CN110364779B - Automatic disassembly sorting machine for anode and cathode electrodes and diaphragms of lithium battery - Google Patents

Automatic disassembly sorting machine for anode and cathode electrodes and diaphragms of lithium battery Download PDF

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Publication number
CN110364779B
CN110364779B CN201910709686.4A CN201910709686A CN110364779B CN 110364779 B CN110364779 B CN 110364779B CN 201910709686 A CN201910709686 A CN 201910709686A CN 110364779 B CN110364779 B CN 110364779B
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China
Prior art keywords
lithium battery
diaphragm
electrode
material receiving
decomposed
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CN201910709686.4A
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CN110364779A (en
Inventor
潘建福
冯荣超
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Suzhou Shitai Intelligent Equipment Co ltd
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Suzhou Shitai Intelligent Equipment Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The invention relates to an automatic disassembly sorting machine for positive and negative electrodes and diaphragms of lithium battery electrodes, which comprises a mounting plate arranged on a frame: the electrode feeding mechanism to be decomposed is used for providing a lithium battery to be decomposed; the diaphragm receiving mechanism is positioned above the electrode feeding mechanism to be decomposed and is used for receiving a diaphragm of the lithium battery positioned on the electrode feeding mechanism to be decomposed; the positive electrode decomposition and transplanting mechanical arm and the negative electrode decomposition and transplanting mechanical arm are arranged at two ends of the electrode feeding mechanism to be decomposed, are respectively used for grabbing the positive electrode and the negative electrode of the lithium battery, and respectively place the positive electrode and the negative electrode of the lithium battery in the positive electrode receiving bin and the negative electrode receiving bin; the invention realizes the automatic disassembly of the positive and negative electrodes of the lithium battery and the diaphragm, classifies the disassembled positive and negative electrodes, reduces the contact time of personnel and the lithium battery electrodes, thereby reducing the harm to the operators, improving the automation degree of the lithium battery disassembly industry, realizing the manpower saving and reducing the operation cost of lithium battery disassembly factories.

