CN110466331B - Hydrophobic automobile sealing strip flocking belt and preparation method thereof - Google Patents

Hydrophobic automobile sealing strip flocking belt and preparation method thereof Download PDF

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CN110466331B
CN110466331B CN201810451203.0A CN201810451203A CN110466331B CN 110466331 B CN110466331 B CN 110466331B CN 201810451203 A CN201810451203 A CN 201810451203A CN 110466331 B CN110466331 B CN 110466331B
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flocking
coating
hydrophobic
strip
automobile
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CN110466331A (en
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陈正林
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/15Sealing arrangements characterised by the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/30Sealing arrangements characterised by the fastening means
    • B60J10/34Sealing arrangements characterised by the fastening means using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J10/00Sealing arrangements
    • B60J10/70Sealing arrangements specially adapted for windows or windscreens
    • B60J10/74Sealing arrangements specially adapted for windows or windscreens for sliding window panes, e.g. sash guides
    • B60J10/76Sealing arrangements specially adapted for windows or windscreens for sliding window panes, e.g. sash guides for window sashes; for glass run channels

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Seal Device For Vehicle (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a hydrophobic automobile sealing strip flocking belt and a preparation method thereof. The preparation method correspondingly comprises the steps of coating, gluing, electrostatic flocking, flocking curing, spraying or roller coating, coating curing and the like. The flocking belt is arranged on the guide groove of the automobile glass, the abnormal sound problem generated in the lifting state of the automobile window glass can be solved, and the flocking coating has smooth hand feeling and slippery feeling.

