CN110466214B - 一种石墨烯面料及其制备方法 - Google Patents

一种石墨烯面料及其制备方法 Download PDF

Info

Publication number
CN110466214B
CN110466214B CN201910757764.8A CN201910757764A CN110466214B CN 110466214 B CN110466214 B CN 110466214B CN 201910757764 A CN201910757764 A CN 201910757764A CN 110466214 B CN110466214 B CN 110466214B
Authority
CN
China
Prior art keywords
interlayer
graphene
surface layer
bottom layer
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201910757764.8A
Other languages
English (en)
Other versions
CN110466214A (zh
Inventor
万金刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Camel Home Textile Technology Co ltd
Original Assignee
Guangzhou Camel Home Textile Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Camel Home Textile Technology Co Ltd filed Critical Guangzhou Camel Home Textile Technology Co Ltd
Priority to CN201910757764.8A priority Critical patent/CN110466214B/zh
Publication of CN110466214A publication Critical patent/CN110466214A/zh
Application granted granted Critical
Publication of CN110466214B publication Critical patent/CN110466214B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/30—Antimicrobial, e.g. antibacterial
    • A41D31/305—Antimicrobial, e.g. antibacterial using layered materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/18—Handling of layers or the laminate
    • B32B38/1808—Handling of layers or the laminate characterised by the laying up of the layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/449—Yarns or threads with antibacterial properties
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/46—Sewing-cottons or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/03—3 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B32B2262/0284—Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0292—Polyurethane fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B32B2307/7246—Water vapor barrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing

Abstract

本发明公开了一种石墨烯面料及其制备方法，石墨烯面料包括面层、隔层和底层；隔层中含有竹碳纤维；面层、隔层和底层依次重叠，并通过缝合线将面层、隔层和底层缝合；缝合线中含有石墨烯；制备方法包括：缝合线制备步骤：将亚麻纤维、壳聚糖、聚丙烯和聚酰胺混合，进行密炼10‑20min后粉碎，然后加入助剂和石墨烯混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；缝制步骤：将面层、隔层和底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，得到石墨烯面料；石墨烯面料属于多功能防护面料，具有高强度、优越的防水防风、保温、抗菌，适合用于制备户外服装。