Description

Automatic disassembly sorting machine for anode and cathode electrodes and diaphragms of lithium battery
Technical Field
The invention belongs to the field of lithium ion battery material recovery, and particularly relates to an automatic disassembly sorting machine for positive and negative electrodes and diaphragms of lithium batteries.
Background
With the large-scale use of power batteries in electric vehicles, battery scrapping and recycling are important problems. The scrapped lithium ion battery contains electrolyte and active materials, so that the scrapped lithium ion battery can directly pollute the land and water sources; the separator, the battery shell, the battery current collector and the like are not easy to corrode, and a large amount of solid waste is polluted. Positive and negative electrode active materials in lithium ion batteries
The value of recycling, especially the market price of lithium salt is increased along with the development of lithium batteries, and if the positive electrode material of the scrapped battery can be effectively recovered, the recycling can save a great amount of cost for enterprises. How to efficiently and cleanly recycle all parts of materials of the scrapped lithium ion battery becomes a hot spot for research of lithium power plant families, and whether the recycling problem can be broken through rapidly determines the competitiveness of lithium power enterprises.
At present, the disassembly mode of the positive electrode/negative electrode and the diaphragm of the lithium battery is manually disassembled, and the lithium battery and electrolyte thereof can cause harm to disassembly personnel and environment, so that the lithium battery positive electrode and negative electrode are extremely easy to mix during the manual disassembly at present, and the lithium battery positive electrode and negative electrode are extremely harmful to long-time contact operators, the disassembly efficiency is low, and the economic and environmental benefits of lithium battery recovery are severely restricted.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the automatic disassembly sorting machine for the positive and negative electrodes of the lithium battery and the diaphragms, which reduces harm to operators, improves the automation degree of the lithium battery disassembly industry and reduces the operation cost.
In order to achieve the above purpose, the invention adopts the following technical scheme: the utility model provides an automatic disassembly sorting machine of lithium cell electrode positive and negative pole and diaphragm, includes the setting on the mounting panel of frame:
the electrode feeding mechanism to be decomposed is used for providing a lithium battery to be decomposed;
The diaphragm receiving mechanism is positioned above the electrode feeding mechanism to be decomposed and is used for receiving a diaphragm of the lithium battery positioned on the electrode feeding mechanism to be decomposed;
The positive electrode decomposition and transplanting mechanical arm and the negative electrode decomposition and transplanting mechanical arm are arranged at two ends of the electrode feeding mechanism to be decomposed, are respectively used for grabbing the positive electrode and the negative electrode of the lithium battery, and respectively place the positive electrode and the negative electrode of the lithium battery in the positive electrode receiving bin and the negative electrode receiving bin;
the positive electrode material receiving bin and the negative electrode material receiving bin are respectively used for placing the positive electrode of the disassembled lithium battery and the negative electrode of the disassembled lithium battery.
Further, the electrode feeding mechanism to be decomposed comprises:
The four-side limiting and fixing assembly is used for fixing the lithium battery and consists of four limiting blocks;
the lifting mechanism comprises a lithium battery bearing plate, and a photoelectric sensor for sensing the lithium battery is arranged on the lithium battery bearing plate; the bottom of the lithium battery bearing plate is provided with a supporting member, and the supporting member is arranged on the jacking bracket in a vertical sliding way through a sliding rail and a driving mechanism.
Further, the diaphragm material receiving mechanism comprises a diaphragm material receiving assembly which can move left and right through a reversing assembly and is arranged on a diaphragm material receiving seat, and an electrode disassembling and positioning mechanism is arranged below the diaphragm material receiving assembly and used for positioning a lithium battery during disassembling; the diaphragm material receiving assembly comprises a material receiving mounting plate, and a material receiving main roller is arranged on the material receiving mounting plate; one side of the material receiving main roller is provided with an angle-adjustable driven roller; a plurality of diaphragm fixing assemblies are arranged below the material receiving main roller, each diaphragm fixing assembly consists of a first fixing block and a second fixing block, and the second fixing blocks compress and fix the diaphragms through fixing cylinders and the first fixing blocks; the diaphragm seat is also provided with a diaphragm fixed-length mechanism for fixing the fixed-length type movable diaphragm.
Further, the motor disassembly positioning mechanism comprises two positioning plates which are oppositely arranged, and a gap for accommodating the diaphragm to pass through is formed between the two positioning plates.
Further, the reversing assembly comprises a reversing cylinder and a reversing slide rail; the reversing slide rail and the reversing cylinder are arranged on the diaphragm receiving seat up and down; the receiving mounting plate is driven to transversely move on the reversing slide rail through the reversing cylinder.
