CN108129948A - Carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field - Google Patents
Carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field Download PDFInfo
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- CN108129948A CN108129948A CN201711331053.1A CN201711331053A CN108129948A CN 108129948 A CN108129948 A CN 108129948A CN 201711331053 A CN201711331053 A CN 201711331053A CN 108129948 A CN108129948 A CN 108129948A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/103—Anti-corrosive paints containing metal dust containing Al
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
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Abstract
The present invention proposes a kind of carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field, include aqueous epoxy curing agent, water aluminum-silver slurry, functional graphene slurry, aqueous zinc phosphate, dispersant, antifoaming agent, aqueous organobentonite, aerosil, zinc powder, carbon nanotube slurry, cosolvent including component A and component B, the component A；Component B is aqueous epoxy resin emulsion；Preparation method includes producing the additions such as aqueous epoxy curing agent in cylinder, stirring；Aqueous zinc phosphate etc. is added in while stirring；Sand mill will be ground；It is slowly added into functional graphene slurry etc., dispersion while stirring；Dry plate is realized, adjusts viscosity, and dry plate places detection traditional performance.Such product of the present invention has very excellent antiseptic property, and salt spray resistance test can reach 6000 hours, have very excellent acid-proof alkaline, workability is excellent, and disposable application reaches 150 microns of not saggings.
Description
Technical field
The present invention relates to painting fields, particularly relate to a kind of carbon nanotubes watersoluble plumbago alkene applied to container field
Epoxy zinc rich primer.
Background technology
Container be international logistics transport specific purpose tool, use environment is complicated and changeable, to be not only subjected to difference variation,
The test of the natural conditions such as wind and weather, ultraviolet radiation, atmospheric corrosion and sea washes, also suffers transport and handling operation
In friction and collision etc., cause its corrosion of steel structure inevitable.
From the point of view of the construction of container, the beam, column and plate member that form babinet are generally made of the different material of thin-walled, and thickness is in 1.6-
Between 2.0mm, therefore, to prevent container corrosion of component, the antiseptic property of coating container is particularly important.Container applies
Material is one of important raw and processed materials for manufacturing container.Up to the present, coating container enters Water-borne modification substantially, in addition to special case
Other than not requiring, remaining all standard packing box is all changed to water paint.
System is as follows currently on the market for container water paint：Case exterior paint：Water-based epoxy zinc-rich primer+water-based epoxy micaceous
Iron intermediate coat+water-based acrylic acid top-coat；Case interior paint：Water-based epoxy zinc-rich primer+water-base epoxy finishing coat.This two sets of systems are city
System the most ripe on field.But used water-based system paint still has various abnormal problems currently on the market,
Protective capacities is poor compared with oleaginous system, and especially the salt spray resistance of water-based epoxy zinc-rich primer is poorer than oiliness epoxy zinc rich primer very
It is more, many coating factories is caused the phenomenon that returning rust, getting rusty occur, container requires to force within 5 years to scrap in principle, but using water
Property protective system, it is difficult to this service life by 5 years.
Invention content
The present invention proposes a kind of carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field, can
With very excellent antiseptic property, salt spray resistance test can reach 6000 hours, have very excellent acid-proof alkaline,
Workability is excellent, and disposable application reaches 150 microns of not saggings.
The technical proposal of the invention is realized in this way：A kind of carbon nanotubes watersoluble plumbago applied to container field
Alkene epoxy zinc rich primer includes the following component according to mass fraction meter including component A and component B, the component A：Aqueous ring
Oxygen curing agent 6-12%, water aluminum-silver slurry 0.5-1%, functional graphene slurry 1-3%, aqueous zinc phosphate 2-4%, dispersant
0.3-0.8%, antifoaming agent 0.3-0.6%, aqueous organobentonite 0.3-0.5%, aerosil 0.5-0.8%, zinc powder
68-80%, carbon nanotube slurry 1-3%, cosolvent 6.2-7.3%；
Component B：Aqueous epoxy resin emulsion 100%；
Preparation method includes the following steps：
Step a. adds in aqueous epoxy curing agent, dispersant, antifoaming agent, cosolvent in production cylinder, stirring；
Step b. adds in aqueous zinc phosphate, aqueous organobentonite, aerosil while stirring, stirring；
Fineness is ground to 30 microns by step c. using sand mill；
Step d. is slowly added into functional graphene slurry, carbon nanotube slurry, stirring while stirring；
Step e. is added to after using cosolvent, water aluminum-silver slurry is fully soaked in production cylinder, stirring；
Step f. adds in zinc powder while stirring, dispersion；
Step g. dry plates are realized：According to component A：Component B=100：32-48 is matched, using deionized-distilled water into
The adjustment of row spray viscosity adjusts viscosity, sprays 2 layers, dry plate places detection traditional performance.
