CN110393875A - Lithium ion battery firebreak device - Google Patents

Lithium ion battery firebreak device Download PDF

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Publication number
CN110393875A
CN110393875A CN201910717059.5A CN201910717059A CN110393875A CN 110393875 A CN110393875 A CN 110393875A CN 201910717059 A CN201910717059 A CN 201910717059A CN 110393875 A CN110393875 A CN 110393875A
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CN
China
Prior art keywords
fire
fire relief
liquid
eruption
lithium ion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910717059.5A
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Chinese (zh)
Inventor
王贺武
李伟峰
张亚军
李成
欧阳明高
李建秋
卢兰光
杜玖玉
韩雪冰
冯旭宁
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Tsinghua University
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Tsinghua University
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Publication date
Application filed by Tsinghua University filed Critical Tsinghua University
Priority to CN201910717059.5A priority Critical patent/CN110393875A/en
Publication of CN110393875A publication Critical patent/CN110393875A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C2/00Fire prevention or containment
    • A62C2/04Removing or cutting-off the supply of inflammable material
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C2/00Fire prevention or containment
    • A62C2/06Physical fire-barriers
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C3/00Fire prevention, containment or extinguishing specially adapted for particular objects or places
    • A62C3/16Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C31/00Delivery of fire-extinguishing material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The application provides a kind of lithium ion battery firebreak device.The eruption that the battery cell occurs to discharge when thermal runaway is introduced in the fluid-tight case by pipeline.At this point, being placed with the liquid in the fluid-tight case.Heat fire-fighting principle can be absorbed according to liquid, eruption imports in the liquid, and the heat that the liquid can discharge eruption absorbs heat.To which the liquid cools down eruption, reduces the temperature of eruption, reduces condition element on fire of burning, and then play the role of preventing propagation of flame.Meanwhile when the flame and the liquid that eruption generates contact, puts out a fire at branch to flame in the liquid containing fire extinguishing, prevent fire spreading.

Description

Lithium ion battery firebreak device
Technical field
This application involves field of lithium ion battery, more particularly to a kind of lithium ion battery firebreak device.
Background technique
In recent years, the market share of electric car is promoted steadily.There is lithium ion battery high voltage, high-energy-density, length to follow The excellent performances such as ring service life, no pollution to the environment by the highest attention of ev industry, and obtain certain application.So And combustion mixture, such as H can be generated during lithium ion battery thermal runaway2、CO、CH4Deng, and accumulate in inside battery.In electricity After reaching certain pressure boundary inside pond, safety valve is opened, and combustion mixture is discharged into battery external world ring as battery erupts In border, it is easy to cause fire.To improve lithium ion battery security, carry out both at home and abroad related to lithium ion battery fire safety evaluating Research work.
Traditional lithium ion battery improves the safety of lithium ion battery by setting cracking pressure.Such as: work as battery Safety valve is opened when internal gas pressure reaches certain value, and gas is discharged to external environment, to avoid causing battery explosion.When soft When gas pressure in packet reaches certain value, the lower Soft Roll part variation of allowable pressure is broken through by gas and releases battery spray Object is sent out, to avoid causing battery explosion.At this point, when the pressure of traditional lithium ion battery box house reaches certain value, peace Full valve opening causes air to enter monomer inside or box house, is easy so that eruption and air contact postignition, and draw Polot flame sprawling, so that the safety of conventional lithium ion battery cabinet is relatively low.
Summary of the invention
Based on this, it is necessary to cause to erupt for after the safety valve unlatching of conventional lithium ion battery cabinet or after Soft Roll rupture Object and air contact postignition and cause propagation of flame, so that the problem that safety is relatively low, providing one kind can significantly be promoted The lithium ion battery firebreak device of lithium ion battery fire safety.
It includes Battery case, cabinet safety valve and liquid back-fire relief knot that the application, which provides a kind of lithium ion battery firebreak device, Structure.The Battery case surrounds to form first storage space.Multiple battery cells are placed in first storage space Or battery pack.The Battery case is provided with cabinet gas outlet.The cabinet safety valve is set to the cabinet gas outlet.It is described Liquid back-fire relief structure includes fluid-tight case.The fluid-tight case is connect with the cabinet safety valve pipeline.The fluid-tight luggage encloses to be formed One liquid containing sky.It is placed with liquid in the liquid-retaining volume, after the multiple battery cell thermal runaway of cooling The eruption of release, with the propagation of flame for preventing eruption from generating.
The application provides a kind of above-mentioned lithium ion battery firebreak device, and the spray discharged when thermal runaway occurs for the battery cell Hair object is introduced in the fluid-tight case by pipeline.At this point, being placed with the liquid in the fluid-tight case.It can be inhaled according to liquid Heat fire-fighting principle is received, eruption imports in the liquid, and the heat that the liquid 252 can discharge eruption absorbs heat. To, the liquid cools down eruption, reduces the temperature of eruption, reduce condition element on fire of burning, into And play the role of preventing propagation of flame.Meanwhile when the flame and the liquid that eruption generates contact, contain in the liquid There is fire extinguishing to put out a fire at branch to flame, prevents fire spreading.