Description

一种石墨烯面料及其制备方法
技术领域
本发明涉及一种石墨烯面料及其制备方法，属于面料技术领域。
背景技术
随着当代人压力日益渐大与对户外大自然景色的崇敬，户外活动越来越成为当代人热爱项目，其不仅可以起到减压效果，且还具备开阔眼界、提高毅力、增强体力的作用；
而户外环境恶劣，时而狂风暴雨、时而高阳艳照，一件具备多功能强防护性能衣物不可少，其可让人在狂风呼啸的高山中隔离冷风防肆虐，亦可在雪山中防止突来大雨冲刷提供保暖防护性，也可在高阳艳照的沙漠阻隔恶劣的紫外线，一件顶多件，轻松减负行李，便携出行。
现有技术中，使得面料产生防风作用的方式是以PU覆膜面料，面料是运用水溶性PU融入纺织物中或覆盖于纺织物上的合成面料，这种面料确实具有防风性能，其还具备防水作用，但是这种面料在夏天其手感稍差并有易融化且透气性弱，穿上身活动易产生噪音与不适感，冬天穿着不耐寒，柔软性差且无弹性不能保障户外穿着自在感，在多变天气无法做到全面性防护人体；在洗涤的过程中比较容易产生开裂的现象，并且不耐高温，也不耐脏，如果造成严重污垢是没有办法彻底清洗干净的。
因此基于户外服装需要体现的多功能性，有必要对面料进行进一步的改进。
发明内容
为了克服现有技术的不足，本发明的第一个目的在于提供一种石墨烯面料，属于多功能防护面料，具有高强度、优越的防水防风、保温、抗菌，适合用于制备户外服装。
本发明的第二个目的在于提供上述石墨烯面料的制备方法。
实现本发明的第一个目的可以通过采取如下技术方案达到：一种石墨烯面料，包括面层、隔层和底层；隔层中含有竹碳纤维；面层、隔层和底层依次重叠，并通过缝合线将面层、隔层和底层缝合；缝合线中含有石墨烯。
进一步地，面层为锦纶面层。
进一步地，隔层由竹碳纤维、石墨烯、涤纶和氨纶混纺成的纱加捻后，进行编织而成。
进一步地，底层为棉纤维底层。
进一步地，缝合线露出于面层的长度占缝合线总长度的55-70％。
进一步地，缝合线的针距为12-18针/3cm。
进一步地，缝合线的针距为15针/3cm。
实现本发明的第二个目的可以通过采取如下技术方案达到：一种石墨烯面料的制备方法，包括：
缝合线制备步骤：将亚麻纤维、壳聚糖、聚丙烯和聚酰胺混合，进行密炼10-20min后粉碎，然后加入助剂和石墨烯混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；
缝制步骤：将面层、隔层和底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，得到石墨烯面料。
进一步地，助剂为硬脂酸钙。
进一步地，缝合线制备步骤：将按重量份计的亚麻纤维12-25份、壳聚糖1-5份、聚丙烯20-35份和聚酰胺10-25份混合，进行密炼10-20min后粉碎，然后加入助剂1-5份和石墨烯5-10份混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线。
本发明的配方设计原理如下：
石墨烯是一种由碳原子以sp2杂化轨道组成六角型呈蜂巢晶格的二维碳纳米材料，只吸收2.3％的光，导热系数高达5300W/m·K，高于碳纳米管和金刚石，常温下其电子迁移率超过15000cm2/V·s。然而，常规的户外服装中，会在面层加入石墨烯，但由于石墨烯处于面层且含量高，面料吸收热量快，但散失也快，难以保留，特别是处于日照强、温度高的环境中，石墨烯面料吸收了热量之后，使得服装内部闷热，难以产生在温度高的环境散热、温度低的环境保温的效果，影响了使用体验。
本发明在缝合线上加入石墨烯，缝合线露出于面层并处于面料的边缘处，可以吸收外界的热量，然后以远红外能量形式输出，并可以导通在含有竹炭纤维的隔层上，面层作为阻挡，和底层之间形成的保温腔，使得面料具有良好的保温效果，维持人体内部温度的稳定。
相比现有技术，本发明的有益效果在于：
1、本发明石墨烯面料属于多功能防护面料，具有高强度、优越的防水防风、保温、抗菌，适合用于制备户外服装；
2、本发明石墨烯面料在缝合线上添加石墨烯，通过石墨烯，将外部的热量导通传递至隔层，隔层的竹炭纤维有利于热量的发散，面层和底层之间形成保温腔，使得面料具有良好的保温效果，维持人体内部温度的稳定；
3、本发明石墨烯面料将石墨烯添加至缝合线上，既可将热量贯通至隔层蓄热，还能输送至底层，石墨烯的远红外能量形式输出的特点，可以改善皮肤微循环，加强细胞的再生能力；并且可以根据需要，调整缝合线的密度和使用量，使得面料产生不同的蓄热效果；
3、本发明石墨烯面料的缝合线上添加有石墨烯，隔层添加竹炭纤维，具有抗菌保温、防静电的作用，并且吸湿透气；
4、本发明石墨烯面料的制备方法简单，适合工业化批量生产。
附图说明
图1为本发明石墨烯面料的结构示意图；
图中，1、面层；2、隔层；3、底层；4、缝合线。
具体实施方式
下面，结合附图以及具体实施方式，对本发明做进一步描述：
参照图1，一种石墨烯面料，包括面层1、隔层2和底层3；隔层2中含有竹碳纤维；面层1、隔层2和底层3依次重叠，并通过缝合线4将面层1、隔层2和底层3缝合；缝合线4中含有石墨烯。
其中，面层为锦纶面层。
其中，隔层由竹碳纤维、石墨烯、涤纶和氨纶混纺成的纱加捻后，进行编织而成。
其中，底层为棉纤维底层。
