CN105885598A - Environment-friendly high-water-resistance glazing paint - Google Patents
Environment-friendly high-water-resistance glazing paint Download PDFInfo
- Publication number
- CN105885598A CN105885598A CN201610328796.2A CN201610328796A CN105885598A CN 105885598 A CN105885598 A CN 105885598A CN 201610328796 A CN201610328796 A CN 201610328796A CN 105885598 A CN105885598 A CN 105885598A
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- glazing paint
- environment
- paint
- copolymer resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses an environment-friendly high-water-resistance glazing paint which comprises the following components in parts by mass: 30-40 parts of acrylate copolymer resin, 10-15 parts of nano titanium dioxide, 8-12 parts of emulsifier, 1-2 parts of initiator, 0.5-1.5 parts of defoaming agent, 0.5-1.5 parts of plasticizer and 33-46 parts of deionized water. The preparation technique of the glazing paint comprises the following steps: (1) mixing the deionized water, emulsifier and acrylate copolymer resin according to the formula quantities, and stirring for 10-15 minutes; (2) adding the initiator, defoaming agent and plasticizer according to the formula quantities, and reacting at 120-140 DEG C for 1.5-2 hours; and (3) after the reaction finishes, cooling to 40-50 DEG C, and filtering to remove impurities, thereby obtaining the glazing paint. The coating prepared from the paint has the advantages of high water resistance and high glossiness, and has the self-cleaning property.
Description
Technical field
The present invention relates to printing technology, particularly relate to a kind of environment-friendly type enhanced water resistance glazing paint.
Background technology
On be just coated with (or spray, print) water white coating of last layer at printed matter surface, through levelling, be dried (press polish) after form uniform and thin transparent optical bright layers at printed matter surface processing method.Leaflet glazing can improve and improve appearance and the serviceability of leaflet, the most also has the performance of protection leaflet, is to improve printing quality and the important means of product specification.
What glazing process was initially use is solvent-borne type oil polish, not only damages the health of operator, and pollutes environment, and therefore, Environmental Water Glazing Oil is subject to people's attention.But, existing water lustering oil is after the dried coating film that glazing process obtains, and water-resistant coating is the highest, glossiness is low, along with the generalization of oil polish purposes, people are more and more higher to the requirement of oil polish resistance to water, and the oil polish preparing enhanced water resistance is the demand in market.
Summary of the invention
Present invention mainly solves technical problem is that: for the deficiencies in the prior art, it is provided that a kind of environment-friendly type enhanced water resistance glazing paint, water-resistant coating is good, glossiness is high, has self-cleaning performance simultaneously.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of environment-friendly type enhanced water resistance glazing paint, and described glazing paint includes the material composition that following mass parts forms: acrylic copolymer resin 30-40 part, nano titanium oxide 10-15 part, emulsifying agent 8-12 part, initiator 1-2 part, defoamer 0.5-1.5 part, plasticizer 0.5-1.5 part, deionized water 33-46 part；
The preparation technology of described glazing paint comprises the steps: that deionized water, emulsifying agent and the acrylic copolymer resin of above-mentioned formula ratio are first mixed by (1), stirs 10-15min；(2) it is subsequently adding the initiator of formula ratio, defoamer, plasticizer, at 120-140 DEG C, reacts 1.5-2h；(3) after reaction terminates, it is cooled to 40-50 DEG C, filters and go the removal of impurity i.e. to obtain described glazing paint.
In a preferred embodiment of the present invention, the particle diameter of described acrylic copolymer resin is 10-15 μm.
In a preferred embodiment of the present invention, the particle diameter of described nano titanium oxide is 30-40nm.
In a preferred embodiment of the present invention, described emulsifying agent is prepared through poly-and reaction by methyl methacrylate, butyl acrylate, acrylic acid, 2-(Acryloyloxy)ethanol.
