CN110387168A - A kind of environmental protection ultraviolet color-changing mill base, preparation method and application - Google Patents
A kind of environmental protection ultraviolet color-changing mill base, preparation method and application Download PDFInfo
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- CN110387168A CN110387168A CN201910722675.XA CN201910722675A CN110387168A CN 110387168 A CN110387168 A CN 110387168A CN 201910722675 A CN201910722675 A CN 201910722675A CN 110387168 A CN110387168 A CN 110387168A
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- mill base
- ultraviolet
- changing
- color
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/0027—Footwear characterised by the material made at least partially from a material having special colours
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/001—Pigment pastes, e.g. for mixing in paints in aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of environmentally friendly ultraviolet color-changing mill bases, preparation method and application, and raw material is formulated as follows in parts by weight: ultraviolet color-changing powder: 55~68 parts, PVC paste resin: 30~38 parts, diatomite: 8~16 parts, environment-friendly plasticizer: 15~30 parts, PVC resin powder: 16~23 parts, white oil: 15~22 parts, deionized water: 26~43 parts, precipitated calcium carbonate: 11~19 parts, ultraviolet absorber: 2~3 parts, nano silica: 7~12 parts；The present invention is by dual grinding, so that the partial size of discoloration mill base becomes smaller, specific surface area increases, and tinting strength, tinting power is also higher；Fineness is small, glossiness is high, it dispersion effect and has excellent storage stability, vegetable esters is synthesized using environment-friendly plasticizer, when in the injection molding medium for dissolving in plastic sandals, foam sandals, it is excellent with the binding performance of plastic sandals, and without aromatic compound, safety is good, passes through ultraviolet color-changing powder, it realizes the automatic color changing function under ultraviolet light irradiation, there is very wide application prospect.
Description
Technical field
The present invention relates to a kind of environmentally friendly ultraviolet color-changing mill bases, preparation method and application, belong to discoloration mill base technical field.
Background technique
Mill base is that mixed slurry obtained from filler material and some auxiliary agents is added in pigment, and mill base is dispersed in paint vehicle,
The coating that could be formed with color, the solvent according to used in mill base is different, and mill base is divided into aqueous color paste, oil pastes, water again
Oily general color paste etc.；It is divided into pigment printing paste, adhesive tape mill base, papermaking mill base, weaving mill base, machinery again according to the purposes of mill base is different
Mill base, toy mill base, latex product mill base etc.；According to using the tool of mill base different, mill base is simply divided into factory by people
With mill base and machine mill base etc..
With the difference of decentralized medium, mill base also has its corresponding type；In actual use, due to the color of addition
Slurry is also easy to produce with product ontology declines in conjunction with dynamics and occurs because of environmental activity phenomena such as color change, for this purpose, feature accordingly,
Some mill bases are applied to discoloration shoes production field, the stronger organic bond of binding force used at present and solvent, all have
Biggish toxicity and carcinogenicity, and these solvents can volatilize to endanger the health of operator in use, simultaneously
Different degrees of pollution can be also caused to the air quality in surrounding enviroment.
In the prior art, the Chinese patent that number of patent application is CN 201510115707.1 discloses a kind of " environmental protection mill base
Material, the raw material according to mass percent include epoxy resin 33-42%, polyethylene glycol 11-20%, paraffin wax emulsions 8-13%,
Mandarin oil 3-8%, nonionic surface active agent 5-10%, titanium dioxide 4-7%, oxide powder and zinc 3-8%, acrylic acid ester emulsion 7-
15% and toner 1-2%；The present invention and the combination dynamics of product ontology are good, have good insulation performance, water-fast, oil resistant,
The weather resistances such as acid and alkali-resistance, wear-resisting, anti-corrosive properties；Due to being not added with volatile, inflammable toxic organic solvents, the present invention has not
Volatilization, nontoxic, environmentally friendly feature have prevented the safety issues such as inflammable of common mill base material during storage ", but still
Existing defects are exposed to the sun through high temperature in the hot summer, and mill base loss of gloss problem is serious, not ageing-resistant.
