CN204855971U - Photochromism prevents blue light resin lenses - Google Patents

Photochromism prevents blue light resin lenses Download PDF

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Publication number
CN204855971U
CN204855971U CN201520375117.8U CN201520375117U CN204855971U CN 204855971 U CN204855971 U CN 204855971U CN 201520375117 U CN201520375117 U CN 201520375117U CN 204855971 U CN204855971 U CN 204855971U
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CN
China
Prior art keywords
blue light
layer
photochromic
photochromism
basic unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201520375117.8U
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Chinese (zh)
Inventor
曹根庭
黄添鸟
贺建友
严清波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Kang Naite Optical Co Ltd
Zhejiang Ocean University ZJOU
Original Assignee
Jiangsu Kang Naite Optical Co Ltd
Zhejiang Ocean University ZJOU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Kang Naite Optical Co Ltd, Zhejiang Ocean University ZJOU filed Critical Jiangsu Kang Naite Optical Co Ltd
Priority to CN201520375117.8U priority Critical patent/CN204855971U/en
Application granted granted Critical
Publication of CN204855971U publication Critical patent/CN204855971U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The utility model belongs to resin lenses makes the field, especially relates to a photochromism prevents blue light resin lenses. The technical problem of its solution is: how to make the function that the lens merges the photochromism function and prevent the blue light, satisfy consumer's pluralism demand, protect people's eyes more effectively. A photochromism prevents blue light resin lenses, includes basic unit, discoloration layeer and anchor coat, the basic unit be one kind and prevent blue light resin lenses, discoloration layeer is photic discoloration layeer, the anchor coat be optical resin adhesion agent, the anchor coat coat in the basic unit with between the discoloration layeer. Prior art compares, the beneficial effects of the utility model are that: (1 )Merged change colour the function with prevent the blue light function, effectively radiate harmful blue light of coming out in cell -phone screen, panel computer screen and the notebook computer screen for people filter, through setting up the photochromism layer, stop strong sunshine for people.

