CN110435318A - A kind of sphere curved surface printing technology - Google Patents

A kind of sphere curved surface printing technology Download PDF

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Publication number
CN110435318A
CN110435318A CN201810410248.3A CN201810410248A CN110435318A CN 110435318 A CN110435318 A CN 110435318A CN 201810410248 A CN201810410248 A CN 201810410248A CN 110435318 A CN110435318 A CN 110435318A
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CN
China
Prior art keywords
layer
curved surface
sphere curved
printing
die head
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810410248.3A
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Chinese (zh)
Other versions
CN110435318B (en
Inventor
庄超然
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wenzhou Kule Dining-Table Articles Co Ltd
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Wenzhou Kule Dining-Table Articles Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wenzhou Kule Dining-Table Articles Co Ltd filed Critical Wenzhou Kule Dining-Table Articles Co Ltd
Priority to CN201810410248.3A priority Critical patent/CN110435318B/en
Publication of CN110435318A publication Critical patent/CN110435318A/en
Application granted granted Critical
Publication of CN110435318B publication Critical patent/CN110435318B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/40Printing on bodies of particular shapes, e.g. golf balls, candles, wine corks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0054After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or film forming compositions cured by thermal means, e.g. infrared radiation, heat

Abstract

The present invention provides a kind of sphere curved surface printing technologies; by carrying out spraying pretreatment layer to sphere curved surface substrate; then apply printing layer on pretreatment layer surface again; the finally spraying protective layer in printing layer; by applying pretreatment layer to sphere curved surface substrate, the affinity of printing layer and sphere curved surface substrate is improved, to improve printing effect; and apply protective layer in printing layer, to improve the wear-resisting property and weather resistance of printed matter;The product prepared by this technique, such as sports are ball, and the mark for being able to maintain ball surface has good wearability, peel resistance and durability, are able to maintain use for a long time and do not scratch, colour-fast, do not fall.

