CN110467940A - 一种利用生物质生产液体燃料的方法 - Google Patents
一种利用生物质生产液体燃料的方法 Download PDFInfo
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- CN110467940A CN110467940A CN201910812308.9A CN201910812308A CN110467940A CN 110467940 A CN110467940 A CN 110467940A CN 201910812308 A CN201910812308 A CN 201910812308A CN 110467940 A CN110467940 A CN 110467940A
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- 239000007788 liquid Substances 0.000 title claims abstract description 94
- 238000000034 method Methods 0.000 title claims abstract description 85
- 239000002028 Biomass Substances 0.000 title claims abstract description 75
- 239000000446 fuel Substances 0.000 title claims abstract description 45
- 238000006243 chemical reaction Methods 0.000 claims abstract description 106
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 37
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 37
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims abstract description 37
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 37
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims abstract description 37
- 235000011613 Pinus brutia Nutrition 0.000 claims abstract description 37
- 241000018646 Pinus brutia Species 0.000 claims abstract description 37
- 241000425037 Toona sinensis Species 0.000 claims abstract description 37
- 240000001866 Vernicia fordii Species 0.000 claims abstract description 37
- 235000006886 Zingiber officinale Nutrition 0.000 claims abstract description 37
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000011425 bamboo Substances 0.000 claims abstract description 37
- 235000008397 ginger Nutrition 0.000 claims abstract description 37
- 239000002023 wood Substances 0.000 claims abstract description 37
- 241000196252 Ulva Species 0.000 claims abstract description 36
- 238000004523 catalytic cracking Methods 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 244000241257 Cucumis melo Species 0.000 claims abstract 4
- 244000082204 Phyllostachys viridis Species 0.000 claims abstract 4
- 244000273928 Zingiber officinale Species 0.000 claims abstract 4
- 238000007233 catalytic pyrolysis Methods 0.000 claims description 104
- 239000000047 product Substances 0.000 claims description 99
- 239000000203 mixture Substances 0.000 claims description 81
- 239000007789 gas Substances 0.000 claims description 69
- 238000000197 pyrolysis Methods 0.000 claims description 42
- 239000000654 additive Substances 0.000 claims description 28
- 230000000996 additive effect Effects 0.000 claims description 28
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 26
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims description 23
- 238000012805 post-processing Methods 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 22
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- 238000005406 washing Methods 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 16
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 13
- 238000006555 catalytic reaction Methods 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 12
- -1 Isooctyl Chemical group 0.000 claims description 11
- 238000009833 condensation Methods 0.000 claims description 11
- 230000005494 condensation Effects 0.000 claims description 11
- 238000000926 separation method Methods 0.000 claims description 11
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical group [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000002525 ultrasonication Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229910002651 NO3 Inorganic materials 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 7
- 230000000903 blocking effect Effects 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 238000002485 combustion reaction Methods 0.000 abstract description 11
- 239000004519 grease Substances 0.000 abstract description 4
- 229920005610 lignin Polymers 0.000 abstract description 3
- 150000001720 carbohydrates Chemical class 0.000 abstract description 2
- 239000001913 cellulose Substances 0.000 abstract description 2
- 229920002678 cellulose Polymers 0.000 abstract description 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 2
- 239000000194 fatty acid Substances 0.000 abstract description 2
- 229930195729 fatty acid Natural products 0.000 abstract description 2
- 150000004665 fatty acids Chemical class 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000012530 fluid Substances 0.000 abstract description 2