Description

A kind of photochromic anti-blue light resin lens
Technical field
The utility model belongs to resin lens and manufactures field, particularly relates to a kind of photochromic anti-blue light resin lens.
Background technology
Along with improving constantly of people's living standard, the continuous progress of mobile Internet science and technology, going deep in our daily life of mobile phone screen, panel computer screen and notebook screens.The retina of high energy shortwave blue light to us of a large amount of irregular frequency that these screens bring impacts.Blue light illumination can make retina produce free radical, and this can cause retinal pigment epithelium to become feeble and die, thus causes photosensitive cell to lack nutrient, and final result is exactly the damage of people's eyesight.
Photochromic lens is the same with ordinary resin eyeglass when indoor can only provide the original function of correcting defects of vision.And at bright open air energy quick color-changing, for people stop strong sunlight, prevent the dizzy and temporary blindness phenomenon because causing during careless direct-view sunlight, and simultaneously again can be the same with sunglasses, become the ornament of the outdoor trip indispensability of people.
Powerful function all respectively had its own by photochromic lens and anti-blue light eyeglass, but consumer's often simultaneously these two kinds of functions of demand, and there is not the eyeglass integrating these two kinds of functions on the market now.
Utility model content
The technical problems to be solved in the utility model is: how to make lens merge the function of photochromic function and anti-blue light, meet the multiple demand of consumer, more effectively protect the eyes of people.
The purpose of this utility model is to provide a kind of photochromic anti-blue light resin lens, this eyeglass has the original function of correcting defects of vision of eyeglass on the one hand, can filter out the harmful blue light radiating out in Mobile phone screen, panel computer screen and notebook computer screen again for people.Energy quick color-changing simultaneously, for people stop strong sunlight, prevents from, because of the dizzy and temporary blindness phenomenon caused during direct-view sunlight, becoming the ornament of the outdoor trip indispensability of people.
For achieving the above object, the utility model adopts following technical scheme: a kind of photochromic anti-blue light resin lens, comprises basic unit, photochromic layer and binding layer, and described basic unit is a kind of anti-blue light resin lens, described photochromic layer is photochromatic layer, and described binding layer is optical resin adhesion agent; Described binding layer is coated between described basic unit and described photochromic layer.By applying binding layer between the basic unit and photochromatic layer of anti-blue light resin lens, make a kind of effectively anti-blue light, can photochromic resin lens.
Further, described photochromatic layer is low crosslinking degree resin monomer containing organic photochromic material or color-changing membrane.Low crosslinking degree resin monomer is very fast at the exchange velocity of manufacturing process intermediate ion, can effectively enhance productivity.
Further, described organic photochromic material is the photochromic adjuvant of spiro-pyrans class or fulgides photochromic adjuvant or diaryl ethylene photochromic adjuvant.Spiral shell adjoin mutter be in organic photochromic material investigation and application the earliest, one of system the most widely, under UV-irradiation, colourless spiral shell adjoins the C mono-O bond rupture open loop of muttering in structure, molecule local rotate and be the coplanar merocyanine structure of formation one and developing the color of making an uproar, the corresponding red shift of absorption spectrum.Under the effect of visible ray or heat, open loop body can be returned to spirane structure again.The rupture time of C mono-O key is in picosecond, and color change is exceedingly fast.Fulgenic acid is liquor-saturated is the general designation that the fragrant dimethylene succinic acid replaced joins compounds, and this compounds has good anti-fatigue performance.Diarylethene has extraordinary thermal stability, chemical stability and excellent sensitivity and fatigue resistence.
Further, described optical resin adhesion agent is a kind of optics epoxy adhesive.Epoxy adhesive viscosity is low, good fluidity.
Further, described anti-blue light eyeglass is a kind of anti-blue light resin lens that with the addition of UV absorbers and blue-light absorbers in resin monomer.
Further, described anti-blue light resin lens is self-regulated myopia anti-blue light eyeglass.Self-regulated spectacles are according to optical principle, and the change of the lenticular flexibility of the conscious induction of energy, makes lens refractive power make corresponding adjustment, add the serviceable life of glasses.
Further, described anti-blue light resin lens is the reflective anti-blue light eyeglass of backsight.Backsight reflective glasses can environment around comprehensive monitoring, and has good hidden effect.
Further, described photochromic anti-blue light resin lens thickness is between 0.5mm ~ 1.5mm.Lens thickness, between 0.5-1.5mm, can guarantee the function of eyeglass, has the weight of wearing that effectively can alleviate the personnel of wearing conveniently to wear.
Further, described photochromatic layer is two-layer, described binding layer is two-layer, described photochromatic layer is bonded in described basic unit tow sides respectively by binding layer.
The glasses be made up of above-mentioned photochromic anti-blue light resin lens, have good Blue light absorbing, and can carry out variable color by photochromic material, can available protecting user eyes, avoid eyes to be subject to the injury of blue light and high light.
To compare prior art, the photochromic anti-blue light resin lens that the utility model provides, there is following beneficial effect: (1) has merged colour change function and anti-blue light function, when indoor except there being the original function of correcting defects of vision of eyeglass, can filter out for people the harmful blue light radiating out in Mobile phone screen, panel computer screen and notebook computer screen again.(2) by arranging photochromatic layer, bright outdoor time, can quick color-changing, for people stop strong sunlight, prevent the dizzy and temporary blindness phenomenon because direct-view sunlight causes, simultaneously again can be the same with sunglasses, become the ornament of the outdoor trip indispensability of people.