The invention has the beneficial effects as follows: by optimizing composition and the proportioning of water glazing coating, and use advantages of simple polyreaction prepare environment-friendly type enhanced water resistance glazing paint, have the advantages that water-resistant coating is good, glossiness is high, simultaneously added with nano titanium oxide, coating is made to have self-cleaning performance.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
The embodiment of the present invention includes:
Embodiment one:
A kind of environment-friendly type enhanced water resistance glazing paint, described glazing paint includes the material composition that following mass parts forms: acrylic copolymer resin 30 parts, nano titanium oxide 12 parts, emulsifying agent 10 parts, initiator 1 part, defoamer 0.5 part, plasticizer 0.5 part, deionized water 46 parts；
The preparation technology of described glazing paint comprises the steps: that deionized water, emulsifying agent and the acrylic copolymer resin of above-mentioned formula ratio are first mixed by (1), stirs 10min；(2) it is subsequently adding the initiator of formula ratio, defoamer, plasticizer, at 120 DEG C, reacts 1.5h；(3) after reaction terminates, it is cooled to 40 DEG C, filters and go the removal of impurity i.e. to obtain described glazing paint.
Wherein, the particle diameter of described acrylic copolymer resin is 10 μm, and the particle diameter of described nano titanium oxide is 30nm.
Described emulsifying agent is prepared through poly-and reaction by methyl methacrylate, butyl acrylate, acrylic acid, 2-(Acryloyloxy)ethanol.
Embodiment two:
A kind of environment-friendly type enhanced water resistance glazing paint, described glazing paint includes the material composition that following mass parts forms: acrylic copolymer resin 35 parts, nano titanium oxide 15 parts, emulsifying agent 12 parts, initiator 2 parts, defoamer 1.5 parts, plasticizer 1.5 parts, deionized water 33 parts；
The preparation technology of described glazing paint comprises the steps: that deionized water, emulsifying agent and the acrylic copolymer resin of above-mentioned formula ratio are first mixed by (1), stirs 12min；(2) it is subsequently adding the initiator of formula ratio, defoamer, plasticizer, at 130 DEG C, reacts 1.5h；(3) after reaction terminates, it is cooled to 45 DEG C, filters and go the removal of impurity i.e. to obtain described glazing paint.
Wherein, the particle diameter of described acrylic copolymer resin is 12 μm, and the particle diameter of described nano titanium oxide is 35nm.
Described emulsifying agent is prepared through poly-and reaction by methyl methacrylate, butyl acrylate, acrylic acid, 2-(Acryloyloxy)ethanol.
Embodiment three:
A kind of environment-friendly type enhanced water resistance glazing paint, described glazing paint includes the material composition that following mass parts forms: acrylic copolymer resin 40 parts, nano titanium oxide 10 parts, emulsifying agent 8 parts, initiator 1 part, defoamer 1 part, plasticizer 1 part, deionized water 39 parts；
The preparation technology of described glazing paint comprises the steps: that deionized water, emulsifying agent and the acrylic copolymer resin of above-mentioned formula ratio are first mixed by (1), stirs 15min；(2) it is subsequently adding the initiator of formula ratio, defoamer, plasticizer, at 140 DEG C, reacts 2h；(3) after reaction terminates, it is cooled to 50 DEG C, filters and go the removal of impurity i.e. to obtain described glazing paint.
Wherein, the particle diameter of described acrylic copolymer resin is 15 μm, and the particle diameter of described nano titanium oxide is 40nm.
Described emulsifying agent is prepared through poly-and reaction by methyl methacrylate, butyl acrylate, acrylic acid, 2-(Acryloyloxy)ethanol.
Present invention is disclosed a kind of environment-friendly type enhanced water resistance glazing paint, by optimizing composition and the proportioning of water glazing coating, and use advantages of simple polyreaction prepare environment-friendly type enhanced water resistance glazing paint, have the advantages that water-resistant coating is good, glossiness is high, simultaneously added with nano titanium oxide, coating is made to have self-cleaning performance.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, the most in like manner it is included in the scope of patent protection of the present invention.