Preferably, the step a the specific steps are add aqueous epoxy curing agent, dispersant, antifoaming agent, cosolvent
Enter to produce in cylinder, be stirred 5 minutes using 400-600 revs/min.
Preferably, the step b the specific steps are while stirring add in aqueous zinc phosphate, aqueous organobentonite,
Aerosil is stirred 5 minutes using 400-600 revs/min.
Preferably, the step d the specific steps are be slowly added into functionality while stirring using 400-600 revs/min
Graphene slurry, carbon nanotube slurry, are stirred 15-20 minutes using 600-800 revs/min.
Preferably, the step e the specific steps are using cosolvent water aluminum-silver slurry is fully soaked after be added to
It produces in cylinder, is stirred 5 minutes using 600-800 revs/min.
Preferably, the step f the specific steps are zinc powder is added in while stirring using 600-800 revs/min, use
800-1000 revs/min is disperseed 15-20 minutes.
Preferably, the step g dry plates realize the specific steps are：According to component A：Component B=100：32-48 into
Row proportioning, the adjustment of spray viscosity is carried out using deionized-distilled water, spray viscosity is adjusted to 25-30S using T-4 glasss, is sprayed
2 layers are applied, dry plate is placed in 25 DEG C of insulating boxs from dry 48 hours detection traditional performances.
Compared with prior art, the advantage of the invention is that：Such product has very excellent antiseptic property, salt spray resistance
Test can reach 6000 hours, have very excellent acid-proof alkaline, workability is excellent, and disposable application reaches
150 microns of not saggings.
In order to promote the service life of water-based epoxy zinc-rich primer, the present invention provides a property of water-bearing carbon nanotube emphatically
The watersoluble plumbago alkene epoxy zinc-rich anticorrosive paint of material, the advantages of taking full advantage of graphene and carbon nanotube, will be entire rich
Zinc layers are combined into a fine and close reticular structure, make it by container integral coating, so as to play extraordinary protection energy
Power.
Graphene is a kind of carbon material of New Two Dimensional layer structure, have high length-diameter ratio and it is excellent it is hydrophobic, conductive, lead
Thermally and chemically stability makes it be with a wide range of applications in anticorrosive paint.Coat organic coating have construction is simple,
It is cheap, have a wide range of application with other safeguard procedures such as barrier propterty is good it is incomparable the advantages of, be that one kind slows down metal corruption
The means of erosion effectively, economic.
Carbon nanotube also known as Baji-tube, are a kind of One-dimensional Quantum materials with special construction, carbon atom in carbon nanotube
Based on sp hydridization, while there are a degree of bendings for hexangle type network, Space expanding are formed, wherein can be formed
Certain sp hybrid bonds, the chemical bond of formation has sp and sp mixed hybridization states simultaneously, and these p tracks overlap each other in carbon
The delocalized big ∏ keys of height are formed outside nanotube graphene sheet layer, the big ∏ keys of carbon nanotube outer surface are carbon nanotube and one
A little macromoleculars with conjugation performance are with the compound chemical fundamentals of non-covalent bond.The intensity that carbon nanotube assigns is added in the coating
Coating Durability and wearability are improved, promotes and is more closely combined between coating and base material, extend the service life of coating,
Tensile strength and elasticity are enhanced, in addition carbon nanotube has excellent heat conductivility so that coating can adapt to the heat of base material
It shrinks and expands.The high-effective conductive of carbon nanotube can increase substantially the anti-corrosive properties of coating.
Specific embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel all other embodiments obtained without creative efforts belong to the model that the present invention protects
It encloses.