Detailed description of the invention
Fig. 1 is the Integral connection structure schematic diagram of lithium ion battery firebreak device in one embodiment provided by the present application;
Fig. 2 is the whole of the lithium ion battery firebreak device containing monomer back-fire relief structure in one embodiment provided by the present application Attachment structure schematic diagram;
Fig. 3 is the structural schematic diagram of monomer back-fire relief structure provided by the present application;
Fig. 4 is the hatch frame schematic diagram of the monomer back-fire relief structure in Fig. 3 provided by the present application;
Fig. 5 is the structural representation of the monomer back-fire relief structure containing the second fire-proof plate in one embodiment provided by the present application Figure;
Fig. 6 is the hatch frame schematic diagram of monomer back-fire relief structure in Fig. 5 provided by the present application;
Fig. 7 is the structural representation of the monomer back-fire relief structure containing the second fire-proof plate in another embodiment provided by the present application Figure;
Fig. 8 is that monomer back-fire relief shell section is rectangular structural schematic diagram in one embodiment provided by the present application;
Fig. 9 is that monomer back-fire relief shell section is rectangular structural schematic diagram in another embodiment provided by the present application;
Figure 10 is the lithium ion battery firebreak device containing battery modules shell in one embodiment provided by the present application Integral connection structure schematic diagram;
Figure 11 is the lithium ion battery firebreak device containing battery modules shell in another embodiment provided by the present application Integral connection structure schematic diagram;
Figure 12 is the Integral connection structure of the lithium ion battery firebreak device provided by the present application containing mould group back-fire relief structure Schematic diagram;
Figure 13 is the lithium ion battery firebreak device containing fiber back-fire relief structure in one embodiment provided by the present application Integral connection structure schematic diagram;
Figure 14 is the lithium ion battery firebreak device containing fiber back-fire relief structure in another embodiment provided by the present application Integral connection structure schematic diagram.
Description of symbols
Lithium ion battery firebreak device 100, Battery case 10, cabinet safety valve 120, liquid back-fire relief structure 20, first are received Receive space 110,320 battery pack 80 of battery cell, cabinet gas outlet 121, fluid-tight case 250, liquid-retaining volume 251, liquid 252, exhaust pipe 230, pressure stabilizing cavity 220, check valve 240, drain valve 253, first pipe 310, the first gas rail 330, monomer peace Full valve 321, monomer back-fire relief structure 40, monomer back-fire relief structure inlet 410, monomer back-fire relief structure export 420, monomer back-fire relief shell 430, the first fire-proof plate 440, back-fire relief space 431, opening the 4422, second fire aisle 442, second resistance of back-fire relief part 4421, second Fiery plate 450, support frame 451, third opening 4431, third fire aisle 443.
Specific embodiment
In order to which the objects, technical solutions and advantages of the application are more clearly understood, by the following examples, and combine attached Figure, is further elaborated the application.It should be appreciated that specific embodiment described herein is only to explain this Shen Please, it is not used to limit the application.
It is herein component institute serialization number itself, such as " first ", " second " etc., is only used for distinguishing described object, Without any sequence or art-recognized meanings.And " connection ", " connection " described in the application, unless otherwise instructed, include directly and It is indirectly connected with (connection).In the description of the present application, it is to be understood that term " on ", "lower", "front", "rear", " left side ", The orientation of the instructions such as " right side ", "vertical", "horizontal", "top", "bottom", "inner", "outside", " clockwise ", " counterclockwise " or position are closed System indicates to be based on the orientation or positional relationship shown in the drawings, being merely for convenience of description the application and simplifying description Or imply that signified device or element must have a particular orientation, be constructed and operated in a specific orientation, therefore cannot understand For the limitation to the application.
In this application unless specifically defined or limited otherwise, fisrt feature in the second feature " on " or " down " can be with It is that the first and second features directly contact or the first and second features pass through intermediary mediate contact.Moreover, fisrt feature exists Second feature " on ", " top " and " above " but fisrt feature be directly above or diagonally above the second feature, or be merely representative of First feature horizontal height is higher than second feature.Fisrt feature can be under the second feature " below ", " below " and " below " One feature is directly under or diagonally below the second feature, or is merely representative of first feature horizontal height less than second feature.
Referring to Figure 1, it is safe including Battery case 10, cabinet to provide a kind of lithium ion battery firebreak device 100 by the application Valve 120 and liquid back-fire relief structure 20.The Battery case 10, which surrounds, forms first storage space 110.Described first receives It receives and is placed with multiple battery cells 320 or battery pack 80 in space 110.The Battery case 10 is provided with cabinet gas outlet 121. The cabinet safety valve 120 is set to the cabinet gas outlet 121.The liquid back-fire relief structure 20 includes fluid-tight case 250.It is described Fluid-tight case 250 is connect with 120 pipeline of cabinet safety valve.The fluid-tight case 250, which surrounds, forms a liquid-retaining volume 251.It is placed with liquid 252 in the liquid-retaining volume 251, to the multiple battery cell 320 of cooling or the battery The eruption discharged after 80 thermal runaways is wrapped, with the propagation of flame for preventing eruption from generating.
It can be produced when the multiple battery cells 320 or the generation thermal runaway of the battery pack 80 in the Battery case 10 Raw mixing imflammable gas.After reaching certain pressure boundary inside the battery cell 320, the peace of the battery cell 320 Full valve can be opened, and combustion mixture is discharged into the Battery case 10 as battery erupts.Heat occurs for the battery pack 80 When out of control, release eruption can be ruptured.When pressure inside the Battery case 10 reaches certain value, the battery can be broken through The cabinet safety valve 120 of cabinet 10, the cabinet safety valve 120 can be opened.At this point, the eruption of imflammable gas discharge it is past Toward along with Mars or other high-temperature particle objects, flame can be easy to produce after contacting with oxygen.
