CN110387174A - A kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacturing process - Google Patents
A kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacturing process Download PDFInfo
- Publication number
- CN110387174A CN110387174A CN201910583356.5A CN201910583356A CN110387174A CN 110387174 A CN110387174 A CN 110387174A CN 201910583356 A CN201910583356 A CN 201910583356A CN 110387174 A CN110387174 A CN 110387174A
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- China
- Prior art keywords
- water
- coil coating
- coating products
- hydrophobic oleophobic
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to Coil Coating Products technical field, a kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacturing process are disclosed.Water-based hydrophobic oleophobic Coil Coating Products of the invention include substrate and the dope layer on the substrate, the mass fraction ratio of the formula of the dope layer are as follows: the resin of (40~60) %, (6~13) % isopropanol, (2~7) % butanol, (8~15) % curing agent, (13~22) % deionized water, (0.5~3) % fluoride, (0.1~0.7) % neutralizer, (0.1~0.6) % adhesive agent, (0.2~0.9) dispersing agent, (0.1~0.5) % levelling agent, (0.3~0.9) % defoaming agent, (0.4~0.9) preservative.Water-based hydrophobic oleophobic Coil Coating Products manufacturing process of the invention is for manufacturing above-mentioned water-based hydrophobic oleophobic Coil Coating Products.Water-based hydrophobic oleophobic Coil Coating Products of the invention can prevent the surface of oil pollution Coil Coating Products.
Description
Technical field
The present invention relates to Coil Coating Products technical fields, more particularly, to a kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacture work
Skill.
Background technique
Existing PCM Coil Coating Products do not have anti-pollution characteristic, and in punching course or finished product use process, surface and oil contaminant cannot
It is quickly and effectively removed, especially kitchen appliance shell, becomes easily infected by greasy dirt, and not easy cleaning, made to people's life use
At great inconvenience.
Summary of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of water-based hydrophobic oleophobic Coil Coating Products, can prevent greasy dirt
Pollution.
The technical solution adopted by the present invention to solve the technical problems is: providing a kind of water-based hydrophobic oleophobic Coil Coating Products, wraps
Include substrate and the dope layer on the substrate, the mass fraction ratio of the formula of the dope layer are as follows: (40~60) %
Resin, (6~13) % isopropanol, (2~7) % butanol, (8~15) % curing agent, (13~22) % deionized water, (0.5~
3) % fluoride, (0.1~0.7) % neutralizer, (0.1~0.6) % adhesive agent, (0.2~0.9) dispersing agent, (0.1~
0.5) % levelling agent, (0.3~0.9) % defoaming agent, (0.4~0.9) preservative.
As a further improvement of the above technical scheme, the mass fraction ratio of the formula of the dope layer are as follows: 50% tree
Rouge, 10% isopropanol, 5% butanol, 12% curing agent, 18% deionized water, 2% fluoride, 0.4% neutralizer, 0.4% adherence
Agent, 0.6% dispersing agent, 0.3% levelling agent, 0.6% defoaming agent, 0.7% preservative.
As a further improvement of the above technical scheme, the resin includes acrylic acid or amino resins.
As a further improvement of the above technical scheme, the curing agent includes different oxygen acid esters.
As a further improvement of the above technical scheme, the dispersing agent includes higher alcohol.
As a further improvement of the above technical scheme, the levelling agent include aromatic hydrocarbons, it is ketone, any one in lipid
Kind.
As a further improvement of the above technical scheme, the defoaming agent includes silicone oil or vegetable oil.
The present invention also provides a kind of water-based hydrophobic oleophobic Coil Coating Products manufacturing process, for manufacturing above-mentioned water-based hydrophobic oleophobic
Coil Coating Products include the following steps: S1, configure coating according to predetermined component;S2 is successively diluted configured coating, stirs
It mixes, filter;S3, coating roll after treatment are applied on substrate;S4 forms dope layer after overbaking, cooling on substrate.