Description

Hydrophobic automobile sealing strip flocking belt and preparation method thereof
Technical Field
The invention relates to a flocking belt for an automobile sealing element, in particular to a hydrophobic automobile sealing strip flocking belt and a preparation method thereof.
Background
With the gradual popularization of automobiles in China society and families, it is very important how to diagnose and find out reasons for mechanical faults and give appropriate treatment to the mechanical faults in the use process of the automobiles, the occurrence of various mechanical faults can have great influence on the running safety and the use efficiency of the automobiles, and in severe cases, the safety of drivers and other people and property can be seriously threatened, so that the correct analysis and diagnosis of the reasons for the mechanical faults of the automobiles are very important for maintenance personnel and drivers, the safety and the efficiency of the use of the automobiles are improved, and the requirements of production and life are better met.
An abnormal sound is a relatively common mechanical fault of an automobile, in which a driver of the automobile can hear a muffled or sharp sound from an engine or a muffled sound from other parts due to abnormal friction, and the abnormal sound may occur alternately at a certain frequency or interval or may not occur intermittently at any regular time.
According to statistics, about 70% of automobile mechanical faults show certain abnormal sound, so that the automobile mechanical faults are diagnosed very practically by an audible method, along with the prolonging of the automobile service time and the acceleration of the abrasion of mechanical parts, when the automobile is braked and works, the abnormal sound is often generated during the work due to the fact that the gaps between the parts are increased, whether the automobile rotates in balance can be judged by hearing the abnormal sound of the automobile, and the fault position can be basically judged by judging the characteristics of the abnormal sound when the abnormal sound occurs, such as whether the abnormal sound is continuous, whether the abnormal sound is regular, whether the abnormal sound occurs intermittently and the like.
Generally, abnormal noise occurs in various parts such as a channel of a glass of an automobile, a door frame of an automobile, a trunk of an automobile, or a sunroof of an automobile. In order to solve the abnormal sound, a common solution is to fill the gap with a plastic or rubber sealing strip or sponge strip to reduce the abnormal sound of the automobile. However, the reduction is not equal to the elimination. In the process of automobile driving, the dynamic abnormal sound still occurs, and the problem cannot be better solved only by the sealing strip or the sponge strip.
At present, the flocking layer is considered as the wear-resistant coating of the sealing strip, but the contact between the flocking layer and the automobile window glass positioned on the flocking layer is still not tight enough, and particularly, the vibration of the automobile window glass in a lifting state still makes the automobile generate abnormal sound during the running process of the automobile.
Disclosure of Invention
The reason for this is that the flocked nap layer has no good adhesive force and wear resistance, so that the flocked nap layer cannot resist the vibration of the automobile window glass in the lifting state during the contact process with the automobile window glass, so that the automobile window glass generates frictional sliding with the flocked nap layer during the lifting vibration process, and abnormal sound is generated accordingly.
Electrostatic flocking is a process which utilizes the physical characteristics that like charges repel each other and opposite charges attract each other to make the fluff take negative charges, and the object to be flocked is placed under the condition of zero potential or grounding, and the fluff is attracted by the flocked object with different potential and vertically accelerated to fly to the surface of the flocked object.
The invention aims to provide a hydrophobic automobile sealing strip flocking belt which can solve the problem of abnormal sound generated in the lifting state of automobile window glass.
The adopted technical scheme is as follows:
the utility model provides a hydrophobic type automobile seal strip flocking area, its includes flocking membrane, flocking glue, fine hair and flocking coating, flocking glue roller coat or spraying are in form flocking glue layer on the flocking membrane, utilize static room high-voltage static will fine hair is implanted on flocking glue layer, flocking coating roller coat or spraying are in form the flocking coating on the fine hair, the flocking coating includes fluorine silicon modified waterborne polyurethane resin, polyurethane modified acrylic acid emulsion, organic molybdenum, organosilicon, curing agent and solvent.
According to the technical scheme, the flocking process is characterized in that the flocks are implanted into a flocking glue layer by utilizing high-voltage static electricity of a static chamber, namely the electrostatic flocking process can enable the flocks to be vertically inserted into glue, and the vertically inserted flocks can be completely coated with roller coating or spraying flocking coating to form a flocking coating.
In the flocking coating, the fluorine-silicon modified waterborne polyurethane resin has adhesive force, can also improve the wear resistance and provide the hydrophobicity of fluff; the polyurethane modified acrylic emulsion has the effects of increasing the bonding force and improving the fastness; the organic molybdenum has the function of providing the product with soft hand feeling and smooth feeling; the organic silicon has the functions of adjusting the friction coefficient of the product, improving the wear resistance, and the solvent has the functions of dissolving and diluting; the curing agent plays a role in crosslinking and curing.
Therefore, the flocking coating has better adhesive force, so that the coating can be firmly attached to the fluff on one hand, and can be firmly attached to the glass on the other hand; and because the automobile window glass has higher wear resistance, the flocking coating attached to the glass can bear the friction between the inner molecules between the glass and the silicon fluorine resin in the lifting process of the automobile window glass, and the abnormal sound problem generated in the lifting state of the automobile window glass is solved.
The fluorine-silicon modified water-based polyurethane resin is polyurethane resin modified or blended and modified by organic silicon or organic fluorine monomer.
The urethane-modified acrylic emulsion may be commercially available, for example, hydroxyl urethane-modified acrylic emulsion D52.
The organic molybdenum comprises organic molybdenum monomer and organic molybdenum polymer; the silicone comprises a silicone monomer and a silicone polymer.
The curing agent is preferably an isocyanate.
The solvent is an alcohol ether solvent or water.
Further, the flocked coating also includes an anti-foaming agent. The defoaming agent is preferably a high molecular weight polysiloxane polymer defoaming agent, and can be obtained commercially. Such as digao TEGO825 defoamer. The role of the defoamer is to eliminate foam during dispersion.
In order to better play the role of the flocked coating, the flocked coating comprises the following components in percentage by weight:
Figure BDA0001658508860000031
the flocking coating can be prepared by uniformly mixing the components, and is formed on the fluff by roller coating or spraying.