The eruption that the battery cell 320 or the battery pack 80 occur to discharge when thermal runaway is introduced to institute by pipeline It states in fluid-tight case 250.At this point, being placed with the liquid 252 in the fluid-tight case 250.Heat fire extinguishing can be absorbed according to liquid Principle, eruption import in the liquid 252, and the heat that the liquid 252 can discharge eruption absorbs heat.To institute It states liquid 252 to cool down eruption, reduces the temperature of eruption, reduce condition element on fire of burning, in turn Play the role of preventing propagation of flame.Meanwhile when the flame and the liquid 252 that eruption generates contact, the liquid 252 In containing fire extinguishing put out a fire at branch to flame, prevent fire spreading.
Wherein, the liquid 252 can may be implemented to hinder for glycerol, tung oil, water or salt and the aqueous solution of calcium chloride etc. The liquid of fiery function.The fluid-tight case 250 has enough mechanical strengths, compression resistance and characteristic resistant to high temperature.
In one embodiment, the liquid back-fire relief structure 20 further includes exhaust pipe 230 and pressure stabilizing cavity 220.It is described Exhaust pipe 230 is set between the fluid-tight case 250 and the cabinet safety valve 120, to by the fluid-tight case 250 and institute State the connection of cabinet safety valve 120.The pressure stabilizing cavity 220 be set to the exhaust pipe 230 and the cabinet safety valve 120 it Between.Described 220 one end of pressure stabilizing cavity is connected to the exhaust pipe 230, and the pressure stabilizing cavity 220 is far from the exhaust pipe 230 1 End is connected to 120 pipeline of cabinet safety valve.And the diameter of the pressure stabilizing cavity 220 is greater than the diameter of the exhaust pipe 230, To ensure that the pressure in the exhaust pipe 230 is stablized.Described 230 one end of exhaust pipe is connected to the pressure stabilizing cavity 220.Institute 230 other end of exhaust pipe is stated to connect and extended in the liquid 252 with the fluid-tight case 250.
Wherein, the exhaust pipe 230 and the pressure stabilizing cavity 220 have enough mechanical strengths, can resist explosion time Pressure.The pressure stabilizing cavity 220 is arranged close to described 120 one end of cabinet safety valve.And the pressure stabilizing cavity 220 is pacified with the cabinet 120 seal for pipe joints of full valve connection, prevents eruption from leaking.Also, the pressure stabilizing cavity 220 and 120 pipeline of cabinet safety valve When sealed connection, the inner diameter of pipeline is greater than the diameter of the cabinet safety valve 120, to by the cabinet safety valve 120 It is completely covered, avoids causing interference effect to the normally-open of cabinet safety valve 120.Meanwhile in the liquid back-fire relief knot The sealed connection position of structure 20 is provided with high-temperature resistant seal ring, the temperature generated when being lost to avoid 320 heat of the battery cell compared with Height damages connecting portion.
The number of the pressure stabilizing cavity 220 with no restrictions, can be set it is multiple, to prevent the burst pressure of eruption is excessive from making It is splashed out at the liquid 252 in the fluid-tight case 250.The shape of the exhaust pipe 230 can connect shape for multiple U-tubes At, or V-shape pipe connects to be formed.At this point, the eruption that the battery cell 320 occurs to discharge when thermal runaway flows through institute It states pressure stabilizing cavity 220 and the exhaust pipe 230 enters in the liquid 252 of the fluid-tight case 250.
In one embodiment, the fluid-tight case 250 can be tightly connected with the exhaust pipe 230, place the liquid Body 252 leaks outside.
In one embodiment, the lithium ion battery firebreak device 100 further includes check valve 240.The check valve 240 It is set in the exhaust pipe 230, to prevent the liquid 252 from flowing backward to the cabinet safety valve 120.
The check valve 240 is disposed in proximity in the exhaust pipe 230 of described 250 one end of fluid-tight case, to prevent The liquid 252 flows backward to the cabinet safety valve 120.
In one embodiment, the lithium ion battery firebreak device 100 further includes drain valve 253.The drain valve 253 It is set to 250 bottom of fluid-tight case.
The drain valve 253 may be mounted at the position for needing drain line minimum in the fluid-tight case 250.When water level height After sluicing line, the drain valve 253 can depressurize in starting sluicing automatically, to protect the safety of the exhaust pipe 230, to mitigate The pressure of the exhaust pipe 230.
In one embodiment, the absorbent heat Q of the liquid 252 is (T1-T2) × c × m.Wherein, T1 is eruption Object enters the temperature of 250 foregoing description liquid 252 of fluid-tight case.T2 is the temperature when liquid 252 gasifies.C is described The specific heat capacity of liquid 252, m are the quality of the liquid 252.The absorbent heat Q of the liquid 252 is greater than the heat of eruption Amount.
When the absorbent heat Q of the liquid 252 is greater than the heat of eruption, eruption is imported in the liquid 252, The heat that the liquid 252 can discharge eruption absorbs heat.To which the liquid 252 cools down eruption, reduces The temperature of eruption reduces condition element on fire of burning, and then plays the role of preventing propagation of flame.
Referring to Figure 1, in one embodiment, the lithium ion battery firebreak device 100 further includes multiple first pipes 310 and the first gas rail 330.The multiple first pipe 310 is set in first storage space 110.One described One pipeline 310 is connect with the monomer safety valve 321 of a battery cell 320.The battery cell 320 is placed in described In one storage space 110.The first gas rail 330 is set in first storage space 110.The first gas rail 330 with Multiple first pipes 310 connect.The first gas rail 330 is connect with the cabinet gas outlet 121.
