CN110415998A - A kind of overload-resistant impact can energy storage sensor - Google Patents

A kind of overload-resistant impact can energy storage sensor Download PDF

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Publication number
CN110415998A
CN110415998A CN201910600127.XA CN201910600127A CN110415998A CN 110415998 A CN110415998 A CN 110415998A CN 201910600127 A CN201910600127 A CN 201910600127A CN 110415998 A CN110415998 A CN 110415998A
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CN
China
Prior art keywords
metal oxide
collector
energy storage
overload
oxide collector
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CN201910600127.XA
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Chinese (zh)
Inventor
王晓峰
周雷臻
李滨
戴伟
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Tsinghua Research Institute Of Pearl River Delta
Guangzhou Guanghua Fine Energy Technology Co Ltd
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Tsinghua Research Institute Of Pearl River Delta
Guangzhou Guanghua Fine Energy Technology Co Ltd
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Priority to CN201910600127.XA priority Critical patent/CN110415998A/en
Publication of CN110415998A publication Critical patent/CN110415998A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/04Hybrid capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/08Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66Current collectors
    • H01G11/68Current collectors characterised by their material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66Current collectors
    • H01G11/70Current collectors characterised by their structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/78Cases; Housings; Encapsulations; Mountings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/78Cases; Housings; Encapsulations; Mountings
    • H01G11/80Gaskets; Sealings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

The invention discloses a kind of overload-resistant impact can energy storage sensor, including capacitor core and shell, in the shell by high-intensity resin encapsulating, the material of shell is hard metal material to capacitor core;Capacitor core includes: that the first metal oxide collector, the first elastic support, vacuum liquid-absorbing module, the second elastic support and the second metal oxide collector pass sequentially through stacked in layers and connect to obtain laminated structure;Energy-storage module is filled in inside elastomeric objects, energy-storage module includes the first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and the second elastic piezoresistive electrodes, and the first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and the second elastic piezoresistive electrodes pass sequentially through stacked in layers and connect to obtain laminated structure;Vacuum liquid-absorbing module includes that third metal oxide collector, the 4th metal oxide collector pass sequentially through stacked in layers with fifth metal oxide collector and connect to obtain laminated structure.

Description

A kind of overload-resistant impact can energy storage sensor
Technical field
The present invention relates to new material and field of new energy technologies more particularly to a kind of overload-resistant impact can energy storage sensing Device.
Background technique
Current most popular four kinds of sensors, comprising: 1. piezoelectric transducers are fixed by PVDF diaphragm by certain It is internal just to generate polarization when the effect of direction external force, while the opposite charge of symbol, shape are generated on certain two surface At certain potential difference, cause voltage change, realizes sensing function;2. piezoresistive transducer, elastic piezoresistive electrodes are by external force Effect when, thickness of electrode can change, and electrode resistance can mutate, cause voltage change, realize sensing function;3. Capacitance type sensor causes the variation of condenser capacity, reaches the mesh of voltage change by changing the spacing between capacitor plate , realize sensing function;4. electrochemical transducer[sensor uses an electrolyte as inertia mass, attached in electrode when being impacted It is close to form convection current, cause the variation of ion concentration near electrode, and then form voltage change, realizes sensing function.
Above-mentioned four kinds of sensors only have sensing function, without having energy storage capacity and power capability, are needing simultaneously In the case where having energy storage and sensing function, generallys use traditional sensors part and energize the shared mode of device, this method It will lead to that system bulk is larger, be unfavorable for whole miniaturization, and this sensor with sensing function is in high overload It is easy that sensing failure occurs because each section impact resistance is poor under impact condition.
Therefore, need at present it is a kind of with energy storage and power capability can energy storage sensor, realize that sensor is provided simultaneously with There is high impact-resistance in the case where energy storage and sensing function.