其中，缝合线的针距为12-18针/3cm，缝合线均匀设置，均匀设置，是指缝合线均匀分布穿设面层、隔层和底层，使得面层、隔层和底层平整贴合为面料整体，缝合线之间于面层和底层围绕可以形成小的腔室，并非只缝合面层、隔层和底层的边缘。此外，也可以面料上的缝合线形成区域，一些区域的缝合线密度高一些，一些区域的缝合线密度低一些，对应服装的不同部位，产生不同的保温效果，灵活调节。
石墨烯面料的制备方法，其特征在于包括：
缝合线制备步骤：将按重量份计的亚麻纤维12-25份、壳聚糖1-5份、聚丙烯20-35份和聚酰胺10-25份混合，进行密炼10-20min后粉碎，然后加入硬脂酸钙1-5份和石墨烯5-10份混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；
缝制步骤：将面层、隔层和底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，得到石墨烯面料。
锦纶面层起到良好的防风防水作用，隔层为竹碳纤维、石墨烯、涤纶和氨纶混纺，竹炭纤维有抗菌和对缝合线石墨烯传递的热量起到导通散射的作用，如果在隔层中也加入石墨烯，则导通的效果更好；棉纤维底层贴合皮肤，透气吸汗；但由于面层、隔层和底层需要进行缝合形成整体，并需要体现面料整体的弹性、延展性等性能，有所不同，因此根据减少或消除内应力而选择面层、隔层和底层的材料，并通过设置缝合线针距和限定缝合线材料，可以使得三层材料平整地贴合，缝合后，面料整体仍然体现良好的柔软性、延展性和耐用性，长期使用，不会起皱，不产生单层脱离，损坏的现象。
实施例1：
缝合线制备步骤：将按重量份计的亚麻纤维15份、壳聚糖2份、聚丙烯30份和聚酰胺20份混合，进行密炼15min后粉碎，然后加入硬脂酸钙2份和石墨烯8份混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；
隔层制备步骤：隔层由竹碳纤维、石墨烯、涤纶和氨纶混纺成的纱加捻后，进行编织而成；
缝制步骤：将锦纶面层、隔层和棉纤维底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，缝合线的针距为14针/3cm，缝合线均匀设置，得到石墨烯面料。
实施例2：
缝合线制备步骤：将按重量份计的亚麻纤维20份、壳聚糖4份、聚丙烯30份和聚酰胺15份混合，进行密炼15min后粉碎，然后加入硬脂酸钙4份和石墨烯6份混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；
隔层制备步骤：隔层由竹碳纤维、石墨烯、涤纶和氨纶混纺成的纱加捻后，进行编织而成；
缝制步骤：将锦纶面层、隔层和棉纤维底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，缝合线的针距为16针/3cm，缝合线均匀设置，得到石墨烯面料。
实施例3：
缝合线制备步骤：将按重量份计的亚麻纤维23份、壳聚糖4份、聚丙烯32份和聚酰胺22份混合，进行密10min后粉碎，然后加入硬脂酸钙4份和石墨烯7份混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；
隔层制备步骤：隔层由竹碳纤维、石墨烯、涤纶和氨纶混纺成的纱加捻后，进行编织而成；
缝制步骤：将锦纶面层、隔层和棉纤维底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，缝合线的针距为13针/3cm，缝合线均匀设置，得到石墨烯面料。
对比例1：
对比例的特征在于：以三层锦纶面料叠合进行缝制，缝合线采用不含石墨烯的普通缝合线；
对比例2：
对比例2的特征在于，以三层棉纤维面料叠合进行缝制，缝合线采用不含石墨烯的普通缝合线；
对比例3：
对比例3的特征在于：为含有石墨烯的锦纶面料，石墨烯加入量为3％。
对实施例1-3和对比例1-3进行保温性能的测试：
将得到的面料平铺，用60℃加热面料表面30min后，停止加热测试面料覆盖处的温度，然后静置30min后，再次测试面料覆盖处的温度，结果如表格1所示。
表格1实施例与对比例的保温情况测试结果
Figure BDA0002169290820000071
Figure BDA0002169290820000081
实施例与对比例相比，实施例的升温幅度比对比例低，说明实施例能够维持温度的稳定，与外界形成温度差，维持穿着者的舒适感；静置后，实施例的温度下降缓慢，有利于人体保温，而对比例的温度下降快，受外界环境影响大。
根据国标GB12703.3-2009进行静电性能的评价，结果如表格2所示：
表格2实施例和对比例的电荷量检测(μC)
项目 洗前 洗后
实施例1 0.4 0.4
实施例2 0.4 0.5
实施例3 0.4 0.5
对比例1 0.6 0.7
对比例2 0.6 0.6
对比例3 0.4 0.4
实施例1-3均符合抗静电纺织品的电荷量要求，而对比例1-2抗静电性能较差。
根据国标GB/T20944.3-2008进行抗菌性能的检测，结果如表格3所示：
表格3实施例和对比例的抑菌率检测(％)
Figure BDA0002169290820000082
Figure BDA0002169290820000091
对于本领域的技术人员来说，可根据以上描述的技术方案以及构思，做出其它各种相应的改变以及变形，而所有的这些改变以及变形都应该属于本发明权利要求的保护范围之内。