The eruption discharged each battery cell 320 by multiple first pipes 310 and the first gas rail 330 into Row leads into from the cabinet gas outlet 121 and is discharged, and carries out back-fire relief into the liquid back-fire relief structure 20.Pass through multiple first Pipeline 310 and the first gas rail 330 can prevent eruption, and arbitrarily flowing causes safety hidden in first storage space 110 Suffer from.
Fig. 2 is referred to, in one embodiment, the lithium ion battery firebreak device 100 further includes multiple monomer back-fire reliefs Structure 40.Each monomer back-fire relief structure 40 has monomer back-fire relief structure inlet 410 and monomer back-fire relief structure outlet 420.Institute Monomer back-fire relief structure outlet 420 is stated to connect with the first gas rail 330.The monomer resistance of one monomer back-fire relief structure 40 Fiery structure inlet 410 is connect with a first pipe 310.
When can be to 320 thermal runaway of battery cell by the monomer back-fire relief structure 40 eruption generate flame into Row stops.Meanwhile it can be by the monomer back-fire relief structure 40 by multiple first pipes 310 and the first gas rail 330 The flame that the eruption missed generates, which guides to enter in the liquid back-fire relief structure 20, to be stopped.To by described The flame that monomer back-fire relief structure 40 can generate eruption with the liquid back-fire relief structure 20 is stopped at many levels, is improved The safety of the lithium ion battery firebreak device 100.
Fig. 3-4 is referred to, in one embodiment, each monomer back-fire relief structure 40 includes monomer back-fire relief shell 430 With multiple spaced first fire-proof plates 440.The monomer back-fire relief shell 430, which surrounds, forms a back-fire relief space 431.It is described Monomer back-fire relief structure inlet 410 is set to the monomer back-fire relief shell 430 close to one end of the first pipe 310.Multiple It is set in the back-fire relief space 431 every first fire-proof plate 440 of setting, the difference of the first fire-proof plate 440 described in every two It is set to the opposite sides of 430 inner wall of monomer back-fire relief shell.And the setting of the first fire-proof plate 440 described in every two is same flat Face.First fire-proof plate 440 described in every two forms a back-fire relief part 4421, the two neighboring interval of back-fire relief part 4421 setting. One second opening 4422 is formed between first fire-proof plate 440 described in every two.Multiple second openings 4422 and multiple Clearance space between the back-fire relief part 4421 forms second fire aisle 442.Second fire aisle 442 is to hinder The only propagation of flame that eruption generates.
First fire-proof plate 440 described in every two is oppositely arranged, and forms second opening 4422.Wherein, Duo Gesuo State the first fire-proof plate 440 structure can with it is identical can be different, second opening 4422 can be round, rectangular, star etc. Multiple modification structures.Two first fire-proof plates 440 in each back-fire relief part 4421 can with it is identical can be different.It is multiple Second fire aisle 442 that second opening 4422 and multiple back-fire relief parts 4421 are formed is a curved resistance Fiery channel.In eruption is from the monomer back-fire relief structure inlet 410 into the back-fire relief space 431, and via described second It is flowed out after fire aisle 442.At this point, the space in the back-fire relief space 431 is utilized in second fire aisle 442, so that Eruption flows through longer route in the back-fire relief space 431.When eruption circulates in second fire aisle 442 When, the distance between two neighboring described back-fire relief part 4421 is less than the cut off diameter for the flame that eruption gas generates, and can make The heat loss for the flame that eruption generates increases, and is obstructed to flame, so that burning cannot continue and extinguish.And And when the flame that eruption generates circulates in second fire aisle 442, multiple 4421 benefits of the back-fire relief part can be hit The destruction rate that chain reaction is conducive to contact surface (contact site when shock) heat transfer and increase active group is terminated with wall effect, To continue to catch fire.
Wherein, eruption gas is methane, hydrogen, acetylene and imflammable gas and the mixture of oxygen etc..
In one embodiment, the maximum diameter of hole of second opening, 4422 (referring to b in Fig. 4) is less than 0.5 millimeter, phase Spacing distance (referring to d in Fig. 4) between adjacent two back-fire relief parts 4421 is less than 0.5 millimeter.
It the maximum diameter of hole of second opening 4422, can be to methane, the hydrogen, second in eruption gas less than 0.5 millimeter The flame that the mixture of alkynes and imflammable gas and oxygen generates is obstructed.Meanwhile when flame is open by described second When 4422, can heat loss be increased suddenly, so that burning cannot continue and extinguish.Also, when flame is described second In fire aisle 442 when circulation, multiple first fire-proof plates 440 can be hit, the temperature of flame can be made to pass through contact surface It radiates, and increases the destruction rate of active group in flame, reduce the factor that flame continues kindling, thus can not be after Continuous kindling, with the propagation of flame for preventing eruption from generating.
Spacing distance between the two neighboring back-fire relief part 4421 can generate eruption gas less than 0.5 millimeter Flame is stopped, and anti-system passes through.At this point, can be with by second opening 4422 and multiple first fire-proof plates 440 It realizes and repeatedly stops, sufficiently flame is stopped, injury is preferably minimized, to ensure lithium ion battery in use Reliability and safety.
