CN110466331A - A kind of hydrophobic type weather strip for automobile velvet belt and preparation method thereof - Google Patents

A kind of hydrophobic type weather strip for automobile velvet belt and preparation method thereof Download PDF

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Publication number
CN110466331A
CN110466331A CN201810451203.0A CN201810451203A CN110466331A CN 110466331 A CN110466331 A CN 110466331A CN 201810451203 A CN201810451203 A CN 201810451203A CN 110466331 A CN110466331 A CN 110466331A
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China
Prior art keywords
flock
coating
automobile
villus
velvet belt
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CN201810451203.0A
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CN110466331B (en
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陈正林
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/15Sealing arrangements characterised by the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/30Sealing arrangements characterised by the fastening means
    • B60J10/34Sealing arrangements characterised by the fastening means using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/70Sealing arrangements specially adapted for windows or windscreens
    • B60J10/74Sealing arrangements specially adapted for windows or windscreens for sliding window panes, e.g. sash guides
    • B60J10/76Sealing arrangements specially adapted for windows or windscreens for sliding window panes, e.g. sash guides for window sashes; for glass run channels

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Seal Device For Vehicle (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of hydrophobic type weather strip for automobile velvet belts and preparation method thereof, velvet belt includes flocking film, flock glue, villus and flock coating, the flock glue roller coating is sprayed on formation Flock Adhesive water layer on the flocking film, the villus is implanted on Flock Adhesive water layer using electrostatic room high-pressure electrostatic, the flock coating roller coating is sprayed on the villus and forms flock coating, and the flock coating includes fluorinated silicone modified waterborne polyurethane resin, polyurethane-modified acrylic acid lotion, organic-molybdenum, organosilicon, curing agent and solvent.Preparation method then includes upper film, gluing, electrostatic spinning, flocking solidification, spraying or roll-coated coatings and curing of coatings accordingly.Velvet belt of the present invention is installed on the guide groove of vehicle glass, is able to solve the abnormal sound problem occurred under automobile window glass jacking condition, and flock coating has submissive feel and sliding sense.

