CN110370781B - Copper-clad plate rubberizing drying device - Google Patents
Copper-clad plate rubberizing drying device Download PDFInfo
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- CN110370781B CN110370781B CN201910584006.0A CN201910584006A CN110370781B CN 110370781 B CN110370781 B CN 110370781B CN 201910584006 A CN201910584006 A CN 201910584006A CN 110370781 B CN110370781 B CN 110370781B
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- copper
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- 238000001035 drying Methods 0.000 title claims abstract description 70
- 238000004026 adhesive bonding Methods 0.000 claims abstract description 53
- 239000003292 glue Substances 0.000 claims abstract description 42
- 238000003860 storage Methods 0.000 claims abstract description 11
- 238000010008 shearing Methods 0.000 claims description 27
- 238000005520 cutting process Methods 0.000 claims description 15
- 230000005540 biological transmission Effects 0.000 claims description 7
- 238000004513 sizing Methods 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 description 13
- 239000003365 glass fiber Substances 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000013461 design Methods 0.000 description 8
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000011265 semifinished product Substances 0.000 description 6
- 235000012424 soybean oil Nutrition 0.000 description 6
- 239000003549 soybean oil Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 229910021389 graphene Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
- B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
- B05C1/08—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
- B05C1/10—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the liquid or other fluent material being supplied from inside the roller
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C13/00—Means for manipulating or holding work, e.g. for separate articles
- B05C13/02—Means for manipulating or holding work, e.g. for separate articles for particular articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C9/00—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
- B05C9/08—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
- B05C9/14—Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation the auxiliary operation involving heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06H—MARKING, INSPECTING, SEAMING OR SEVERING TEXTILE MATERIALS
- D06H7/00—Apparatus or processes for cutting, or otherwise severing, specially adapted for the cutting, or otherwise severing, of textile materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0022—Glass fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
- D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/022—Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/02—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/04—Time
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/08—PCBs, i.e. printed circuit boards
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Drying Of Solid Materials (AREA)
Abstract
The invention belongs to the technical field of copper-clad plate preparation, and particularly relates to a copper-clad plate gluing and drying device which comprises a traction bracket and a drying box; the traction support is provided with two traction supports which are right-side-to-side, the traction support is in an inverted U shape, a lug is integrally formed at the right end of the top surface of the traction support, an inclined supporting block which is low at the left side and high at the right side is integrally formed at the top end of the right side surface of the traction support, a gluing component is installed between the two right-side-to-side lugs at the front side and the rear side, the gluing component also is installed between the two right-to-side supporting blocks at the front side and the rear side, the gluing component comprises a gluing motor, a gluing roller, a fixing plate and a glue storage box, the fixing plate is fixedly installed on a power output shaft of the gluing motor, the glue storage box is installed on the fixing plate, a sleeve.
Description
Technical Field
The invention belongs to the technical field of copper-clad plate preparation, and particularly relates to a copper-clad plate gluing and drying device.
Background
The copper-clad plate is an extremely important basic material of the printed circuit board, and various printed circuit boards with different forms and different functions are manufactured into different printed circuits (single-sided, double-sided and multilayer) by selectively carrying out the working procedures of processing, etching, drilling, copper plating and the like on the copper-clad plate. The copper-clad plate is used as a substrate material in the manufacture of the printed circuit board, mainly plays roles of interconnection conduction, insulation and support for the printed circuit board, and has great influence on the transmission speed, energy loss, characteristic impedance and the like of signals in a circuit, so that the performance, the quality, the processability in the manufacture, the manufacture level, the manufacture cost, the long-term reliability and the stability of the printed circuit board are greatly dependent on the copper-clad plate. The copper-clad plate is an indispensable important electronic material for all electronic complete machines, including all electronic products such as aviation, aerospace, remote sensing, remote measuring, remote control, communication, computers, industrial control, household appliances and even advanced toys for children. With the increasing level of technology, some special electronic copper clad laminates have been used to directly manufacture printed electronic components in recent years.
Due to the miniaturization, light weight and thinness of electronic products, the printed circuit board is forced to have various high-quality and high-technical characteristics, so that the manufacturing technology of the printed circuit board directly relates to various high and new technologies in the present day, and the copper-clad plate, which is the main and most important material, must have various high-quality and high-technical characteristics along with the manufacturing technology of the printed circuit board. Therefore, the status of copper-clad plate in electronic information industry is more and more important.