In one embodiment, the maximum diameter of hole of second opening 4422 is less than 0.4 millimeter, the two neighboring back-fire relief Spacing distance between part 4421 is less than 0.4 millimeter.Since the cut off diameter of the flame of methane generation is 0.4mm~0.5mm, institute State what the second opening 4422 and the two neighboring back-fire relief part 4421 can adequately generate the methane in eruption gas Flame is stopped.
In one embodiment, the maximum diameter of hole of second opening 4422 is less than 0.1 millimeter, the two neighboring back-fire relief Spacing distance between part 4421 is less than 0.1 millimeter.At this point, since the cut off diameter of hydrogen and the flame of acetylene generation is 0.1mm~0.2mm, second opening 4422 and the two neighboring back-fire relief part 4421 can be adequately to eruption gases In hydrogen and acetylene generate flame stopped.
In one embodiment, the maximum diameter of hole of second opening 4422 is less than 0.07 millimeter, the two neighboring resistance Spacing distance between fiery part 4421 is less than 0.07 millimeter.At this point, due to the fire of the mixture of imflammable gas and oxygen generation The cut off diameter of flame is 0.07mm~0.5mm, and second opening 4422 and the two neighboring back-fire relief part 4421 can be with The flame adequately generated to the mixture of imflammable gas and oxygen in eruption gas stops.Meanwhile described second The maximum diameter of hole of opening 4422 is less than 0.07 millimeter, and the spacing distance between the two neighboring back-fire relief part 4421 is less than 0.07 milli The mixture of rice, the flame and imflammable gas and oxygen that can generate to flame, hydrogen and the acetylene that methane generates generates Flame stopped, with prevent eruption generate propagation of flame.
Fig. 5-7 is referred to, in one embodiment, the lithium ion battery firebreak device 100 further includes that multiple intervals are set The second fire-proof plate 450 and multiple support frames 451 set.Second fire-proof plate 450 is set in the back-fire relief space 431. And each second fire-proof plate 450 is set between the two neighboring back-fire relief part 4421.Each second fire-proof plate 450 The inner wall of edge and the monomer back-fire relief shell 430 forms a third opening 4431.Each second opening 4422 It is set to the axial centerline in the back-fire relief space 431.Multiple third openings 4431, multiple second openings 4422 And the clearance space between each second fire-proof plate 450 and each back-fire relief part 4421 forms a third back-fire relief and leads to Road 443.Propagation of flame of the third fire aisle 443 to prevent eruption generation.Each 451 one end of support frame as described above with Second fire-proof plate 450 connects.Each 451 other end of support frame as described above is connect with the inner wall of the cabinet back-fire relief shell 220, To support second fire-proof plate 250.
The inner wall of each second fire-proof plate, 450 edge and the monomer back-fire relief shell 430 forms a third Opening 4431.That is, the size of second fire-proof plate 450 is less than the monomer back-fire relief shell 430 perpendicular to center The size of the section of axis.For example, the monomer back-fire relief shell 430 is cylinder when second fire-proof plate 450 is round When, the diameter of second fire-proof plate 450 is less than the section diameter of the monomer back-fire relief shell 430.Also, second back-fire relief Inner wall of the edge of plate 450 with the monomer back-fire relief shell 430 is not connected to, and forms an annular third opening 4431.At this point, the inner wall of second fire-proof plate 450 and the monomer back-fire relief shell 430 forms a third opening 4431.
When eruption enters in the back-fire relief space 431 from the monomer back-fire relief structure inlet 410, pass through the third 4431 meetings be open so that eruption is dispersed, and is formed along third opening 4431 without several air-flows.Then without several Air-flow flows through second opening 4422 after assembling.And so on, eruption is after the monomer back-fire relief structure inlet 410 entrance It can be by multiple third openings 4431 and second opening 4422.
Wherein, third opening 4431 disperses eruption, can by the energy of eruption and impact force into Row dispersion, reduces the energy of eruption.Meanwhile it can be made by third opening 4431 and second opening 4422 The path of the third fire aisle 443 is more times of traditional fire aisle path.Therefore, logical by increasing the third back-fire relief The path in road 443 and the energy of dispersion eruption, can reduce danger caused by eruption, to ensure that lithium ion battery is using Reliability and safety in the process.
Meanwhile when the flame that eruption generates circulates in the third fire aisle 443, two neighboring described second When the distance between fire-proof plate 450 and the back-fire relief part 4421 are less than the cut off diameter of flame, eruption can be made to generate The heat loss of flame increases, and is obstructed to flame, so that burning cannot continue and extinguish.Also, work as eruption When the flame of generation circulates in the third fire aisle 443, second fire-proof plate 450 and the back-fire relief part can be hit 4421, the pin that chain reaction is conducive to contact surface (contact site when shock) heat transfer and increase active group is terminated using wall effect Rate is ruined, to can not continue to catch fire.
In one embodiment, the maximum diameter of hole of the third opening 4431 is less than 0.5 millimeter, the adjacent back-fire relief part Spacing distance between 4421 and second fire-proof plate 450 is less than 0.5 millimeter.