Description

A kind of hydrophobic type weather strip for automobile velvet belt and preparation method thereof
Technical field
A kind of velvet belt that the present invention relates to a kind of on automotive sealant, and in particular to automobile sealed hedge planting of hydrophobic type Suede band and preparation method thereof.
Background technique
It is how former to the machinery of appearance in automobile use process with automobile gradually popularizing in Chinese society and family Barrier carry out diagnosis find out reason and give it is appropriate processing it is very important, the appearance of various mechanical breakdowns can be to garage It sails safety and service efficiency generates significant impact, serious prestige can be constituted to driver and other people person and property safety when serious The side of body, therefore no matter for maintenance personal or driver, the reason of occurring to automobile mechanical failure carry out Correct Analysis with It is very important for diagnosis, helps to promote safety and efficiency that automobile uses, better meets the needs of production and living.
The sound is a kind of relatively common automobile mechanical failure extremely, and motorist can be heard when there is this failure Engine issues dull or sharp sound or other component and issues pause and transition in rhythm or melody sound because of improper friction, this abnormal sound Sound is alternately present sometimes with certain frequency or interval time, or is intermittently occurred without any rule.
About 70% automobile mechanical failure can all show certain abnormal sound according to statistics, therefore the method by listening attentively to is to vapour Vehicle mechanical breakdown diagnose it is very useful, with automobile using the time extension and component of machine abrasion quickening, in vapour When vehicle braking operation due to components agree between gap increase so that work when often there is abnormal sound, by listening attentively to automobile Abnormal sound can be determined that whether automobile rotation balances, feature when by the way that abnormal sound occurring such as whether it is continuous, with the presence or absence of rule Whether rule intermittent occurs etc., so that it may the position that primitive decision failure occurs.
Generally, such as the guide groove of vehicle glass, automobile door frame, car trunk or each position of vehicle dormer window are all that can send out In place of raw abnormal sound.In order to solve abnormal sound, general solution is filled out using the sealing strip or sponge strip of plastics or rubber It fills in gap and reduces the abnormal sound of automobile.But it reduces not equal to elimination.It is this dynamic during running car Abnormal sound still can occur, and only can not better solve problem with sealing strip or sponge strip.
At present consciously using flocked pile layer as the wear-resistant coating of sealing strip, but this flocked pile layer be located at this The contact still defective tightness of automobile window glass on flocked pile layer, especially in car running process, automobile window glass Vibration of the glass under jacking condition still makes automobile that abnormal sound occur.
Summary of the invention
The reason is that flocked pile layer itself does not have good adhesive force and wearability, make its with automobile window During glass contact, vibration of the automobile window glass under jacking condition can not be resisted, automobile window glass is caused to rise Frictional Slipping is generated with flocked pile layer during shock dropping is dynamic, abnormal sound generates therewith.
Electrostatic spinning is to make negative electrical charge on villus band, needs using charge identical charges repel each other the physical characteristic that there is a natural attraction between the sexes The object of flocking is placed under zero potential or grounding requirement, and villus is attracted by different current potential by flocking object, and perpendicular shape accelerates It ascends to heaven on by flocking body surface, due to being coated with adhesive by flocking object, villus is just vertically sticked to by plant, because This electrostatic spinning is the technique generated using the natural characteristic of charge.
The purpose of the present invention is to provide a kind of hydrophobic type weather strip for automobile velvet belts, are able to solve automobile window glass The abnormal sound problem occurred under jacking condition.
Used technical solution are as follows:
A kind of hydrophobic type weather strip for automobile velvet belt comprising flocking film, flock glue, villus and flock coating, it is described Flock glue roller coating is sprayed on formation Flock Adhesive water layer on the flocking film, is planted the villus using electrostatic room high-pressure electrostatic Enter on Flock Adhesive water layer, the flock coating roller coating or is sprayed on the villus and forms flock coating, the flock coating Including fluorinated silicone modified waterborne polyurethane resin, polyurethane-modified acrylic acid lotion, organic-molybdenum, organosilicon, curing agent and solvent.