The structure of the copper-clad plate comprises: the insulating laminated board composed of the substrate, the high polymer synthetic resin and the reinforcing material can be used as the substrate of the copper-clad plate; the copper foil is a key material for manufacturing the copper-clad plate and has high conductivity and good weldability; the copper-clad plate adhesive is an important factor for firmly covering the copper foil on the substrate, and the peel strength of the copper-clad plate mainly depends on the performance of the adhesive.
In the preparation process of the copper-clad plate, the gluing and drying of the substrate are the most important processes, and the traditional method comprises the following steps: pumping the mixed glue solution into a glue tank by a pump, continuously immersing the glass fiber cloth into the glue tank by a gluing machine to enable the glue solution to be adhered to the glass fiber cloth, and drying the glued glass fiber cloth in an oven of the gluing machine at high temperature to form a bonding sheet. Because the single piece is directly dried in an oven at 200-300 ℃ after the glue is applied and the surface is dried, the baking time is 20 minutes to 1 hour, the method has the defects that: 1) the glue is cut, stacked into a required thickness and pressed, so that the foaming is easy to occur, the reject ratio is high, the gluing speed is low, the speed is only about 10 minutes and 5-10 meters, and the gluing efficiency is low; 2) the height of a gluing machine is limited (6-9 m high), and the height of a factory building is difficult to match; 3) the precision requirement on the laminating machine is high, and the equipment investment is large; 4) the production of workers is complex, the process is difficult to master, and defective products are easy to produce; 5) the electrical properties are not stable enough; 6) the pressing time is long, and the electricity cost is 30-50% more; 7) in Guangdong areas, typhoons are more, and factory buildings need to be made into dust-free workshops for a long time; typhoon is afraid, and the finding of a factory building is difficult; once the plant is damaged by typhoon, the plant is shut down (the maintenance equipment consumes electricity and time, and the production is influenced).
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a copper-clad plate gluing and drying device, which is used for solving the problems of high reject ratio, low gluing speed and the like of the existing copper-clad plate gluing and drying device and device.
In order to solve the technical problems, the invention adopts the following technical scheme:
copper-clad plate rubberizing drying device includes the following step:
step one, preparing glue solution;
step two, gluing the glass fiber cloth:
adding the glue solution prepared in the step one into a glue storage box, and then drawing and guiding glass fiber cloth to realize gluing;
step three, surface drying treatment:
conveying the semi-finished product glued in the step two to a surface drying box for surface drying, wherein the surface drying time is 5-30 seconds, and the temperature of the surface drying box is controlled between 80-150 ℃ to realize surface drying;
step four, cutting:
conveying the semi-finished product dried in the third step to a cutting bracket for cutting to obtain the required size;
step five, stacking and drying:
and (4) stacking a plurality of semi-finished products cut in the step four, and drying in a drying box, wherein the drying time is 18-22 minutes, and the temperature of the drying box is controlled between 150-300 ℃.
Further, the step one comprises the following raw materials in parts by weight:
brominated bisphenol A resin 130-135 parts 14PT resin 1400-1500 parts
2000 parts of epoxy soybean oil modified phenolic resin 1200-800 parts of epoxy resin 500-800 parts
Phenolic resin 150 part, flame retardant 300 part, and flame retardant 700 part
Curing agent 250 and 350 parts of curing accelerator 1-5 parts
50-150 parts of inorganic filler and 300 parts of organic solvent 100-
The epoxidized soybean oil modified phenolic resin comprises the following raw materials in parts by weight:
epoxidized soybean oil 1200-1600 parts phenol 500-700 parts
1000-1300 parts of bisphenol A, 5-10 parts of 2-methylimidazole
800 portions of formaldehyde-containing alkali catalyst and 1200 portions of alkali catalyst, 60 to 150 portions
Solvent 2500-3000 parts of graphene 5-60 parts
5-40 parts of graphene oxide.
Further, in the third step, the surface drying time is 30 seconds, and the temperature of the surface drying box is 150 ℃.
Further, in the fifth step, the drying time is 20 minutes, and the temperature of the drying box is 200-300 ℃.
