is good on workpiece, it is thick Film does not crack, thick film impact resistance buckling performance is excellent, freeze-thawing resistant stability is good, water-tolerant, antiseptic property are excellent, it is heat-resist, The excellent performance of adhesive force can be widely used in all kinds of large-scale steel structures, water-born paint for car chassis, automobile water compartment, train chassis paint, engineering The fields such as machinery.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (3)

1. a kind of watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt, it is characterised in that: including according to mass fraction meter as Lower component: aqueous acrylic emulsion 22.5-30%, water-base epoxy ester resin 3-10%, aqueous dispersion 0.25-0.5%, aqueous Defoaming agent 0.2-0.4%, aqueous substrate wetting agents 0.1-0.4%, anti-flash rusting agent 0.4-0.8%, deionized water 5.3-10.1%, Coalescing agent 3-6%, drier 0.2-0.4%, organobentonite 0.3-0.5%, fumed silica 0.3-0.5%, oxidation Iron oxide red 10-15%, coarse whiting 27-32%, aqueous zinc phosphate 4-7%, sericite 3-5%, aqueous phosphate aluminium 3-4%, aqueous thickening Agent 0.2-0.4%.
2. the watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt according to claim 1, it is characterised in that: described aqueous Epoxy ester resin includes the water-base epoxy ester resin of different oil content；Oil-containing or fatty acid amount 30- i.e. in water-base epoxy ester resin Between 70%.
3. the preparation method of the watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt according to claim 1 or 2, feature Be: the water-base epoxy ester need to be preferentially completely dispersed, and preparation method includes the following steps:
Water-base epoxy ester is added in production cylinder A step a., is slowly added into neutralizer while stirring using 400-600 revs/min, urges Dry agent, deionized water, using 600-800 revs/min of high speed dispersion, until water-base epoxy ester resin is completely dissolved, fineness < 5um is waited for With；
Aqueous acrylic emulsion, aqueous dispersion, aqueous substrate wetting agents, aqueous defoamer, coalescing agent are added step b. It produces in cylinder, is stirred 5 minutes using 300-500 revs/min；
Organobentonite, aqueous phosphate aluminium, fumed silica, thin,tough silk cloud is added using 300-600 revs/min in step c. while stirring Mother, iron oxide red, coarse whiting, aqueous zinc phosphate, using 600-800 revs/min stirring 10-15 minutes；
Fineness is ground to 50 microns using horizontal sand mill by step d.；
Step e. is slowly added into anti-flash rusting agent using 800-1000 revs/min while stirring, water-based thickener is added in production cylinder, after Continuous stirring 5 minutes.
CN201910771009.5A 2019-08-20 2019-08-20 Watersoluble modified acrylic acid iron oxide red anti-corrosive primer of resistance to greasy dirt and preparation method thereof Pending CN110499079A (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN111334160A (en) * 2020-03-25 2020-06-26 广州集泰化工股份有限公司 Water-based anticorrosive primer and preparation method thereof
CN111423788A (en) * 2020-05-11 2020-07-17 龙海市大华涂料有限公司 Preparation method of epoxy resin aqueous paint
CN112143309A (en) * 2020-09-16 2020-12-29 广州集泰化工股份有限公司 Water-based anti-sticking anticorrosion primer and preparation method and application thereof
CN112480760A (en) * 2020-11-06 2021-03-12 广东红蜘蛛纳米新材料有限公司 Environment-friendly nano oil-stain-resistant adsorptive coating and production method thereof
CN112552810A (en) * 2020-12-29 2021-03-26 湖南金化科技集团有限公司 Water-based steel pipe antirust coating and preparation method thereof

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CN109135455A (en) * 2018-07-06 2019-01-04 河北晨阳工贸集团有限公司 A kind of aqueous protective paint of high-performance water proof and wearable and preparation method thereof
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111334160A (en) * 2020-03-25 2020-06-26 广州集泰化工股份有限公司 Water-based anticorrosive primer and preparation method thereof
CN111423788A (en) * 2020-05-11 2020-07-17 龙海市大华涂料有限公司 Preparation method of epoxy resin aqueous paint
CN112143309A (en) * 2020-09-16 2020-12-29 广州集泰化工股份有限公司 Water-based anti-sticking anticorrosion primer and preparation method and application thereof
CN112480760A (en) * 2020-11-06 2021-03-12 广东红蜘蛛纳米新材料有限公司 Environment-friendly nano oil-stain-resistant adsorptive coating and production method thereof
CN112552810A (en) * 2020-12-29 2021-03-26 湖南金化科技集团有限公司 Water-based steel pipe antirust coating and preparation method thereof

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Application publication date: 20191126