Accompanying drawing explanation
Fig. 1 is the structural representation of the first embodiment of the present utility model;
Fig. 2 is the structural representation of the second embodiment of the present utility model;
Fig. 3 is the structural representation of the 3rd embodiment of the present utility model;
Fig. 4 is the making schematic diagram of the photochromic anti-blue light resin lens of the utility model;
1-picture frame, 21-anti-blue light resin lens, 22-optical resin adhesion agent, 23-photochromatic layer, 24-teleblem, 3-leg of spectacles, 5-patrix, 6-space, 7-counterdie.
Embodiment
The technical matters solved to make the utility model, technical scheme and beneficial effect are clearly understood, below in conjunction with embodiment, and utilize accompanying drawing, are further elaborated to the utility model.Should be appreciated that specific embodiment described herein only in order to explain.
Embodiment 1
As shown in Figure 1, a kind of photochromic anti-blue light resin lens, comprises basic unit, photochromic layer and binding layer, and described basic unit is a kind of anti-blue light resin lens 21, and described photochromic layer is photochromatic layer 23, and described binding layer is optical resin adhesion agent 22; Described binding layer is coated between described basic unit and described photochromic layer.Photochromatic layer 23 is the low crosslinking degree resin monomer or the color-changing membrane that contain organic photochromic material, the first-selected spiro-pyrans class of organic photochromic material or fulgides; Adhering layer is optics epoxy adhesive 22; Anti-blue light layer is a kind of anti-blue light resin lens 21 adding ultraviolet absorber and blue-light absorbers in resin monomer.
The method for making of this photochromic anti-blue light resin lens is as follows:
(1) photochromatic layer 23 is made: take 20KG low crosslinking degree optical resin, add the photochromic material solution that 50-100g contains 350-500ppm wherein, the first-selected spiro-pyrans class of photochromic material or fulgides, add 30-50g initiating agent again, the first-selected v-65 (ABVN) of initiating agent, through vacuum stirring 2-3 hour, vacuum left standstill after 40 minutes, to be poured into by monomer in the mould got togather by filter core.In the one-step solidification stove of computing machine temperature control, through the Thermal cure profile polymerizing curable of 20-25 hour, through die sinking, edging, cleaning, regelate and inspection after shaping, finally by qualified product warehousing.
(2) be incorporated among glass mold by anti-blue light eyeglass 21, lower mould is close to by eyeglass, reserved one section of space between patrix and eyeglass, and the thickness in space can unrestricted choice according to the requirement of different crowd, and reference thickness is 0.5-1.5mm.
(3) smear one deck optics epoxy adhesive 22 at anti-blue light resin lens 21 upper surface, then the photochromatic layer 23 eyeglass adhesion with it that will be polymerized in advance, monomer 23 is poured in the mould got togather by filter core.In the one-step solidification stove of computing machine temperature control, through the Thermal cure profile polymerizing curable of 20-25 hour, through die sinking, edging, cleaning, regelate and inspection after shaping, finally by qualified product warehousing.The thickness of photochromic layer eyeglass can unrestricted choice according to the requirement of different crowd, and reference thickness is 0.5-1.5mm.By suitable intensification, adhesion agent is solidified completely, then put in storage after edging, cleaning, inspection.
Embodiment 2
As different from Example 1, in this embodiment, photochromatic layer and epoxy resin bonding agent are two-layer.
A kind of photochromic anti-blue light resin lens, comprise basic unit, photochromic layer and binding layer, described basic unit is a kind of anti-blue light resin lens 21, and described photochromic layer is photochromatic layer 23, and described binding layer is optical resin adhesion agent 22; Described photochromatic layer 23 is pasted onto the tow sides of described anti-blue light resin lens 21 by optical resin adhesion agent.Photochromatic layer 23 is the low crosslinking degree resin monomer or the color-changing membrane that contain organic photochromic material, the first-selected spiro-pyrans class of organic photochromic material or fulgides; Adhering layer is optics epoxy adhesive 22; Anti-blue light layer is a kind of anti-blue light resin lens 21 adding ultraviolet absorber and blue-light absorbers in resin monomer.
(2) photochromatic layer 23 is made: take 20KG low crosslinking degree optical resin, add the photochromic material solution that 50-100g contains 350-500ppm wherein, the first-selected spiro-pyrans class of photochromic material or fulgides, add 30-50g initiating agent again, the first-selected v-65 (ABVN) of initiating agent, through vacuum stirring 2-3 hour, vacuum left standstill after 40 minutes, to be poured into by monomer in the mould got togather by filter core.In the one-step solidification stove of computing machine temperature control, through the Thermal cure profile polymerizing curable of 20-25 hour, through die sinking, edging, cleaning, regelate and inspection after shaping, finally by qualified product warehousing.
(2) be incorporated among glass mold by anti-blue light eyeglass 21, lower mould is close to by eyeglass, reserved one section of space between patrix and eyeglass, and the thickness in space can unrestricted choice according to the requirement of different crowd, and reference thickness is 0.5-1.5mm.
(3) smear one deck optics epoxy adhesive 22 at anti-blue light resin lens 21 upper surface, then the photochromatic layer 23 eyeglass adhesion with it that will be polymerized in advance, monomer 23 is poured in the mould got togather by filter core.In the one-step solidification stove of computing machine temperature control, through the Thermal cure profile polymerizing curable of 20-25 hour, through die sinking, edging, cleaning, regelate and inspection after shaping, finally by qualified product warehousing.The thickness of photochromic layer eyeglass can unrestricted choice according to the requirement of different crowd, and reference thickness is 0.5-1.5mm.By suitable intensification, adhesion agent is solidified completely, then put in storage after edging, cleaning, inspection.
(4) step (2) is repeated.
(5) step (3) is repeated.
Embodiment 3
As shown in Figure 3, a kind of anti-blue light glasses, comprise blue light absorption type plated film resin lens, install the picture frame 1 of described blue light absorption type plated film resin lens, leg of spectacles 3.