In one embodiment, the maximum diameter of hole of 4431 (c in Fig. 6) of the third opening is less than 0.5 millimeter, adjacent institute The spacing distance between back-fire relief part 4421 and second fire-proof plate 450 is stated less than 0.5 millimeter.By being open to the third Spacing distance between the setting of 4431 maximum diameter of hole and adjacent the back-fire relief part 4421 and second fire-proof plate 450 Setting, can to eruption gas in methane, hydrogen, acetylene and imflammable gas and oxygen mixture generate flame It is obstructed.Meanwhile when flame is by third opening 4431 and second opening 4422, heat loss can be made unexpected Increase, so that burning cannot continue and extinguish.Also, it when flame circulates in the third fire aisle 443, can hit Hitting the back-fire relief part 4421 and second fire-proof plate 450 can make the temperature of flame radiate by wall surface, and increase The destruction rate of active group in flame reduces the factor that flame continues kindling, to can not continue to catch fire, to prevent to spray Send out the propagation of flame that object generates.
Similarly, in one embodiment, the maximum diameter of hole of the third opening 4431 and second opening 4422 is arranged 0.4mm can be less than, be less than 0.1mm, 0.07mm, the flame generated to realize the flame generated to methane, hydrogen and acetylene Or the flame of the mixture generation of imflammable gas and oxygen is stopped, with the propagation of flame for preventing eruption from generating.
In one embodiment, the spacing distance between adjacent the back-fire relief part 4421 and second fire-proof plate 450 0.4mm can be less than, be less than 0.1mm, 0.07mm, the flame generated to realize the flame generated to methane, hydrogen and acetylene Or the flame of the mixture generation of imflammable gas and oxygen is stopped, with the propagation of flame for preventing eruption from generating.
Wherein, support frame as described above 451 can be fixed second fire-proof plate 450, so that each described second The inner wall of 450 edge of fire-proof plate and the monomer back-fire relief shell 430 forms the third opening 4431.Support frame as described above It can be adopted in welded or bolted way when 451 connection.
Fig. 8-9 is referred to, in one embodiment, is provided with the back-fire relief part 4421 and second fire-proof plate 450 The shape for setting the monomer back-fire relief shell 430 at place can be the shape of cylindrical body or cubic shaped etc., and concrete shape is not done Limitation.
0-12 referring to Figure 1, in one embodiment, the lithium ion battery firebreak device 100 further include multiple batteries Module casing 50, multiple second pipes 710 and the second gas rail 720.Multiple battery modules shells 50, which surround, forms one Second storage space 510.Multiple battery modules shells 50 are set in first storage space 110.Each electricity Pond module casing 50 is provided with shell gas outlet 521.Each shell gas outlet 521 is provided with vessel safety valve 520.It is multiple The first pipe 310 is set in second storage space 510 with the first gas rail 330.The first gas rail 330 with The shell gas outlet 521 connects.Multiple second pipes 710 are set in first storage space 110.Described in one Second pipe 710 is connect with the vessel safety valve 520 of a battery modules shell 50.The second gas rail 720 is set It is placed in first storage space 110.The second gas rail 720 is connect with multiple second pipes 710.Second gas Rail 720 is connect with the cabinet gas outlet 121.
When being provided with the battery modules shell 50 in first storage space 110, pass through multiple second pipes Eruption by multiple first pipes 310 and the first gas rail 330 can be introduced the second gas rail by road 710 In 720.Meanwhile entering the liquid back-fire relief structure 20 via the cabinet gas outlet 121 and the cabinet safety valve 120.From And pass through multiple first pipes 310, the first gas rail 330, multiple second pipes 710 and second gas Rail 720 can be to avoid eruption arbitrarily flows in first storage space 110 and causes danger.
In one embodiment, the lithium ion battery firebreak device 100 further includes multiple mould group back-fire relief structures 60.Each The mould group back-fire relief structure 60 has mould group back-fire relief structure inlet 610 and mould group back-fire relief structure outlet 620.Each mould group resistance The mould group back-fire relief structure outlet 620 of fiery structure 60 is connect with the second gas rail 720.One mould group back-fire relief structure 60 The mould group back-fire relief structure inlet 610 connect with a second pipe 710.
Wherein, the mould group back-fire relief structure 60 is identical as the structure of the monomer back-fire relief structure 40.It is hindered by the mould group The flame that fiery structure 60 can generate the eruption that the battery cell 320 in the battery modules shell 50 generates carries out Stop.Meanwhile the eruption that the first pipe 310 and the first gas rail 330 can miss the monomer back-fire relief structure 40 The flame that object generates is guided into the mould group back-fire relief structure 60.And pass through the second pipe 710 and second gas Rail 720 guides the flame that the eruption that the mould group back-fire relief structure 60 is missed generates into the liquid back-fire relief structure 20 Inside stopped.To pass through the mould group back-fire relief structure 60, the monomer back-fire relief structure 40 and the liquid back-fire relief structure 20 The flame that can be generated to eruption is stopped at many levels, improves the safety of the lithium ion battery firebreak device 100.
Referring to Figure 13, in one embodiment, the lithium ion battery firebreak device 100 further includes battery pack 80.Institute Battery pack 80 is stated to be set in first storage space 110.When explosion leakage occurring when 80 thermal runaway of battery pack, when After inside reaches certain pressure boundary, the cabinet safety valve 120 can be opened.At this point, eruption can enter the liquid back-fire relief Structure 20.Blocking fire extinguishing is carried out by the flame that the liquid back-fire relief structure 20 can generate eruption, it is ensured that the electricity The safety of pond packet 80 in actual use.
3-14 referring to Figure 1, in one embodiment, the lithium ion battery firebreak device 100 further include fiber back-fire relief Structure 130.The fiber back-fire relief structure 130 is filled in first storage space 110, and the fiber back-fire relief structure 130 is Flexible flame retardant fibre structure.And the fiber back-fire relief structure 130 is for surrounding the multiple battery cell 320 or battery pack 80 Setting, to prevent the propagation of flame that eruption generates after 80 thermal runaway of the multiple battery cell 320 or battery pack.
