CN110446724B - 表面活性剂响应性乳液聚合微凝胶 - Google Patents

表面活性剂响应性乳液聚合微凝胶 Download PDF

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CN110446724B
CN110446724B CN201780086565.8A CN201780086565A CN110446724B CN 110446724 B CN110446724 B CN 110446724B CN 201780086565 A CN201780086565 A CN 201780086565A CN 110446724 B CN110446724 B CN 110446724B
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meth
acrylate
weight
emulsion polymer
monomer
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CN110446724A (zh
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李东翠
S-J·R·徐
K·沙里
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Lubrizol Advanced Materials Inc
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
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    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61Q5/00—Preparations for care of the hair
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    • C08F2/00—Processes of polymerisation
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    • C08F2/16—Aqueous medium
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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    • C08F220/10—Esters
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
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    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
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  • Health & Medical Sciences (AREA)
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  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
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  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
CN201780086565.8A 2016-12-19 2017-12-15 表面活性剂响应性乳液聚合微凝胶 Active CN110446724B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662435968P 2016-12-19 2016-12-19
US62/435,968 2016-12-19
PCT/US2017/066655 WO2018118679A1 (en) 2016-12-19 2017-12-15 Surfactant responsive emulsion polymerized micro-gels

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CN110446724A CN110446724A (zh) 2019-11-12
CN110446724B true CN110446724B (zh) 2021-11-05

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US (1) US11254766B2 (enExample)
EP (1) EP3555147B1 (enExample)
JP (2) JP7328893B2 (enExample)
KR (1) KR102529819B1 (enExample)
CN (1) CN110446724B (enExample)
ES (1) ES2867394T3 (enExample)
WO (1) WO2018118679A1 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102532022B1 (ko) * 2018-07-12 2023-05-12 다우 글로벌 테크놀로지스 엘엘씨 수성 중합체 분산액 및 이의 제조 방법
US12466945B2 (en) * 2019-12-18 2025-11-11 Rohm And Haas Company Aqueous dispersion of occluded polymer particles
EP4005599A1 (en) * 2020-11-30 2022-06-01 Elkem Silicones France SAS Method for manufacturing a silicone elastomer article using a 3d printer
CN114989551A (zh) * 2022-06-30 2022-09-02 芜湖美的智能厨电制造有限公司 可再生干燥材料及其制备方法、洗碗机