The copper-clad plate gluing and drying device comprises a traction bracket and a drying box;
the traction support is provided with two traction supports which are right-angled front and back, the traction support is in an inverted U shape, a lug is integrally formed at the right end of the top surface of the traction support, an inclined supporting block which is low at the left and high at the right is integrally formed at the top end of the right side surface of the traction support, a gluing component is arranged between the two lugs which are right-angled front and back, a gluing component is also arranged between the two inclined supporting blocks which are right-angled front and back, the gluing component comprises a gluing motor, a gluing roller, a fixing plate and a glue storage box, the fixing plate is fixedly arranged on a power output shaft of the gluing motor, the glue storage box is arranged on the fixing plate, a sleeve shaft is arranged at the rear end of the power output shaft of the gluing motor in a transmission manner, the gluing roller is sleeved on the sleeve shaft and is fixed with the sleeve shaft, first bearings are fixedly arranged at the two, the gluing roller is of a hollow shell structure, a plurality of glue outlet holes are formed in the shell wall of the gluing roller, the glue storage box is communicated with the inner cavity of the gluing roller, a first motor and a second motor are installed at the left end of the traction support close to the front from bottom to top, two rows of guide rollers capable of rolling are installed between the beams of the two traction supports which are right opposite from the front to the rear, the number of the guide rollers on the upper row is three, first gears are fixedly installed at the front ends of the three guide rollers, first toothed belts are meshed and wound on the three first gears, a power output shaft of the second motor is fixed with the first gear at the leftmost end, second gears are fixedly installed at the front ends of the two guide rollers on the lower row, second toothed belts are meshed and wound on the two second gears, the power output shaft of the first motor is fixed with the second gear at the leftmost end, and the second motor rotates anticlockwise, the first motor rotates clockwise;
the drying oven is characterized in that a U-shaped support is integrally formed at the bottom of the left end of the drying oven, the opening of the U-shaped support faces to the left, vertical plates are fixedly mounted in the middle of front and rear cross beams of the U-shaped support, rotatable guide rollers are mounted at the tops of the front and rear opposite vertical plates, a guide motor is mounted at the front end of each guide roller in a transmission manner, vertical columns are fixedly mounted at the right parts of the front and rear cross beams of the U-shaped support, a surface drying oven is fixedly mounted at the top ends of the front and rear opposite vertical columns, a shearing mechanism is mounted at the right end of the top surface of the surface drying oven and comprises a top plate, a front side plate, a rear side plate and a shearing assembly, the tops of the front side plate and the rear side plate are detachably connected with the front and rear ends of the top plate, the shearing assembly comprises a third motor and a shearing guide rod, the third motor is mounted at the, the front end of the shearing guide rod is fixed with the front side plate, the rear end of the shearing guide rod is fixed with the rear side plate, a convex plate is integrally formed on the top surface of the front end of the shearing guide rod, a mounting blind hole is formed in the top surface of the convex plate, a second bearing is mounted in the mounting blind hole, a short column is fixed on the inner ring of the second bearing, a second umbrella-shaped gear capable of being meshed with the first umbrella-shaped gear is fixed at the top end of the short column, a first connecting rod is vertically fixed on the outer wall of the short column below the second umbrella-shaped gear, a second connecting rod is hinged to the free end of the first connecting rod, a sliding plate is hinged to the free end of the second connecting rod, the sliding plate is sleeved on the shearing guide rod and can slide back and forth along the shearing guide rod, a hydraulic cylinder is mounted on the bottom surface of the sliding plate, an L-shaped plate is fixedly mounted at the tail end of a telescopic rod of the hydraulic cylinder vertically downward, install the fourth motor on the horizontal board of L shaped plate, the telescopic link of the power output shaft hydraulic cylinder that staggers perpendicularly of fourth motor, the power output shaft of fourth motor passes the vertical board of L shaped plate and has the saw cutting dish in terminal department fixed mounting, two apex angle position fixed mounting have the landing leg around the bottom surface right-hand member of stoving case, two spinal branch poles are all installed at both sides board top around the stoving case, four the support is tailor to the top fixed mounting of spinal branch pole, tailor the support and be the U-shaped that the opening is rightwards, tailor the support and seted up the slotting in the below of saw cutting dish, tailor two inner walls around the opening of support and seted up spacing step, two spacing step go up the card and be equipped with the inserted block that can the horizontal slip.
Furthermore, a rotatable guide rod is arranged between the inner sides of the left ends of the traction supports which are right opposite to each other in the front-back direction, and limiting discs are integrally formed at the front end and the back end of the guide rod.