- 102000004169 proteins and genes Human genes 0.000 abstract description 2
- 108090000623 proteins and genes Proteins 0.000 abstract description 2
- 239000000341 volatile oil Substances 0.000 abstract description 2
- 241001330002 Bambuseae Species 0.000 description 33
- 241000219112 Cucumis Species 0.000 description 33
- 241000234314 Zingiber Species 0.000 description 33
- 230000000052 comparative effect Effects 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 230000003760 hair shine Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 210000000952 spleen Anatomy 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000006114 decarboxylation reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910015421 Mo2N Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000032696 parturition Effects 0.000 description 1
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- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1018—Biomass of animal origin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
生物质转化率(%) | 含氧值(%) | 热值(MJ/kg) | 灰分(%) | |
实施例1 | 88 | 6.8 | 40.9 | ≤2.8 |
实施例2 | 88 | 6.9 | 40.8 | ≤2.8 |
实施例3 | 89 | 6.6 | 40.9 | ≤2.7 |
实施例4 | 88 | 6.6 | 40.9 | ≤2.8 |
实施例5 | 90 | 6.5 | 41 | ≤2.6 |
对比例1 | 80 | 9.8 | 22.7 | 22.6 |
对比例2 | 81 | 9.3 | 26.4 | 26.5 |
对比例3 | 70 | 8.3 | 33.1 | 11.1 |
对比例4 | 70 | 8.2 | 31.2 | 12.7 |
Claims (10)
Priority Applications (2)
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CN201910812308.9A CN110467940B (zh) | 2019-08-30 | 2019-08-30 | 一种利用生物质生产液体燃料的方法 |
CN202110760802.2A CN113293022A (zh) | 2019-08-30 | 2019-08-30 | 一种液体燃料的生产方法 |
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CN201910812308.9A CN110467940B (zh) | 2019-08-30 | 2019-08-30 | 一种利用生物质生产液体燃料的方法 |
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CN202110760802.2A Division CN113293022A (zh) | 2019-08-30 | 2019-08-30 | 一种液体燃料的生产方法 |
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CN110467940A true CN110467940A (zh) | 2019-11-19 |
CN110467940B CN110467940B (zh) | 2021-07-13 |
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CN202110760802.2A Withdrawn CN113293022A (zh) | 2019-08-30 | 2019-08-30 | 一种液体燃料的生产方法 |
CN201910812308.9A Active CN110467940B (zh) | 2019-08-30 | 2019-08-30 | 一种利用生物质生产液体燃料的方法 |
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CN202110760802.2A Withdrawn CN113293022A (zh) | 2019-08-30 | 2019-08-30 | 一种液体燃料的生产方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111086981A (zh) * | 2019-12-31 | 2020-05-01 | 三峡大学 | 一种生物质碳纳米片锂离子电池负极材料及制备方法 |
CN111689813A (zh) * | 2020-06-22 | 2020-09-22 | 襄阳职业技术学院 | 一种环保型生物炭基有机无机复混肥及其制备方法 |
CN111849527A (zh) * | 2020-07-29 | 2020-10-30 | 许洁 | 一种基于生物质的液体燃料及其生产工艺 |
CN113150844A (zh) * | 2021-05-07 | 2021-07-23 | 孙水平 | 一种绿色节能环保的液体燃料及其制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114606019A (zh) * | 2022-03-31 | 2022-06-10 | 周金 | 一种裂解催化生产生物质液体燃料的方法 |
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CN102936511A (zh) * | 2012-11-05 | 2013-02-20 | 北京华电光大新能源环保技术有限公司 | 一种在线催化裂解生物质快速热解产物制备高品位生物油的方法 |
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CN107446631A (zh) * | 2017-09-17 | 2017-12-08 | 长沙仲善新能源科技有限公司 | 一种环保型生物液体燃料及其制备方法 |
CN108048122A (zh) * | 2017-12-11 | 2018-05-18 | 华中科技大学 | 一种控制藻制备液体油过程中氮排放的方法 |
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2019
- 2019-08-30 CN CN202110760802.2A patent/CN113293022A/zh not_active Withdrawn
- 2019-08-30 CN CN201910812308.9A patent/CN110467940B/zh active Active
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WO2014064008A1 (en) * | 2012-10-25 | 2014-05-01 | Shell Internationale Research Maatschappij B.V. | Process for catalytic cracking of a biomass |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111086981A (zh) * | 2019-12-31 | 2020-05-01 | 三峡大学 | 一种生物质碳纳米片锂离子电池负极材料及制备方法 |
CN111086981B (zh) * | 2019-12-31 | 2022-06-21 | 三峡大学 | 一种生物质碳纳米片锂离子电池负极材料及制备方法 |
CN111689813A (zh) * | 2020-06-22 | 2020-09-22 | 襄阳职业技术学院 | 一种环保型生物炭基有机无机复混肥及其制备方法 |
CN111849527A (zh) * | 2020-07-29 | 2020-10-30 | 许洁 | 一种基于生物质的液体燃料及其生产工艺 |
CN113150844A (zh) * | 2021-05-07 | 2021-07-23 | 孙水平 | 一种绿色节能环保的液体燃料及其制备方法 |
Also Published As
Publication number | Publication date |
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CN113293022A (zh) | 2021-08-24 |
CN110467940B (zh) | 2021-07-13 |
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