CN110408465A - 一种数控机床金属加工用防锈切削液及其制备方法 - Google Patents

一种数控机床金属加工用防锈切削液及其制备方法 Download PDF

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CN110408465A
CN110408465A CN201810390704.2A CN201810390704A CN110408465A CN 110408465 A CN110408465 A CN 110408465A CN 201810390704 A CN201810390704 A CN 201810390704A CN 110408465 A CN110408465 A CN 110408465A
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cutting fluid
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颜勇
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Foshan Jiayi Agricultural Science And Technology Co Ltd
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Abstract

本发明公开了一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、消泡剂、丙烯腈、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、四氮唑、油酸、十二烷基二甲基甜菜碱、松香、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油、丙二醇、钝化液、清洁剂。本发明具有无刺激、无腐蚀、杀菌效果和稳定性好的优点，有效的避免了其他有机防腐剂强刺激气味和腐蚀性强的缺点，大大提高切削液的润滑性，使加工件的光洁度提高，最大限度的提高产品生产加工效率，可有效延长刀具和机床的使用寿命，成本低、方法简单、经济环保，适用于多种金属的切削和研磨。

Description

一种数控机床金属加工用防锈切削液及其制备方法
技术领域
本发明涉及一种切削液，具体是一种数控机床金属加工用防锈切削液及其制备方法。
背景技术
切削液是金属切削加工的重要的配套材料，使用金属切削液的目的就是降低切削力及刀具与工件之间的摩擦，及时带走切削区内产生的热量以降低切削温度，减少刀具磨损，提高刀具耐用度，从而提高生产效率，改善工件表面粗糙度，保证工件加工精度，从而达到最佳经济效果。
目前，装备制造业使用的切削液有切削油和乳化液两类。切削油在高温切削生产中会产生大量的油烟，既污染环境，又影响安全生产；而且切削油需要原液切削，生产成本高；再是防锈能力差，甚至1-2h后零件即可锈蚀。乳化液是一种混合水溶液，乳化液中含有的动、植物油脂，极易变质，稳定性差；在使用过程中易发生破乳，不仅使用周期短，而且废液对环境污染严重。
数控机床工业是装备制造业的龙头，是关系到国计民生和国防尖端建设的基础性工业和战略性产业，随着数控机床向着专业化、小型化、精密化和高速化的发展，数控机床作为复杂而精密的机器，采用多种多样的传动装置，根据设备的种类、工作环境及精密度的要求对切削液的相关性能都有不同的要求，呈现出数控机床对切削液的专有特点。通过切削液的使用，可以大幅度减少切削能耗，降低切削温度、提高刀具的使用寿命，保证工件加工精度和表面质量，提高加工效率，达到最佳的经济效果。中国专利CN105296126A公开了一种绿色环保型水基防锈切削液及其制备方，制备得到的切削液具有优良的防锈性能和润滑性能；中国专利CN102311864A公开了一种数控机床专用切削液及其制备方法，其制备的切削液具有使用寿命长，清洗性能、防锈性、润滑性、冷却性良好等优点。但上述两个专利使用的有机杀菌剂具有强烈腐蚀性，气味刺鼻，对操作人员具有潜在的危害。
发明内容
本发明的目的在于提供一种数控机床金属加工用防锈切削液及其制备方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：
一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺40-60份、聚苯胺15-25份、癸二酸1-3份、乙二胺四乙酸二钠盐2-4份、太古油6-8份、防锈剂3-5份、消泡剂0.3-0.5份、丙烯腈1-2份、壬基酚聚氧乙烯醚3-5份、聚氯乙烯胶乳5-15份、四氮唑4-6份、油酸3-5份、十二烷基二甲基甜菜碱1-2份、松香0.5-1份、松香酸聚氧乙烯酯2-4份、月桂酸1-3份、水杨酸1-3份、大豆蜡5-7份、棉籽油2-4份、丙二醇6-10份、钝化液6-10份、清洁剂100-120份。