The flocking film is used as a coating substrate and is a base fabric of electrostatic flocking. In the material selection of the flocking film, the flocking film can be preferably one or more of TPV, PVC and TPE flocking film.
The flocking glue is used for adhering the fluff on the coated substrate, and can be preferably PU water-based flocking glue. The PU water-based flocking glue belongs to a water-based adhesive, and can comprise modified water-based polyurethane emulsion, acrylic emulsion and water-based epoxy resin, and has the functions of environmental protection, no toxicity, good water resistance, firm adhesion, water washing resistance and the like. PU water-based flocking glues are available directly from the market.
The fluff may preferably be PET or PA fluff. PET fluff, namely polyester fluff; the PA fluff is nylon fluff. PET or PA fluff has better wear resistance.
The invention also aims to provide a preparation method of the hydrophobic automobile sealing strip flocking belt.
A preparation method of a hydrophobic automobile sealing strip flocking belt comprises the following steps:
(1) coating flocking glue on the flocking film in a roller coating or spraying manner;
(2) implanting the fluff into a flocking glue layer by using high-voltage static electricity of a static chamber, and entering a drying tunnel for baking and curing; after the semi-finished product is taken out of the drying channel, the semi-finished product flocking tape is obtained through rolling;
(3) and then the semi-finished product flocked belt is put into an unreeling table to spray or roll the prepared flocked coating, and enters a drying tunnel to be baked and cured.
And further, the method also comprises the step (4) of rolling, slitting, fine cutting, rolling and packaging after the materials are taken out of the drying tunnel.
The invention has the beneficial effects that:
the flocking belt is arranged on the guide groove of the automobile glass, the loudness is tested in the running process of an automobile, the test results are all less than 3SONE (Song), the abnormal sound problem generated in the lifting state of the automobile window glass is solved, and the flocking coating has soft hand feeling and smooth feeling.
The flocking belt is suitable for the field of surface flocking of automobile rubber sealing strips, and comprises but is not limited to surface flocking of automobile glass sealing strips and sponge strips.
Detailed Description
The technical solution of the present invention is further described below with reference to preferred embodiments, but the scope of the claimed invention is not limited thereto.
Example 1
The utility model provides a hydrophobic type automobile seal strip flocking area, it includes TPV flocking membrane, the water base flocking glue of PU, PET fine hair and flocking coating, the water base flocking glue of PU roller coat or spraying forms the flocking glue layer on TPV flocking membrane, utilize static room high-tension static with PET fine hair implantation on the flocking glue layer, flocking coating roller coat or spraying form the flocking coating on PET fine hair, the flocking coating includes the component of following weight ratio:
Figure BDA0001658508860000051
the preparation method of the hydrophobic automobile sealing strip flocking strip comprises the following steps:
(1) coating the PU water-based flocking glue on the TPV flocking film in a roller coating or spraying manner;
(2) implanting PET fluff into a flocking glue layer by using high-voltage static electricity of a static chamber, and entering a drying tunnel for baking and curing; after the semi-finished product is taken out of the drying channel, the semi-finished product flocking tape is obtained through rolling;
(3) then the flocked belt is put into an unreeling table to be sprayed or roll-coated with the flocked coating which is prepared according to the process, and then the flocked belt enters a drying tunnel to be baked and cured;
(4) and (4) after the flocked belt is taken out of the drying channel, the flocked belt is obtained through the processes of rolling, slitting, fine cutting, rolling and packaging.
Example 2
The utility model provides a hydrophobic type automobile seal strip flocking belt, it includes TPV/PVC flocking membrane, the water-based flocking glue of PU, PET fine hair and flocking coating, the water-based flocking glue roller coat of PU or the spraying forms the flocking glue layer on TPV/PVC flocking membrane, utilize static room high-tension static with PET fine hair implantation on the flocking glue layer, flocking coating roller coat or spraying form the flocking coating on PET fine hair, the flocking coating includes the component of following weight ratio:
Figure BDA0001658508860000052
Figure BDA0001658508860000061
the preparation method of the hydrophobic automobile sealing strip flocking strip comprises the following steps:
(1) coating the PU water-based flocking glue on the TPV/PVC flocking film in a roller coating or spraying manner;
(2) implanting PET fluff into a flocking glue layer by using high-voltage static electricity of a static chamber, and entering a drying tunnel for baking and curing; after the semi-finished product is taken out of the drying channel, the semi-finished product flocking tape is obtained through rolling;
(3) then the flocked belt is put into an unreeling table to be sprayed or roll-coated with the flocked coating which is prepared according to the process, and then the flocked belt enters a drying tunnel to be baked and cured;
(4) and (4) after the flocked belt is taken out of the drying channel, the flocked belt is obtained through the processes of rolling, slitting, fine cutting, rolling and packaging.
Example 3
The utility model provides a hydrophobic type car sealing strip flocking belt, it includes TPV/PVC/TPE flocking membrane, the water-based flocking glue of PU, PA fine hair and flocking coating, the water-based flocking glue of PU roller coat or spray forms the flocking glue layer on TPV/PVC/TPE flocking membrane, utilize electrostatic chamber high-tension static with PA fine hair implantation on the flocking glue layer, flocking coating roller coat or spray form the flocking coating on PA fine hair, the flocking coating includes the component of following weight ratio:
Figure BDA0001658508860000062
the preparation method of the hydrophobic automobile sealing strip flocking strip comprises the following steps:
(1) coating the PU water-based flocking glue on the TPV/PVC/TPE flocking film in a roller coating or spraying manner;
(2) implanting PA fluff into a flocking glue layer by using high-voltage static electricity of a static chamber, and entering a drying tunnel for baking and curing; after the semi-finished product is taken out of the drying channel, the semi-finished product flocking tape is obtained through rolling;
(3) then the flocked belt is put into an unreeling table to be sprayed or roll-coated with the flocked coating which is prepared according to the process, and then the flocked belt enters a drying tunnel to be baked and cured;
(4) and (4) after the flocked belt is taken out of the drying channel, the flocked belt is obtained through the processes of rolling, slitting, fine cutting, rolling and packaging.
The hydrophobic automobile sealing strip flocking strip prepared in the above examples 1-3 is installed on a guide groove of automobile glass, loudness generated when an automobile moves and the automobile window glass is lifted is tested, test results are all less than 3SONE (Song), and the flocking coating has soft hand feeling and smooth feeling.
Therefore, the hydrophobic automobile sealing strip flocking belt can solve the abnormal sound problem generated in the lifting state of automobile window glass, and the flocking coating has soft hand feeling and smooth feeling.