Further, the negative electrode decomposing and transferring mechanical arm comprises a servo synchronous belt module, and a vacuum chuck mounting bracket is arranged on the servo synchronous belt module; a digital display vacuum meter is arranged on the vacuum chuck mounting bracket; the vacuum chuck mounting bracket is provided with a turnover cylinder; the overturning cylinder is used for driving the plurality of vacuum chucks to overturn and take materials.
Further, the positive electrode decomposing and transferring mechanical arm and the negative electrode decomposing and transferring mechanical arm are symmetrically arranged on the left and right sides.
Further, the positive electrode material receiving bin and the negative electrode material receiving bin are boxes with openings facing upwards.
Due to the application of the technical scheme, compared with the prior art, the invention has the following advantages:
The automatic disassembly sorting machine for the anode and the cathode of the lithium battery motor and the diaphragm realizes the automatic disassembly of the anode and the cathode of the lithium battery and the diaphragm, sorts the disassembled anode and cathode, reduces the contact time of personnel and the lithium battery electrode, thereby reducing the harm to the operators, improving the automation degree of the lithium battery disassembly industry, realizing the manpower saving, reducing the operation cost of lithium battery disassembly factories, and having higher practicability and popularization value.
Drawings
The technical scheme of the invention is further described below with reference to the accompanying drawings:
FIG. 1 is a schematic view of the internal structure of the present invention;
FIG. 2 is a schematic perspective view of the present invention;
FIG. 3 is a schematic perspective view of a diaphragm receiving mechanism;
FIG. 4 is a schematic perspective view of the other view of FIG. 3;
fig. 5 is a schematic diagram of a three-dimensional structure of the electrode feeding mechanism to be decomposed, the positive electrode decomposing and transplanting mechanical arm and the negative electrode decomposing and transplanting mechanical arm which are matched;
FIG. 6 is a schematic perspective view of an electrode feeding mechanism to be decomposed;
FIG. 7 is a schematic diagram of a three-dimensional structure of a negative electrode decomposing and transplanting mechanical arm;
Wherein: the device comprises a frame 1, an electrode feeding mechanism 2 to be decomposed, a diaphragm receiving mechanism 3, an anode decomposing and transplanting mechanical arm 4, a cathode decomposing and transplanting mechanical arm 5, an anode receiving bin 6, a cathode receiving bin 7, a mounting plate 8, a negative pressure suction hood 9, a control panel 10, a limiting block 20, a lithium battery bearing plate 21, a photoelectric sensor 22, a supporting member 23, a sliding rail 24, a driving mechanism 25, a lifting support 26, a diaphragm receiving seat 31, a diaphragm receiving assembly 32, an electrode disassembling and positioning mechanism 33, a diaphragm fixed length mechanism 34, a servo synchronous belt module 40, a vacuum chuck mounting support 41, a digital display vacuum gauge 42, a turnover cylinder 43, a vacuum chuck 44, a turnover cylinder 301, a turnover sliding rail 302, a receiving mounting plate 320, a receiving main roller 321, a driven roller 322, a first fixed block 323, a second fixed block 324 and a fixed cylinder 325.
Detailed Description
The invention will be described in further detail with reference to the accompanying drawings and specific examples.
Referring to fig. 1-2, the automatic disassembly and sorting machine for lithium battery electrodes, positive and negative electrodes and diaphragms according to the present invention comprises a mounting plate 8 arranged on a frame 1: the electrode feeding mechanism 2 to be decomposed is used for providing a lithium battery to be decomposed; the diaphragm receiving mechanism 3 is positioned above the electrode feeding mechanism 2 to be decomposed and is used for receiving a diaphragm of the lithium battery positioned on the electrode feeding mechanism 2 to be decomposed; the positive electrode decomposition and transplanting mechanical arm 4 and the negative electrode decomposition and transplanting mechanical arm 5 are arranged at two ends of the electrode feeding mechanism 2 to be decomposed, are respectively used for grabbing the positive electrode and the negative electrode of the lithium battery, and respectively place the positive electrode and the negative electrode of the lithium battery in the positive electrode receiving bin 6 and the negative electrode receiving bin 7; the positive electrode material receiving bin 6 and the negative electrode material receiving bin 7 are respectively used for placing the disassembled positive electrode and negative electrode of the lithium battery.
As a further preferred embodiment, the electrode feeding mechanism to be decomposed 2 includes: the four-side limiting and fixing assembly for fixing the lithium battery is composed of four limiting blocks 20 forming a rectangle; a climbing mechanism for climbing lithium cell, climbing mechanism includes lithium cell loading board 21, is equipped with the photoelectric sensor that is used for responding to lithium cell on lithium cell loading board 21
22; The bottom of the lithium battery bearing plate 21 is provided with a supporting member 23, the supporting member 23 is arranged on a jacking bracket 26 in a vertically sliding way through a sliding rail 24 and a driving mechanism 25, a lithium battery is placed on the lithium battery bearing plate 21, the photoelectric sensor 22 senses the existence of a workpiece, and the photoelectric sensor 22 controls the driving mechanism 25 to be started so as to move the lithium battery up to a set position.