Raw material is as follows：
Aqueous epoxy resin emulsion (6520 U.S.'s Hexion)
Water aluminum-silver slurry (XH330 Shenzhen Xin Hangwang)
Aqueous zinc phosphate (ZIP-M Chongqing wheat figure)
Graphene (10% Suzhou high pass science and technology of functional graphene slurry)
Carbon receive tube cell slurry (the organic institute in 13.8% slurry Chengdu of TNIM8)
Dispersant (6208 allnex)
Antifoaming agent (6393 allnex)
Aerosil (hydrophobic types such as A200, R972, R812S, R202 sea ease chemistry)
Aqueous organobentonite (LT, SD-2, DE etc. engrave this in sea)
Cosolvent (ethylene glycol monobutyl ether, dipropylene glycol, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, ethyl alcohol,
The alcohol ethers solvent such as n-butanol, isopropanol sinopec)
Aqueous epoxy curing agent (8538 U.S.'s Hexion)
Anti- flash rusting agent (the positive row of FA-179 favours)
Associated matter thickener (8W Tao Shi)
Table 1：The formulation ratio of 1~embodiment of embodiment 5
Preparation method is：
1st, aqueous epoxy curing agent, dispersant, antifoaming agent, cosolvent are added in production cylinder, using 400-600 revs/min
Stirring 5 minutes；
2nd, while stirring add in aqueous zinc phosphate, aqueous organobentonite, aerosil, using 400-600 turn/
Divide stirring 5 minutes；
3rd, fineness is ground to 30 microns using sand mill；
4th, it is slowly added into functional graphene slurry, carbon nanotube slurry while stirring using 400-600 revs/min, using 600-
800 revs/min are stirred 15-20 minutes；
5th, it is added to after water aluminum-silver slurry is fully soaked using cosolvent in production cylinder, is stirred using 600-800 revs/min
It mixes 5 minutes；
6th, zinc powder is added in while stirring using 600-800 revs/min, disperseed 15-20 minutes using 800-1000 revs/min；
Performance test
Test method is：By A after B component mixes, stir evenly, be diluted using deionized-distilled water viscous to spraying
Spend (25-30S, T-4 glass), standard tinplate sheet progress phosphatization or grinding process, in tinplate sheet thickness control at 15-25 μm,
All-round property testing is done after 48 hours do solid work completely, container priming paint salt spray resistance dry plate thickness control is applied at 30-35 μm
Railway bearing priming paint salt spray resistance dry plate thickness control detects salt spray resistance at 80-100 μm after 7 days do solid work completely.
Drying time according to GB/T1728, adhesive force according to GB/T1720, impact according to GB/T1732, toughness according to
GB/T6742, hardness are according to GB/T6739, water resistance according to GB/T1733, solid content test according to GB/T1725, chemically-resistant
Performance according to GB/T9274, resistance to neutral salt spray according to GB/T1771, comprehensive performance and patent CN 102863874A,
CN101104771A is compared.
Table 2：Embodiment 1-5 and CN 102093805A performance comparison test results
By illustrating above, Experimental Comparison is analyzed, and the epoxy zinc rich primer made of graphene combination aqueous zinc phosphate is resistance to
Salt fog can reach more than 1500h, and after water aluminum-silver slurry is added, salt spray resistance is promoted to 1800h, when using carbon nanotube with
The effect of graphene combines, and forms fine and close protective film, and zinc powder combination aluminum paste reaches sacrificial anode jointly so that individual layer zinc-rich
For primer dry films thickness at 30-40 microns, salt spray resistance can reach 3500h, when individual layer zinc rich primer thickness of dry film is micro- in 80-100
Meter Shi, salt spray resistance can reach more than 6000h！It is very good to ground protective capacities！Greatly improve water-based epoxy zinc-rich primer pair
The protective capability of container.Simultaneously the product can be applied to railway bearing, highway bearing, railroad bridge, highway bridge, locomotive,
The fields such as engineering machinery, mining machinery, petroleum machinery, petroleum and petrochemical industry pipeline, chemical industry equipment, steel-structure factory building.
In order to promote the service life of water-based epoxy zinc-rich primer, the present invention provides a property of water-bearing carbon nanotube emphatically
The watersoluble plumbago alkene epoxy zinc-rich anticorrosive paint of material, the advantages of taking full advantage of graphene and carbon nanotube, will be entire rich
Zinc layers are combined into a fine and close reticular structure, make it by container integral coating, so as to play extraordinary protection energy
Power.
Graphene is a kind of carbon material of New Two Dimensional layer structure, have high length-diameter ratio and it is excellent it is hydrophobic, conductive, lead
Thermally and chemically stability makes it be with a wide range of applications in anticorrosive paint.Coat organic coating have construction is simple,
It is cheap, have a wide range of application with other safeguard procedures such as barrier propterty is good it is incomparable the advantages of, be that one kind slows down metal corruption
The means of erosion effectively, economic.
