CN110452636A - A kind of multiple fabric aqueous rubber cement of new formula and preparation method thereof - Google Patents
A kind of multiple fabric aqueous rubber cement of new formula and preparation method thereof Download PDFInfo
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- CN110452636A CN110452636A CN201910782123.8A CN201910782123A CN110452636A CN 110452636 A CN110452636 A CN 110452636A CN 201910782123 A CN201910782123 A CN 201910782123A CN 110452636 A CN110452636 A CN 110452636A
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- rubber cement
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J121/00—Adhesives based on unspecified rubbers
- C09J121/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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Abstract
The present invention relates to the multiple fabric aqueous rubber cements and preparation method thereof that one kind is newly formulated, and include the main body rubber cement of 95% content and the water mill decomposed solution of 5% content, main body rubber cement includes following weight ratio: (1) 90-100 parts of latex；(2) stone needle powder of 10-20 parts of 10-20 parts of talcum powder (3)；(4) 1-10 parts of oleic acid.It is not volatile and inflammable liquid to the aqueous multiple cloth rubber cement of one kind of this programme production, and when production and application will not generate vaporization, without off-odor, solves the security risk that rubber overshoes industry gasoline is starched yet.A kind of aqueous multiple cloth rubber cement is safe and reliable compound rubber cement.
Description
Technical field
The present invention relates to footwear technology, such as the adhesive of footwear, especially a kind of multiple fabric aqueous rubber cement being newly formulated and its
Preparation method, the Gasoline rubber paste of the replaceable slurry preparation of gasoline at present.
Background technique
Conventional vulcanized shoes composite surface cloth glue substantially uses gasoline to starch, and the multiple cloth resultant effect of gasoline slurry is fair, but gasoline
Combination process is starched there are biggish security risk, fire alarm caused by starching due to gasoline has generation in rubber shoe industry every year, to enterprise
Industry and employee bring very huge economic loss and mental suffering.
Gasoline rubber paste is mainly that rubber and volatile organic gasoline form, and in heating recombination process, workshop can be produced
Raw a large amount of VOC harmful exhaust, affects air environment, also influences whether the health of employee.
Gasoline rubber paste 70% be volatile organic gasoline, main component is 4~C of C, 12 hydro carbons, be hydrocarbon mixture article it
One.It is a kind of colourless or faint yellow, volatile and flammable liquid, there is off-odor.Gasoline has an important physical characteristic,
I.e. it is very easy to gasification, high volatility.Sometimes we with the naked eye it can be seen that gasoline level have one layer of transpiration fog.1
100~400 liters of steams can be volatilized by rising gasoline, be diffused into very large space.Sometimes fire source leaves gasoline and seems far, but and vapour
Oil vapour contact can still cause to burn.Gasoline boiling point is 40~200 DEG C, and flash-point is -58~10 DEG C, and specific gravity is 0.67~0.71,
Explosion limit is about 1.3~6%.There are many more enterprises at present in industry is starched using gasoline, but there is very big security risk, vapour
Fire alarm caused by slurry oil has generation in rubber shoe industry every year, especially is easier to occur in dry climate, fire alarm is not only made to enterprise
At extreme loss, and adjacent enterprise also will receive security threat.
Applicant just did a large amount of test, but to solve the security hidden trouble of rubber overshoes industry before more than ten years
It fails.
With the development of Modern Fine Chemical Industry industry, we are selected chemical materials, a kind of multiple cloth rubber cement formula, by a large amount of
Scientific experimentation and test, successfully had developed a kind of multiple fabric aqueous rubber cement, can replacing gasoline rubber cement combination process completely, go forward side by side
It has gone multiple scale up test, has put into mass production.
Summary of the invention
The present invention proposes a kind of multiple fabric aqueous rubber cement and preparation method thereof being newly formulated, and solves and used in the prior art
The above problem present in journey.
A kind of multiple fabric aqueous rubber cement of new formula, it is characterised in that: include the main body rubber cement and 5% content of 95% content
Water mill decomposed solution, main body rubber cement includes following weight ratio: (1) 90-100 parts of latex；(2) 10-20 parts of talcum powder (3)
10-20 parts of stone needle powder；(4) 1-10 parts of oleic acid.
Preferably, main body rubber cement includes following weight ratio: (1) 100 parts of latex；(3) 15 parts of talcum powder of (2) 15 parts
Stone needle powder；(4) 5 parts of oleic acid.
Water mill decomposed solution includes captax, diphenylguanidine, altax, zinc oxide, sulphur, anti-aging agent and brightening agent.
A kind of preparation method of multiple fabric aqueous rubber cement, includes the following steps:
(1): the equipment for choosing preparation, using the mixing plant with defoaming function；
(2): preparing water mill liquid；
(3): preparing main body rubber cement；
(4): above-mentioned procedure of processing are as follows: first prepare main body rubber cement, and stirred in mixing plant, uniformly stirred as requested
It mixes, is subsequently added into oleic acid, by technique requirement, uniform stirring, step (2) prepared water mill liquid is then added, uniform stirring is complete
At a kind of aqueous multiple cloth rubber cement production.