Further, integrated into one piece has three conducting bars in the opening of U-shaped support, the conducting bar on the cover be equipped with the slider of horizontal slip, three the slider wear to be equipped with J-shaped gag lever post, thereby the J-shaped gag lever post insert in three slider and fix three slider on the conducting bar, thereby the top surface integrated into one piece of slider has the pole setting to form the structure of falling T shape, the pole setting endotheca be equipped with T shape slider, the lower extreme of T shape slider inserts the pole setting and can slide from top to bottom and fix in the pole setting, T shape slider threaded connection have J shape screw rod, it is three the left end of J shape screw rod is installed and is connect gluey case.
Further, the bottom of the glue receiving box is communicated with a glue return pipe.
Furthermore, the leftmost end of the conducting bar is upwards and vertically turned to form a limiting lug, and the sliding block is limited by the limiting lug.
Furthermore, two hand-pulling holes are formed in the right end of the inserting block.
Compared with the prior art, the invention has the following beneficial effects:
1. the production speed is 50 percent higher (namely the original time from gluing to pressing and cooling is 4 to 5 hours, which is now 2.5 hours), and the new technology can reach 10 minutes and 30 to 50 meters;
2. the new technology has low requirement on the precision of the laminating machine, and can reduce the equipment investment cost;
3. the success rate of passing the test reaches 100 percent;
4. the pressing time is short, and the electricity is saved by 30-50%;
5. the requirements on the factory building are highly popular, the rent is reduced, and typhoon resistance is easy;
6. the pressing is tight, no bubble or wrinkle is generated, and the surface is flat;
7. the glue is applied for 30 minutes to 1 hour before being dried, and only about 20 minutes is needed at present;
8. the percent defective is about 5-10% according to the prior art, and is only below 1%;
9. electricity charges 1 kw by 5 hours =5 kw, electricity charges 1 kw by 2 hours =2 kw, and the machine capacity also rises by half.
Drawings
Fig. 1 is a schematic perspective view of an embodiment of the present invention (in a use state, reference numeral 3 is a glass fiber fabric);
fig. 2 is a schematic perspective view of a second embodiment of the apparatus of the present invention (in a use state, reference numeral 3 is a glass fiber cloth);
FIG. 3 is a schematic structural diagram of the apparatus according to the present invention in a front view (in a use state, reference numeral 3 is a glass fiber cloth);
FIG. 4 is a schematic perspective view of the traction bracket assembly of an embodiment of the present invention;
FIG. 5 is a schematic perspective view of a glue applying assembly in an embodiment of the apparatus of the present invention;
FIG. 6 is a first schematic view of a three-dimensional structure of a drying box in an embodiment of the present invention;
FIG. 7 is a schematic view of a second three-dimensional structure for installing a drying box in an embodiment of the apparatus of the present invention;
FIG. 8 is a schematic perspective view of a part of a drying box in an embodiment of the apparatus of the present invention;
fig. 9 is a schematic perspective view of the glue receiving box in the embodiment of the apparatus of the present invention.
Detailed Description
In order that those skilled in the art can better understand the present invention, the following technical solutions are further described with reference to the accompanying drawings and examples.
As shown in figures 1-9, the sizing and drying device for the copper-clad plate comprises the following steps:
step one, preparing glue solution;
step two, gluing the glass fiber cloth:
adding the glue solution prepared in the first step into a glue storage box 1061, and then drawing and guiding the glass fiber cloth to realize gluing;
step three, surface drying treatment:
conveying the semi-finished product glued in the step two to a surface drying box 2060 for surface drying, wherein the surface drying time is 5-30 seconds, and the temperature of the surface drying box 2060 is controlled between 80-150 ℃ so as to realize surface drying;
step four, cutting:
conveying the semi-finished product dried in the third step to a cutting bracket 22 for cutting to obtain the required size;
step five, stacking and drying:
and (3) stacking a plurality of semi-finished products cut in the step four, and drying in a drying box 2, wherein the drying time is 18-22 minutes, and the temperature of the drying box 2 is controlled between 150-300 ℃.