Claims (4)
1. an environment-friendly type enhanced water resistance glazing paint, it is characterized in that, described glazing paint includes the material composition that following mass parts forms: acrylic copolymer resin 30-40 part, nano titanium oxide 10-15 part, emulsifying agent 8-12 part, initiator 1-2 part, defoamer 0.5-1.5 part, plasticizer 0.5-1.5 part, deionized water 33-46 part；
The preparation technology of described glazing paint comprises the steps: that deionized water, emulsifying agent and the acrylic copolymer resin of above-mentioned formula ratio are first mixed by (1), stirs 10-15min；(2) it is subsequently adding the initiator of formula ratio, defoamer, plasticizer, at 120-140 DEG C, reacts 1.5-2h；(3) after reaction terminates, it is cooled to 40-50 DEG C, filters and go the removal of impurity i.e. to obtain described glazing paint.
Environment-friendly type enhanced water resistance glazing paint the most according to claim 1, it is characterised in that the particle diameter of described acrylic copolymer resin is 10-15 μm.
Environment-friendly type enhanced water resistance glazing paint the most according to claim 1, it is characterised in that the particle diameter of described nano titanium oxide is 30-40nm.
Environment-friendly type enhanced water resistance glazing paint the most according to claim 1, it is characterised in that described emulsifying agent is prepared through poly-and reaction by methyl methacrylate, butyl acrylate, acrylic acid, 2-(Acryloyloxy)ethanol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610328796.2A CN105885598A (en) | 2016-05-18 | 2016-05-18 | Environment-friendly high-water-resistance glazing paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610328796.2A CN105885598A (en) | 2016-05-18 | 2016-05-18 | Environment-friendly high-water-resistance glazing paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105885598A true CN105885598A (en) | 2016-08-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610328796.2A Pending CN105885598A (en) | 2016-05-18 | 2016-05-18 | Environment-friendly high-water-resistance glazing paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN105885598A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610728A (en) * | 2017-01-18 | 2018-10-02 | 赵鹏飞 | Environment-friendlywater-based water-based paint |
| CN109278435A (en) * | 2018-09-10 | 2019-01-29 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of environmental protection sense of touch oil glazing process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300211A (en) * | 2003-03-28 | 2004-10-28 | Asahi Kasei Chemicals Corp | Curable aqueous coating composition |
| CN1621436A (en) * | 2003-11-26 | 2005-06-01 | 中国科学院成都有机化学有限公司 | Crosslinkable macromolecular emulsifier and its preparing process |
| CN102517983A (en) * | 2011-12-31 | 2012-06-27 | 上海东升新材料有限公司 | High-luster water-based paint for papermaking coating and preparation method thereof |
| CN102533034A (en) * | 2011-11-22 | 2012-07-04 | 上海东升新材料有限公司 | Preparation method and application of high-glaze aqueous glazing paint |
| CN102587203A (en) * | 2011-12-31 | 2012-07-18 | 上海东升新材料有限公司 | High-gloss water-borne coating and preparation method as well as application thereof |
-
2016
- 2016-05-18 CN CN201610328796.2A patent/CN105885598A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300211A (en) * | 2003-03-28 | 2004-10-28 | Asahi Kasei Chemicals Corp | Curable aqueous coating composition |
| CN1621436A (en) * | 2003-11-26 | 2005-06-01 | 中国科学院成都有机化学有限公司 | Crosslinkable macromolecular emulsifier and its preparing process |
| CN102533034A (en) * | 2011-11-22 | 2012-07-04 | 上海东升新材料有限公司 | Preparation method and application of high-glaze aqueous glazing paint |
| CN102517983A (en) * | 2011-12-31 | 2012-06-27 | 上海东升新材料有限公司 | High-luster water-based paint for papermaking coating and preparation method thereof |
| CN102587203A (en) * | 2011-12-31 | 2012-07-18 | 上海东升新材料有限公司 | High-gloss water-borne coating and preparation method as well as application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 尚堆才等: "《精细化学品绿色合成技术与实例》", 31 March 2011, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108610728A (en) * | 2017-01-18 | 2018-10-02 | 赵鹏飞 | Environment-friendlywater-based water-based paint |
| CN109278435A (en) * | 2018-09-10 | 2019-01-29 | 河南省防伪保密印刷公司（河南省邮电印刷厂） | A kind of environmental protection sense of touch oil glazing process |
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Application publication date: 20160824 |