In the technical solution of the present invention, the villus is implanted on Flock Adhesive water layer using electrostatic room high-pressure electrostatic and is A kind of electrostatic flocking technology, electrostatic spinning can be such that villus setting is inserted on glue, and the villus for erectting insertion can be comprehensively Roller coating or spraying flock coating form flock coating.
In flock coating, fluorinated silicone modified waterborne polyurethane resin has bonding force, also can be improved wear-resisting property, provides The hydrophobicity of villus;The effect of polyurethane-modified acrylic acid lotion is to increase bonding force, promotion fastness;Organic-molybdenum acts on Feel in providing the submissive feel of product and sliding;The effect of organosilicon is to adjust product coefficient of friction, raising wear-resisting property, solvent To dissolution and diluted effect;Curing agent plays the role of crosslinking curing.
To which this flock coating has preferable bonding force, is on the one hand securely attached to coating on villus, separately On the one hand it can also be securely attached on glass;Again due to wear-resisting property with higher, so as in vehicle glass liter During drop, the flock coating being attached on glass can bear the intermolecular of the inside between glass and fluosilicic resin and rub It wipes, solves the problems, such as the abnormal sound occurred under automobile window glass jacking condition.
Fluorinated silicone modified waterborne polyurethane resin is comprising organosilicon or Organic fluoride is monomer modified or the polyurethane of blending and modifying Resin.
Polyurethane-modified acrylic acid lotion, commercially available acquisition, such as hydroxyl polyurethane modified acrylic acid emulsion D52.
Organic-molybdenum is comprising organic-molybdenum monomer and organic-molybdenum polymer;Organosilicon is poly- comprising organic silicon monomer and organosilicon Close object.
Curing agent preferred isocyanate.
Solvent is including but not limited to for alcohol ethers solvent or water.
Further, the flock coating further includes defoaming agent.The preferred polyphosphazene polymer siloxane polymer defoaming of defoaming agent Agent, commercially available acquisition.Such as Digao TEGO825 defoaming agent.The effect of defoaming agent is to eliminate the foam in dispersion process.
Preferably to play flock coating effect, which includes the component of following weight ratio:
Flock coating can be prepared by mixing the above components evenly, flock coating roller coating or be sprayed on villus formed plant Suede coating.
Flocking film is the base fabric of electrostatic spinning as cloth base material is applied.In the material selection of flocking film, the flocking film can Preferably one of TPV, PVC, TPE flocking film or a variety of mixing.
The flock glue is applying cloth base material for being bonded villus, is preferably PU water-based flock glue.The water base plant of PU Suede glue belongs to aqueous adhesive, such as may include modified aqueous polyurethane emulsion, acrylic emulsion, aqueous epoxy resins, Have the function of that environment-protecting and non-poisonous, water resistance is good, bonding is secured, water-fastness etc..PU water-based flock glue can from the market directly It obtains.
The villus is preferably PET or PA villus.PET villus, that is, terylene villus;PA villus, that is, nylon villus.PET or PA villus has preferable wearability.
Another object of the present invention is to provide the preparation methods of the hydrophobic type weather strip for automobile velvet belt of above scheme.
A kind of preparation method of hydrophobic type weather strip for automobile velvet belt, includes the following steps:
(1) mode of flock glue roller coating or spraying is coated on flocking film;
(2) villus is implanted into Flock Adhesive water layer using electrostatic room high-pressure electrostatic, carries out baking-curing into drying tunnel;Drying tunnel out Semi-finished product velvet belt is obtained by winding afterwards;
(3) then semi-finished product velvet belt is put into the flock coating for unreeling that platform sprays or roller coating is deployed again, enters Drying tunnel carries out baking-curing.
It further, further include that step (4) goes out after drying tunnel by winding, cutting, fine cut, winds packaging again.
The beneficial effects of the present invention are:
Velvet belt of the present invention is installed on the guide groove of vehicle glass, during automobilism, loudness is surveyed Examination, test result is < 3SONE (Song), solves the problems, such as the abnormal sound occurred under automobile window glass jacking condition, Er Qiezhi Suede coating has submissive feel and sliding sense.
