CN110407474A - A kind of high-performance glass fiber - Google Patents
A kind of high-performance glass fiber Download PDFInfo
- Publication number
- CN110407474A CN110407474A CN201810386073.7A CN201810386073A CN110407474A CN 110407474 A CN110407474 A CN 110407474A CN 201810386073 A CN201810386073 A CN 201810386073A CN 110407474 A CN110407474 A CN 110407474A
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- titanium dioxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
- C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
- C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
- C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of high-performance glass fiber, the raw material according to parts by weight includes: silica, aluminum oxide, silicon carbide, barium monoxide, boron oxide, magnesia, calcium oxide, lithia, titanium dioxide, potassium oxide, di-iron trioxide, cerium oxide, tungsten oxide, sodium sulphate, zirconium oxide, sodium oxide molybdena, zinc oxide, calcirm-fluoride.Glass fibre flat appearance produced by the invention, color uniformity can be suitable for various post-processing manufacturing process well.And mechanical performance, wearability are good, high mechanical strength, chemical stability and thermal stability are good；Acid resistance is improved；Reduce thermal expansion coefficient.High temperature resistance is excellent, can be suitable for 1100 DEG C for a long time hereinafter, being widely used in manufacturing the fields such as precision instrument heat shield, ablator, heat-insulating material with good ablation property, better heat-resisting quantity, chemical corrosion resistance and elasticity modulus.
Description
Technical field
The present invention relates to a kind of glass fibre, specifically a kind of high-performance glass fiber.
Background technique
Glass fibre is a kind of inorganic non-metallic material haveing excellent performance, many kinds of, and advantage is good insulating, heat resistance
By force, corrosion resistance is good, high mechanical strength, but the disadvantage is that property is crisp, wearability is poor.It is using glass marble or post-consumer glass as raw material
Through caused by the techniques systems such as high temperature melting, wire drawing, doff, woven fabric, the diameter of monofilament is several microns to twenties microns,
It is equivalent to the 1/20-1/5 of a hairline, every bundle fiber precursor is all made of hundreds of even thousands of monofilament.Glass fibre
The reinforcing material being typically used as in composite material, electrically insulating material and heat-insulating material, the national economy such as circuit substrate are each
Field.
As economy continues to develop, the industries such as industry is smelted, welded partially make the rush of demand of glass fibre at present
With alkali-free glass fibre, the service life is extremely short, and thermal insulation is bad, becomes fragile for a long time in material under hot environment, easily damaged, from
And personal safety is endangered, resistance to acid and alkali, rigid, anti-aging, heat-resisting quantity are all up for improving.
Summary of the invention
The purpose of the present invention is to provide a kind of high-performance glass fibers, to solve mentioned above in the background art ask
Topic.
To achieve the above object, the invention provides the following technical scheme:
A kind of high-performance glass fiber, the raw material according to parts by weight include: 40-60 parts of silica, aluminum oxide 10-15
Part, 10-15 parts of silicon carbide, 5-7 parts of barium monoxide, 4-6 parts of boron oxide, 10-15 parts of magnesia, 5-7 parts of calcium oxide, lithia 0.1-
0.3 part, 0.1-0.3 parts of titanium dioxide, 2-4 parts of potassium oxide, 0.3-0.5 parts of di-iron trioxide, 0.1-0.5 parts of cerium oxide, oxidation
0.2-0.4 parts of tungsten, 0.5-1 parts of sodium sulphate, 0.3-0.7 parts of zirconium oxide, 0.1-0.3 parts of sodium oxide molybdena, 1.5-2.5 parts of zinc oxide, fluorine
Change calcium 2.5-3.5 parts.
As a further solution of the present invention:
The high-performance glass fiber, the raw material according to parts by weight include: 45-55 parts of silica, aluminum oxide 11-14
Part, 11-14 parts of silicon carbide, 5.5-6.5 parts of barium monoxide, 4.5-5.5 parts of boron oxide, 11-14 parts of magnesia, calcium oxide 5.5-6.5
Part, 0.15-0.25 parts of lithia, 0.15-0.25 parts of titanium dioxide, 2.5-3.5 parts of potassium oxide, di-iron trioxide 0.35-0.45
Part, 0.2-0.4 parts of cerium oxide, 0.25-0.35 parts of tungsten oxide, 0.6-0.9 parts of sodium sulphate, 0.4-0.6 parts of zirconium oxide, sodium oxide molybdena
0.15-0.25 parts, 1.8-2.2 parts of zinc oxide, 2.8-3.2 parts of calcirm-fluoride.