Summary of the invention
The present invention provides a kind of overload-resistant impact can energy storage sensor, do not have energy storage to solve existing sensor Ability and power capability, and the technical problem of impact resistance difference, so that energy storage and biography can be achieved at the same time by constructing one kind Feel function without external battery can energy storage sensor, and use hard metal shell and high-intensity resin encapsulating, it is real Showed can energy storage sensor under high overload impact condition can resistance, enhance anti-shot ability.
In order to solve the above-mentioned technical problem, the embodiment of the invention provides a kind of overload-resistant impact can energy storage sensor, Including capacitor core and shell, the capacitor core passes through high-intensity resin encapsulating in the housing, the material of the shell For hard metal material;
The capacitor core includes: the first metal oxide collector, the first elastic support, vacuum liquid-absorbing module, Two elastic supports and the second metal oxide collector;The first metal oxide collector, first resilient support Body, the vacuum liquid-absorbing module, second elastic support and the second metal oxide collector pass sequentially through stratiform It stacks connection and obtains laminated structure;The elastic support includes elastomeric objects and energy-storage module, the energy-storage module filling Inside the elastomeric objects, the energy-storage module includes the first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and second Elastic piezoresistive electrodes, the described first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and the second elastic pressure drag electricity Pole passes sequentially through stacked in layers and obtains laminated structure;The vacuum liquid-absorbing module includes third metal oxide collector, Four metal oxide collectors and fifth metal oxide collector, the third metal oxide collector, the 4th gold medal Category oxide collector passes sequentially through stacked in layers with the fifth metal oxide collector and connects to obtain laminated structure.
Preferably, between the first metal oxide collector and first elastic support, described Between one elastic support and the vacuum liquid-absorbing module, between the vacuum liquid-absorbing module and second elastic support, And between second elastic support and the second metal oxide collector, bonding formation is carried out by adhesive Point glue-line.
Preferably, between the third metal oxide collector and the 4th metal oxide collector, Between the 4th metal oxide collector and the fifth metal oxide collector, bonding shape is carried out by adhesive At a glue-line.
Preferably, between the third metal oxide collector and the 4th metal oxide collector The second dispensing between first glue-line and the 4th metal oxide collector and the fifth metal oxide collector Layer, all has notch.
Preferably, the notch on first glue-line and the direction of the gap position on the second point glue-line one It causes.
Preferably, the third metal oxide collector and the fifth metal oxide collector are ring Shape structure;The 4th metal oxide collector is laminated structure.
Preferably, the elastomeric objects are ring structure.
Preferably, the shape of the supercapacitor includes round, rectangular, triangle or various obform bodies.
Preferably, the elastic support and the vacuum liquid-absorbing module by the increase of internal series-connection quantity and It reduces, the operating voltage and capacitance of control device, sensing scope and sensitivity can also be changed by changing internal series-connection quantity, be fitted For more application scenarios.
Compared with the prior art, the embodiment of the present invention has the following beneficial effects:
The present invention by construct it is a kind of can be achieved at the same time energy storage and sensing function without external battery can energy storage Sensor, and hard metal shell and high-intensity resin encapsulating are used, it solves existing sensor and does not have energy storage capacity and confession Can ability, and the technical problem of impact resistance difference, thus realize can energy storage sensor can under high overload impact condition Resistance enhances anti-shot ability.