In the prior art, number of patent application is that the Chinese patent of CN 201621379032.8 discloses that " a kind of ultraviolet light is hidden
Shape color-changing shoes, including upper of a shoe and sole, the upper of a shoe are fixedly connected on the top of sole, and the upper of a shoe includes upper of a shoe internal layer, institute
The outer surface for stating upper of a shoe internal layer is fixedly connected with the surface of skin corium, and the skin corium is fixedly connected far from the surface of upper of a shoe internal layer
There is stealth material, the upper surface of the sole is in contact with the lower surface of insole, the lower surface of the insole and the top of supporting block
Portion is fixedly connected, and the bottom insertion empty slot of the supporting block and the inside for extending to empty slot, the empty slot are provided on sole；It should
Ultraviolet light stealth color-changing shoes make shoes that can occur pattern under the shining of sunlight by the setting of stealth material, solve existing
Some shoes are all excessively dull, allow shoes so that pattern is changed according to the variation of sunlight, so that shoes is more had individual character in this way
And fashion, shoes can be more suitable for the consumer of youth, fashion, individual character and trend ", but still existing defects, stealth material with
The binding ability of shoes is poor, is easy to fall off, and stability is poor.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of environmentally friendly ultraviolet color-changing mill bases, preparation method and application.
(2) technical solution
Environmentally friendly ultraviolet color-changing mill base of the invention, raw material are formulated as follows in parts by weight:
Ultraviolet color-changing powder: 55~68 parts
PVC paste resin: 30~38 parts
Diatomite: 8~16 parts
Environment-friendly plasticizer: 15~30 parts
PVC resin powder: 16~23 parts
White oil: 15~22 parts
Deionized water: 26~43 parts
Precipitated calcium carbonate: 11~19 parts
Ultraviolet absorber: 2~3 parts
Nano silica: 7~12 parts.
Further, the ultraviolet absorber is salicylate type ultraviolet light absorber.
Further, the environment-friendly plasticizer is synthesis vegetable esters.
Further, the size range of the nano silica is in 1~100nm.
Further, the partial size of the light sodium carbonate is 1~3um.
The preparation method of environmentally friendly ultraviolet color-changing mill base, comprising the following steps:
S1: grinding: by whole PVC paste resin, PVC resin powder and ultraviolet color-changing powder be transferred in three-roll grinder with
The grinding rate of 100r/min carries out rough lapping 5 times, obtains the uniformly mixed particle that effective nominal diameter is no more than 0.5cm；
S2: toning: white oil, environment-friendly plasticizer are dissolved in deionized water, the stirring of high-speed mixer 3000r/min is used
Rate is stirred, so that white oil, environment-friendly plasticizer are dissolved in deionized water and are uniformly mixed；
S3: dispersion: the ground hybrid particles of S1 are transferred in dispersion machine, and S2 system is added while being dispersed with stirring
The material liquid obtained adds precipitated calcium carbonate, ultraviolet absorber, nano silica and diatom after material liquid is added completely into
Soil disperses 1h；
S4: it grinds again: the scattered material of S3 is put into three-roll grinder, ground with the grinding rate of 150r/min
3 times, the partial size for being ground to mill base internal particle is 15nm, obtains environmentally friendly ultraviolet color-changing mill base.
Further, the preparation process of the ultraviolet color-changing mill base carries out in the environment of no ultraviolet light irradiates.
The application of environmentally friendly ultraviolet color-changing mill base, the method includes the ultraviolet color-changing mill base is dissolved in plastic sandals
It is uniformly mixed in the injection molding medium of production, the mass percent of the discoloration mill base and plastic medium is 1%~20%.
(3) beneficial effect
The present invention compared with prior art, compare by environmentally friendly ultraviolet color-changing mill base of the invention, preparation method and application
Slurry is made in pigment in traditional, is then added in coating and coating is coloured, this ultraviolet color-changing mill base passes through dual
Grinding, so that the partial size of discoloration mill base becomes smaller, specific surface area increases, and the light energy of absorption increases, and perceives the sensitivity of ultraviolet light
It greatly improves, thus covering power also just increases, tinting strength, tinting power is also higher；Fineness is small, and gloss is higher, dispersion effect and storage
Excellent in stability synthesizes vegetable esters using environment-friendly plasticizer, when in the injection molding medium for dissolving in plastic sandals, foam sandals, with
The binding performance of plastic sandals is excellent, and without aromatic compound, safety is good, by ultraviolet color-changing powder, realizes in ultraviolet light
Automatic color changing function under irradiation has very wide application prospect.
Nontoxic, tasteless, pollution-free nanometer grade silica has to anti-ultraviolet optical property, it is ultraviolet to improve its
Line discoloration mill base anti-aging property.
Specific embodiment
The ultraviolet absorber that following embodiment uses is salicylate type ultraviolet light absorber.