Claims (5)

1.一种石墨烯面料，其特征在于包括面层、隔层和底层；所述隔层中含有竹碳纤维；所述面层、隔层和底层依次重叠，并通过缝合线将面层、隔层和底层缝合；所述缝合线中含有按重量份计的亚麻纤维12-25份、壳聚糖1-5份、聚丙烯20-35份、聚酰胺10-25份、助剂1-5份和石墨烯5-10份；所述助剂为硬脂酸钙；所述缝合线的针距为12-18针/3cm；缝合线均匀分布穿设面层、隔层和底层；所述隔层由竹碳纤维、石墨烯、涤纶和氨纶混纺成的纱加捻后，进行编织而成。
2.如权利要求1所述的石墨烯面料，其特征在于，所述面层为锦纶面层。
3.如权利要求1所述的石墨烯面料，其特征在于，所述底层为棉纤维底层。
4.如权利要求1所述的石墨烯面料，其特征在于，所述缝合线的针距为14针/3cm。
5.一种如权利要求1所述的石墨烯面料的制备方法，其特征在于包括：
缝合线制备步骤：将亚麻纤维、壳聚糖、聚丙烯和聚酰胺混合，进行密炼10-20min后粉碎，然后加入助剂和石墨烯混合均匀，得到混合物；将混合物置于双螺杆熔融纺丝机中挤出进行纺丝，加捻成线，得到缝合线；
缝制步骤：将面层、隔层和底层重叠后，用缝合线贯穿面层、隔层和底层进行缝合，得到石墨烯面料。
CN201910757764.8A 2019-08-16 2019-08-16 一种石墨烯面料及其制备方法 Active CN110466214B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910757764.8A CN110466214B (zh) 2019-08-16 2019-08-16 一种石墨烯面料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910757764.8A CN110466214B (zh) 2019-08-16 2019-08-16 一种石墨烯面料及其制备方法

Publications (2)

Publication Number Publication Date
CN110466214A CN110466214A (zh) 2019-11-19
CN110466214B true CN110466214B (zh) 2021-12-31

Family

ID=68510852

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910757764.8A Active CN110466214B (zh) 2019-08-16 2019-08-16 一种石墨烯面料及其制备方法

Country Status (1)

Country Link
CN (1) CN110466214B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111300944A (zh) * 2020-04-09 2020-06-19 江苏新凯盛企业发展有限公司 一种石墨烯混纺面料
CN113430670A (zh) * 2021-05-10 2021-09-24 东台市竹林高科技材料有限公司 一种化学纤维锦纶丝及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040100803A (ko) * 2003-05-21 2004-12-02 (주)풍전티.티 중간층에 기능성 포를 배치한 다층직물지
TW201004582A (en) * 2008-07-25 2010-02-01 Racer Sporting Goods Co Ltd Nano-far infrared belt
CN106120333A (zh) * 2016-06-27 2016-11-16 苏州宇希新材料科技有限公司 一种石墨烯/亚麻复合纤维的制备方法
CN107237120A (zh) * 2017-07-10 2017-10-10 山东圣泉新材料股份有限公司 一种纤维制品浸渍液、改性纤维制品及制备方法
CN108327359A (zh) * 2018-01-30 2018-07-27 四川省安德盖姆石墨烯科技有限公司 一种石墨烯睡袋
CN108754669A (zh) * 2018-06-27 2018-11-06 合肥远科服装设计有限公司 一种缝纫线的制备方法
CN208148682U (zh) * 2018-03-15 2018-11-27 郑惠尹 一种自发热亲肤内衣面料