The beneficial effects of the present invention are:
The present invention provides a kind of water-based hydrophobic oleophobic Coil Coating Products, dope layer is arranged on substrate, dope layer is using specific
Component prevents greasy dirt to be infected with color coating plate surface so that dope layer has the characteristic of water-based hydrophobic oleophobic.
Detailed description of the invention
Present invention will be further explained below with reference to the attached drawings and examples.
Fig. 1 is the structural schematic diagram of the water-based hydrophobic oleophobic Coil Coating Products of one embodiment of the invention;
Fig. 2 is the effect picture scribbled in common color coating plate surface;
Fig. 3 is effect picture of the Coil Coating Products of Fig. 2 after wiping;
Fig. 4 is the effect picture that water-based hydrophobic oleophobic color coating plate surface of the invention is scribbled;
Fig. 5 is effect picture of the Coil Coating Products of Fig. 4 after wiping;
Fig. 6 is the flow chart of the manufacturing process of the water-based hydrophobic oleophobic Coil Coating Products of one embodiment of the invention.
Specific embodiment
It is carried out below with reference to technical effect of the embodiment and attached drawing to design of the invention, specific structure and generation clear
Chu, complete description, to be completely understood by the purpose of the present invention, scheme and effect.It should be noted that the case where not conflicting
Under, the features in the embodiments and the embodiments of the present application can be combined with each other.
It should be noted that unless otherwise specified, when a certain feature referred to as " fixation ", " connection " are in another feature,
It can directly fix, be connected to another feature, and can also fix, be connected to another feature indirectly.In addition, this
The descriptions such as up, down, left, right, before and after used in invention are only relative to the mutual of each component part of the invention in attached drawing
For positional relationship.
In addition, unless otherwise defined, the technology of all technical and scientific terms used herein and the art
The normally understood meaning of personnel is identical.Term used in the description is intended merely to description specific embodiment herein, without
It is to limit the present invention.Term " and or " used herein includes the arbitrary of one or more relevant listed items
Combination.
Referring to Fig.1, the structural schematic diagram of one embodiment of the invention water-based hydrophobic oleophobic Coil Coating Products is shown.It is a kind of aqueous
Hydrophobic oleophobic Coil Coating Products, including substrate 100, dope layer 200, dope layer 200 are set to 100 surface of substrate, and dope layer 200 has
The characteristic of water-based hydrophobic oleophobic can prevent the surface contamination greasy dirt of the Coil Coating Products.
The formula constituent that dope layer 200 uses is (calculating) based on mass fraction: resin, (6~13) % of (40~60) %
Isopropanol, (2~7) % butanol, (8~15) % curing agent, (13~22) % deionized water, (0.5~3) % fluoride, (0.1
~0.7) % neutralizer, (0.1~0.6) % adhesive agent, (0.2~0.9) dispersing agent, (0.1~0.5) % levelling agent, (0.3~
0.9) % defoaming agent, (0.4~0.9) preservative.
Wherein, resin includes acrylic acid or amino resins;Curing agent includes different oxygen acid esters;Dispersing agent includes higher alcohol;Stream
Flat agent includes one of aromatic hydrocarbons, ketone, esters;Defoaming agent includes silicone oil or vegetable oil.
Embodiment 1:
In embodiment 1, the formula constituent ratio that dope layer 200 uses is (calculating) based on mass fraction: 50% resin,
10% isopropanol, 5% butanol, 12% curing agent, 18% deionized water, 2% fluoride, 0.4% neutralizer, 0.4% adhesive agent,
0.6% dispersing agent, 0.3% levelling agent, 0.6% defoaming agent, 0.7% preservative.Dope layer 200 is using optimal in embodiment 1
Recipe ingredient ratio, referring to Fig. 2 and Fig. 3, Fig. 2 shows the effects scribbled using common Coil Coating Products (not set dope layer) on surface
Fruit figure, Fig. 3 show the effect picture after wiping, comparison diagram 2 and Fig. 3, and common Coil Coating Products surface and oil contaminant is difficult to wipe, then joins
According to the effect picture that Fig. 4 and Fig. 5, Fig. 4 Coil Coating Products (setting dope layer) for showing the present embodiment are scribbled on surface, Fig. 5 is shown
Effect picture of the Coil Coating Products of the present embodiment after wiping, comparison diagram 4 and Fig. 2, it is found that the Coil Coating Products of the present embodiment, table
Face is difficult to form the ink of cleaning, comparison diagram 5 and Fig. 4, and the position after wiping, the surface of Coil Coating Products is substantially not visible greasy dirt
Trace.