The environment-friendly plasticizer that following embodiment uses is synthesis vegetable esters.
The size for the nano silica that following embodiment uses is in 1~100nm.
The partial size for the light sodium carbonate that following embodiment uses is 1~3um.
Embodiment 1:
In the embodiment of the present invention, a kind of environmental protection ultraviolet color-changing mill base, raw material is formulated as follows in parts by weight:
Ultraviolet color-changing powder: 55 parts
PVC paste resin: 30 parts
Diatomite: 8 parts
Environment-friendly plasticizer: 15 parts
PVC resin powder: 16 parts
White oil: 15 parts
Deionized water: 26 parts
Precipitated calcium carbonate: 11 parts
Ultraviolet absorber: 2 parts
Nano silica: 7 parts.
The preparation method of environmentally friendly ultraviolet color-changing mill base, specific steps are as follows:
S1: grinding: by whole PVC paste resin, PVC resin powder and ultraviolet color-changing powder be transferred in three-roll grinder with
The grinding rate of 100r/min carries out rough lapping 5 times, obtains the uniformly mixed particle that effective nominal diameter is no more than 0.5cm；
S2: toning: white oil, environment-friendly plasticizer are dissolved in deionized water, the stirring of high-speed mixer 3000r/min is used
Rate is stirred, so that white oil, environment-friendly plasticizer are dissolved in deionized water and are uniformly mixed；
S3: dispersion: the ground hybrid particles of S1 are transferred in dispersion machine, and S2 system is added while being dispersed with stirring
The material liquid obtained adds precipitated calcium carbonate, ultraviolet absorber, nano silica and diatom after material liquid is added completely into
Soil disperses 1h；
S4: it grinds again: the scattered material of S3 is put into three-roll grinder, ground with the grinding rate of 150r/min
3 times, the partial size for being ground to mill base internal particle is 15nm, obtains environmentally friendly ultraviolet color-changing mill base.
In the injection molding medium for dissolving in plastic sandals of obtained ultraviolet light environmental protection discoloration mill base, dispersion effect and stable storing
Property it is excellent, the binding ability of the sandals of production and the mill base that changes colour is excellent, since ultraviolet color-changing mill base is by dual grinding so that
The partial size of discoloration mill base becomes smaller, and specific surface area increases, and the light energy of absorption increases, and the sensitivity for perceiving ultraviolet light greatly improves,
When being irradiated with ultraviolet radiation, vamp discoloration after losing sunlight/ultraviolet energy, is reduced into original color, nontoxic, nothing
Taste, pollution-free nanometer grade silica have to anti-ultraviolet optical property, it is anti-aging to improve its ultraviolet color-changing mill base
Performance.
Embodiment 2:
In the embodiment of the present invention, a kind of environmental protection ultraviolet color-changing mill base, raw material is formulated as follows in parts by weight:
Ultraviolet color-changing powder: 60 parts
PVC paste resin: 33 parts
Diatomite: 12 parts
Environment-friendly plasticizer: 25 parts
PVC resin powder: 20 parts
White oil: 20 parts
Deionized water: 30 parts
Precipitated calcium carbonate: 15 parts
Ultraviolet absorber: 2 parts
Nano silica: 9 parts.
The preparation method of environmentally friendly ultraviolet color-changing mill base, specific steps are as follows:
S1: grinding: by whole PVC paste resin, PVC resin powder and ultraviolet color-changing powder be transferred in three-roll grinder with
The grinding rate of 100r/min carries out rough lapping 5 times, obtains the uniformly mixed particle that effective nominal diameter is no more than 0.5cm；
S2: toning: white oil, environment-friendly plasticizer are dissolved in deionized water, the stirring of high-speed mixer 3000r/min is used
Rate is stirred, so that white oil, environment-friendly plasticizer are dissolved in deionized water and are uniformly mixed；
S3: dispersion: the ground hybrid particles of S1 are transferred in dispersion machine, and S2 system is added while being dispersed with stirring
The material liquid obtained adds precipitated calcium carbonate, ultraviolet absorber, nano silica and diatom after material liquid is added completely into
Soil disperses 1h；
S4: it grinds again: the scattered material of S3 is put into three-roll grinder, ground with the grinding rate of 150r/min
3 times, the partial size for being ground to mill base internal particle is 15nm, obtains environmentally friendly ultraviolet color-changing mill base.
