CN110435318A - A kind of sphere curved surface printing technology - Google Patents
A kind of sphere curved surface printing technology Download PDFInfo
- Publication number
- CN110435318A CN110435318A CN201810410248.3A CN201810410248A CN110435318A CN 110435318 A CN110435318 A CN 110435318A CN 201810410248 A CN201810410248 A CN 201810410248A CN 110435318 A CN110435318 A CN 110435318A
- Authority
- CN
- China
- Prior art keywords
- layer
- curved surface
- sphere curved
- printing
- die head
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/40—Printing on bodies of particular shapes, e.g. golf balls, candles, wine corks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0054—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or film forming compositions cured by thermal means, e.g. infrared radiation, heat
Abstract
The present invention provides a kind of sphere curved surface printing technologies; by carrying out spraying pretreatment layer to sphere curved surface substrate; then apply printing layer on pretreatment layer surface again; the finally spraying protective layer in printing layer; by applying pretreatment layer to sphere curved surface substrate, the affinity of printing layer and sphere curved surface substrate is improved, to improve printing effect; and apply protective layer in printing layer, to improve the wear-resisting property and weather resistance of printed matter;The product prepared by this technique, such as sports are ball, and the mark for being able to maintain ball surface has good wearability, peel resistance and durability, are able to maintain use for a long time and do not scratch, colour-fast, do not fall.
Description
Technical field
The present invention relates to printed matter manufacturing fields, more particularly to a kind of sphere curved surface printing technology.
Background technique
The printed matter of sphere curved surface has that printing difficulty is big, and printed matter is easy to fall off due to the shape of substrate.Especially body
Educate sports globoid, due to use during often grazing, the printing information of spherome surface is difficult to keep, existing in order to overcome
There is the above problem in technology, the present invention provides a kind of sphere curved surface printing technology, the sports ball prepared by this technique
The printing layer of body, spherome surface has stable connection, and wear-resisting, the performances such as resistance to oxidation, the mark for being able to maintain ball surface has
Good wearability, peel resistance and durability are able to maintain use for a long time and do not scratch, colour-fast, do not fall.
Summary of the invention
The present invention provides a kind of sphere curved surface printing technologies, by carrying out spraying pretreatment layer to sphere curved surface substrate,
Then apply printing layer on pretreatment layer surface again, finally in the spraying protective layer in printing layer, by sphere curved surface substrate
Apply pretreatment layer, the affinity of printing layer and sphere curved surface substrate is improved, to improve printing effect, and in printing layer
Apply protective layer, to improve the wear-resisting property and weather resistance of printed matter.
Specific scheme is as follows:
A kind of sphere curved surface printing technology, including following steps:
1) pretreating agent, the pre- place the step of, spraying pretreatment layer: are sprayed to the region to be printed of sphere curved surface substrate
Reason agent is the polymethyl of the polyacrylic acid containing 3-5wt%, the N.N- double hydroxyethyl alkylamide of 1-3wt%, 4-8wt%
The alcoholic solution of the carboxymethyl cellulose of acid esters, the polyamide wax of 1-2wt% and 3-5wt%;It is done in room temperature under 40 degrees Celsius
It is dry, obtain pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described
Above intaglio plate, presses down on the rubber die head and obtain ink, be then moved to above sphere curved surface substrate, press down on
So that the rubber die head deformation is surrounded the region to be printed of the substrate surface, transfers the ink to the pretreatment layer, it is dry,
Printing layer is obtained, wherein the radius of curvature of the sphere curved surface substrate is R, the radius of curvature of the rubber die head is R1,3R≤
R1≤6R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation
20-50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20-25wt%,
The butyl acrylate of 15-20wt%, the Kynoar of 3-5wt%, the alcoholic solution of the dodecyl sodium sulfate of 2-3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3, dry, institute
Stating surface protection paint is the dimethyl diphenyl polysiloxanes containing 10-15wt%, the dodecyl sodium sulfate of 3-8wt%, 4-
The alcoholic solution of the Kynoar of 6wt% and the nano silica of 2-4wt% or titanium dioxide.
Further, wherein the viscosity of the ink is 20-100Pas, further preferred 40-60Pas.
Further, dry 5-30min in the step 1.
Further, wherein the drying temperature in the step 2 is room temperature.
