CN110361873A - A kind of discoloration antifogging type sunglasses lenses and its manufacturing process - Google Patents

A kind of discoloration antifogging type sunglasses lenses and its manufacturing process Download PDF

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Publication number
CN110361873A
CN110361873A CN201910626936.8A CN201910626936A CN110361873A CN 110361873 A CN110361873 A CN 110361873A CN 201910626936 A CN201910626936 A CN 201910626936A CN 110361873 A CN110361873 A CN 110361873A
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CN
China
Prior art keywords
discoloration
sunglasses lenses
photochromic layer
antifogging type
complex optics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910626936.8A
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Chinese (zh)
Inventor
林瑞泽
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Zhangzhou Dongli Optics Technology Co Ltd
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Zhangzhou Dongli Optics Technology Co Ltd
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Priority to CN201910626936.8A priority Critical patent/CN110361873A/en
Publication of CN110361873A publication Critical patent/CN110361873A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/10Filters, e.g. for facilitating adaptation of the eyes to the dark; Sunglasses
    • G02C7/102Photochromic filters
    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/14Mirrors; Prisms

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Eyeglasses (AREA)

Abstract

The present invention relates to sunglasses technical fields, and disclose a kind of discoloration antifogging type sunglasses lenses, including photochromic layer, side wall on the downside of the photochromic layer is connected with colourless mirror plate layers, the photochromic layer is connected with reflective layer far from the side of colourless mirror plate layers, the reflective layer is coated with hydrophilic coating far from the side of photochromic layer, and the colourless mirror plate layers are coated with hydrophobic coating far from the side of photochromic layer.The discoloration antifogging type sunglasses lenses and its manufacturing process, can be antifog to the progress of the two sides of sunglasses lenses, effectively raises the anti-fog effect of sunglasses lenses.