As a further solution of the present invention:
The high-performance glass fiber, the raw material according to parts by weight include: 50 parts of silica, 12 parts of aluminum oxide, carbonization
12 parts of silicon, 6 parts of barium monoxide, 5 parts of boron oxide, 12 parts of magnesia, 6 parts of calcium oxide, 0.2 part of lithia, 0.2 part of titanium dioxide, oxygen
Change 3 parts of potassium, 0.4 part of di-iron trioxide, 0.3 part of cerium oxide, 0.3 part of tungsten oxide, 0.8 part of sodium sulphate, 0.5 part of zirconium oxide, oxidation
0.2 part of sodium, 2 parts of zinc oxide, 3 parts of calcirm-fluoride.
As further scheme of the invention:
The raw material of the silica is quartz sand, and the raw material of the aluminum oxide is pyrophillite, the original of the titanium dioxide
Material is titanium dioxide, and the raw material of the sodium oxide molybdena is soda ash.
Compared with prior art, the beneficial effects of the present invention are:
Glass fibre flat appearance produced by the invention, color uniformity can be suitable for well various post-processings and manufacture work
Skill.And mechanical performance, wearability are good, high mechanical strength, chemical stability and thermal stability are good；Acid resistance is improved；It reduces
Thermal expansion coefficient.High temperature resistance is excellent, can for a long time be suitable for 1100 DEG C hereinafter, have good ablation property, preferably
Heat-resisting quantity, chemical corrosion resistance and elasticity modulus are widely used in manufacturing precision instrument heat shield, ablator, insulation
The fields such as thermal insulation material.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
A kind of high-performance glass fiber, the raw material according to parts by weight include: 40 parts of silica, 10 parts of aluminum oxide, carbonization
10 parts of silicon, 5 parts of barium monoxide, 4 parts of boron oxide, 10 parts of magnesia, 5 parts of calcium oxide, 0.1 part of lithia, 0.1 part of titanium dioxide, oxygen
Change 2 parts of potassium, 0.3 part of di-iron trioxide, 0.1 part of cerium oxide, 0.2 part of tungsten oxide, 0.5 part of sodium sulphate, 0.3 part of zirconium oxide, oxidation
0.1 part of sodium, 1.5 parts of zinc oxide, 2.5 parts of calcirm-fluoride.
Embodiment 2
A kind of high-performance glass fiber, the raw material according to parts by weight include: 45 parts of silica, 11 parts of aluminum oxide, carbonization
11 parts of silicon, 5.5 parts of barium monoxide, 4.5 parts of boron oxide, 11 parts of magnesia, 5.5 parts of calcium oxide, 0.15 part of lithia, titanium dioxide
0.15 part, 2.5 parts of potassium oxide, 0.35 part of di-iron trioxide, 0.2 part of cerium oxide, 0.25 part of tungsten oxide, 0.6 part of sodium sulphate, oxidation
0.4 part of zirconium, 0.15 part of sodium oxide molybdena, 1.8 parts of zinc oxide, 2.8 parts of calcirm-fluoride.
Embodiment 3
A kind of high-performance glass fiber, the raw material according to parts by weight include: 50 parts of silica, 12 parts of aluminum oxide, carbonization
12 parts of silicon, 6 parts of barium monoxide, 5 parts of boron oxide, 12 parts of magnesia, 6 parts of calcium oxide, 0.2 part of lithia, 0.2 part of titanium dioxide, oxygen
Change 3 parts of potassium, 0.4 part of di-iron trioxide, 0.3 part of cerium oxide, 0.3 part of tungsten oxide, 0.8 part of sodium sulphate, 0.5 part of zirconium oxide, oxidation
0.2 part of sodium, 2 parts of zinc oxide, 3 parts of calcirm-fluoride.