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040100803A (ko) * 2003-05-21 2004-12-02 (주)풍전티.티 중간층에 기능성 포를 배치한 다층직물지
TW201004582A (en) * 2008-07-25 2010-02-01 Racer Sporting Goods Co Ltd Nano-far infrared belt
CN106120333A (zh) * 2016-06-27 2016-11-16 苏州宇希新材料科技有限公司 一种石墨烯/亚麻复合纤维的制备方法
CN107237120A (zh) * 2017-07-10 2017-10-10 山东圣泉新材料股份有限公司 一种纤维制品浸渍液、改性纤维制品及制备方法
CN108327359A (zh) * 2018-01-30 2018-07-27 四川省安德盖姆石墨烯科技有限公司 一种石墨烯睡袋
CN208148682U (zh) * 2018-03-15 2018-11-27 郑惠尹 一种自发热亲肤内衣面料
CN108754669A (zh) * 2018-06-27 2018-11-06 合肥远科服装设计有限公司 一种缝纫线的制备方法

Also Published As

Publication number Publication date
CN110466214A (zh) 2019-11-19

Similar Documents

Publication Publication Date Title
CN110466214B (zh) 一种石墨烯面料及其制备方法
CN103469435A (zh) 一种多功能弹力牛仔布
CN205736257U (zh) 一种新型针织面料
CN203137148U (zh) 一种保健泳衣面料
CN209456654U (zh) 一种三层结构针织面料
CN202727469U (zh) 超强延展柔软吸水透气的功能面料
CN104385752A (zh) 一种保暖型针织面料及其制备方法
CN207984247U (zh) 一种弹性保暖复合布
CN208305953U (zh) 一种抗皱免烫面料
CN207310737U (zh) 一种保暖面料
CN203141950U (zh) 一种具有抗菌功能的防水透湿型泳衣面料
KR101873258B1 (ko) 냉감기능이 우수한 직물의 제조방법
CN204994641U (zh) 一种吸湿发热抗静电毛衫
CN214736408U (zh) 一种真丝牛仔面料
CN203141951U (zh) 一种柔软吸水透气的纺织面料
CN206941085U (zh) 舒适耐用型亚麻涤纶交织窗帘织物
CN207466042U (zh) 弹性编织带
WO2020000564A1 (zh) 一种高舒适性面料及其加工工艺
CN213441557U (zh) 吸湿排汗高弹高强面料
CN216659192U (zh) 一种防风防水四面弹面料
CN103494386A (zh) 一种非透明雪纺布料
CN107549904A (zh) 一种防水透气毛纺西服复合面料
CN216708651U (zh) 一种草珊瑚纤维混纺鞋面网布
CN218749698U (zh) 一种可降解环保舒适性醋酯保湿经编面料
CN216001695U (zh) 一种抗皱面料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 510000 room 107, No. 1, Xinlong Shaxi, Liwan District, Guangzhou, Guangdong

Applicant after: Guangzhou Columbus Media Co.,Ltd.

Address before: 510000 Room 302, No. 6, Fumin Road, Guangzhou promotion neighborhood committee, Guangdong Province (office use only)

Applicant before: Guangzhou Columbus Technology Development Co.,Ltd.

CB02 Change of applicant information
TA01 Transfer of patent application right

Effective date of registration: 20211118

Address after: Room 101, 48 Xiaoping south street, Xinshi street, Baiyun District, Guangzhou, Guangdong 510000

Applicant after: Guangzhou camel Home Textile Technology Co.,Ltd.

Address before: 510000 room 107, No. 1, Xinlong Shaxi, Liwan District, Guangzhou, Guangdong

Applicant before: Guangzhou Columbus Media Co.,Ltd.

TA01 Transfer of patent application right
GR01 Patent grant
GR01 Patent grant