The fiber back-fire relief structure 130 is filled in first storage space 110 and by the multiple battery cell 320 Or the battery pack 80 is surrounded.Even if after the battery cell 320 discharges eruption or the rupture of the battery pack 80, the fiber Back-fire relief structure 130 is flexible flame retardant fibre structure, still can be covered on multiple battery cells 320 or the battery pack 80 Or around the Battery case 10.Can eruption be isolated by the fiber back-fire relief structure 130 with air, prevent Only the burning mixture in eruption, Mars are contacted with air.Meanwhile the fiber back-fire relief structure 130 is covered on multiple institutes It states around battery cell 320, can also to be isolated between the two neighboring battery cell 320.To avoid The battery cell 320 around influencing after one of them described 320 thermal runaway of battery cell, plays the role of isolation, subtracts Burning condition element on fire is lacked.To which the flame generated to eruption prevents, and then play prevention propagation of flame Effect.
Simultaneously as the fiber back-fire relief structure 130 is fire resistance fibre structure, erupted when the battery cell 320 discharges After object or the Battery case 10 rupture, the air that can obstruct surrounding contacts the battery cell 320 after thermal runaway, prevents Enhancing flame causes new flame to generate.To which lithium ion battery can be improved in reality by the fiber back-fire relief structure 130 Safety in the use process of border.
In one embodiment, the fiber back-fire relief structure 130 is fibre bundle, has plurality of fibers silk, adjacent described The distance between fiber filament is less than 0.5 millimeter.
It is also assumed that the fiber back-fire relief structure 130 is fibrous composite, the fiber filament of the fibrous composite Diameter is less than 0.5 millimeter.
The flame transmitting cut off diameter generated according to gas with various or steam is different, the fiber filament of the fibrous composite Diameter setting can also be different.The fiber string diameter of the fibrous composite less than 0.5 millimeter, can to eruption gas in methane, The flame that the mixture of hydrogen, acetylene and imflammable gas and oxygen generates is obstructed.Meanwhile when flame passes through the fibre When tieing up back-fire relief structure 130, since the fiber string diameter of the fibrous composite is less than 0.5 millimeter, heat loss can be made unexpected Increase, reduces the condition element that flame continues kindling, so that burning cannot continue and extinguish, and then prevent eruption The propagation of flame of generation.
In one embodiment, the fiber back-fire relief structure 130 is fibre bundle, has plurality of fibers silk, adjacent described The distance between fiber filament is less than 0.4 millimeter.Since the cut off diameter of the flame of methane generation is 0.4mm~0.5mm, the fibre The flame that dimension back-fire relief structure 130 can sufficiently generate the methane in eruption gas stops.
In one embodiment, the fiber back-fire relief structure 130 is fibre bundle, has plurality of fibers silk, adjacent described The distance between fiber filament is less than 0.1 millimeter.Since the cut off diameter of hydrogen and the flame of acetylene generation is 0.1mm~0.2mm, The flame that the fiber back-fire relief structure 130 can sufficiently generate the hydrogen and acetylene that erupt in gas stops.
In one embodiment, the fiber back-fire relief structure 130 is fibre bundle, has plurality of fibers silk, adjacent described The distance between fiber filament is less than 0.07 millimeter.It is also assumed that the fiber string diameter of the fibrous composite is less than 0.07 milli Rice.
It is described since the cut off diameter of the flame of the mixture of imflammable gas and oxygen generation is 0.07mm~0.5mm Fiber back-fire relief structure 130 can sufficiently to eruption gas in imflammable gas and oxygen mixture generate flame hinder It blocks.
In one embodiment, the fiber back-fire relief structure 130 is quartz fibre.
Wherein, quartz fibre is that SiO2 content is higher than extraordinary glass fibers of 99.95% or more the, string diameter at 1 μm~15 μm Dimension, is fabricated by high-purity silicon dioxide and natural quartz crystal.Also, quartz fibre is in all inorfils, and intensity is most Continuous fiber of the standby temperature at 1000 DEG C or more when high, long-term, the short time is using temperature up to 1300 DEG C.Quartz fibre tool There are high temperature resistance, insulation performance good, resistivity is high, can stop the flame generated in eruption, play fire extinguishing Effect.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, all should be considered as described in this specification.
The several embodiments of the application above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously The limitation to the application the scope of the patents therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the concept of this application, various modifications and improvements can be made, these belong to the guarantor of the application Protect range.Therefore, the scope of protection shall be subject to the appended claims for the application patent.

Claims (11)

1. a kind of lithium ion battery firebreak device characterized by comprising
Battery case (10) surrounds and forms first storage space (110), is placed in first storage space (110) Multiple battery cells (320) or battery pack (80), the Battery case (10) are provided with cabinet gas outlet (121);
Cabinet safety valve (120) is set to the cabinet gas outlet (121);
Liquid back-fire relief structure (20), including fluid-tight case (250), the fluid-tight case (250) and cabinet safety valve (120) pipeline Connection, the fluid-tight case (250), which is surrounded, forms a liquid-retaining volume (251), places in the liquid-retaining volume (251) There are liquid (252), to the eruption discharged after the multiple battery cell of cooling (320) or the battery pack (80) thermal runaway Object, with the propagation of flame for preventing eruption from generating.