Velvet belt of the present invention is suitable for Rubber Seal Strip for Automobile surface flocking field, includes but to be not limited only to vehicle glass close Strip of paper used for sealing, sponge strip surface flocking.
Specific embodiment
Further describe technical solution of the present invention below with reference to preferred embodiment, but the present invention claims protection model It encloses and is not limited thereto.
Embodiment 1
A kind of hydrophobic type weather strip for automobile velvet belt comprising TPV flocking film, PU water-based flock glue, PET villus and plant Suede coating, PU water-based flock glue roller coating or is sprayed on TPV flocking film formation Flock Adhesive water layer, utilizes electrostatic room high-pressure electrostatic PET villus villus is implanted on Flock Adhesive water layer, flock coating roller coating or is sprayed on PET villus and forms flock coating, is planted Suede coating includes the component of following weight ratio:
The hydrophobic type weather strip for automobile velvet belt the preparation method is as follows:
(1) mode of PU water-based flock glue roller coating or spraying is coated on TPV flocking film;
(2) PET villus is implanted into Flock Adhesive water layer using electrostatic room high-pressure electrostatic, carries out baking-curing into drying tunnel;Out Semi-finished product velvet belt is obtained by winding after drying tunnel;
(3) then velvet belt is put into the flock coating for unreeling that platform sprays or roller coating is deployed by technique again, enters Drying tunnel carries out baking-curing;
(4) go out after drying tunnel by winding, cutting, fine cut, again wind the technique of packaging, obtain velvet belt.
Embodiment 2
A kind of hydrophobic type weather strip for automobile velvet belt comprising TPV/PVC flocking film, PU water-based flock glue, PET villus And flock coating, PU water-based flock glue roller coating or it is sprayed on TPV/PVC flocking film formation Flock Adhesive water layer, utilizes electrostatic room PET villus villus is implanted on Flock Adhesive water layer by high-pressure electrostatic, flock coating roller coating or is sprayed on PET villus and is formed flocking Coating, flock coating include the component of following weight ratio:
The hydrophobic type weather strip for automobile velvet belt the preparation method is as follows:
(1) mode of PU water-based flock glue roller coating or spraying is coated on TPV/PVC flocking film;
(2) PET villus is implanted into Flock Adhesive water layer using electrostatic room high-pressure electrostatic, carries out baking-curing into drying tunnel;Out Semi-finished product velvet belt is obtained by winding after drying tunnel;
(3) then velvet belt is put into the flock coating for unreeling that platform sprays or roller coating is deployed by technique again, enters Drying tunnel carries out baking-curing;
(4) go out after drying tunnel by winding, cutting, fine cut, again wind the technique of packaging, obtain velvet belt.
Embodiment 3
A kind of hydrophobic type weather strip for automobile velvet belt comprising TPV/PVC/TPE flocking film, PU water-based flock glue, PA Villus and flock coating, PU water-based flock glue roller coating or are sprayed on TPV/PVC/TPE flocking film formation Flock Adhesive water layer, benefit PA villus villus is implanted on Flock Adhesive water layer with electrostatic room high-pressure electrostatic, flock coating roller coating or is sprayed on shape on PA villus At flock coating, flock coating includes the component of following weight ratio:
The hydrophobic type weather strip for automobile velvet belt the preparation method is as follows:
(1) mode of PU water-based flock glue roller coating or spraying is coated on TPV/PVC/TPE flocking film;
(2) PA villus is implanted into Flock Adhesive water layer using electrostatic room high-pressure electrostatic, carries out baking-curing into drying tunnel;It dries out Semi-finished product velvet belt is obtained by winding behind road;
(3) then velvet belt is put into the flock coating for unreeling that platform sprays or roller coating is deployed by technique again, enters Drying tunnel carries out baking-curing;
(4) go out after drying tunnel by winding, cutting, fine cut, again wind the technique of packaging, obtain velvet belt.
Hydrophobic type weather strip for automobile velvet belt made from above embodiments 1-3 is installed on the guide groove of vehicle glass, it is right Automobile under motion state, tested by the loudness occurred under automobile window glass jacking condition, and test result is < 3SONE (Song), and flock coating has submissive feel and sliding sense.
To hydrophobic type weather strip for automobile velvet belt of the present invention, it is able to solve and occurs under automobile window glass jacking condition Abnormal sound problem, and flock coating has submissive feel and sliding sense.