Claims (4)

1. a photochromic anti-blue light resin lens, comprises basic unit, photochromic layer and binding layer, it is characterized in that: described basic unit is a kind of anti-blue light resin lens, and described photochromic layer is photochromatic layer, and described binding layer is optical resin adhesion agent; Described binding layer is coated between described basic unit and described photochromic layer, and described anti-blue light resin lens is self-regulated myopia anti-blue light eyeglass or described anti-blue light resin lens is the reflective anti-blue light eyeglass of backsight.
2. photochromic anti-blue light resin lens according to claim 1, is characterized in that: described photochromic anti-blue light resin lens thickness is between 0.5mm ~ 1.5mm.
3. photochromic anti-blue light resin lens according to claim 1, is characterized in that: described photochromatic layer is two-layer, described binding layer is two-layer, described photochromatic layer is bonded in described basic unit tow sides respectively by binding layer.
4. photochromic anti-blue light glasses, is characterized in that: described glasses comprise the described photochromic anti-blue light resin lens of one of claim 1-3.
CN201520375117.8U 2015-06-02 2015-06-02 Photochromism prevents blue light resin lenses Expired - Fee Related CN204855971U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107519964A (en) * 2017-10-19 2017-12-29 浙江迪特西科技有限公司 A kind of glass resolution test tube for monitoring temperature change
CN109143614A (en) * 2018-11-02 2019-01-04 姜玉梅 Anti- blue light Intelligent light-sensitive color-changing lens
CN109337559A (en) * 2018-09-28 2019-02-15 江苏视科新材料股份有限公司 A kind of difunctional coated optical material of anti-blue light/discoloration and preparation method thereof
WO2020042527A1 (en) * 2018-08-25 2020-03-05 东莞市雅思电子有限公司 Cosmetic sun protection mask, and manufacturing method for same
CN111983819A (en) * 2020-08-24 2020-11-24 江苏黄金屋光学眼镜有限公司 Processing technology of film layer color-changing sheet for glasses film
CN113448005A (en) * 2021-06-29 2021-09-28 江西沃格光电股份有限公司 Optical composite film, preparation method and application thereof and display device

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107519964A (en) * 2017-10-19 2017-12-29 浙江迪特西科技有限公司 A kind of glass resolution test tube for monitoring temperature change
CN107519964B (en) * 2017-10-19 2020-07-03 浙江迪特西科技有限公司 But test tube is cleared up to glass of control temperature variation
WO2020042527A1 (en) * 2018-08-25 2020-03-05 东莞市雅思电子有限公司 Cosmetic sun protection mask, and manufacturing method for same
CN109337559A (en) * 2018-09-28 2019-02-15 江苏视科新材料股份有限公司 A kind of difunctional coated optical material of anti-blue light/discoloration and preparation method thereof
CN109143614A (en) * 2018-11-02 2019-01-04 姜玉梅 Anti- blue light Intelligent light-sensitive color-changing lens
CN111983819A (en) * 2020-08-24 2020-11-24 江苏黄金屋光学眼镜有限公司 Processing technology of film layer color-changing sheet for glasses film
CN113448005A (en) * 2021-06-29 2021-09-28 江西沃格光电股份有限公司 Optical composite film, preparation method and application thereof and display device
CN113448005B (en) * 2021-06-29 2022-12-02 江西沃格光电股份有限公司 Optical composite film, preparation method and application thereof and display device

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C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20151209

Termination date: 20170602

CF01 Termination of patent right due to non-payment of annual fee