As a further preferred embodiment, the negative electrode disassembling and transferring mechanical arm 5 includes a servo synchronous belt module 40, and a vacuum chuck mounting bracket 41 is disposed on the servo synchronous belt module 40; the vacuum chuck mounting bracket 41 is provided with a digital display vacuum meter 42 for displaying whether the disassembling motor is taken out for confirmation; the vacuum chuck mounting bracket 41 is also provided with a turnover cylinder 43; the overturning cylinder 43 is used for driving the plurality of vacuum chucks 44 to overturn and take materials, wherein the structures of the positive electrode decomposing and transferring mechanical arm and the negative electrode decomposing and transferring mechanical arm are symmetrically arranged left and right; during operation, the vacuum chuck 44 transversely moves through the servo synchronous belt module 40, and meanwhile, the overturning cylinder 43 is utilized to drive the vacuum chuck 44 to overturn and take materials for the negative electrode of the lithium battery.
As a further preferred embodiment, the diaphragm receiving mechanism 3 includes a diaphragm receiving assembly 32 disposed on a diaphragm receiving seat 31 and capable of moving left and right through a reversing assembly 30, and an electrode disassembling and positioning mechanism 33 is disposed below the diaphragm receiving assembly 32 for positioning the lithium battery during disassembly; the electrode disassembling and positioning mechanism 33 comprises two positioning plates 330 which are oppositely arranged, and a gap for accommodating the diaphragm to pass through is arranged between the two positioning plates 330.
The diaphragm material receiving assembly 32 comprises a material receiving mounting plate 320, and a material receiving main roller 321 is arranged on the material receiving mounting plate 320; an angle-adjustable driven roller 322 is arranged on one side of the material receiving main roller 321; the below of driven gyro wheel 322 is equipped with a plurality of diaphragm fixed subassembly, and diaphragm fixed subassembly comprises first fixed block 323 and second fixed block 324, and second fixed block 324 compresses tightly the diaphragm with first fixed block 323 via fixed cylinder 325 and is fixed, and when collecting the diaphragm, receive material main gyro wheel 321 and bring the drive power, through the cooperation with driven gyro wheel 322 with the diaphragm roll-up to receive material main gyro wheel 321 to utilize diaphragm fixed subassembly to fix the diaphragm that curls up.
The diaphragm receiving seat 31 is also provided with a diaphragm fixed-length mechanism 34 for fixing a fixed-length type movable diaphragm.
The reversing assembly 30 comprises a reversing cylinder 301 and a reversing slide rail 302; the reversing slide rail 302 and the reversing cylinder 301 are arranged on the diaphragm receiving seat 31 up and down; the material receiving mounting plate 320 is driven to transversely move on the reversing slide rail 302 by the reversing cylinder 301, so that the diaphragm material receiving assembly 32 is driven to transversely move on the diaphragm material receiving seat 31, and the grabbing switching of the positive and negative batteries is realized.
As a further preferred embodiment, the positive electrode material receiving bin 6 and the negative electrode material receiving bin 7 are boxes with upward openings, and are respectively positioned at two ends of the electrode feeding mechanism to be decomposed.
The electrode is disassembled as follows: the membrane fixed length mechanism 34 draws the membrane fixed length from the bottom membrane, the membrane collecting seat 31 is used for collecting the membrane to the collecting winding drum, the membrane is fixed by the membrane fixing component after collecting, and meanwhile, the electrode to be decomposed is pressed down by the electrode disassembling and positioning mechanism 33 for preset positioning.
Electrode decomposition, take the negative pole to decompose to take the example, negative pole decomposition moves and carries arm 5 to reach the negative pole top, upset cylinder 43 pushes down and laminates vacuum chuck 44 to the negative pole, digital display vacuum gauge 42 detects and reaches the vacuum numerical value of predetermineeing, vacuum chuck installing support 41 upwarp the angle and draw up the product, upset cylinder 43 reverse action is risen, decompose the product from the carrier film and tear open, finally move arm 5 through the negative pole and put into negative pole storage silo 7 with the lithium cell negative pole, in addition the positive decomposition mode of lithium cell is the same with the mode of lithium cell negative pole, only need through reversing assembly 30 to the corresponding left and right sides change of diaphragm material receiving assembly 32's position.
In addition, a negative pressure suction hood 9 and a control panel 10 are further arranged at the top of the frame 1, wherein the negative pressure suction hood 9 provides a negative pressure interface for the automatic disassembly and sorting machine, and the control panel 10 is used for controlling related operations in the automatic disassembly and sorting machine.
The automatic disassembly sorting machine for the anode and the cathode of the lithium battery motor and the diaphragm realizes the automatic disassembly of the anode and the cathode of the lithium battery and the diaphragm, sorts the disassembled anode and cathode, reduces the contact time of personnel and the lithium battery electrode, thereby reducing the harm to the operators, improving the automation degree of the lithium battery disassembly industry, realizing the manpower saving, reducing the operation cost of lithium battery disassembly factories, and having higher practicability and popularization value.
The foregoing is merely a specific application example of the present invention, and the protection scope of the present invention is not limited in any way. All technical schemes formed by equivalent transformation or equivalent substitution fall within the protection scope of the invention.