Embodiment 4
A kind of high-performance glass fiber, the raw material according to parts by weight include: 55 parts of silica, 14 parts of aluminum oxide, carbonization
14 parts of silicon, 6.5 parts of barium monoxide, 5.5 parts of boron oxide, 14 parts of magnesia, 6.5 parts of calcium oxide, 0.25 part of lithia, titanium dioxide
0.25 part, 3.5 parts of potassium oxide, 0.45 part of di-iron trioxide, 0.4 part of cerium oxide, 0.35 part of tungsten oxide, 0.9 part of sodium sulphate, oxidation
0.6 part of zirconium, 0.25 part of sodium oxide molybdena, 2.2 parts of zinc oxide, 3.2 parts of calcirm-fluoride.
Embodiment 5
A kind of high-performance glass fiber, the raw material according to parts by weight include: 60 parts of silica, 15 parts of aluminum oxide, carbonization
15 parts of silicon, 7 parts of barium monoxide, 6 parts of boron oxide, 15 parts of magnesia, 7 parts of calcium oxide, 0.3 part of lithia, 0.3 part of titanium dioxide, oxygen
Change 4 parts of potassium, 0.5 part of di-iron trioxide, 0.5 part of cerium oxide, 0.4 part of tungsten oxide, 1 part of sodium sulphate, 0.7 part of zirconium oxide, sodium oxide molybdena
0.3 part, 2.5 parts of zinc oxide, 3.5 parts of calcirm-fluoride.
The raw material of the silica is quartz sand, and the raw material of the aluminum oxide is pyrophillite, the titanium dioxide
Raw material be titanium dioxide, the raw material of the sodium oxide molybdena is soda ash.
Glass fibre flat appearance produced by the invention, color uniformity can be suitable for various post-processing systems well
Make technique.And mechanical performance, wearability are good, high mechanical strength, chemical stability and thermal stability are good；Acid resistance is improved；
Reduce thermal expansion coefficient.High temperature resistance is excellent, can be suitable for 1100 DEG C for a long time hereinafter, having good ablation property, more
Good heat-resisting quantity, chemical corrosion resistance and elasticity modulus, be widely used in manufacturing precision instrument heat shield, ablator,
The fields such as heat-insulating material.
The preferred embodiment of the patent is described in detail above, but this patent is not limited to above-mentioned embodiment party
Formula within the knowledge of one of ordinary skill in the art can also be under the premise of not departing from this patent objective
Various changes can be made.
Claims (4)
1. a kind of high-performance glass fiber, which is characterized in that the raw material according to parts by weight includes: 40-60 parts of silica, three oxygen
Change 10-15 parts of two aluminium, 10-15 parts of silicon carbide, 5-7 parts of barium monoxide, 4-6 parts of boron oxide, 10-15 parts of magnesia, calcium oxide 5-7
Part, 0.1-0.3 parts of lithia, 0.1-0.3 parts of titanium dioxide, 2-4 parts of potassium oxide, 0.3-0.5 parts of di-iron trioxide, cerium oxide
0.1-0.5 parts, 0.2-0.4 parts of tungsten oxide, 0.5-1 parts of sodium sulphate, 0.3-0.7 parts of zirconium oxide, 0.1-0.3 parts of sodium oxide molybdena, oxidation
1.5-2.5 parts of zinc, 2.5-3.5 parts of calcirm-fluoride.
2. high-performance glass fiber according to claim 1, which is characterized in that the raw material according to parts by weight includes: dioxy
45-55 parts of SiClx, 11-14 parts of aluminum oxide, 11-14 parts of silicon carbide, 5.5-6.5 parts of barium monoxide, 4.5-5.5 parts of boron oxide,
11-14 parts of magnesia, 5.5-6.5 parts of calcium oxide, 0.15-0.25 parts of lithia, 0.15-0.25 parts of titanium dioxide, potassium oxide
2.5-3.5 parts, 0.35-0.45 parts of di-iron trioxide, 0.2-0.4 parts of cerium oxide, 0.25-0.35 parts of tungsten oxide, sodium sulphate 0.6-
0.9 part, 0.4-0.6 parts of zirconium oxide, 0.15-0.25 parts of sodium oxide molybdena, 1.8-2.2 parts of zinc oxide, 2.8-3.2 parts of calcirm-fluoride.