Description

A kind of sphere curved surface printing technology
Technical field
The present invention relates to printed matter manufacturing fields, more particularly to a kind of sphere curved surface printing technology.
Background technique
The printed matter of sphere curved surface has that printing difficulty is big, and printed matter is easy to fall off due to the shape of substrate.Especially body Educate sports globoid, due to use during often grazing, the printing information of spherome surface is difficult to keep, existing in order to overcome There is the above problem in technology, the present invention provides a kind of sphere curved surface printing technology, the sports ball prepared by this technique The printing layer of body, spherome surface has stable connection, and wear-resisting, the performances such as resistance to oxidation, the mark for being able to maintain ball surface has Good wearability, peel resistance and durability are able to maintain use for a long time and do not scratch, colour-fast, do not fall.
Summary of the invention
The present invention provides a kind of sphere curved surface printing technologies, by carrying out spraying pretreatment layer to sphere curved surface substrate, Then apply printing layer on pretreatment layer surface again, finally in the spraying protective layer in printing layer, by sphere curved surface substrate Apply pretreatment layer, the affinity of printing layer and sphere curved surface substrate is improved, to improve printing effect, and in printing layer Apply protective layer, to improve the wear-resisting property and weather resistance of printed matter.
Specific scheme is as follows:
A kind of sphere curved surface printing technology, including following steps:
1) pretreating agent, the pre- place the step of, spraying pretreatment layer: are sprayed to the region to be printed of sphere curved surface substrate Reason agent is the polymethyl of the polyacrylic acid containing 3-5wt%, the N.N- double hydroxyethyl alkylamide of 1-3wt%, 4-8wt% The alcoholic solution of the carboxymethyl cellulose of acid esters, the polyamide wax of 1-2wt% and 3-5wt%;It is done in room temperature under 40 degrees Celsius It is dry, obtain pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described Above intaglio plate, presses down on the rubber die head and obtain ink, be then moved to above sphere curved surface substrate, press down on So that the rubber die head deformation is surrounded the region to be printed of the substrate surface, transfers the ink to the pretreatment layer, it is dry, Printing layer is obtained, wherein the radius of curvature of the sphere curved surface substrate is R, the radius of curvature of the rubber die head is R1,3R≤ R1≤6R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 20-50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20-25wt%, The butyl acrylate of 15-20wt%, the Kynoar of 3-5wt%, the alcoholic solution of the dodecyl sodium sulfate of 2-3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3, dry, institute Stating surface protection paint is the dimethyl diphenyl polysiloxanes containing 10-15wt%, the dodecyl sodium sulfate of 3-8wt%, 4- The alcoholic solution of the Kynoar of 6wt% and the nano silica of 2-4wt% or titanium dioxide.
Further, wherein the viscosity of the ink is 20-100Pas, further preferred 40-60Pas.
Further, dry 5-30min in the step 1.
Further, wherein the drying temperature in the step 2 is room temperature.
Further, wherein the alcohol is selected from ethylene glycol, propylene glycol.
Further, the sphere curved surface substrate is sports globoid, is further selected from basketball, football, vollyball, olive Olive ball.
The invention has the following beneficial effects:
1, apply pretreatment layer, the resistance to corrosion of substrate is improved by spraying pretreating agent, is added and scratches in pretreatment layer Property agent, improve the binding ability of pretreatment layer and spherical surface, while pretreatment layer and ink have better affinity, can be improved The binding ability of ink layer and substrate;
2, using flexible inflatable rubber die head, die head deformation it can be completely covered in printing and be bonded song to be printed Face, improves the printing effect of curved surface, and die head curvature diameter ensure that mould between the curvature diameter of 3-6 times of brushware to be printed Head comes into full contact with curved surface to be printed;
3, the first protective layer light transmittance is high, is able to maintain the visibility of printing layer, and oxidative resistance with higher, Corrosion resistance and caking property, enhanced protection layer adhesive force is strong, not easy to crack and fall off, and printing layer can be effectively protected;
4, it joined nano-oxide particles and siloxanes in the second protective layer, wear-resisting property with higher and have Lower interfacial energy can be improved the wearability and stain resistance on printed matter surface, make the printing of ball product surface Layer can keep visual in prolonged use, do not scratch, do not fall off.
Specific embodiment
The present invention will be described in more detail below by specific embodiment, but protection scope of the present invention not by It is limited to these embodiments.
Embodiment 1
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed Agent be the polyacrylic acid containing 3wt%, the N.N- double hydroxyethyl alkylamide of 1wt%, 4wt% polymethacrylates, The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 3wt% of 1wt%;It is dried at room temperature for 30min, obtains pre- place Manage layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 20Pas ink, is then moved to sphere curved surface substrate Top presses down on the region to be printed for making the rubber die head deformation surround the substrate surface, transfers the ink to described Pretreatment layer, drying at room temperature 10min, obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber The radius of curvature of die head is R1,3R=R1;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20wt%, 15wt% Butyl acrylate, the Kynoar of 3wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 2wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius Dry 30min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 10wt%, the dodecyl of 3wt% Sodium sulfonate, the ethylene glycol solution of the nano silica of the Kynoar and 2wt% of 4wt%.
Embodiment 2
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed Agent be the polyacrylic acid containing 5wt%, the N.N- double hydroxyethyl alkylamide of 3wt%, 8wt% polymethacrylates, The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 5wt% of 2wt%;Dry 5min, obtains pre- under 40 degrees Celsius Process layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 100Pas ink, is then moved to sphere curved surface base Above material, the region to be printed for making the rubber die head deformation surround the substrate surface is pressed down on, institute is transferred the ink to Pretreatment layer is stated, drying at room temperature 5min obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber The radius of curvature of die head is R1, R1=6R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 25wt%, 20wt% Butyl acrylate, the Kynoar of 5wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius Dry 20min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 15wt%, the dodecyl of 8wt% Sodium sulfonate, the ethylene glycol solution of the nano silica of the Kynoar and 4wt% of 6wt%.
Embodiment 3
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed Agent be the polyacrylic acid containing 4wt%, the N.N- double hydroxyethyl alkylamide of 2wt%, 6wt% polymethacrylates, The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 4wt% of 2wt%;Dry 10min, obtains under 30 degrees Celsius Pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 40Pas ink, is then moved to sphere curved surface substrate Top presses down on the region to be printed for making the rubber die head deformation surround the substrate surface, transfers the ink to described Pretreatment layer, drying at room temperature 10min, obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber The radius of curvature of die head is R1, R1=4R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 30s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20wt%, 20wt% Butyl acrylate, the Kynoar of 4wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius Dry 25min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 13wt%, the dodecyl of 5wt% Sodium sulfonate, the ethylene glycol solution of the nano silica of the Kynoar and 3wt% of 5wt%.
Embodiment 4
1) pretreating agent, the pretreatment the step of, spraying pretreatment layer: are sprayed to the region to be printed of basketball to be printed Agent be the polyacrylic acid containing 4wt%, the N.N- double hydroxyethyl alkylamide of 2wt%, 6wt% polymethacrylates, The ethylene glycol solution of the carboxymethyl cellulose of the polyamide wax and 4wt% of 2wt%;Dry 10min, obtains under 30 degrees Celsius Pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, spherical inflating rubber die head is moved to described Above intaglio plate, pressing down on the rubber die head and obtaining viscosity is 60Pas ink, is then moved to sphere curved surface substrate Top presses down on the region to be printed for making the rubber die head deformation surround the substrate surface, transfers the ink to described Pretreatment layer, drying at room temperature 10min, obtains printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the rubber The radius of curvature of die head is R1, R1=5R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 40s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 25wt%, 15wt% Butyl acrylate, the Kynoar of 5wt%, the ethylene glycol solution of the dodecyl sodium sulfate of 3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3,40 is Celsius Dry 30min is spent, the surface protection paint is the dimethyl diphenyl polysiloxanes containing 10wt%, the dodecyl of 8wt% Sodium sulfonate, the ethylene glycol solution of the nano-titanium dioxide of the Kynoar and 4wt% of 5t%.
Experiment and result
The basketball printed matter that embodiment 1-4 is obtained is placed in 2 meters of diameter of rotating kettle with a small amount of sandy soil, revolving speed is 30r/min rotates 30h, imitates outdoor service condition, checks the abrasion condition of ball surface marker.
Table 1
Embodiment Indicate abrasion condition
1 Mild wear, identification are clear
2 Mild wear, identification are clear
3 Mild wear, identification are clear
4 Mild wear, identification are clear
The ball product of printing being prepared using technique of the invention, have good wearability, peel resistance and Durability is able to maintain use for a long time and does not scratch, colour-fast, does not fall.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it would be recognized that above-mentioned Description be not considered as limitation of the present invention.