In the injection molding medium for dissolving in plastic sandals of obtained ultraviolet light environmental protection discoloration mill base, dispersion effect and stable storing
Property it is excellent, the binding ability of the sandals of production and the mill base that changes colour is excellent, since ultraviolet color-changing mill base is by dual grinding so that
The partial size of discoloration mill base becomes smaller, and specific surface area increases, and the light energy of absorption increases, and the sensitivity for perceiving ultraviolet light greatly improves,
When being irradiated with ultraviolet radiation, vamp discoloration after losing sunlight/ultraviolet energy, is reduced into original color, nontoxic, nothing
Taste, pollution-free nanometer grade silica have to anti-ultraviolet optical property, it is anti-aging to improve its ultraviolet color-changing mill base
Performance.
Embodiment 3:
In the embodiment of the present invention, a kind of environmental protection ultraviolet color-changing mill base, raw material is formulated as follows in parts by weight:
Ultraviolet color-changing powder: 68 parts
PVC paste resin: 38 parts
Diatomite: 16 parts
Environment-friendly plasticizer: 30 parts
PVC resin powder: 23 parts
White oil: 22 parts
Deionized water: 43 parts
Precipitated calcium carbonate: 119 parts
Ultraviolet absorber: 3 parts
Nano silica: 12 parts.
The preparation method of environmentally friendly ultraviolet color-changing mill base, specific steps are as follows:
S1: grinding: by whole PVC paste resin, PVC resin powder and ultraviolet color-changing powder be transferred in three-roll grinder with
The grinding rate of 100r/min carries out rough lapping 5 times, obtains the uniformly mixed particle that effective nominal diameter is no more than 0.5cm；
S2: toning: white oil, environment-friendly plasticizer are dissolved in deionized water, the stirring of high-speed mixer 3000r/min is used
Rate is stirred, so that white oil, environment-friendly plasticizer are dissolved in deionized water and are uniformly mixed；
S3: dispersion: the ground hybrid particles of S1 are transferred in dispersion machine, and S2 system is added while being dispersed with stirring
The material liquid obtained adds precipitated calcium carbonate, ultraviolet absorber, nano silica and diatom after material liquid is added completely into
Soil disperses 1h；
S4: it grinds again: the scattered material of S3 is put into three-roll grinder, ground with the grinding rate of 150r/min
3 times, the partial size for being ground to mill base internal particle is 15nm, obtains environmentally friendly ultraviolet color-changing mill base.
In the injection molding medium for dissolving in plastic sandals of obtained ultraviolet light environmental protection discoloration mill base, dispersion effect and stable storing
Property it is excellent, the binding ability of the sandals of production and the mill base that changes colour is excellent, since ultraviolet color-changing mill base is by dual grinding so that
The partial size of discoloration mill base becomes smaller, and specific surface area increases, and the light energy of absorption increases, and the sensitivity for perceiving ultraviolet light greatly improves,
When being irradiated with ultraviolet radiation, vamp discoloration after losing sunlight/ultraviolet energy, is reduced into original color, nontoxic, nothing
Taste, pollution-free nanometer grade silica have to anti-ultraviolet optical property, it is anti-aging to improve its ultraviolet color-changing mill base
Performance.
In the present invention unless specifically defined or limited otherwise, term " installation ", " setting ", " connection ", " fixation ",
Terms such as " being screwed on " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integral；It can be with
It is mechanical connection, is also possible to be electrically connected；It can be directly connected, two can also be can be indirectly connected through an intermediary
The interaction relationship of connection or two elements inside a element, unless otherwise restricted clearly, for the common of this field
For technical staff, the specific meanings of the above terms in the present invention can be understood according to specific conditions.
Above-described embodiment is only better embodiment of the invention, therefore all according to structure described in present patent application range
It makes, the equivalent change or modification that feature and principle are done, is included in present patent application range.
Claims (8)
1. a kind of environmental protection ultraviolet color-changing mill base, it is characterised in that: its raw material is formulated as follows in parts by weight:
Ultraviolet color-changing powder: 55~68 parts
PVC paste resin: 30~38 parts
Diatomite: 8~16 parts
Environment-friendly plasticizer: 15~30 parts
PVC resin powder: 16~23 parts
White oil: 15~22 parts
Deionized water: 26~43 parts
Precipitated calcium carbonate: 11~19 parts
Ultraviolet absorber: 2~3 parts
Nano silica: 7~12 parts.
2. environmental protection ultraviolet color-changing mill base according to claim 1, it is characterised in that: the ultraviolet absorber is salicylic acid
Esters UV absorbers.