Preferably, the first step comprises the following raw materials in parts by weight:
brominated bisphenol A resin 130-135 parts 14PT resin 1400-1500 parts
2000 parts of epoxy soybean oil modified phenolic resin 1200-800 parts of epoxy resin 500-800 parts
Phenolic resin 150 part, flame retardant 300 part, and flame retardant 700 part
Curing agent 250 and 350 parts of curing accelerator 1-5 parts
50-150 parts of inorganic filler and 300 parts of organic solvent 100-
The epoxidized soybean oil modified phenolic resin comprises the following raw materials in parts by weight:
epoxidized soybean oil 1200-1600 parts phenol 500-700 parts
1000-1300 parts of bisphenol A, 5-10 parts of 2-methylimidazole
800 portions of formaldehyde-containing alkali catalyst and 1200 portions of alkali catalyst, 60 to 150 portions
Solvent 2500-3000 parts of graphene 5-60 parts
5-40 parts of graphene oxide. With the design, the adhesive performance of the glue solution is better.
Preferably, in step three, the open time is 30 seconds and the temperature of the open oven 2060 is 150 ℃. With the design, the surface drying effect is better.
Preferably, in the fifth step, the drying time is 20 minutes, and the temperature of the drying box 2 is 200-300 ℃. Such design, the stoving effect is preferred.
The copper-clad plate gluing and drying device comprises a traction bracket 1 and a drying box 2;
the traction bracket 1 is provided with two opposite front and back, the traction bracket 1 is in an inverted U shape, a convex block 100 is integrally formed at the right end of the top surface of the traction bracket 1, an inclined supporting block 101 with a lower left part and a higher right part is integrally formed at the top end of the right side surface of the traction bracket 1, a gluing component is arranged between the two opposite front and back convex blocks 100, a gluing component is also arranged between the two opposite front and back inclined supporting blocks 101, the gluing component comprises a gluing motor 106, a gluing roller 1063, a fixing plate 1060 and a glue storage box 1061, the fixing plate 1060 is fixedly arranged on a power output shaft of the gluing motor 106, the glue storage box 1061 is arranged on the fixing plate 1060, a sleeve shaft is arranged at the rear end of the power output shaft of the gluing motor 106 in a transmission manner, the gluing roller 1063 is sleeved on the sleeve shaft and fixed with the sleeve shaft, first bearings 1062 are fixedly arranged at, the gluing roller 1063 is of a hollow shell structure, a plurality of glue outlet holes are formed in the shell wall of the gluing roller 1063, the glue storage box 1061 is communicated with the inner cavity of the gluing roller 1063, the left end of the traction support 1 close to the front is provided with a first motor 102 and a second motor 103 from bottom to top, two rows of guide rollers 104 capable of rolling are arranged between the cross beams of the two traction supports 1 facing front and back, the number of the guide rollers 104 in the upper row is three, the front ends of the guide rollers are fixedly provided with first gears, the three first gears are meshed and wound with first toothed belts, the power output shaft of the second motor 103 is fixed with the first gear at the leftmost end, the number of the guide rollers 104 in the lower row is two, the front ends of the guide rollers are fixedly provided with second gears, the two second gears are meshed and wound with second toothed belts, the power output shaft of the first motor 102 is fixed with the second gear at the leftmost end, the second motor 103 rotates anticlockwise;
the bottom of the left end of the drying box 2 is integrally formed with a U-shaped support 20, the opening of the U-shaped support 20 faces to the left, vertical plates 205 are fixedly mounted in the middle of front and rear cross beams of the U-shaped support 20, rotatable guide rollers 2050 are mounted on the tops of the front and rear vertical plates 205 which are right opposite, a guide motor is mounted at the front end of each guide roller 2050 in a transmission manner, vertical columns 206 are fixedly mounted on the right of the front and rear cross beams of the U-shaped support 20, a surface drying box 2060 is fixedly mounted at the top ends of the front and rear opposite vertical columns 206, a shearing mechanism 2061 is mounted at the right end of the top surface of the surface drying box 2060, the shearing mechanism 2061 comprises a top plate, a front side plate, a rear side plate and a shearing assembly, the tops of the front side plate and the rear side plate are detachably connected