Description

A kind of discoloration antifogging type sunglasses lenses and its manufacturing process
Technical field
The present invention relates to sunglasses technical field, specially a kind of discoloration antifogging type sunglasses lenses and its manufacturing process.
Background technique
Sunglasses, also referred to as sunshade mirror, are used as sunshade.It is logical that people usually will adjust light by adjusting pupil size in the sun Amount, when light intensity be more than human eye regulating power, human eye will be damaged.So playground outdoors, especially exists Summer needs to keep the sun off using sunshade mirror, to mitigate injury caused by fatigue caused by eyes are adjusted or strong light stimulus.
Existing sunglasses lenses due to moisture rapid condensation in eyeglass surrounding air, cause when the outer temperature difference is larger indoors The surface fogging of eyeglass, fogging will affect the normal line of sight of wearer, influence the wear comfort of sunglasses.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of discoloration antifogging type sunglasses lenses and its manufacturing process, tools Standby the advantages of avoiding sunglasses lenses surface fogging, solve in the prior art sunglasses lenses indoors outer excessive temperature differentials when surface knot The problem of mist.
(2) technical solution
To realize that above-mentioned can quantify adds cement and sandstone and the purpose automatically added water, the present invention provides following technical side Case: a kind of discoloration antifogging type sunglasses lenses, including photochromic layer, the side wall on the downside of the photochromic layer are connected with colourless mirror plate layers, institute It states photochromic layer and is connected with reflective layer far from the side of colourless mirror plate layers, the reflective layer is coated with hydrophily far from the side of photochromic layer Coating, the colourless mirror plate layers are coated with hydrophobic coating far from the side of photochromic layer.
Preferably, the specific material of the photochromic layer is silver halide microcrystal glass.
Preferably, the hydrophilic coating is ultraviolet-curing paint.
Preferably, the specific material of the hydrophobic coating is acrylic acid, methyl methacrylate and hydroxypropyl acrylate Polymer.
Preferably, concrete technology the following steps are included: step 1, using transparent adhesion glue by photochromic layer and colourless mirror plate layers It is bonded together with reflective layer, is suppressed using press device, obtain complex optics;Step 2, the composite mirrors for completing compacting The side of piece is covered with film, and complex optics are immersed 2-3min in ultraviolet curing coating, complex optics are placed on 100- 1-2min in 110 DEG C of environment;Step 3, the side that complex optics are coated with to ultraviolet curing coating are covered with film, will be compound 2-3min in eyeglass immersion acrylic acid, methyl methacrylate and hydroxypropyl acrylate polymer, complex optics are placed on 1-2min in 100-110 DEG C of environment.
Preferably, the transparent adhesion glue is SL-L0987 series ultraviolet cured adhesive.
Preferably, the film is high-temperature resistant membrane.
Preferably, the size of the film is greater than the size of complex optics.
(3) beneficial effect
Compared with prior art, the present invention provides a kind of discoloration antifogging type sunglasses lenses and its manufacturing process, have with It is lower the utility model has the advantages that
The discoloration antifogging type sunglasses lenses and its manufacturing process, by the photochromic layer of setting, colourless mirror plate layers, reflective layer, Hydrophilic coating and hydrophobic coating, hydrophilic coating can make lens surface in hydrophiling characteristic, and contain in hydrophilic coating There is the hydrophilic radical factor, it is hydrophilic water mist to be adsorbed into the factor when being contacted with water mist, water mist can also be reduced Surface tension, the contact angle for reducing hydrone and lens surface, so that steam be made not to be agglomerated into tiny water with lens surface Before pearl, the surface of eyeglass will be soaked, spread or be adsorbed on, forms one layer of ultra-thin transparent moisture film, ultra-thin moisture film will not The effect that scattering is generated to incident ray, to avoid interfering the sight of user;Hydrophobic coating can make eyeglass Surface is in hydrophobization, and contains the hydrophobic grouping factor in hydrophobic coating, and the hydrophobic grouping factor can be mutually exclusive with hydrone, The contact angle for increasing hydrone and lens surface, gradually form into steam in lens surface has very big contact angle one by one Water droplet, there is the water droplet of very big contact angle to be difficult to stop in smooth lens surface for these, and water droplet can be constantly automatically from smooth It is slid on eyeglass, has achieved the purpose that antifog, cooperated by hydrophilic coating and hydrophobic coating, it can be to sunglasses lenses Two sides carry out it is antifog, effectively raise the anti-fog effect of sunglasses lenses.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of antifogging type sunglasses lenses that change colour proposed by the present invention;
Fig. 2 is a kind of main view of antifogging type sunglasses lenses that change colour proposed by the present invention.
In figure: 1 photochromic layer, 2 colourless mirror plate layers, 3 reflective layers, 4 hydrophilic coatings, 5 hydrophobic coatings.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
A kind of discoloration antifogging type sunglasses lenses referring to FIG. 1-2, including photochromic layer 1, the side wall connection of 1 downside of photochromic layer Whether there is or not Look mirror lamella 2, photochromic layer 1 is connected with reflective layer 3 far from the side of colourless mirror plate layers 2, and reflective layer 3 is far from photochromic layer 1 Side is coated with hydrophilic coating 4, and colourless mirror plate layers 2 are coated with hydrophobic coating 5,4 energy of hydrophilic coating far from the side of photochromic layer 1 Enough make lens surface in hydrophiling characteristic, and contain the hydrophilic radical factor in hydrophilic coating 4, it is hydrophilic into the factor with water mist Water mist can be adsorbed when contact, surface tension that water mist can also be reduced, reduce contact of the hydrone with lens surface Angle will soak, spread or be adsorbed on eyeglass to make steam before not being agglomerated into tiny droplet with lens surface Surface forms one layer of ultra-thin transparent moisture film, and ultra-thin moisture film will not generate the effect of scattering to incident ray, to avoid to making The sight of user interferes;Hydrophobic coating 5 can make lens surface in hydrophobization, and containing hydrophobic in hydrophobic coating 5 Group factor, the hydrophobic grouping factor can be mutually exclusive with hydrone, increase the contact angle of hydrone and lens surface, make steam Water droplet one by one with very big contact angle is gradually formed into lens surface, there is the water droplet of very big contact angle to be difficult for these Smooth lens surface stops, and water droplet can constantly slide from smooth eyeglass automatically, achieved the purpose that it is antifog, by hydrophilic Property coating 4 and hydrophobic coating 5 cooperate, can to the two sides of sunglasses lenses carry out it is antifog, effectively raise sunglasses The anti-fog effect of piece.