Further, wherein the alcohol is selected from ethylene glycol, propylene glycol.
Further, the sphere curved surface substrate is sports globoid, is further selected from basketball, football, vollyball, olive
Olive ball.
The invention has the following beneficial effects:
1, apply pretreatment layer, the resistance to corrosion of substrate is improved by spraying pretreating agent, is added and scratches in pretreatment layer
Property agent, improve the binding ability of pretreatment layer and spherical surface, while pretreatment layer and ink have better affinity, can be improved
The binding ability of ink layer and substrate;
2, using flexible inflatable rubber die head, die head deformation it can be completely covered in printing and be bonded song to be printed
Face, improves the printing effect of curved surface, and die head curvature diameter ensure that mould between the curvature diameter of 3-6 times of brushware to be printed
Head comes into full contact with curved surface to be printed;
3, the first protective layer light transmittance is high, is able to maintain the visibility of printing layer, and oxidative resistance with higher,
Corrosion resistance and caking property, enhanced protection layer adhesive force is strong, not easy to crack and fall off, and printing layer can be effectively protected;
4, it joined nano-oxide particles and siloxanes in the second protective layer, wear-resisting property with higher and have
Lower interfacial energy can be improved the wearability and stain resistance on printed matter surface, make the printing of ball product surface
Layer can keep visual in prolonged use, do not scratch, do not fall off.
Specific embodiment
The present invention will be described in more detail below by specific embodiment, but protection scope of the present invention not by
It is limited to these embodiments.
Embodiment 1
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed
Agent be the polyacrylic acid containing 3wt%, the N.N- double hydroxyethyl alkylamide of 1wt%, 4wt% polymethacrylates,
The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 3wt% of 1wt%;It is dried at room temperature for 30min, obtains pre- place
Manage layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described
Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 20Pas ink, is then moved to sphere curved surface substrate
Top presses down on the region to be printed for making the rubber die head deformation surround the substrate surface, transfers the ink to described
Pretreatment layer, drying at room temperature 10min, obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber
The radius of curvature of die head is R1,3R=R1;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation
50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20wt%, 15wt%
Butyl acrylate, the Kynoar of 3wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 2wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius
Dry 30min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 10wt%, the dodecyl of 3wt%
Sodium sulfonate, the ethylene glycol solution of the nano silica of the Kynoar and 2wt% of 4wt%.
Embodiment 2
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed
Agent be the polyacrylic acid containing 5wt%, the N.N- double hydroxyethyl alkylamide of 3wt%, 8wt% polymethacrylates,
The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 5wt% of 2wt%;Dry 5min, obtains pre- under 40 degrees Celsius
Process layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described
Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 100Pas ink, is then moved to sphere curved surface base
Above material, the region to be printed for making the rubber die head deformation surround the substrate surface is pressed down on, institute is transferred the ink to
Pretreatment layer is stated, drying at room temperature 5min obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber
The radius of curvature of die head is R1, R1=6R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation
50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 25wt%, 20wt%
Butyl acrylate, the Kynoar of 5wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius
Dry 20min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 15wt%, the dodecyl of 8wt%
Sodium sulfonate, the ethylene glycol solution of the nano silica of the Kynoar and 4wt% of 6wt%.
Embodiment 3
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed
Agent be the polyacrylic acid containing 4wt%, the N.N- double hydroxyethyl alkylamide of 2wt%, 6wt% polymethacrylates,
The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 4wt% of 2wt%;Dry 10min, obtains under 30 degrees Celsius
Pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described
Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 40Pas ink, is then moved to sphere curved surface substrate
Top presses down on the region to be printed for making the rubber die head deformation surround the substrate surface, transfers the ink to described
Pretreatment layer, drying at room temperature 10min, obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber
The radius of curvature of die head is R1, R1=4R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation
30s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20wt%, 20wt%
Butyl acrylate, the Kynoar of 4wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius
Dry 25min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 13wt%, the dodecyl of 5wt%
Sodium sulfonate, the ethylene glycol solution of the nano silica of the Kynoar and 3wt% of 5wt%.