2. lithium ion battery firebreak device as described in claim 1, which is characterized in that the liquid back-fire relief structure (20) is also wrapped It includes:
Exhaust pipe (230) is set between the fluid-tight case (250) and the cabinet safety valve (120), to by the liquid Joint sealing (250) is connected to the cabinet safety valve (120);
Pressure stabilizing cavity (220) is set between the exhaust pipe (230) and the cabinet safety valve (120), the pressure stabilizing cavity (220) one end is connected to the exhaust pipe (230), and the pressure stabilizing cavity (220) is far from the exhaust pipe (230) one end and institute The connection of cabinet safety valve (120) pipeline is stated, and the diameter of the pressure stabilizing cavity (220) is greater than the diameter of the exhaust pipe (230), To ensure that the pressure in the exhaust pipe (230) is stablized;
Described exhaust pipe (230) one end is connected to the pressure stabilizing cavity (220), exhaust pipe (230) other end with it is described Fluid-tight case (250) is connected and is extended in the liquid (252).
3. lithium ion battery firebreak device as claimed in claim 2, which is characterized in that the liquid back-fire relief structure (20) is also wrapped It includes:
Check valve (240) is set in the exhaust pipe (230), to prevent the liquid (252) from flowing backward to the cabinet Safety valve (120).
4. lithium ion battery firebreak device as claimed in claim 2, which is characterized in that the liquid back-fire relief structure (20) is also wrapped It includes:
Drain valve (253) is set to fluid-tight case (250) bottom.
5. lithium ion battery firebreak device as described in claim 1, which is characterized in that the absorbent heat of the liquid (252) Amount Q is (T1-T2) × c × m, wherein T1 is the temperature that eruption enters fluid-tight case (250) foregoing description liquid (252), T2Temperature when gasifying for the liquid (252), c are the specific heat capacity of the liquid (252), and m is the matter of the liquid (252) Amount;
The absorbent heat Q of liquid (252) is greater than the heat of eruption.
6. lithium ion battery firebreak device as described in claim 1, which is characterized in that further include:
Multiple first pipes (310) are set in first storage space (110), a first pipe (310) and one The monomer safety valve (321) of a battery cell (320) connects, and the battery cell (320) is placed in first storage In space (110);
First gas rail (330) is set in first storage space (110), the first gas rail (330) and multiple described the One pipeline (310) connection, the first gas rail (330) connect with the cabinet gas outlet (121).
7. lithium ion battery firebreak device as claimed in claim 6, which is characterized in that further include:
Multiple monomer back-fire relief structures (40), each monomer back-fire relief structure (40) have monomer back-fire relief structure inlet (410) with Monomer back-fire relief structure exports (420), and the monomer back-fire relief structure outlet (420) connect with the first gas rail (330);
The monomer back-fire relief structure inlet (410) of one monomer back-fire relief structure (40) and a first pipe (310) it connects.
8. lithium ion battery firebreak device as claimed in claim 7, which is characterized in that each monomer back-fire relief structure (40) Including monomer back-fire relief shell (430) and multiple spaced first fire-proof plates (440);
The monomer back-fire relief shell (430), which is surrounded, forms a back-fire relief space (431), the monomer back-fire relief structure inlet (410) It is set to the one end of the monomer back-fire relief shell (430) close to the first pipe (310);
Multiple spaced first fire-proof plates (440) are set in the back-fire relief space (431), the described in every two One fire-proof plate (440) is respectively arranged at the opposite sides of monomer back-fire relief shell (430) inner wall, and the first resistance described in every two Fiery plate (440) is arranged in same plane;
First fire-proof plate (440) described in every two forms a back-fire relief part (4421), between the two neighboring back-fire relief part (4421) Every setting;
One second opening (4422) is formed between first fire-proof plate (440) described in every two;
Clearance space between multiple second openings (4422) and multiple back-fire relief parts (4421) forms one second Fire aisle (442), propagation of flame of second fire aisle (442) to prevent eruption generation.
9. lithium ion battery firebreak device as claimed in claim 8, which is characterized in that further include:
Multiple spaced second fire-proof plates (450) are set in the back-fire relief space (431), and each second resistance Fiery plate (450) is set between the two neighboring back-fire relief part (4421);
The inner wall of each second fire-proof plate (450) edge and the monomer back-fire relief shell (430) forms a third It is open (4431);
Each second opening (4422) is set to the axial centerline of the back-fire relief space (431);
Multiple third openings (4431), multiple second openings (4422) and each second fire-proof plate (450) Clearance space between each back-fire relief part (4421) forms a third fire aisle (443), and the third back-fire relief is logical Propagation of flame of the road (443) to prevent eruption generation;
Multiple support frames (451), each support frame as described above (451) one end are connect with second fire-proof plate (450), each described Support frame (451) other end is connect with the inner wall of the cabinet back-fire relief shell (220), to support second fire-proof plate (250)。
10. lithium ion battery firebreak device as claimed in claim 8, which is characterized in that second opening (4422) is most Large aperture is less than 0.5 millimeter, and the spacing distance between the two neighboring back-fire relief part (4421) is less than 0.5 millimeter.
11. lithium ion battery firebreak device as claimed in claim 9, which is characterized in that the third opening (4431) is most Less than 0.5 millimeter, the spacing distance between the adjacent back-fire relief part (4421) and second fire-proof plate (450) is small for large aperture In 0.5 millimeter.
CN201910717059.5A 2019-08-05 2019-08-05 Lithium ion battery firebreak device Pending CN110393875A (en)

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