The specific material of photochromic layer 1 is silver halide microcrystal glass, and silver halide microcrystal glass is visible through ultraviolet light and shortwave After light irradiation, silver halide microcrystal glass colour can be deepened, and cause light transmission rate to reduce, to avoid ultraviolet light and shortwave light Eyes are caused to damage;Indoors or dark place silver halide microcrystal glass transmitance improves, the lighter of silver halide microcrystal glass, To improve indoors or the sight clarity of dark place.
Hydrophilic coating 4 is ultraviolet-curing paint, and ultraviolet photo-curing coating can be quickly solid under ultraviolet light irradiation Change, hydrophily will not be lost because ultraviolet light irradiates, guarantee the service life of hydrophilic coating 4.
The specific material of hydrophobic coating 5 is acrylic acid, methyl methacrylate and hydroxypropyl acrylate polymer, propylene Acid, the curing rate of methyl methacrylate and hydroxypropyl acrylate polymer are fast, and hydrophobic performance is good, can rapid curing, mention The high production efficiency of sunglasses lenses, and cost is relatively low for acrylic acid, methyl methacrylate and hydroxypropyl acrylate polymer, Convenient for storage, use is more convenient, reduces the production cost of sunglasses lenses.
Photochromic layer 1 and colourless mirror plate layers 2 and reflective layer 3 are bonded together by step 1 using transparent adhesion glue, use pressure Control equipment is suppressed, and complex optics are obtained;Step 2 covers the side for the complex optics that compacting is completed with film, will be compound Eyeglass immerses 2-3min in ultraviolet curing coating, and complex optics are placed on to 1-2min in 100-110 DEG C of environment;Step 3, The side that complex optics are coated with ultraviolet curing coating is covered with film, complex optics are immersed into acrylic acid, methacrylic acid Complex optics, are placed on 1-2min in 100-110 DEG C of environment by 2-3min in methyl esters and hydroxypropyl acrylate polymer.
Transparent adhesion glue is SL-L0987 series ultraviolet cured adhesive, SL-L0987 series ultraviolet cured adhesive, optical lens Bright property is good, and cured glue-line is flexible, and fatigue resistance is good, and adhesive strength is high, and good weatherability does not turn yellow, and do not haze flower, to glass, The rigid plastics such as ceramics, metal, PVC, polycarbonate have good adhesive force.
Film is high-temperature resistant membrane, prevents film from softening damage in the high temperature environment.
In conclusion the discoloration antifogging type sunglasses lenses and its manufacturing process, hydrophilic coating 4 can make the lens surface be in Hydrophiling characteristic, and in hydrophilic coating 4 contain the hydrophilic radical factor, it is hydrophilic can be to water when being contacted with water mist into the factor Mist adsorbed, can also reduce water mist surface tension, the contact angle for reducing hydrone and lens surface, so that steam be made to exist It is not agglomerated into lens surface before tiny droplet, will soak, spread or be adsorbed on the surface of eyeglass, formed one layer and surpass Thin transparent moisture film, ultra-thin moisture film will not generate the effect of scattering to incident ray, to avoid causing the sight of user Interference;Hydrophobic coating 5 can make lens surface in hydrophobization, and contain the hydrophobic grouping factor, hydrophobic group in hydrophobic coating 5 Group the factor can be mutually exclusive with hydrone, increase hydrone and lens surface contact angle, make steam lens surface gradually Water droplet one by one with very big contact angle is formed into, there is the water droplet of very big contact angle to be difficult in smooth lens surface for these Stop, water droplet can constantly slide from smooth eyeglass automatically, achieved the purpose that it is antifog, by hydrophilic coating 4 with it is hydrophobic Property coating 5 cooperate, can to the two sides of sunglasses lenses carry out it is antifog, effectively raise the anti-fog effect of sunglasses lenses.
It should be noted that term " includes ", so that including the process, methods of a series of elements, article or setting Standby includes not only those elements, but also including other elements that are not explicitly listed, or further includes for this process, side Method, article or the intrinsic element of equipment.In the absence of more restrictions, limited by sentence "including a ..." Element, it is not excluded that there is also other identical elements in the process, method, article or apparatus that includes the element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. a kind of discoloration antifogging type sunglasses lenses, including photochromic layer (1), which is characterized in that the side wall on the downside of the photochromic layer (1) It is connected with colourless mirror plate layers (2), the photochromic layer (1) is connected with reflective layer (3) far from the side of colourless mirror plate layers (2), described Reflective layer (3) is coated with hydrophilic coating (4) far from the side of photochromic layer (1), and the colourless mirror plate layers (2) are far from photochromic layer (1) Side be coated with hydrophobic coating (5).
2. a kind of discoloration antifogging type sunglasses lenses according to claim 1, it is characterised in that: the tool of the photochromic layer (1) Body material is silver halide microcrystal glass.
3. a kind of discoloration antifogging type sunglasses lenses according to claim 1, it is characterised in that: the hydrophilic coating (4) For ultraviolet-curing paint.
4. a kind of discoloration antifogging type sunglasses lenses according to claim 1, it is characterised in that: the hydrophobic coating (5) Specific material be acrylic acid, methyl methacrylate and hydroxypropyl acrylate polymer.
5. a kind of discoloration antifogging type sunglasses lenses manufacturing process, it is characterised in that: concrete technology is the following steps are included: step 1, make Photochromic layer (1) and colourless mirror plate layers (2) and reflective layer (3) are bonded together with transparent adhesion glue, carried out using press device Compacting, obtains complex optics;Step 2 covers the side for the complex optics that compacting is completed with film, complex optics is immersed purple Complex optics, are placed on 1-2min in 100-110 DEG C of environment by the coating material solidified middle 2-3min of outside line;Step 3, by complex optics The side for being coated with ultraviolet curing coating is covered with film, and complex optics are immersed acrylic acid, methyl methacrylate and propylene Complex optics, are placed on 1-2min in 100-110 DEG C of environment by 2-3min in sour hydroxypropyl ester polymer.
6. a kind of discoloration antifogging type sunglasses lenses manufacturing process according to claim 5, it is characterised in that: described transparent viscous Conjunction glue is SL-L0987 series ultraviolet cured adhesive.
7. a kind of discoloration antifogging type sunglasses lenses according to claim 5 and its manufacturing process, it is characterised in that: described thin Film is high-temperature resistant membrane.
8. a kind of discoloration antifogging type sunglasses lenses according to claim 5 and its manufacturing process, it is characterised in that: described thin The size of film is greater than the size of complex optics.
CN201910626936.8A 2019-07-12 2019-07-12 A kind of discoloration antifogging type sunglasses lenses and its manufacturing process Pending CN110361873A (en)