Claims (10)

1. a kind of hydrophobic type weather strip for automobile velvet belt, which is characterized in that it includes flocking film, flock glue, villus and flocking Coating, the flock glue roller coating or is sprayed on the flocking film formation Flock Adhesive water layer, utilizes electrostatic room high-pressure electrostatic will The villus is implanted on Flock Adhesive water layer, the flock coating roller coating or is sprayed on the villus and is formed flock coating, institute Stating flock coating includes fluorinated silicone modified waterborne polyurethane resin, polyurethane-modified acrylic acid lotion, organic-molybdenum, organosilicon, solidification Agent and solvent.
2. hydrophobic type weather strip for automobile velvet belt according to claim 1, which is characterized in that the flock coating further includes Defoaming agent.
3. hydrophobic type weather strip for automobile velvet belt according to claim 2, which is characterized in that the flock coating includes such as The component of lower weight ratio:
4. hydrophobic type weather strip for automobile velvet belt according to claim 3, which is characterized in that the curing agent is isocyanic acid Ester;The solvent is alcohol ethers solvent or water.
5. hydrophobic type weather strip for automobile velvet belt according to claim 3, which is characterized in that the defoaming agent is macromolecule Polysiloxane polymer defoaming agent.
6. hydrophobic type weather strip for automobile velvet belt according to claim 1, which is characterized in that the flocking film be TPV, One of PVC, TPE flocking film or a variety of mixing.
7. hydrophobic type weather strip for automobile velvet belt according to claim 1, which is characterized in that the flock glue is PU water Base flock glue.
8. hydrophobic type weather strip for automobile velvet belt according to claim 1, which is characterized in that the villus is PET or PA Villus.
9. a kind of preparation method of hydrophobic type weather strip for automobile velvet belt described in claim 1, which is characterized in that including as follows Step:
(1) mode of flock glue roller coating or spraying is coated on flocking film;
(2) villus is implanted into Flock Adhesive water layer using electrostatic room high-pressure electrostatic, carries out baking-curing into drying tunnel;It is passed through after drying tunnel out It crosses winding and obtains semi-finished product velvet belt;
(3) then semi-finished product velvet belt is put again into the flock coating for unreeling that platform sprays or roller coating is deployed, into drying tunnel Carry out baking-curing.
10. the preparation method of hydrophobic type weather strip for automobile velvet belt according to claim 9, which is characterized in that further include Step (4) goes out after drying tunnel by winding, cutting, fine cut, winds packaging again.
CN201810451203.0A 2018-05-11 2018-05-11 Hydrophobic automobile sealing strip flocking belt and preparation method thereof Active CN110466331B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112958407A (en) * 2021-02-01 2021-06-15 海信(山东)空调有限公司 Flocking method, guide plate obtained by flocking method and air conditioner
CN114308576A (en) * 2022-01-20 2022-04-12 浙江希尔达汽车零部件有限公司 Production method for cross flocking of automobile B upper column camera area

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CN1951968A (en) * 2006-10-09 2007-04-25 中国科学技术大学 Fluorin-silicon modified core-shell structure polyurethane-acrylate emulsion preparation method
EP2121303B1 (en) * 2007-01-19 2010-07-14 Dimontonate Floccati S.p.A. Multi-layered film and flocked material comprising such a film
CN102585681A (en) * 2012-02-08 2012-07-18 上海三恩化工有限公司 Coating for automobile sealing strip and preparation method thereof
CN106700918A (en) * 2017-01-09 2017-05-24 上海三恩化工有限公司 Coating for flocking tape roller coating and preparation method of coating
CN107652867A (en) * 2017-09-30 2018-02-02 上海三恩化工有限公司 Application type flocking belt of sealing strip for automobile preparation method
CN107695902A (en) * 2017-10-18 2018-02-16 河北思瑞恩新材料科技有限公司 One flocked material and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1951968A (en) * 2006-10-09 2007-04-25 中国科学技术大学 Fluorin-silicon modified core-shell structure polyurethane-acrylate emulsion preparation method
EP2121303B1 (en) * 2007-01-19 2010-07-14 Dimontonate Floccati S.p.A. Multi-layered film and flocked material comprising such a film
CN102585681A (en) * 2012-02-08 2012-07-18 上海三恩化工有限公司 Coating for automobile sealing strip and preparation method thereof
CN106700918A (en) * 2017-01-09 2017-05-24 上海三恩化工有限公司 Coating for flocking tape roller coating and preparation method of coating
CN107652867A (en) * 2017-09-30 2018-02-02 上海三恩化工有限公司 Application type flocking belt of sealing strip for automobile preparation method
CN107695902A (en) * 2017-10-18 2018-02-16 河北思瑞恩新材料科技有限公司 One flocked material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112958407A (en) * 2021-02-01 2021-06-15 海信(山东)空调有限公司 Flocking method, guide plate obtained by flocking method and air conditioner
CN112958407B (en) * 2021-02-01 2023-02-24 海信空调有限公司 Flocking method, guide plate obtained by flocking method and air conditioner
CN114308576A (en) * 2022-01-20 2022-04-12 浙江希尔达汽车零部件有限公司 Production method for cross flocking of automobile B upper column camera area
CN114308576B (en) * 2022-01-20 2022-08-12 浙江希尔达汽车零部件有限公司 Production method for cross flocking of automobile B upper column camera area

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