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US33156A (en) 1861-08-27 Improvement in machinery for ringing fog-bells
US2798053A (en) 1952-09-03 1957-07-02 Goodrich Co B F Carboxylic polymers
US2858281A (en) 1954-01-22 1958-10-28 Goodrich Co B F Insoluble, acid and alkali-resistant carboxylic polymers
US3032538A (en) 1959-04-28 1962-05-01 Goodrich Co B F Cross-linked carboxylic polymers
EP0019315B1 (en) 1979-05-16 1983-05-25 Procter & Gamble European Technical Center Highly concentrated fatty acid containing liquid detergent compositions
US4384096A (en) 1979-08-27 1983-05-17 The Dow Chemical Company Liquid emulsion polymers useful as pH responsive thickeners for aqueous systems
US4284532A (en) 1979-10-11 1981-08-18 The Procter & Gamble Company Stable liquid detergent compositions
US4421902A (en) 1982-09-30 1983-12-20 Rohm And Haas Company Alkyl, poly(oxyethylene) poly(carbonyloxyethylene) acrylate emulsion copolymers for thickening purposes
US4514552A (en) 1984-08-23 1985-04-30 Desoto, Inc. Alkali soluble latex thickeners
US4600761A (en) 1985-04-04 1986-07-15 Alco Chemical Corporation Acrylic emulsion copolymers for thickening aqueous systems and copolymerizable surfactant monomers for use therein
US4616074A (en) 1985-10-01 1986-10-07 Alco Chemical Corporation Acrylic-methylene succinic ester emulsion copolymers for thickening aqueous systems
US4722962A (en) 1986-06-12 1988-02-02 Desoto, Inc. Nonionic associative thickeners
US4758641A (en) 1987-02-24 1988-07-19 The B F Goodrich Company Polycarboxylic acids with small amount of residual monomer
US5011978A (en) 1989-03-02 1991-04-30 National Starch And Chemical Investment Holding Corporation Copolymers as thickeners and modifiers for latex systems
US5139770A (en) 1990-12-17 1992-08-18 Isp Investments Inc. Cosmetic compositions containing strongly swellable, moderately crosslinked polyvinylpyrrolidone
US5292843A (en) 1992-05-29 1994-03-08 Union Carbide Chemicals & Plastics Technology Corporation Polymers containing macromonomers
IT1272109B (it) 1993-03-19 1997-06-11 Eniricerche Spa Processo per la preparazione di apg
US5294692A (en) 1993-06-30 1994-03-15 National Starch And Chemical Investment Holding Corporation Associative monomers and polymers
US5874495A (en) 1994-10-03 1999-02-23 Rhodia Inc. Polymers useful as PH responsive thickeners and monomers therefor
US5663258A (en) 1996-02-20 1997-09-02 Isp Investments Inc. Strongly swellable, moderately crosslinked copolymers of vinylpyrrolidone and vinyl acetate
US5770543A (en) 1996-09-06 1998-06-23 Henkel Corporation Agricultural compositions comprising alkyl polyglycosides and fatty acids
EP1069142B1 (de) 1999-07-15 2010-04-28 Clariant Produkte (Deutschland) GmbH Wasserlösliche Polymere und ihre Verwendung in kosmetischen und pharmazeutischen Mitteln
US6533873B1 (en) 1999-09-10 2003-03-18 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Suspending clear cleansing formulation
US6635702B1 (en) 2000-04-11 2003-10-21 Noveon Ip Holdings Corp. Stable aqueous surfactant compositions
US6573375B2 (en) 2000-12-20 2003-06-03 Union Carbide Chemicals & Plastics Technology Corporation Liquid thickener for surfactant systems
US7378479B2 (en) 2002-09-13 2008-05-27 Lubrizol Advanced Materials, Inc. Multi-purpose polymers, methods and compositions
DE602006000100T2 (de) 2005-02-14 2008-06-12 Rohm And Haas Co. Verdickungsmittel für wässrige Systeme
US7786027B2 (en) 2006-05-05 2010-08-31 The Procter & Gamble Company Functionalized substrates comprising perfume microcapsules
BR112012013051A2 (pt) * 2009-12-01 2016-11-22 Lubrizol Advanced Mat Inc composição e produto
US9051341B2 (en) 2011-08-29 2015-06-09 Ethox Chemicals Llc Reactive surfactants for emulsion polymerization, pigment dispersion, and UV coatings
ES2554951T5 (es) * 2011-09-13 2019-07-18 Lubrizol Advanced Mat Inc Micro-geles polimerizados en dispersión con respuesta frente a tensioactivos
KR101963693B1 (ko) * 2011-09-13 2019-03-29 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 계면활성제 반응성 마이크로-겔
CN104053723B (zh) * 2011-10-21 2017-10-13 埃瑟克斯化学有限责任公司 用于冻融稳定乳液聚合物的新型反应性表面活性剂以及包含其的涂料
US9579272B2 (en) * 2012-06-15 2017-02-28 Lubrizol Advanced Materials, Inc. Alkyl glycoside-based micellar thickeners for surfactant systems
US20160304646A1 (en) * 2013-12-17 2016-10-20 Lubrizol Advanced Materials, Inc. Surfactant Responsive Emulsion Polymerization Micro-Gels
CN107072910A (zh) * 2014-08-28 2017-08-18 路博润先进材料公司 调理组合物
JP2018505252A (ja) * 2014-12-17 2018-02-22 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド 界面活性剤応答性乳化重合マイクロゲル

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US20190345282A1 (en) 2019-11-14
US11254766B2 (en) 2022-02-22
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JP7328893B2 (ja) 2023-08-17
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WO2018118679A1 (en) 2018-06-28
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