Claims (6)

1. a kind of sphere curved surface printing technology, including following steps:
1) pretreating agent, the pretreating agent the step of, spraying pretreatment layer: are sprayed to the region to be printed of sphere curved surface substrate For the polyacrylic acid containing 3-5wt%, the N.N- double hydroxyethyl alkylamide of 1-3wt%, 4-8wt% polymethylacrylic acid The alcoholic solution of the carboxymethyl cellulose of ester, the polyamide wax of 1-2wt% and 3-5wt%;In room temperature to dry under 40 degrees Celsius, Obtain pretreatment layer;
2), sphere curved surface print steps: tile ink on printing gravure, and spherical inflating rubber die head is moved to the intaglio plate Top presses down on the rubber die head and obtains ink, is then moved to above sphere curved surface substrate, and downward push makes institute The region to be printed that the substrate surface is surrounded in the deformation of rubber die head is stated, the pretreatment layer is transferred the ink to, it is dry, it obtains Printing layer, wherein the radius of curvature of the sphere curved surface substrate is R, the radius of curvature of the rubber die head is R1,3R≤R1≤ 6R;
3), spray the first protective layer step: the printing layer surface that step 2 obtains sprays the first protective paint, ultraviolet light irradiation 20- 50s obtains the first protective layer;First protective paint is the urethane methacrylate containing chlorine containing 20-25wt%, 15- The butyl acrylate of 20wt%, the Kynoar of 3-5wt%, the alcoholic solution of the dodecyl sodium sulfate of 2-3wt%;
4) it, sprays the second protective layer step: spraying the second protective paint to the first protective layer in step 3, dry, the table Face protective paint is the dimethyl diphenyl polysiloxanes containing 10-15wt%, the dodecyl sodium sulfate of 3-8wt%, 4-6wt% Kynoar and 2-4wt% nano silica or titanium dioxide alcoholic solution.
2. technique as described in claim 1, wherein the viscosity of the ink is 20-100Pas, further preferred 40- 60Pa·s。
3. technique as described in claim 1, dry 5-30min in the step 1.
4. technique as described in claim 1, wherein the drying temperature in the step 2 is room temperature.
5. technique as described in claim 1, wherein the alcohol is selected from ethylene glycol, propylene glycol.
6. technique as described in claim 1, the sphere curved surface substrate is sports globoid, is further selected from basketball, Football, vollyball, rugby.
CN201810410248.3A 2018-05-02 2018-05-02 Spherical curved surface printing process Expired - Fee Related CN110435318B (en)