Detailed description of the invention
Fig. 1: in the embodiment of the present invention can energy storage sensor overall structure diagram;
Fig. 2: for the structural schematic diagram of the energy-storage module in the embodiment of the present invention;
Fig. 3: for the structural schematic diagram of the vacuum liquid-absorbing module in the embodiment of the present invention;
Fig. 4: for the schematic illustration of the realization sensing effect in the embodiment of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Please refer to Fig. 1, the preferred embodiment of the present invention provide a kind of overload-resistant impact can energy storage sensor, including capacitor Device core and shell, in the housing by high-intensity resin encapsulating, the material of the shell is hard gold to the capacitor core Belong to material;
The capacitor core includes: the first metal oxide collector, the first elastic support, vacuum liquid-absorbing module, Two elastic supports and the second metal oxide collector;The first metal oxide collector, first resilient support Body, the vacuum liquid-absorbing module, second elastic support and the second metal oxide collector pass sequentially through stratiform It stacks connection and obtains laminated structure;The elastic support includes elastomeric objects and energy-storage module, the energy-storage module filling Inside the elastomeric objects, the energy-storage module includes the first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and second Elastic piezoresistive electrodes, the described first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and the second elastic pressure drag electricity Pole passes sequentially through stacked in layers and obtains laminated structure;The vacuum liquid-absorbing module includes third metal oxide collector, Four metal oxide collectors and fifth metal oxide collector, the third metal oxide collector, the 4th gold medal Category oxide collector passes sequentially through stacked in layers with the fifth metal oxide collector and connects to obtain laminated structure.
In the present embodiment, between the first metal oxide collector and first elastic support, described Between one elastic support and the vacuum liquid-absorbing module, between the vacuum liquid-absorbing module and second elastic support, And between second elastic support and the second metal oxide collector, bonding formation is carried out by adhesive Point glue-line.
Device is designed using laminated structure, and metal oxide collector, elastomeric objects and vacuum liquid-absorbing module are carried out Stacked in layers, interlayer are bonded using adhesive, the specific structure such as following figure, and top layer is the titanium alloy of surface sintering oxidation ruthenium film Collector, as a pole of device, next layer is annular elastomer, be piezoresistive electrodes and silver-plated PVDF inside ring-shaped rubber every Film, then lower layer are vacuum liquid-absorbing module, then lower layer is annular elastomer, and lowest level is metal oxide collector as device Another pole, adhesive bonding is all made of between each layer.
In the present embodiment, the elastomeric objects are ring structure.
Referring to figure 2., it fixing and seals by annular resilient object outside energy-storage module, inside uses laminated construction, Three layers are always divided into, upper layer is elastic piezoresistive electrodes, and middle layer is silver-plated PVDF diaphragm, and lower layer is also elastic piezoresistive electrodes, will be stored up Energy module is having inside elastomeric objects made from elastomer with this structure filling, provides the energy storage of double electric layers supercapacitor The sensing capability of ability and piezoelectric transducer and piezoresistive transducer.
In the present embodiment, between the third metal oxide collector and the 4th metal oxide collector, Between the 4th metal oxide collector and the fifth metal oxide collector, bonding shape is carried out by adhesive At a glue-line.
In the present embodiment, between the third metal oxide collector and the 4th metal oxide collector The second dispensing between first glue-line and the 4th metal oxide collector and the fifth metal oxide collector Layer, all has notch.
In the present embodiment, the notch on first glue-line and the direction of the gap position on the second point glue-line one It causes.
In the present embodiment, the third metal oxide collector and the fifth metal oxide collector are ring Shape structure;The 4th metal oxide collector is laminated structure.
Referring to figure 3., vacuum liquid-absorbing inside modules structure: top layer is closed using the titanium of annular surface sintering oxidation ruthenium film Golden collector, middle layer use sheet collector, and upper layer and middle layer are bonded using hot melt adhesive dispensing mode, and when dispensing sets One section of notch is counted out as vacuum liquid-absorbing mouth, lowest level also uses the titanium alloy collector of annular surface sintering oxidation ruthenium film, Interlayer is also bonded using jaggy glue-line, and notch direction is consistent with upper layer dispensing break mouth direction.
In the present embodiment, the shape of the supercapacitor includes round, rectangular, triangle or various obform bodies.Device Part can be made by using titanium alloy collector of different shapes, elastomer elastomeric objects, round, rectangular, triangle etc. Various shapes realize the shape customization of device.
In the present embodiment, the elastic support and the vacuum liquid-absorbing module by the increase of internal series-connection quantity and It reduces, the operating voltage and capacitance of control device, sensing scope and sensitivity can also be changed by changing internal series-connection quantity, be fitted For more application scenarios.