with the front and rear ends of the top plate, the shearing assembly comprises a third motor and a, the front end of the shearing guide rod is fixed with the front side plate, the rear end of the shearing guide rod is fixed with the rear side plate, a convex plate is integrally formed on the top surface of the front end of the shearing guide rod, a mounting blind hole is formed in the top surface of the convex plate, a second bearing is mounted in the mounting blind hole, a short column is fixed on the inner ring of the second bearing, a second bevel gear capable of being meshed with the first bevel gear is fixed at the top end of the short column, a first connecting rod is vertically fixed on the outer wall of the short column below the second bevel gear, a second connecting rod is hinged to the free end of the first connecting rod, a sliding plate is hinged to the free end of the second connecting rod, the sliding plate is sleeved on the shearing guide rod and can slide back and forth along the shearing guide rod, a hydraulic cylinder is mounted on the bottom surface of the sliding plate, an L-shaped plate is vertically arranged downwards, and fixedly mounted at the tail end of a telescopic rod of the hydraulic, the telescopic link of the power output shaft vertically staggered hydraulic cylinder of the fourth motor, the power output shaft of the fourth motor passes through the vertical plate of the L-shaped plate and has a sawing disc at the tail end, two apex angle position fixed mounting have landing legs 21 around the bottom surface right-hand member of drying box 2, two posts are all installed at both sides board top around drying box 2, the top fixed mounting of four posts has a cutting support 22, cutting support 22 is the U-shaped that the opening is rightwards, cutting support 22 has seted up slotting 220 in the below of sawing the disc, two inner walls have seted up spacing step 221 around cutting the opening of support 22, but two spacing step 221 go up the card and be equipped with inserted block 222 of horizontal slip.
Preferably, a rotatable guide rod is arranged between the inner sides of the left ends of the front and rear opposite traction supports 1, and a limiting disc 105 is integrally formed at the front end and the rear end of the guide rod. Due to the design, a good guiding function can be provided for the introduction of the glass fiber cloth 3, and the drawing of the glass fiber cloth 3 is smoother.
Preferably, three guide bars 200 are integrally formed in an opening of the U-shaped bracket 20, a slider 201 capable of sliding left and right is sleeved on the guide bar 200, a J-shaped limiting rod 2010 penetrates through the three slider 201, the J-shaped limiting rod 2010 is inserted into the three slider 201 so as to fix the three slider 201 on the guide bar 200, a vertical rod 202 is integrally formed on the top surface of the slider 201 so as to form an inverted T-shaped structure, a T-shaped slider 203 is sleeved in the vertical rod 202, the lower end of the T-shaped slider 203 is inserted into the vertical rod 202 and can slide and fix in the vertical rod 202 up and down, the T-shaped slider 203 is in threaded connection with a J-shaped screw 2030, and a glue receiving box 204 is installed at the left end of the three J-shaped screw. By adopting the design, the glue solution dripped by the gluing roller 1063 in the gluing component on the bump 100 can be recovered, and the dripping on the ground is avoided, so that the glue solution is environment-friendly and the cost can be reduced.
Preferably, the bottom of the glue receiving box 204 is connected with a glue return pipe 2040 in a communicating manner. By the design, the glue solution in the glue receiving box 204 can be timely recycled, and the cost is reduced.
Preferably, the leftmost end of the guide bar 200 is turned upwards vertically to form a limiting bump, and the sliding block 201 is limited by the limiting bump. By the design, the sliding block 201 can be prevented from slipping off the guide strip 200, and the safety of the glue receiving box 204 is ensured.
Preferably, the right end of the insertion block 222 is provided with two hand-pulled holes. By means of the design, the insertion block 222 can be conveniently and quickly inserted or pulled out, so that the glass fiber cloth 3 can be conveniently cut or fall and stacked after being cut, stacking and drying are facilitated, glue is shared and air is exhausted, and no air bubbles exist when the copper sheet is placed and pressed into the copper-clad plate from the front side and the back side.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.