Carbon nanotube also known as Baji-tube, are a kind of One-dimensional Quantum materials with special construction, carbon atom in carbon nanotube
Based on sp hydridization, while there are a degree of bendings for hexangle type network, Space expanding are formed, wherein can be formed
Certain sp hybrid bonds, the chemical bond of formation has sp and sp mixed hybridization states simultaneously, and these p tracks overlap each other in carbon
The delocalized big ∏ keys of height are formed outside nanotube graphene sheet layer, the big ∏ keys of carbon nanotube outer surface are carbon nanotube and one
A little macromoleculars with conjugation performance are with the compound chemical fundamentals of non-covalent bond.The intensity that carbon nanotube assigns is added in the coating
Coating Durability and wearability are improved, promotes and is more closely combined between coating and base material, extend the service life of coating,
Tensile strength and elasticity are enhanced, in addition carbon nanotube has excellent heat conductivility so that coating can adapt to the heat of base material
It shrinks and expands.The high-effective conductive of carbon nanotube can increase substantially the anti-corrosive properties of coating
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (7)
1. a kind of carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field, including component A and component
B, it is characterised in that：The component A includes the following component according to mass fraction meter：It is aqueous epoxy curing agent 6-12%, aqueous
Aluminum paste 0.5-1%, functional graphene slurry 1-3%, aqueous zinc phosphate 2-4%, dispersant 0.3-0.8%, antifoaming agent 0.3-
0.6%th, aqueous organobentonite 0.3-0.5%, aerosil 0.5-0.8%, zinc powder 68-80%, carbon nanotube slurry 1-
3%th, cosolvent 6.2-7.3%；
Component B：Aqueous epoxy resin emulsion 100%；
Preparation method includes the following steps：
Step a. adds in aqueous epoxy curing agent, dispersant, antifoaming agent, cosolvent in production cylinder, stirring；
Step b. adds in aqueous zinc phosphate, aqueous organobentonite, aerosil while stirring, stirring；
Fineness is ground to 30 microns by step c. using sand mill；
Step d. is slowly added into functional graphene slurry, carbon nanotube slurry, stirring while stirring；
Step e. is added to after using cosolvent, water aluminum-silver slurry is fully soaked in production cylinder, stirring；
Step f. adds in zinc powder while stirring, dispersion；
Step g. dry plates are realized：According to component A：Component B=100：32-48 is matched, and is sprayed using deionized-distilled water
The adjustment of viscosity is applied, adjusts viscosity, sprays 2 layers, dry plate places detection traditional performance.
2. the carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer according to claim 1 applied to container field,
It is characterized in that：The step a the specific steps are by aqueous epoxy curing agent, dispersant, antifoaming agent, cosolvent add in production
In cylinder, stirred 5 minutes using 400-600 revs/min.
3. the carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer according to claim 1 applied to container field,
It is characterized in that：The step b the specific steps are while stirring add in aqueous zinc phosphate, aqueous organobentonite, gas phase two
Silica is stirred 5 minutes using 400-600 revs/min.
4. the carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer according to claim 1 applied to container field,
It is characterized in that：The step d the specific steps are be slowly added into functional graphene while stirring using 400-600 revs/min
Slurry, carbon nanotube slurry, are stirred 15-20 minutes using 600-800 revs/min.
5. the carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer according to claim 1 applied to container field,
It is characterized in that：The step e the specific steps are using cosolvent water aluminum-silver slurry is fully soaked after be added to production cylinder
In, it is stirred 5 minutes using 600-800 revs/min.
6. the carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer according to claim 1 applied to container field,
It is characterized in that：The step f the specific steps are zinc powder is added in while stirring using 600-800 revs/min, using 800-1000
Rev/min dispersion 15-20 minutes.
7. the carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer according to claim 1 applied to container field,
It is characterized in that：The step g dry plates realize the specific steps are：According to component A：Component B=100：32-48 is matched,
The adjustment of spray viscosity is carried out using deionized-distilled water, spray viscosity is adjusted to 25-30S using T-4 glasss, sprays 2 layers, is done
Plate is placed in 25 DEG C of insulating boxs from dry 48 hours detection traditional performances.
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| CN201711331053.1A CN108129948A (en) | 2017-12-13 | 2017-12-13 | Carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field |
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| CN201711331053.1A CN108129948A (en) | 2017-12-13 | 2017-12-13 | Carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181466A (en) * | 2018-07-03 | 2019-01-11 | 成都普瑞斯特新材料有限公司 | Waterborne anti-corrosive primer and preparation method thereof |
| CN109233565A (en) * | 2018-08-22 | 2019-01-18 | 潍坊鼎盛化学工业有限公司 | A kind of heavy antisepsis graphene modified epoxy zinc-rich paint and preparation method thereof |
| CN111793405A (en) * | 2020-07-31 | 2020-10-20 | 江苏华夏制漆科技有限公司 | Waterborne epoxy graphene zinc-containing anticorrosive primer |
| CN114621654A (en) * | 2022-03-29 | 2022-06-14 | 北京碧海云智新材料技术有限公司 | Water-based epoxy zinc-rich primer and preparation method and application thereof |
| CN116004080A (en) * | 2022-12-21 | 2023-04-25 | 广东仕诚塑料机械有限公司 | Main cooling roller heat-conducting coating, preparation method thereof and casting equipment |
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| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN105086760A (en) * | 2015-08-20 | 2015-11-25 | 成都拜迪新材料有限公司 | Preparation method of waterborne epoxy graphene antiseptic primer |
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