作为本发明进一步的方案：所述数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺45-55份、聚苯胺18-22份、癸二酸1.5-2.5份、乙二胺四乙酸二钠盐2.5-3.5份、太古油6.5-7.5份、防锈剂3.5-4.5份、消泡剂0.35-0.45份、丙烯腈1.2-1.8份、壬基酚聚氧乙烯醚3.5-4.5份、聚氯乙烯胶乳8-12份、四氮唑4.5-5.5份、油酸3.5-4.5份、十二烷基二甲基甜菜碱1.2-1.8份、松香0.6-0.9份、松香酸聚氧乙烯酯2.5-3.5份、月桂酸1.5-2.5份、水杨酸1.5-2.5份、大豆蜡5.5-6.5份、棉籽油2.5-3.5份、丙二醇7-9份、钝化液7-9份、清洁剂105-115份。
作为本发明进一步的方案：所述数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺50份、聚苯胺20份、癸二酸2份、乙二胺四乙酸二钠盐3份、太古油7份、防锈剂4份、消泡剂0.4份、丙烯腈1.5份、壬基酚聚氧乙烯醚4份、聚氯乙烯胶乳10份、四氮唑5份、油酸4份、十二烷基二甲基甜菜碱1.5份、松香0.8份、松香酸聚氧乙烯酯3份、月桂酸2份、水杨酸2份、大豆蜡6份、棉籽油3份、丙二醇8份、钝化液8份、清洁剂110份。
作为本发明进一步的方案：所述的防锈剂选用485防锈剂，是由有机杂环多元羧酸和三嗪化合物复合反应制得。
作为本发明进一步的方案：所述的消泡剂选用二甲基硅油。
作为本发明进一步的方案：所述的钝化液为50％的10％亚硝酸酸钠水溶液和50％的0.5％碳酸钠水溶液组成。
作为本发明再进一步的方案：所述的清洁剂为苯甲酸钠10％、二异丙基萘磺酸钠20％、助剂5％份、硼酸5％、尼泊金甲酯10％、柚子汁50％与90℃加热混合制备所得。
所述数控机床金属加工用防锈切削液的制备方法，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至90-110℃，搅拌20-40min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，1-2h加完，升高温度至120-140℃，保温反应3-5h，降至50-60℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在800-1200r/min的转速条件下，搅拌混合1-2h后降温至室温，即得。
与现有技术相比，本发明的有益效果是：
本发明具有无刺激、无腐蚀、杀菌效果和稳定性好的优点，有效的避免了其他有机防腐剂强刺激气味和腐蚀性强的缺点，并且对人体友好无毒害，能有效保障操作人员的健康和安全，不会对周围环境造成污染，大大提高切削液的润滑性，使加工件的光洁度提高，最大限度的提高产品生产加工效率，可有效延长刀具和机床的使用寿命，成本低、方法简单、经济环保，适用于多种金属的切削和研磨。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺40份、聚苯胺15份、癸二酸1份、乙二胺四乙酸二钠盐2份、太古油6份、防锈剂3份、消泡剂0.3份、丙烯腈1份、壬基酚聚氧乙烯醚3份、聚氯乙烯胶乳5份、四氮唑4份、油酸3份、十二烷基二甲基甜菜碱1份、松香0.5份、松香酸聚氧乙烯酯2份、月桂酸1份、水杨酸1份、大豆蜡5份、棉籽油2份、丙二醇6份、钝化液6份、清洁剂100份。
所述数控机床金属加工用防锈切削液的制备方法，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至90℃，搅拌20min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，1h加完，升高温度至120℃，保温反应3h，降至50℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在800r/min的转速条件下，搅拌混合1h后降温至室温，即得。
实施例2
一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺45份、聚苯胺18份、癸二酸1.5份、乙二胺四乙酸二钠盐2.5份、太古油6.5份、防锈剂3.5份、消泡剂0.35份、丙烯腈1.2份、壬基酚聚氧乙烯醚3.5份、聚氯乙烯胶乳8份、四氮唑4.5份、油酸3.5份、十二烷基二甲基甜菜碱1.2份、松香0.6份、松香酸聚氧乙烯酯2.5份、月桂酸1.5份、水杨酸1.5份、大豆蜡5.5份、棉籽油2.5份、丙二醇7份、钝化液7份、清洁剂105份。