Claims (10)

1. The utility model provides a hydrophobic type automobile seal strip flocking belt, its characterized in that, it is including flocking membrane, flocking glue, fine hair and flocking coating, flocking glue roller coat or spraying are in form flocking glue layer on the flocking membrane, utilize static room high-voltage static will fine hair is implanted on flocking glue layer, flocking coating roller coat or spraying are in form the flocking coating on the fine hair, the flocking coating includes fluorine silicon modified waterborne polyurethane resin, polyurethane modified acrylic emulsion, organo-molybdenum, organosilicon, curing agent and solvent.
2. The hydrophobic automotive sealer flocked tape according to claim 1, wherein said flocked coating further comprises an antifoaming agent.
3. The hydrophobic automobile seal strip flocking strip according to claim 2, wherein the flocking coating comprises the following components in percentage by weight:
Figure FDA0001658508850000011
4. the hydrophobic automobile seal strip flocking strip according to claim 3 wherein the curing agent is isocyanate; the solvent is alcohol ether solvent or water.
5. The hydrophobic automobile seal strip flocking strip as recited in claim 3, wherein the antifoaming agent is a high molecular weight polysiloxane polymer antifoaming agent.
6. The hydrophobic automobile sealing strip flocking strip as recited in claim 1, wherein the flocking film is a blend of one or more of TPV, PVC and TPE flocking films.
7. The hydrophobic automotive sealer flocking tape according to claim 1 wherein the flocking glue is a PU water-based flocking glue.
8. The hydrophobic automobile seal strip flocking strip according to claim 1 wherein said pile is PET or PA pile.
9. The preparation method of the hydrophobic automobile sealing strip flocking strip according to claim 1, which is characterized by comprising the following steps:
(1) coating flocking glue on the flocking film in a roller coating or spraying manner;
(2) implanting the fluff into a flocking glue layer by using high-voltage static electricity of a static chamber, and entering a drying tunnel for baking and curing; after the semi-finished product is taken out of the drying channel, the semi-finished product flocking tape is obtained through rolling;
(3) and then the semi-finished product flocked belt is put into an unreeling table to spray or roll the prepared flocked coating, and enters a drying tunnel to be baked and cured.
10. The method for preparing the hydrophobic automobile sealing strip flocking strip according to claim 9, further comprising the step (4) of rolling, slitting, fine cutting, rolling and packaging after being taken out of the drying tunnel.
CN201810451203.0A 2018-05-11 2018-05-11 Hydrophobic automobile sealing strip flocking belt and preparation method thereof Active CN110466331B (en)

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CN112958407B (en) * 2021-02-01 2023-02-24 海信空调有限公司 Flocking method, guide plate obtained by flocking method and air conditioner
CN114308576B (en) * 2022-01-20 2022-08-12 浙江希尔达汽车零部件有限公司 Production method for cross flocking of automobile B upper column camera area

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CN1951968A (en) * 2006-10-09 2007-04-25 中国科学技术大学 Fluorin-silicon modified core-shell structure polyurethane-acrylate emulsion preparation method
EP2121303B1 (en) * 2007-01-19 2010-07-14 Dimontonate Floccati S.p.A. Multi-layered film and flocked material comprising such a film
CN102585681A (en) * 2012-02-08 2012-07-18 上海三恩化工有限公司 Coating for automobile sealing strip and preparation method thereof
CN106700918A (en) * 2017-01-09 2017-05-24 上海三恩化工有限公司 Coating for flocking tape roller coating and preparation method of coating
CN107652867A (en) * 2017-09-30 2018-02-02 上海三恩化工有限公司 Application type flocking belt of sealing strip for automobile preparation method
CN107695902A (en) * 2017-10-18 2018-02-16 河北思瑞恩新材料科技有限公司 One flocked material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1951968A (en) * 2006-10-09 2007-04-25 中国科学技术大学 Fluorin-silicon modified core-shell structure polyurethane-acrylate emulsion preparation method
EP2121303B1 (en) * 2007-01-19 2010-07-14 Dimontonate Floccati S.p.A. Multi-layered film and flocked material comprising such a film
CN102585681A (en) * 2012-02-08 2012-07-18 上海三恩化工有限公司 Coating for automobile sealing strip and preparation method thereof
CN106700918A (en) * 2017-01-09 2017-05-24 上海三恩化工有限公司 Coating for flocking tape roller coating and preparation method of coating
CN107652867A (en) * 2017-09-30 2018-02-02 上海三恩化工有限公司 Application type flocking belt of sealing strip for automobile preparation method
CN107695902A (en) * 2017-10-18 2018-02-16 河北思瑞恩新材料科技有限公司 One flocked material and preparation method thereof

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