Claims (3)

1. The utility model provides an automatic disassembly sorting machine of lithium cell electrode positive negative pole and diaphragm which characterized in that, including setting up on the mounting panel of frame:
the electrode feeding mechanism to be decomposed is used for providing a lithium battery to be decomposed;
The diaphragm receiving mechanism is positioned above the electrode feeding mechanism to be decomposed and is used for receiving a diaphragm of the lithium battery positioned on the electrode feeding mechanism to be decomposed;
The positive electrode decomposition and transplanting mechanical arm and the negative electrode decomposition and transplanting mechanical arm are arranged at two ends of the electrode feeding mechanism to be decomposed, are respectively used for grabbing the positive electrode and the negative electrode of the lithium battery, and respectively place the positive electrode and the negative electrode of the lithium battery in the positive electrode receiving bin and the negative electrode receiving bin;
The positive electrode material receiving bin and the negative electrode material receiving bin are respectively used for placing the disassembled positive electrode and negative electrode of the lithium battery;
Wherein, wait to decompose electrode feeding mechanism includes:
The four-side limiting and fixing assembly is used for fixing the lithium battery and consists of four limiting blocks;
The lifting mechanism comprises a lithium battery bearing plate, and a photoelectric sensor for sensing the lithium battery is arranged on the lithium battery bearing plate; the bottom of the lithium battery bearing plate is provided with a supporting member which is arranged on the jacking bracket in a vertical sliding way through a sliding rail and a driving mechanism;
The diaphragm material receiving mechanism comprises a diaphragm material receiving assembly which can move left and right through a reversing assembly and is arranged on a diaphragm material receiving seat, and an electrode disassembling and positioning mechanism is arranged below the diaphragm material receiving assembly and used for positioning the lithium battery during disassembling; the diaphragm material receiving assembly comprises a material receiving mounting plate, and a material receiving main roller is arranged on the material receiving mounting plate; one side of the material receiving main roller is provided with an angle-adjustable driven roller; a plurality of diaphragm fixing assemblies are arranged below the material receiving main roller, each diaphragm fixing assembly consists of a first fixing block and a second fixing block, and the second fixing blocks compress and fix the diaphragms through fixing cylinders and the first fixing blocks; the diaphragm seat is also provided with a diaphragm fixed-length mechanism for fixing a fixed-length type movable diaphragm;
The negative electrode decomposing and transferring mechanical arm comprises a servo synchronous belt module, and a vacuum chuck mounting bracket is arranged on the servo synchronous belt module; a digital display vacuum meter is arranged on the vacuum chuck mounting bracket; the vacuum chuck mounting bracket is provided with a turnover cylinder; the overturning cylinder is used for driving the plurality of vacuum chucks to overturn and take materials; the positive electrode decomposing and transferring mechanical arm and the negative electrode decomposing and transferring mechanical arm are symmetrically arranged on the left and right sides; the positive electrode material receiving bin and the negative electrode material receiving bin are boxes with upward openings.
2. The automatic disassembly sorting machine for positive and negative electrodes and diaphragms of lithium batteries according to claim 1, characterized in that: the electrode disassembling and positioning mechanism comprises two positioning plates which are oppositely arranged, and a gap for accommodating the diaphragm to pass through is arranged between the two positioning plates.
3. The automatic disassembly sorting machine for positive and negative electrodes and diaphragms of lithium batteries according to claim 1, characterized in that: the reversing assembly comprises a reversing cylinder and a reversing slide rail; the reversing slide rail and the reversing cylinder are arranged on the diaphragm receiving seat up and down; the receiving mounting plate is driven to transversely move on the reversing slide rail through the reversing cylinder.
CN201910709686.4A 2019-08-02 2019-08-02 Automatic disassembly sorting machine for anode and cathode electrodes and diaphragms of lithium battery Active CN110364779B (en)