Preparation water mill liquid mode in step (2) are as follows: by captax, diphenylguanidine, altax, zinc oxide, sulphur, prevent
The compounding agent that old agent, brightening agent are constituted, is prepared by formula rate, completes water mill decomposed solution.
Main body rubber cement manner of formulation in step (3) are as follows: latex is prepared with talcum powder, stone needle powder by formulation dosage, is pressed
Order is put into the mixing plant of customization, by technique requirement, uniform stirring at a kind of aqueous main body rubber cement for answering cloth rubber cement.
Above-mentioned scheme: it is not volatile and inflammable liquid for a kind of aqueous multiple cloth rubber cement, and when production and application will not produce
Raw vaporization solves the security risk of rubber overshoes industry gasoline slurry also without off-odor.The aqueous multiple cloth rubber cement of one kind is safe and reliable
Compound rubber cement.
In conclusion the beneficial effects of the present invention are:
A kind of aqueous compound rubber cement selects talcum powder, stone needle powder as rubber cement material of main part, talcum powder have disinfection, it is mould proof,
The effect of bactericidal antiphlogistic.According to Chinese medicine " Liu Yi San " introduce, talcum powder can play the role of it is clearing summer-heat and damp, and stone needle powder issue it is remote red
Outside line can generate a variety of effects and effect:
1) improve the circulatory system
The far-infrared engergy activating cell that stone needle powder issues, the peculiar energy field of generation acts on human body, can with qi and blood circulation promotion,
Logical numbness gas, melts muscles and bones at wind-damp dispelling.
2) improve arthralgia
The penetration for the far infrared that stone needle powder issues keeps body interior warm, drives micro- blood up to muscle arthrosis depths
The oxygen and nutrient of pipe network exchange.To swelling in eliminating, it is obvious to mitigate effect of aching.Have to the people of " athlete's foot " and biggish prevents work
With.
The aqueous multiple cloth rubber cement of one kind improves combination process and product quality level, meets environmental requirement；It is a kind of aqueous multiple
Cloth rubber cement solves the security hidden trouble of rubber overshoes industry；A kind of aqueous multiple cloth rubber cement also has special effect.It is a kind of peace
Entirely, environmental protection, the compound rubber cement with special efficacy.
In summary, a kind of aqueous multiple cloth rubber cement is mainly water and stone needle, aluminite, talcum powder composition, is heating compound mistake
Cheng Zhong, workshop will not generate any harmful exhaust, eliminate the pernicious gas of production scene organic solvent volatilization, favorably
In environmental protection and safety in production.The present invention is environmentally friendly machine, has in industry obtained the favor of many enterprises.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
The multiple fabric aqueous rubber cement and preparation method thereof that one kind disclosed by the invention is newly formulated:
A kind of aqueous multiple cloth rubber cement formula:
1) latex 5) captax 9) sulphur
2) talcum powder 6) diphenylguanidine 10) anti-aging agent
3) stone needle powder 7) altax 11) brightening agent
4) oleic acid 8) zinc oxide
Wherein: the compounding agent that captax, diphenylguanidine, altax, zinc oxide, sulphur, anti-aging agent, brightening agent form is pressed
Formula rate is prepared, and water mill decomposed solution is completed, and 5% water mill decomposed solution is added in 100 latexes.2 one sulfydryl benzene of captax chemical name
And thiazole；Diphenylguanidine is mainly used as the medium accelerator of natural rubber and synthetic rubber；Rubber accelerator DM chemical name: 2,
2'- dithio-bis-benzothiazole.
A kind of aqueous multiple cloth rubber cement formula production groundwork step:
Step 1:
Prepare water mill liquid: water-insoluble powdered compounding agent used in rubber cement formula, being made can be very well with latex
Mixing and finely dispersed water decomposition liquid.Wherein " captax, diphenylguanidine, altax, zinc oxide, sulphur, anti-aging agent, increasing
White dose " etc. compounding agents by formula rate prepare, complete water mill decomposed solution.
Step 2:
The materials such as latex and " talcum powder, stone needle powder " are put into the mixing plant of customization by formulation dosage preparation, in order
In, by technique requirement, uniform stirring at a kind of aqueous main body rubber cement for answering cloth rubber cement.
Step 3:
Oleic acid is added in a kind of aqueous multiple cloth rubber cement material of main part, plays emulsifier surface active function, by technique requirement,
Uniform stirring.
Step 4:
Add compounding agents water such as " captax, diphenylguanidine, altax, zinc oxide, sulphur, anti-aging agent, brightening agents "
Grind decomposed solution.By technique requirement, uniform stirring, a kind of aqueous multiple cloth rubber cement production is completed.
A kind of aqueous multiple cloth rubber cement formula production points for attention:
1) a kind of aqueous multiple cloth rubber cement formula production, it is necessary to which there is the mixing plant of defoaming function using customization.Traditional
Mixing plant can generate a large amount of bubble in whipping process, also will affect the quality of joint product.