Embodiment 2:
In embodiment 2, the formula constituent ratio that dope layer 200 uses is (calculating) based on mass fraction: 40% resin,
13% isopropanol, 7% butanol, 15% curing agent, 17.5% deionized water, 3% fluoride, 0.7% neutralizer, 0.6% adherence
Agent, 0.9% dispersing agent, 0.5% levelling agent, 0.9% defoaming agent, 0.9% preservative.The effect of embodiment 2 and the effect of embodiment 1
Fruit is slightly worse than the effect of embodiment 1.
Embodiment 3:
In embodiment 3, the formula constituent ratio that dope layer 200 uses is (calculating) based on mass fraction: 60% resin,
7% isopropanol, 3% butanol, 10% curing agent, 18% deionized water, 0.8% fluoride, 0.1% neutralizer, 0.1% adherence
Agent, 0.2% dispersing agent, 0.1% levelling agent, 0.3% defoaming agent, 0.4% preservative.The effect of embodiment 3 is slightly worse than embodiment 1
Effect.
The present invention also provides a kind of water-based hydrophobic oleophobic Coil Coating Products manufacturing process, such as Fig. 6, detailed manufacturing process is as follows:
S1, according to above-mentioned dope layer formula constituent proportional arrangement coating, in a preferred embodiment, the formula group of coating
Part ratio is configured according to the formula in embodiment 3.
S2 adds water to be diluted configured coating, is then stirred, and makes it dissolve uniformly, is finally filtered
Processing removes the impurity in solution.
S3 is carried out carrying out roller coating to the surface of substrate using obtained coating solution, be formed on the surface of the substrate initially
Dope layer.
S4, the initial dope layer formed to substrate surface carry out baking processing, and the dope layer for keeping this initial solidifies, then
Cooling treatment is carried out, required dope layer is formed it into.
It is to be illustrated to what preferable implementation of the invention carried out, but the invention is not limited to the implementation above
Example, those skilled in the art can also make various equivalent variations on the premise of without prejudice to spirit of the invention or replace
It changes, these equivalent deformations or replacement are all included in the scope defined by the claims of the present application.
Claims (8)
1. a kind of water-based hydrophobic oleophobic Coil Coating Products, it is characterised in that: the dope layer including substrate and on the substrate, institute
State the mass fraction ratio of the formula of dope layer are as follows: the resin of (40~60) %, (6~13) % isopropanol, (2~7) % butanol,
(8~15) % curing agent, (13~22) % deionized water, (0.5~3) % fluoride, (0.1~0.7) % neutralizer, (0.1~
0.6) % adhesive agent, (0.2~0.9) dispersing agent, (0.1~0.5) % levelling agent, (0.3~0.9) % defoaming agent, (0.4~
0.9) preservative.
2. water-based hydrophobic oleophobic Coil Coating Products according to claim 1, it is characterised in that: the quality of the formula of the dope layer
Fraction scale are as follows: 50% resin, 10% isopropanol, 5% butanol, 12% curing agent, 18% deionized water, 2% fluoride,
0.4% neutralizer, 0.4% adhesive agent, 0.6% dispersing agent, 0.3% levelling agent, 0.6% defoaming agent, 0.7% preservative.
3. water-based hydrophobic oleophobic Coil Coating Products according to claim 1 or 2, it is characterised in that: the resin includes acrylic acid
Or amino resins.
4. water-based hydrophobic oleophobic Coil Coating Products according to claim 1 or 2, it is characterised in that: the curing agent includes different oxygen
Acid esters.
5. water-based hydrophobic oleophobic Coil Coating Products according to claim 1 or 2, it is characterised in that: the dispersing agent includes advanced
Alcohol.