3. environmental protection ultraviolet color-changing mill base according to claim 2, it is characterised in that: the environment-friendly plasticizer is that synthesis is planted
Object ester.
4. environmental protection ultraviolet color-changing mill base according to claim 3, it is characterised in that: the size of the nano silica
Range is in 1~100nm.
5. environmental protection ultraviolet color-changing mill base according to claim 4, it is characterised in that: the partial size of the light sodium carbonate is
1~3um.
6. a kind of preparation method of environmentally friendly ultraviolet color-changing mill base as described in any one in claim 1-5, it is characterised in that: packet
Include following steps:
S1: grinding: by whole PVC paste resin, PVC resin powder and ultraviolet color-changing powder be transferred in three-roll grinder with
The grinding rate of 100r/min carries out rough lapping 5 times, obtains the uniformly mixed particle that effective nominal diameter is no more than 0.5cm；
S2: toning: white oil, environment-friendly plasticizer are dissolved in deionized water, the stirring rate of high-speed mixer 3000r/min is used
It is stirred, so that white oil, environment-friendly plasticizer are dissolved in deionized water and are uniformly mixed；
S3: dispersion: the ground hybrid particles of S1 are transferred in dispersion machine, are added made from S2 while being dispersed with stirring
Material liquid adds precipitated calcium carbonate, ultraviolet absorber, nano silica and diatomite after material liquid is added completely into, point
Dissipate 1h；
S4: it grinds again: the scattered material of S3 is put into three-roll grinder, ground 3 times with the grinding rate of 150r/min,
The partial size for being ground to mill base internal particle is 15nm, obtains environmentally friendly ultraviolet color-changing mill base.
7. the preparation method of environmental protection ultraviolet color-changing mill base according to claim 6, it is characterised in that: the ultraviolet light becomes
The preparation process of color mill base carries out in the environment of no ultraviolet light irradiates.
8. a kind of application of environmentally friendly ultraviolet color-changing mill base as described in any one in claim 1-5, it is characterised in that: will be described
Ultraviolet color-changing mill base, which dissolves in the injection molding medium of plastic sandals production, to be uniformly mixed, the matter of the discoloration mill base and plastic medium
Measuring percentage is 1%~20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910722675.XA CN110387168A (en) | 2019-08-06 | 2019-08-06 | A kind of environmental protection ultraviolet color-changing mill base, preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910722675.XA CN110387168A (en) | 2019-08-06 | 2019-08-06 | A kind of environmental protection ultraviolet color-changing mill base, preparation method and application |
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| CN110387168A true CN110387168A (en) | 2019-10-29 |
Family
ID=68288587
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| CN201910722675.XA Pending CN110387168A (en) | 2019-08-06 | 2019-08-06 | A kind of environmental protection ultraviolet color-changing mill base, preparation method and application |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111287004A (en) * | 2020-04-13 | 2020-06-16 | 无锡红豆运动装有限公司 | Anti-counterfeiting color paste and thermal transfer printing method thereof |
| CN111518348A (en) * | 2020-05-25 | 2020-08-11 | 苏州德加画材科技有限公司 | PVC (polyvinyl chloride) environment-friendly color paste and preparation method thereof |
| CN113462100A (en) * | 2021-07-30 | 2021-10-01 | 浙江纳美新材料股份有限公司 | Environment-friendly color paste for polyvinyl chloride and preparation method thereof |
| WO2021195869A1 (en) * | 2020-03-30 | 2021-10-07 | 加通汽车内饰(常熟)有限公司 | Light-transmitting artificial leather, preparation method therefor, and automobile interior |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021195869A1 (en) * | 2020-03-30 | 2021-10-07 | 加通汽车内饰(常熟)有限公司 | Light-transmitting artificial leather, preparation method therefor, and automobile interior |
| CN111287004A (en) * | 2020-04-13 | 2020-06-16 | 无锡红豆运动装有限公司 | Anti-counterfeiting color paste and thermal transfer printing method thereof |
| CN111518348A (en) * | 2020-05-25 | 2020-08-11 | 苏州德加画材科技有限公司 | PVC (polyvinyl chloride) environment-friendly color paste and preparation method thereof |
| CN113462100A (en) * | 2021-07-30 | 2021-10-01 | 浙江纳美新材料股份有限公司 | Environment-friendly color paste for polyvinyl chloride and preparation method thereof |
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Application publication date: 20191029 |