所述数控机床金属加工用防锈切削液的制备方法，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至95℃，搅拌25min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，1.2h加完，升高温度至125℃，保温反应3.5h，降至52℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在900r/min的转速条件下，搅拌混合1.2h后降温至室温，即得。
实施例3
一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺50份、聚苯胺20份、癸二酸2份、乙二胺四乙酸二钠盐3份、太古油7份、防锈剂4份、消泡剂0.4份、丙烯腈1.5份、壬基酚聚氧乙烯醚4份、聚氯乙烯胶乳10份、四氮唑5份、油酸4份、十二烷基二甲基甜菜碱1.5份、松香0.8份、松香酸聚氧乙烯酯3份、月桂酸2份、水杨酸2份、大豆蜡6份、棉籽油3份、丙二醇8份、钝化液8份、清洁剂110份。
所述数控机床金属加工用防锈切削液的制备方法，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至100℃，搅拌30min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，1.5h加完，升高温度至130℃，保温反应4h，降至55℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在1000r/min的转速条件下，搅拌混合1.5h后降温至室温，即得。
实施例4
一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺55份、聚苯胺22份、癸二酸2.5份、乙二胺四乙酸二钠盐3.5份、太古油7.5份、防锈剂4.5份、消泡剂0.45份、丙烯腈1.8份、壬基酚聚氧乙烯醚4.5份、聚氯乙烯胶乳12份、四氮唑5.5份、油酸4.5份、十二烷基二甲基甜菜碱1.8份、松香0.9份、松香酸聚氧乙烯酯3.5份、月桂酸2.5份、水杨酸2.5份、大豆蜡6.5份、棉籽油3.5份、丙二醇9份、钝化液9份、清洁剂115份。
所述数控机床金属加工用防锈切削液的制备方法，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至105℃，搅拌35min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，1.8h加完，升高温度至135℃，保温反应4.5h，降至58℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在1100r/min的转速条件下，搅拌混合1.8h后降温至室温，即得。
实施例5
一种数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺60份、聚苯胺25份、癸二酸3份、乙二胺四乙酸二钠盐4份、太古油8份、防锈剂5份、消泡剂0.5份、丙烯腈2份、壬基酚聚氧乙烯醚5份、聚氯乙烯胶乳15份、四氮唑6份、油酸5份、十二烷基二甲基甜菜碱2份、松香1份、松香酸聚氧乙烯酯4份、月桂酸3份、水杨酸3份、大豆蜡7份、棉籽油4份、丙二醇10份、钝化液10份、清洁剂120份。
所述数控机床金属加工用防锈切削液的制备方法，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至110℃，搅拌40min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，2h加完，升高温度至140℃，保温反应5h，降至60℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在1200r/min的转速条件下，搅拌混合2h后降温至室温，即得。
所述的防锈剂选用485防锈剂，是由有机杂环多元羧酸和三嗪化合物复合反应制得。所述的消泡剂选用二甲基硅油。所述的钝化液为50％的10％亚硝酸酸钠水溶液和50％的0.5％碳酸钠水溶液组成。所述的清洁剂为苯甲酸钠10％、二异丙基萘磺酸钠20％、助剂5％份、硼酸5％、尼泊金甲酯10％、柚子汁50％与90℃加热混合制备所得。
本发明具有无刺激、无腐蚀、杀菌效果和稳定性好的优点，有效的避免了其他有机防腐剂强刺激气味和腐蚀性强的缺点，并且对人体友好无毒害，能有效保障操作人员的健康和安全，不会对周围环境造成污染，大大提高切削液的润滑性，使加工件的光洁度提高，最大限度的提高产品生产加工效率，可有效延长刀具和机床的使用寿命，成本低、方法简单、经济环保，适用于多种金属的切削和研磨。
上面对本专利的较佳实施方式作了详细说明，但是本专利并不限于上述实施方式，在本领域的普通技术人员所具备的知识范围内，还可以在不脱离本专利宗旨的前提下作出各种变化。