Claims (6)
1. Copper-clad plate rubberizing drying device, its characterized in that: comprises a traction bracket (1) and a drying box (2);
traction support (1) set up two and just right around, traction support (1) be the shape of falling the U, the top surface right-hand member integrated into one piece of traction support (1) has lug (100), the right flank top integrated into one piece of traction support (1) has low right side in a left side high oblique supporting shoe (101), just right two around install the rubberizing subassembly between lug (100), just right two around also install the rubberizing subassembly between oblique supporting shoe (101), the rubberizing subassembly include rubberizing motor (106), rubberizing cylinder (1063), fixed plate (1060) and deposit gluey case (1061), fixed plate (1060) fixed mounting on the power output shaft of rubberizing motor (106), deposit gluey case (1061) and install on fixed plate 1060, the sleeve axle is installed in the power output shaft rear end transmission of rubberizing motor (106), the gluing device is characterized in that the gluing roller (1063) is sleeved on the sleeve shaft and fixed with the sleeve shaft, first bearings (1062) are fixedly mounted at two ends of the sleeve shaft, an outer ring of each first bearing (1062) can be fixedly mounted in a bump (100) or an inclined supporting block (101), the gluing roller (1063) is of a hollow shell structure, a plurality of glue outlet holes are formed in the shell wall of the gluing roller (1063), the glue storage box (1061) is communicated with an inner cavity of the gluing roller (1063), a first motor (102) and a second motor (103) are mounted at the left end of the traction support (1) from bottom to top in front, two rows of guide rollers (104) capable of rolling are mounted between beams of the traction support (1) in front-back dead front, the guide rollers (104) in the upper row are three, first gears are fixedly mounted at the front ends of the guide rollers, and the first gears are meshed with first toothed belts, the power output shaft of the second motor (103) is fixed with the first gear at the leftmost end, the number of the guide rollers (104) at the lower row is two, the front ends of the two guide rollers are fixedly provided with the second gears, the two second gears are meshed and wound with a second toothed belt, the power output shaft of the first motor (102) is fixed with the second gear at the leftmost end, the second motor (103) rotates anticlockwise, and the first motor (102) rotates clockwise;
the drying box is characterized in that a U-shaped support (20) is integrally formed at the bottom of the left end of the drying box (2), the opening of the U-shaped support (20) faces to the left, vertical plates (205) are fixedly mounted in the middle of front and rear cross beams of the U-shaped support (20), rotatable guide rollers (2050) are mounted at the tops of the front and rear opposite vertical plates (205), a guide motor is mounted at the front end of each guide roller (2050) in a transmission manner, vertical columns (206) are fixedly mounted at the right parts of the front and rear cross beams of the U-shaped support (20), a surface drying box (2060) is fixedly mounted at the top ends of the front and rear opposite vertical columns (206), a shearing mechanism (2061) is mounted at the right end of the top surface of the surface drying box (2060), each shearing mechanism (2061) comprises a top plate, a front side plate, a rear side plate and a shearing assembly, the tops of, the shearing assembly comprises a third motor and a shearing guide rod, the third motor is arranged at the front end of the top surface of the top plate, a power output shaft of the third motor penetrates through the top plate and is fixedly provided with a first bevel gear, the front end of the shearing guide rod is fixed with the front side plate, the rear end of the shearing guide rod is fixed with the rear side plate, a convex plate is integrally formed on the top surface of the front end of the shearing guide rod, a mounting blind hole is formed in the top surface of the convex plate, a second bearing is arranged in the mounting blind hole, a short column is fixed on the inner ring of the second bearing, a second bevel gear capable of being meshed with the first bevel gear is fixed at the top end of the short column, a first connecting rod is vertically fixed on the outer wall of the short column below the second bevel gear, a second connecting rod is hinged to the free end of the first connecting rod, a sliding plate is hinged to the free end of the second connecting rod, the sliding plate is sleeved on the shearing guide rod and, the bottom surface of the sliding plate is provided with a hydraulic cylinder, a telescopic rod of the hydraulic cylinder is vertically downward and is fixedly provided with an L-shaped plate at the tail end, the L-shaped plate is formed by integrally forming a transverse plate at the lower part and a vertical plate at the right part, a fourth motor is arranged on the transverse plate of the L-shaped plate, a power output shaft of the fourth motor is vertically staggered with a telescopic rod of the hydraulic cylinder, the power output shaft of the fourth motor penetrates through the vertical plate of the L-shaped plate and is fixedly provided with a sawing disc at the tail end, supporting legs (21) are fixedly arranged at the front vertex angle position and the rear vertex angle position of the right end of the bottom surface of the drying box (2), two column rods are arranged at the tops of the front side plate and the rear side plate of the drying box (2), cutting supports (22) are fixedly arranged at the tops of the four column rods, the cutting supports (22) are U-shaped, the front inner wall and the rear inner wall of the opening of the cutting support (22) are provided with limiting steps (221), and the two limiting steps (221) are provided with inserting blocks (222) capable of sliding left and right in a clamping mode.