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CN110435318B CN110435318B (en) 2020-11-10

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CN104527249A (en) * 2014-11-21 2015-04-22 杭州中粮包装有限公司 Partial pearly luster mixing metal printing method
CN204605088U (en) * 2015-04-23 2015-09-02 曹小静 A kind of wear-resisting artificial stereo graining film
CN105925152A (en) * 2016-05-09 2016-09-07 江苏凯特尔新型复合饰材有限公司 Production process of metal printing plate roll coated with nano ceramic paint in advance
CN106519796A (en) * 2016-12-13 2017-03-22 永发印务(东莞)有限公司 Water-borne transparent oil with high scratch resistance and preparing method thereof
CN206383684U (en) * 2017-01-16 2017-08-08 南阳九鼎材料科技股份有限公司 A kind of ink jet printing film
CN107571654A (en) * 2017-08-31 2018-01-12 广东星弛光电科技有限公司 A kind of printing process of cambered surface color crystal glass
CN206934642U (en) * 2017-06-27 2018-01-30 江苏道尔体育科技有限公司 A kind of high intensity skins of balls
CN207291374U (en) * 2016-05-30 2018-05-01 旭硝子株式会社 Plate and display device with printing layer

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0756947A2 (en) * 1995-05-11 1997-02-05 Unice, S.A. Method for printing balls with designs visible independently from inside and outside the balls, and balls produced by said method
JP2000094638A (en) * 1998-09-21 2000-04-04 Fujitsu Takamisawa Component Ltd Method for printing in pad transfer type, key top and method for indicating it and printing
CN101007475A (en) * 2006-01-27 2007-08-01 上海伊诺特玩具有限公司 Spherical/special-shaped product all-print printing process and apparatus
CN101600578A (en) * 2006-11-22 2009-12-09 普拉斯蒂派克包装公司 Digital printing plastic containers
CN101565570A (en) * 2008-04-22 2009-10-28 中国科学院过程工程研究所 Composite latex for paints, water paint and preparation method of water paint
CN201533971U (en) * 2009-04-22 2010-07-28 福建元吉体育用品有限公司(外资企业) Ball with pattern or trademark as textile form
CN101580570A (en) * 2009-06-17 2009-11-18 厦门大学 Siloxane-acrylate copolymer/nano-silicon dioxide organic/inorganic hybrid nano-material and preparation method thereof
CN101955728A (en) * 2009-07-17 2011-01-26 黄祥道 Organic-inorganic hybrid wear-resistant transparent coating for reinforcing surface of optical plastics
JP2011104162A (en) * 2009-11-18 2011-06-02 Sony Corp Soccer ball
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CN103614948A (en) * 2013-11-28 2014-03-05 金华盛纸业(苏州工业园区)有限公司 Antibacterial chromo board coating and antibacterial chromo board
CN104527249A (en) * 2014-11-21 2015-04-22 杭州中粮包装有限公司 Partial pearly luster mixing metal printing method
CN204605088U (en) * 2015-04-23 2015-09-02 曹小静 A kind of wear-resisting artificial stereo graining film
CN105925152A (en) * 2016-05-09 2016-09-07 江苏凯特尔新型复合饰材有限公司 Production process of metal printing plate roll coated with nano ceramic paint in advance
CN207291374U (en) * 2016-05-30 2018-05-01 旭硝子株式会社 Plate and display device with printing layer
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CN206383684U (en) * 2017-01-16 2017-08-08 南阳九鼎材料科技股份有限公司 A kind of ink jet printing film
CN206934642U (en) * 2017-06-27 2018-01-30 江苏道尔体育科技有限公司 A kind of high intensity skins of balls
CN107571654A (en) * 2017-08-31 2018-01-12 广东星弛光电科技有限公司 A kind of printing process of cambered surface color crystal glass

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