6. water-based hydrophobic oleophobic Coil Coating Products according to claim 1 or 2, it is characterised in that: the levelling agent include aromatic hydrocarbons,
Any one in ketone, lipid.
7. water-based hydrophobic oleophobic Coil Coating Products according to claim 1 or 2, it is characterised in that: the defoaming agent includes silicone oil
Or vegetable oil.
8. a kind of water-based hydrophobic oleophobic Coil Coating Products manufacturing process, for manufacturing as according to any one of claims 1 to 7 aqueous
Hydrophobic oleophobic Coil Coating Products, characterized by the following steps:
S1 configures coating according to predetermined component;
S2 is successively diluted configured coating, stirs, filters;
S3, coating roll after treatment are applied on substrate;
S4 forms dope layer after overbaking, cooling on substrate.
Priority Applications (1)
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CN201910583356.5A CN110387174A (en) | 2019-07-01 | 2019-07-01 | A kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacturing process |
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CN201910583356.5A CN110387174A (en) | 2019-07-01 | 2019-07-01 | A kind of water-based hydrophobic oleophobic Coil Coating Products and its manufacturing process |
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Citations (6)
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CN1441147A (en) * | 2003-03-14 | 2003-09-10 | 国玉江 | Production process of metal pipe and rod with hydrophobic, olephobic and three-preventing functions and the paint used |
CN103097576A (en) * | 2010-06-30 | 2013-05-08 | 日新制钢株式会社 | Coated steel sheet having excellent corrosion resistance and alkali resistance |
CN104403538A (en) * | 2014-12-08 | 2015-03-11 | 上海涂料有限公司技术中心 | High-corrosion-resistance, high-weather-resistance and excellent-hydrophobicity chromium-free fingerprint-resistant coating used for galvanized steel sheet |
CN107858046A (en) * | 2017-10-31 | 2018-03-30 | 郑州大学 | A kind of super-hydrophobic coat with automatically cleaning and antibacterial functions and preparation method thereof |
CN109251613A (en) * | 2018-08-09 | 2019-01-22 | 深圳华美板材有限公司 | A kind of aqueous PCM steel plate and its manufacturing process |
CN109777291A (en) * | 2019-01-11 | 2019-05-21 | 湖北新四海化工股份有限公司 | A kind of self-cleaning glass hydrophobing agent |
-
2019
- 2019-07-01 CN CN201910583356.5A patent/CN110387174A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1441147A (en) * | 2003-03-14 | 2003-09-10 | 国玉江 | Production process of metal pipe and rod with hydrophobic, olephobic and three-preventing functions and the paint used |
CN103097576A (en) * | 2010-06-30 | 2013-05-08 | 日新制钢株式会社 | Coated steel sheet having excellent corrosion resistance and alkali resistance |
CN104403538A (en) * | 2014-12-08 | 2015-03-11 | 上海涂料有限公司技术中心 | High-corrosion-resistance, high-weather-resistance and excellent-hydrophobicity chromium-free fingerprint-resistant coating used for galvanized steel sheet |
CN107858046A (en) * | 2017-10-31 | 2018-03-30 | 郑州大学 | A kind of super-hydrophobic coat with automatically cleaning and antibacterial functions and preparation method thereof |
CN109251613A (en) * | 2018-08-09 | 2019-01-22 | 深圳华美板材有限公司 | A kind of aqueous PCM steel plate and its manufacturing process |
CN109777291A (en) * | 2019-01-11 | 2019-05-21 | 湖北新四海化工股份有限公司 | A kind of self-cleaning glass hydrophobing agent |
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SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20210210 Address after: 518000 Room 501, unit 4, No.2, Huamei Industrial Zone, Dongfang community, Songgang street, Bao'an District, Shenzhen City, Guangdong Province Applicant after: Shenzhen Huamei metal material technology Co.,Ltd. Address before: 518000 Huamei metal material industrial park, Songgang street, Bao'an District, Shenzhen City, Guangdong Province Applicant before: SHENZHEN WELMETAL PANEL Co.,Ltd. |
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RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191029 |