2. The copper-clad plate sizing and drying device according to claim 1, which is characterized in that: a rotatable guide rod is arranged between the inner sides of the left ends of the front and rear opposite traction supports (1), and limiting discs (105) are integrally formed at the front end and the rear end of the guide rod.
3. The copper-clad plate sizing and drying device according to claim 2, characterized in that: the opening of U-shaped support (20) is internally and integrally formed with three conducting bars (200), the conducting bars (200) are sleeved with sliders (201) capable of sliding left and right, the three sliders (201) penetrate through J-shaped limiting rods (2010), the J-shaped limiting rods (2010) are inserted into the three sliders (201) so that the three sliders (201) are fixed on the conducting bars (200), the top surfaces of the sliders (201) are integrally formed with vertical rods (202) to form an inverted T-shaped structure, the vertical rods (202) are internally sleeved with T-shaped sliders (203), the lower ends of the T-shaped sliders (203) are inserted into the vertical rods (202) and can slide up and down and be fixed in the vertical rods (202), the T-shaped sliders (203) are in threaded connection with J-shaped screw rods (2030), and the left ends of the J-shaped screw rods (2030) are installed with glue receiving boxes (204).
4. The copper-clad plate sizing and drying device according to claim 3, which is characterized in that: the bottom of the glue receiving box (204) is communicated with a glue return pipe (2040).
5. The copper-clad plate sizing and drying device according to claim 4, characterized in that: the leftmost end of the guide strip (200) is turned upwards vertically to form a limiting bump, and the sliding block (201) is limited by the limiting bump.
6. The copper-clad plate sizing and drying device according to claim 5, which is characterized in that: two hand-pulled holes are formed in the right end of the inserting block (222).
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CN112371451B (en) * | 2020-10-19 | 2021-10-19 | 福建智罗科技有限公司 | Composite melt-blown cloth production device and composite melt-blown cloth production method |
CN112590352B (en) * | 2020-11-10 | 2022-12-02 | 江西应用科技学院 | Manufacturing device for cloth art and wallpaper integrated wallboard |
CN113561544B (en) * | 2021-09-26 | 2021-12-10 | 南通骏标自密封安全轮胎科技有限公司 | Self-sealing safety tire film rolling type rubber coating machine and tire rubber coating method thereof |
CN115837792B (en) * | 2022-12-12 | 2023-07-11 | 广东嘉元科技股份有限公司 | Automatic copper foil bonding device |
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JPH0592504A (en) * | 1991-09-30 | 1993-04-16 | Sumitomo Bakelite Co Ltd | Production of laminated sheet made of phenolic resin |
JP2000077803A (en) * | 1998-08-31 | 2000-03-14 | Airex Inc | Organic fiber reinforced printed wiring board and manufacture thereof |
CN105472895A (en) * | 2014-09-26 | 2016-04-06 | 松下知识产权经营株式会社 | Method for manufacturing double-faced metal laminate, method for manufacturing printed circuit board, method for manufacturing multiple layered laminate and method for manufacturing multiple layered printed circuit board |
CN106398110A (en) * | 2016-09-13 | 2017-02-15 | 抚州市龙兴电子材料有限公司 | Glue solution for copper-clad plate, composite based CEM-1 copper-clad plate, and preparation methods of glue solution and composite based CEM-1 copper-clad plate |
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2019
- 2019-07-01 CN CN201910584006.0A patent/CN110370781B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0592504A (en) * | 1991-09-30 | 1993-04-16 | Sumitomo Bakelite Co Ltd | Production of laminated sheet made of phenolic resin |
JP2000077803A (en) * | 1998-08-31 | 2000-03-14 | Airex Inc | Organic fiber reinforced printed wiring board and manufacture thereof |
CN105472895A (en) * | 2014-09-26 | 2016-04-06 | 松下知识产权经营株式会社 | Method for manufacturing double-faced metal laminate, method for manufacturing printed circuit board, method for manufacturing multiple layered laminate and method for manufacturing multiple layered printed circuit board |
CN106398110A (en) * | 2016-09-13 | 2017-02-15 | 抚州市龙兴电子材料有限公司 | Glue solution for copper-clad plate, composite based CEM-1 copper-clad plate, and preparation methods of glue solution and composite based CEM-1 copper-clad plate |
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