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Application Number Priority Date Filing Date Title
CN201910626936.8A CN110361873A (en) 2019-07-12 2019-07-12 A kind of discoloration antifogging type sunglasses lenses and its manufacturing process

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Application Number Priority Date Filing Date Title
CN201910626936.8A CN110361873A (en) 2019-07-12 2019-07-12 A kind of discoloration antifogging type sunglasses lenses and its manufacturing process

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112624628A (en) * 2020-12-17 2021-04-09 陈治兰 Thermochromic laminated glass and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101602913A (en) * 2009-06-26 2009-12-16 广州慧谷化学有限公司 A kind of ultraviolet light curing anti fogging coating composite and compound method thereof
CN106189642A (en) * 2016-07-28 2016-12-07 上海维凯光电新材料有限公司 Ultraviolet light curing anti fogging coating composite
CN106240115A (en) * 2016-07-27 2016-12-21 惠州市摩码菱丽光电材料有限公司 A kind of long-acting optics antifog film and preparation method thereof
CN107573835A (en) * 2017-08-23 2018-01-12 东莞粤恒光学有限公司 A kind of eyeglass allochroic paint and a kind of color-changing lens
CN109856705A (en) * 2019-02-26 2019-06-07 合肥酷飞新材料科技有限公司 A kind of compound anti-mist eyeglass and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101602913A (en) * 2009-06-26 2009-12-16 广州慧谷化学有限公司 A kind of ultraviolet light curing anti fogging coating composite and compound method thereof
CN106240115A (en) * 2016-07-27 2016-12-21 惠州市摩码菱丽光电材料有限公司 A kind of long-acting optics antifog film and preparation method thereof
CN106189642A (en) * 2016-07-28 2016-12-07 上海维凯光电新材料有限公司 Ultraviolet light curing anti fogging coating composite
CN107573835A (en) * 2017-08-23 2018-01-12 东莞粤恒光学有限公司 A kind of eyeglass allochroic paint and a kind of color-changing lens
CN109856705A (en) * 2019-02-26 2019-06-07 合肥酷飞新材料科技有限公司 A kind of compound anti-mist eyeglass and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112624628A (en) * 2020-12-17 2021-04-09 陈治兰 Thermochromic laminated glass and preparation method thereof

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Application publication date: 20191022