3. high-performance glass fiber according to claim 1, which is characterized in that the raw material according to parts by weight includes: dioxy
50 parts of SiClx, 12 parts of aluminum oxide, 12 parts of silicon carbide, 6 parts of barium monoxide, 5 parts of boron oxide, 12 parts of magnesia, 6 parts of calcium oxide,
0.2 part of lithia, 0.2 part of titanium dioxide, 3 parts of potassium oxide, 0.4 part of di-iron trioxide, 0.3 part of cerium oxide, 0.3 part of tungsten oxide,
0.8 part of sodium sulphate, 0.5 part of zirconium oxide, 0.2 part of sodium oxide molybdena, 2 parts of zinc oxide, 3 parts of calcirm-fluoride.
4. high-performance glass fiber according to claim 1 to 3, which is characterized in that the raw material of the silica
For quartz sand, the raw material of the aluminum oxide is pyrophillite, and the raw material of the titanium dioxide is titanium dioxide, the sodium oxide molybdena
Raw material is soda ash.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810386073.7A CN110407474A (en) | 2018-04-26 | 2018-04-26 | A kind of high-performance glass fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810386073.7A CN110407474A (en) | 2018-04-26 | 2018-04-26 | A kind of high-performance glass fiber |
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| Publication Number | Publication Date |
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| CN110407474A true CN110407474A (en) | 2019-11-05 |
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| CN201810386073.7A Withdrawn CN110407474A (en) | 2018-04-26 | 2018-04-26 | A kind of high-performance glass fiber |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111039568A (en) * | 2020-01-08 | 2020-04-21 | 宋磊 | Preparation method of inorganic non-metallic material with energy conversion function |
| CN112174537A (en) * | 2020-10-26 | 2021-01-05 | 浙江鸿盛环保科技集团有限公司 | Acid-resistant glass fiber composition, acid-resistant glass fiber and preparation method thereof |
| CN112299724A (en) * | 2020-10-23 | 2021-02-02 | 紫水晶(海南)再生医学科技有限公司 | Bioactive glass material for orthopedic repair and preparation method thereof |
| CN112679096A (en) * | 2020-12-31 | 2021-04-20 | 山东天舜环保科技有限公司 | High-performance colored glass fiber and preparation method thereof |
| CN113354292A (en) * | 2021-06-25 | 2021-09-07 | 五河信达新材料有限公司 | Preparation method of high-strength glass fiber |
| CN113979635A (en) * | 2021-11-23 | 2022-01-28 | 清远忠信世纪电子材料有限公司 | Low-expansion-coefficient glass fiber |
-
2018
- 2018-04-26 CN CN201810386073.7A patent/CN110407474A/en not_active Withdrawn
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111039568A (en) * | 2020-01-08 | 2020-04-21 | 宋磊 | Preparation method of inorganic non-metallic material with energy conversion function |
| CN112299724A (en) * | 2020-10-23 | 2021-02-02 | 紫水晶(海南)再生医学科技有限公司 | Bioactive glass material for orthopedic repair and preparation method thereof |
| CN112174537A (en) * | 2020-10-26 | 2021-01-05 | 浙江鸿盛环保科技集团有限公司 | Acid-resistant glass fiber composition, acid-resistant glass fiber and preparation method thereof |
| WO2022088452A1 (en) * | 2020-10-26 | 2022-05-05 | 浙江鸿盛新材料科技集团股份有限公司 | Acid-resistant glass fiber composition, and acid-resistant glass fiber and preparation method therefor |
| CN112679096A (en) * | 2020-12-31 | 2021-04-20 | 山东天舜环保科技有限公司 | High-performance colored glass fiber and preparation method thereof |
| CN113354292A (en) * | 2021-06-25 | 2021-09-07 | 五河信达新材料有限公司 | Preparation method of high-strength glass fiber |
| CN113979635A (en) * | 2021-11-23 | 2022-01-28 | 清远忠信世纪电子材料有限公司 | Low-expansion-coefficient glass fiber |
| CN113979635B (en) * | 2021-11-23 | 2022-06-10 | 清远忠信世纪电子材料有限公司 | Low-expansion-coefficient glass fiber |
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Application publication date: 20191105 |