2) various cooperation agent dispersing liquids carry out water mill in special equipment, by technique requirement, reach optimal water mill effect
Time is settled with gravimetric method and is measured, to determine the time for reaching effective water mill.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (6)
1. the multiple fabric aqueous rubber cement that one kind is newly formulated, it is characterised in that: include the main body rubber cement and 5% content of 95% content
Water mill decomposed solution, main body rubber cement include following weight ratio: (1) 90-100 parts of latex；(2) 10-20 parts talcum powder (3) 10-
20 parts of stone needle powder；(4) 1-10 parts of oleic acid.
2. a kind of multiple fabric aqueous rubber cement and preparation method thereof being newly formulated according to claim 1, it is characterised in that: main gel
Slurry includes following weight ratio: (1) 100 parts of latex；(2) 15 parts of (3) 15 parts of talcum powder of stone needle powder；(4) 5 parts of oleic acid.
3. a kind of multiple fabric aqueous rubber cement and preparation method thereof being newly formulated according to claim 1, it is characterised in that: water mill point
Solving liquid includes captax, diphenylguanidine, altax, zinc oxide, sulphur, anti-aging agent and brightening agent.
4. the multiple fabric aqueous rubber cement that one kind according to claim 1 is newly formulated, it is characterised in that: including multiple fabric aqueous rubber cement
Preparation method, include the following steps:
(1): the equipment for choosing preparation, using the mixing plant with defoaming function；
(2): preparing water mill liquid；
(3): preparing main body rubber cement；
(4): above-mentioned procedure of processing are as follows: first prepare main body rubber cement, and stirred in mixing plant, uniform stirring, connects as requested
Addition oleic acid step (2) prepared water mill liquid is then added by technique requirement, uniform stirring, uniform stirring completes one
The aqueous multiple cloth rubber cement production of kind.
5. the multiple fabric aqueous rubber cement that one kind according to claim 4 is newly formulated, it is characterised in that: the preparation in step (2)
Water mill liquid mode are as follows: with being made of captax, diphenylguanidine, altax, zinc oxide, sulphur, anti-aging agent, brightening agent
Agent is prepared by formula rate, completes water mill decomposed solution.
6. the multiple fabric aqueous rubber cement that one kind according to claim 4 is newly formulated, it is characterised in that: the main body in step (3)
Rubber cement manner of formulation are as follows: latex and talcum powder, stone needle powder are put by formulation dosage preparation, in order the mixing plant of customization
In, by technique requirement, uniform stirring at a kind of aqueous main body rubber cement for answering cloth rubber cement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910782123.8A CN110452636A (en) | 2019-08-23 | 2019-08-23 | A kind of multiple fabric aqueous rubber cement of new formula and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910782123.8A CN110452636A (en) | 2019-08-23 | 2019-08-23 | A kind of multiple fabric aqueous rubber cement of new formula and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110452636A true CN110452636A (en) | 2019-11-15 |
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| CN201910782123.8A Pending CN110452636A (en) | 2019-08-23 | 2019-08-23 | A kind of multiple fabric aqueous rubber cement of new formula and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011160334A1 (en) * | 2010-06-25 | 2011-12-29 | Wan Xianneng | Environmental protection sole and manufacture method of body layer thereof |
| CN104015418A (en) * | 2014-05-08 | 2014-09-03 | 北京服装学院 | Stone needle coating function fabric and processing technology thereof |
| CN104987551A (en) * | 2015-08-04 | 2015-10-21 | 晋江金飞鞋材有限公司 | Environmental-friendly ventilation type composite natural emulsion product as well as preparation method and application thereof |
| CN105968463A (en) * | 2016-06-24 | 2016-09-28 | 广州恩熙鞋业有限公司 | High-elasticity sole rubber and preparation method thereof |
| CN107446183A (en) * | 2016-06-01 | 2017-12-08 | 唐建国 | A kind of acidproof all rubber shoes vamp rubber |
| CN109294478A (en) * | 2018-10-31 | 2019-02-01 | 际华三五三七制鞋有限责任公司 | Duck Foxing strip for rubber shoes bonds aqueous rubber cement and preparation method thereof |
-
2019
- 2019-08-23 CN CN201910782123.8A patent/CN110452636A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011160334A1 (en) * | 2010-06-25 | 2011-12-29 | Wan Xianneng | Environmental protection sole and manufacture method of body layer thereof |
| CN104015418A (en) * | 2014-05-08 | 2014-09-03 | 北京服装学院 | Stone needle coating function fabric and processing technology thereof |
| CN104987551A (en) * | 2015-08-04 | 2015-10-21 | 晋江金飞鞋材有限公司 | Environmental-friendly ventilation type composite natural emulsion product as well as preparation method and application thereof |
| CN107446183A (en) * | 2016-06-01 | 2017-12-08 | 唐建国 | A kind of acidproof all rubber shoes vamp rubber |
| CN105968463A (en) * | 2016-06-24 | 2016-09-28 | 广州恩熙鞋业有限公司 | High-elasticity sole rubber and preparation method thereof |
| CN109294478A (en) * | 2018-10-31 | 2019-02-01 | 际华三五三七制鞋有限责任公司 | Duck Foxing strip for rubber shoes bonds aqueous rubber cement and preparation method thereof |
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