To adapt to different application scenarios, need to produce the device that can be used under the conditions of different voltages, the present invention Can by way of controlling internal series-connection module number control device operating voltage and capacitance, and increase can be passed through Or reduce control of the concatenated module realization to sensing measurement range
As described in Figure 4, using device when being impacted, the voltage jump of generation reaches sensing effect.In discharge process In, device is impacted, after device is impacted, whole deformation occurs, causes piezoelectricity, pressure drag, capacitor, electric chemical formula sensing principle Response forms voltage jump, reaches sensing effect.
Supercapacitor of the present invention realize energy storage device from sensing function, by using pressure drag in supercapacitor Formula active carbon elasticity piezoresistive electrodes and silver-plated PVDF diaphragm realize pressure drag and piezoelectric type sensing function, and using elastomeric objects by Internal flow to change in shape and electrolyte when impact realizes condenser type and electric chemical formula sensing function.
Supercapacitor of the present invention also achieves the self-powered function of senser element, by inside using activated carbon electrodes Laminated structure realizes the energy storage of double electric layers supercapacitor, there is the RuO of oxidation ruthenium film by using surface2/H2SO4Body System and inside realize the energy storage of fake capacitance supercapacitor from concatenated laminated construction.
Supercapacitor of the present invention also achieves the continuous sensitive response to the impact of high frequency high overload;It realizes and passes through pole piece The different selections of diaphragm, using different energy storage or sensing principle;The shape for realizing device special-shaped can customize, using not similar shape Device can be made into different shape by the metal oxide collector and rubber washer of shape, be applicable in different application scenarios and environment; Freely adjusting for the voltage of device is realized, the requirement under multiple power sources environment is met, by being gone here and there certainly inside control device The flexible modulation for using device voltage and capacitance may be implemented in the amount of monomer of connection;Realize oneself of sensing measurement range By adjusting, meeting plurality of application scenes, being surveyed by, from concatenated amount of monomer, may be implemented to sense device inside control device Measure the flexible modulation of range;Using modularization assembling technology and continuous productive process, the small lot production of device is realized, batch is made Make elastomeric objects part, vacuum liquid-absorbing module, energy-storage module, then is successively assembled the producing efficiency, it can be achieved that high, and It can guarantee preferable stability and consistency.
Traditional sensors usually require external power supply, to maintain the energy supply of sensor and to the record of heat transfer agent and anti- Feedback, and sensor can not preferably cope with the impact signal of high frequency, may result in signal can not accurately record, " energy storage-biography The integrated supercapacitor of sense " combines the advantage of a variety of sensor mechanisms, and precision is high, and induction range is wide, and the response time is exceedingly fast, institute There is accurate, sensitive counting response ability under the conditions of high-frequency percussion with device.
Common supercapacitor or sensor are easy to send out because each section impact resistance is poor under high overload impact condition Raw failure, " energy storage-sensing " integration supercapacitor using high duty metal as support, using hard metal shell and Situations such as high-intensity resin dosing technology, leakage caused by having prevented because of impact, deformation, impacts during also achieving in high overload Under the conditions of normal, stable operation.
Flexible package technology: the flexible package method being sealed using annular elastomer circle is made using ring-shaped rubber For sealing ring, body rubber will be supported to bond and seal with collector metal using binder, so that device is in impact condition lower edge There is certain compressible ability, after removing external force, rubber rebound, device can restore to the original state, and realize device on thickness direction The capacitive sensing function of part;
Vacuum liquid-absorbing technology: using perforated metal pole piece and metal pole piece, vacuum liquid-absorbing mould is made in lamination in the way of dispensing Block, design dispensing notch realize monomer cavity intercommunication as vacuum liquid-absorbing mouth, and pole piece is fixed shares collector etc. between mould group Multiple functions;
Overload-resistant impact encapsulation technology: metal shell, in the shell with high-intensity resin encapsulating by device, Ke Yi great are used The impact resistance of width promotion device entirety;
Modularization assembling technology: device is divided into energy-storage module using the different function and usage in device part, vacuum is inhaled Liquid module and sensing module assemble by each functional module of batch making, then by each functional module, realize device Small lot is hand-made.