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CN201910709686.4A CN110364779B (en) 2019-08-02 2019-08-02 Automatic disassembly sorting machine for anode and cathode electrodes and diaphragms of lithium battery

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CN110364779B true CN110364779B (en) 2024-05-28

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CN110921027B (en) * 2019-12-02 2021-10-26 苏州爱本科技有限公司 Full-automatic battery film stripping equipment
CN112563602A (en) * 2020-12-08 2021-03-26 合肥国轩电池材料有限公司 Classified recovery device and classified recovery method for power lithium battery
CN112652831B (en) * 2020-12-09 2022-07-22 深圳供电局有限公司 Double-insulation type disassembling and crushing device for waste lithium ion batteries
CN114361633B (en) * 2021-12-31 2024-09-13 智昌科技集团股份有限公司 Battery disassembling equipment

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JPH10241750A (en) * 1996-12-24 1998-09-11 Canon Inc Method and system for recovering battery member
JP2013045540A (en) * 2011-08-23 2013-03-04 Panasonic Corp Disassembling method and device of battery
CN102969546A (en) * 2012-11-01 2013-03-13 中航锂电(洛阳)有限公司 Method for disassembly and classification collection of electrical core and device for disassembly and collection of electrical core by using the method
CN204029951U (en) * 2014-08-21 2014-12-17 广东邦普循环科技有限公司 The full-automatic device for disassembling of a kind of novel waste and old electrokinetic cell
CN204385309U (en) * 2014-12-24 2015-06-10 金川集团股份有限公司 A kind of starting sheet machine for cutting charge into pieces
CN210092279U (en) * 2019-08-02 2020-02-18 苏州诠泰智能装备有限公司 Automatic disassembling and sorting machine for positive and negative electrodes and diaphragms of lithium battery

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10241750A (en) * 1996-12-24 1998-09-11 Canon Inc Method and system for recovering battery member
JP2013045540A (en) * 2011-08-23 2013-03-04 Panasonic Corp Disassembling method and device of battery
CN102969546A (en) * 2012-11-01 2013-03-13 中航锂电(洛阳)有限公司 Method for disassembly and classification collection of electrical core and device for disassembly and collection of electrical core by using the method
CN204029951U (en) * 2014-08-21 2014-12-17 广东邦普循环科技有限公司 The full-automatic device for disassembling of a kind of novel waste and old electrokinetic cell
CN204385309U (en) * 2014-12-24 2015-06-10 金川集团股份有限公司 A kind of starting sheet machine for cutting charge into pieces
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