Embodiment 4
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed
Agent be the polyacrylic acid containing 4wt%, the N.N- double hydroxyethyl alkylamide of 2wt%, 6wt% polymethacrylates,
The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 4wt% of 2wt%;Dry 10min, obtains under 30 degrees Celsius
Pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described
Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 60Pas ink, is then moved to sphere curved surface substrate
Top presses down on the region to be printed for making the rubber die head deformation surround the substrate surface, transfers the ink to described
Pretreatment layer, drying at room temperature 10min, obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber
The radius of curvature of die head is R1, R1=5R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation
40s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 25wt%, 15wt%
Butyl acrylate, the Kynoar of 5wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius
Dry 30min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 10wt%, the dodecyl of 8wt%
Sodium sulfonate, the ethylene glycol solution of the nano-titanium dioxide of the Kynoar and 4wt% of 5t%.
Experiment and result
The basketball printed matter that embodiment 1-4 is obtained is placed in 2 meters of diameter of rotating kettle with a small amount of sandy soil, revolving speed is
30r/min rotates 30h, imitates outdoor service condition, checks the abrasion condition of ball surface marker.
Table 1
Embodiment | Indicate abrasion condition |
1 | Mild wear, identification are clear |
2 | Mild wear, identification are clear |
3 | Mild wear, identification are clear |
4 | Mild wear, identification are clear |
The ball product of printing being prepared using technique of the invention, have good wearability, peel resistance and
Durability is able to maintain use for a long time and does not scratch, colour-fast, does not fall.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it would be recognized that above-mentioned
Description be not considered as limitation of the present invention.
Claims (6)
1. a kind of sphere curved surface printing technology, including following steps:
1) pretreating agent, the pretreating agent the step of, spraying pretreatment layer: are sprayed to the region to be printed of sphere curved surface substrate
For the polyacrylic acid containing 3-5wt%, the N.N- double hydroxyethyl alkylamide of 1-3wt%, 4-8wt% polymethylacrylic acid
The alcoholic solution of the carboxymethyl cellulose of ester, the polyamide wax of 1-2wt% and 3-5wt%;In room temperature to dry under 40 degrees Celsius,
Obtain pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, and spherical inflating rubber die head is moved to the intaglio plate
Top presses down on the rubber die head and obtains ink, is then moved to above sphere curved surface substrate, and downward push makes institute
The region to be printed that the substrate surface is surrounded in the deformation of rubber die head is stated, the pretreatment layer is transferred the ink to, it is dry, it obtains
Printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the radius of curvature of the rubber die head is R1,3R≤R1≤
6R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 20-
50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20-25wt%, 15-
The butyl acrylate of 20wt%, the Kynoar of 3-5wt%, the alcoholic solution of the dodecyl sodium sulfate of 2-3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3, dry, the table
Face protective paint is the dimethyl diphenyl polysiloxanes containing 10-15wt%, the dodecyl sodium sulfate of 3-8wt%, 4-6wt%
Kynoar and 2-4wt% nano silica or titanium dioxide alcoholic solution.
2. technique as described in claim 1, wherein the viscosity of the ink is 20-100Pas, further preferred 40-
60Pa·s。
3. technique as described in claim 1, dry 5-30min in the step 1.
4. technique as described in claim 1, wherein the drying temperature in the step 2 is room temperature.
5. technique as described in claim 1, wherein the alcohol is selected from ethylene glycol, propylene glycol.
6. technique as described in claim 1, the sphere curved surface substrate is sports globoid, is further selected from basketball,
Football, vollyball, rugby.
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CN201810410248.3A CN110435318B (en) | 2018-05-02 | 2018-05-02 | Spherical curved surface printing process |
Applications Claiming Priority (1)
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CN201810410248.3A CN110435318B (en) | 2018-05-02 | 2018-05-02 | Spherical curved surface printing process |
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CN110435318A true CN110435318A (en) | 2019-11-12 |
CN110435318B CN110435318B (en) | 2020-11-10 |
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Address after: 325000 room 2401-1, building 3, haijingjiayuan, Wangjiang West Road, Lucheng District, Wenzhou City, Zhejiang Province Applicant after: WENZHOU KULE TABLEWARE Co.,Ltd. Address before: 325000 workshop 3, No. 386, Binhai 21 Road, Wenzhou Economic and Technological Development Zone, Wenzhou City, Zhejiang Province Applicant before: WENZHOU KULE TABLEWARE Co.,Ltd. |
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GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20201110 |