Metal pole piece in the present invention uses metal oxide pole piece, the active metal oxidation of metal oxide pole piece Object film, by using metal oxide pole piece, application be fake capacitance supercapacitor energy storage principle;Bullet in the present invention Property electrode use piezoresistive electrodes, wherein using the sensing principle that pressure drag senses, using piezoresistive electrodes, pass through the sensing that is pressurized;This hair Diaphragm in bright uses silver-plated PVDF diaphragm, wherein PVDF (Kynoar) has most obdurability, low friction in fluoroplastics The features such as coefficient, corrosion resistance be strong, resistance to ag(e)ing, weatherability, and radiation-resistant property is good.
The present invention produces a kind of novel micro- energy device, firstly, the device is integrated with the energy-storage function of supercapacitor With the sensing function of piezoelectric transducer, piezoresistive transducer, capacitance type sensor and electrochemical transducer[sensor, combine super The energy storage principle of capacitor and the sensing principle of sensor, by using RuO2/H2SO4Fake capacitance super capacitor system, and Active carbon/H2SO4Double electric layers supercapacitor system, to meet the application demand of device energy storage and power supply;Using silver-plated PVDF diaphragm realizes the piezoelectric sensing effect under shock environment, can polarize when the diaphragm is impacted, electronics is assembled In in the side of diaphragm, to form potential difference, lead to voltage change, realize piezoelectric sensing function;Using rubber and active carbon Funtion part of the elastic piezoresistive electrodes that electrode fabrication goes out as piezoresistive transducer, when being impacted, piezoresistive electrodes can be produced Raw deformation, the resistance value that deformation will lead to piezoresistive electrodes change, and voltage fluctuation is generated in charge and discharge process, realize that pressure drag passes Feel function, while the activated carbon electrodes also can be used as the pole piece of double electric layers supercapacitor and carry out energy storage, activated carbon electrodes can be with The zwitterion in electrolyte is adsorbed, potential difference is formed in the two sides of diaphragm, to realize energy storage;Device uses H2SO4As electricity Liquid is solved, electrolyte can be moved when being impacted along impact direction, to form certain concentration difference, device in device inside The distribution of charges that the concentration difference variation of internal partial electrolysis liquid will lead to device inside each section is uneven, is formed in device inside Potential difference leads to voltage change, to realize the electrochemical sensing function of device;Using titanium alloy as the collector of device, gold Using rubber as elastomeric objects between category oxide current collector layers, when being impacted, elastomeric objects can compress, and reduce two Spacing between collector causes the capacitance variation of capacitor, device voltage is caused to change, and realizes that the condenser type of device passes Sense.
The invention enables the dual functions that single device realizes energy storage and sensing, reduce sensing system to a certain extent The volume of system;Second, the present invention using inside the laminated type based on titanium alloy and elastomer from concatenated design method, this Kind structure farthest reduces the redundant space of device inside, and not extra gap structure avoids in impact process The mechanical failures such as solder joint failure, structural break caused by local stress is excessive, and also avoid high impact loads lower outer portion and lead Line and the possibility of circuit element failure;Third, laminated type expandable structure make device can with flexibly adjustment sensing scope and Voltage has expanded the use scope and application scenarios of device;4th, using metal shell, and high-intensity resin encapsulating is used, resisted Impact capacity is extremely strong, and the reliability of device greatly improved.
The present invention develops a novel micro- energy device, changes traditional sensors and needs by external energy supply and overload-resistant The disadvantage of impact capacity difference realizes device itself energy storage and energy supply, and improve traditional sensors not rushing in high frequency high overload Sensitive response and accurate metering problem under the conditions of hitting realize sensitive response under the conditions of the impact of high frequency high overload and accurate It counts.