Claims (8)

1.一种数控机床金属加工用防锈切削液，其特征在于，按照重量份的原料包括：三乙醇胺40-60份、聚苯胺15-25份、癸二酸1-3份、乙二胺四乙酸二钠盐2-4份、太古油6-8份、防锈剂3-5份、消泡剂0.3-0.5份、丙烯腈1-2份、壬基酚聚氧乙烯醚3-5份、聚氯乙烯胶乳5-15份、四氮唑4-6份、油酸3-5份、十二烷基二甲基甜菜碱1-2份、松香0.5-1份、松香酸聚氧乙烯酯2-4份、月桂酸1-3份、水杨酸1-3份、大豆蜡5-7份、棉籽油2-4份、丙二醇6-10份、钝化液6-10份、清洁剂100-120份。
2.根据权利要求1所述的数控机床金属加工用防锈切削液，其特征在于，按照重量份的原料包括：三乙醇胺45-55份、聚苯胺18-22份、癸二酸1.5-2.5份、乙二胺四乙酸二钠盐2.5-3.5份、太古油6.5-7.5份、防锈剂3.5-4.5份、消泡剂0.35-0.45份、丙烯腈1.2-1.8份、壬基酚聚氧乙烯醚3.5-4.5份、聚氯乙烯胶乳8-12份、四氮唑4.5-5.5份、油酸3.5-4.5份、十二烷基二甲基甜菜碱1.2-1.8份、松香0.6-0.9份、松香酸聚氧乙烯酯2.5-3.5份、月桂酸1.5-2.5份、水杨酸1.5-2.5份、大豆蜡5.5-6.5份、棉籽油2.5-3.5份、丙二醇7-9份、钝化液7-9份、清洁剂105-115份。
3.根据权利要求1所述的数控机床金属加工用防锈切削液，其特征在于，所述数控机床金属加工用防锈切削液，按照重量份的原料包括：三乙醇胺50份、聚苯胺20份、癸二酸2份、乙二胺四乙酸二钠盐3份、太古油7份、防锈剂4份、消泡剂0.4份、丙烯腈1.5份、壬基酚聚氧乙烯醚4份、聚氯乙烯胶乳10份、四氮唑5份、油酸4份、十二烷基二甲基甜菜碱1.5份、松香0.8份、松香酸聚氧乙烯酯3份、月桂酸2份、水杨酸2份、大豆蜡6份、棉籽油3份、丙二醇8份、钝化液8份、清洁剂110份。
4.根据权利要求1-3任一所述的数控机床金属加工用防锈切削液，其特征在于，所述的防锈剂选用485防锈剂，是由有机杂环多元羧酸和三嗪化合物复合反应制得。
5.根据权利要求1所述的数控机床金属加工用防锈切削液，其特征在于，所述的消泡剂选用二甲基硅油。
6.根据权利要求1所述的数控机床金属加工用防锈切削液，其特征在于，所述的钝化液为50％的10％亚硝酸酸钠水溶液和50％的0.5％碳酸钠水溶液组成。
7.根据权利要求1所述的数控机床金属加工用防锈切削液，其特征在于，所述的清洁剂为苯甲酸钠10％、二异丙基萘磺酸钠20％、助剂5％份、硼酸5％、尼泊金甲酯10％、柚子汁50％与90℃加热混合制备所得。
8.一种如权利要求1-3任一所述的数控机床金属加工用防锈切削液的制备方法，其特征在于，具体步骤如下：
（1）按照重量份称取各原料；
（2）将三乙醇胺、聚苯胺、癸二酸、乙二胺四乙酸二钠盐、太古油、防锈剂、松香酸聚氧乙烯酯、月桂酸、水杨酸、大豆蜡、棉籽油加入到密闭反应釜中，升温至90-110℃，搅拌20-40min；
（3）向步骤（2）的体系中依次加入消泡剂、壬基酚聚氧乙烯醚、聚氯乙烯胶乳、油酸、松香、丙二醇、钝化液、清洁剂，1-2h加完，升高温度至120-140℃，保温反应3-5h，降至50-60℃；
（4）向步骤（3）的体系中加入四氮唑、十二烷基二甲基甜菜碱、丙烯腈，在800-1200r/min的转速条件下，搅拌混合1-2h后降温至室温，即得。
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CN113563957A (zh) * 2021-07-22 2021-10-29 东莞市卓骏润滑科技有限公司 一种抗真菌全合成磨削液、制备方法及其使用方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113563957A (zh) * 2021-07-22 2021-10-29 东莞市卓骏润滑科技有限公司 一种抗真菌全合成磨削液、制备方法及其使用方法

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