Particular embodiments described above has carried out further the purpose of the present invention, technical scheme and beneficial effects It is described in detail, it should be understood that the above is only a specific embodiment of the present invention, the protection being not intended to limit the present invention Range.It particularly points out, to those skilled in the art, all within the spirits and principles of the present invention, that is done any repairs Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of overload-resistant impact can energy storage sensor, which is characterized in that including capacitor core and shell, the capacitor core In the housing by high-intensity resin encapsulating, the material of the shell is hard metal material;
The capacitor core includes: the first metal oxide collector, the first elastic support, vacuum liquid-absorbing module, the second bullet Property supporter and the second metal oxide collector;The first metal oxide collector, first elastic support, institute It states vacuum liquid-absorbing module, second elastic support and the second metal oxide collector and passes sequentially through stacked in layers company It connects to obtain laminated structure;The elastic support includes elastomeric objects and energy-storage module, and the energy-storage module is filled in described Inside elastomeric objects, the energy-storage module includes the first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and the second elasticity pressure Resistance electrode, the described first elastic piezoresistive electrodes, nano silver spraying PVDF diaphragm and the second elastic piezoresistive electrodes are successively Laminated structure is obtained by stacked in layers;The vacuum liquid-absorbing module includes third metal oxide collector, the 4th metal Oxide collector and fifth metal oxide collector, the third metal oxide collector, the 4th metal oxidation Object collector passes sequentially through stacked in layers with the fifth metal oxide collector and connects to obtain laminated structure.
2. overload-resistant impact as described in claim 1 can energy storage sensor, which is characterized in that first metal oxide Between collector and first elastic support, between first elastic support and the vacuum liquid-absorbing module, it is described Between vacuum liquid-absorbing module and second elastic support and second elastic support is aoxidized with second metal Between object collector, bonding is carried out by adhesive and forms point glue-line.
3. overload-resistant impact as described in claim 1 can energy storage sensor, which is characterized in that the third metal oxide Between collector and the 4th metal oxide collector, the 4th metal oxide collector and the fifth metal oxygen Between compound collector, bonding is carried out by adhesive and forms point glue-line.
4. overload-resistant impact as claimed in claim 3 can energy storage sensor, which is characterized in that the third metal oxide First glue-line and the 4th metal oxide collector between collector and the 4th metal oxide collector with Second point glue-line between the fifth metal oxide collector, all has notch.
5. overload-resistant impact as claimed in claim 4 can energy storage sensor, which is characterized in that on first glue-line Gap position on notch and the second point glue-line is towards unanimously.
6. overload-resistant impact as described in claim 1 can energy storage sensor, which is characterized in that the third metal oxide Collector and the fifth metal oxide collector are ring structure;The 4th metal oxide collector is sheet knot Structure.
7. overload-resistant impact as described in claim 1 can energy storage sensor, which is characterized in that the elastomeric objects are annular Structure.
8. overload-resistant impact as described in claim 1 can energy storage sensor, which is characterized in that the shape of the supercapacitor Shape includes round, rectangular, triangle or various obform bodies.
9. overload-resistant impact as described in claim 1 can energy storage sensor, which is characterized in that the elastic support and institute It states vacuum liquid-absorbing module increasing and decreasing by internal series-connection quantity, the operating voltage and capacitance of control device, in change Portion's serial number can also change sensing scope and sensitivity, be suitable for more application scenarios.
CN201910600127.XA 2019-07-04 2019-07-04 A kind of overload-resistant impact can energy storage sensor Pending CN110415998A (en)

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XIONG PU: "《Toward Wearable Self-Charging Power Systems: The Integration of Energy-Harvesting and Storage Devices》", 《REVIER》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2606707A (en) * 2021-05-03 2022-11-23 Jamieson Luke Supercapacitor and electrical system
GB2606707B (en) * 2021-05-03 2024-01-10 Jamieson Luke Supercapacitor and electrical system

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Application publication date: 20191105