CN110358493A - A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization - Google Patents
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization Download PDFInfo
- Publication number
- CN110358493A CN110358493A CN201910697218.XA CN201910697218A CN110358493A CN 110358493 A CN110358493 A CN 110358493A CN 201910697218 A CN201910697218 A CN 201910697218A CN 110358493 A CN110358493 A CN 110358493A
- Authority
- CN
- China
- Prior art keywords
- reworkable
- situ polymerization
- acrylate
- ultraviolet light
- waterproof gasket
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
- C09J163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
Abstract
The invention discloses a kind of ultraviolet lights to solidify the reworkable waterproof gasket cement of in-situ polymerization, is related to photocuring adhesive field, including the following raw material: acrylate prepolymer；Reactive diluent；Photoinitiator；Filler；Thixotropic agent；Wax；Stabilizer.The ultraviolet light of the application solidifies the reworkable waterproof gasket cement of in-situ polymerization suitable for various plastic basis materials, the exemplar of various irregular shapes, may replace silica gel sealing materials'use.Meanwhile the ultraviolet cured adhesive stick agent can in-situ polymerization, construction technology is simple, easy to operate, it is only necessary to which tens of seconds can be fully cured.Colloid after solidification is moderate to the bonding force of substrate, can easily be reprocessed.Hardness after solidification is between ShoreA20-80, and breaking strength is between 2-10Mpa, and elongation at break is between 100-500%.
Description
Technical field
The present invention relates to photocuring adhesive field, specifically a kind of ultraviolet light solidifies the reworkable waterproof sealing of in-situ polymerization
Glue.
Background technique
The waterproof sealing product of silica gel material is widely used in hardware plastic cement, Heating,Ventilating and Air Conditioning, fire-fighting, water supply and drainage, ship
Oceangoing ship, pharmacy, pipe-line system, automobile, toy, motorcycle, household electrical appliance, electronics, various machinery, sports equipment, pneumatic element and
The every field such as bathroom.Such silica gel sealing material needs to first pass through certain preparation process, assigns special shape,
Specific field can be just applied to.However the exemplar more special for some shapes, the waterproof sealing silica gel of conventional specification
Material is not applicable, needs specific customization, will cause the pressure and waste of time of cost in this way.
Currently, having already appeared the low-cost modified silica gel and silica gel product of many maturations on the market, directly adhesive is beaten
Enter in special exemplar, after a period of time, colloid curing molding, to play the role of waterproof sealing, which is usually required
It takes hours or the time of a couple of days.Also, the curing time of colloid is affected by external environment.This kind of sealant is logical
It is often that disposably, after solidification, preferable bonding can be formed to substrate or bulk strength is weaker, to the demand of reprocessing
The case where it is very unfavorable.
Ultraviolet cured adhesive, which sticks agent, has rapid curing, the feature insensitive to external environmental condition.Certain company opens recently
A ultraviolet light/moisture dual cure silica gel product is issued, can be applied to reworkable waterproof sealing field.It first passes around in short-term
Between ultraviolet light, the product can primary solidification forming.Using the moisture-curable of a few hours, adhesive is up to final property
Energy.This is the expensive of this adhesive, so that many fields are unbearable.
Ultraviolet curing acrylic ester adhesive equally has rapid curing, on the spot shaping characteristic.It is double with ultraviolet light/moisture
The cured silica gel of weight is compared, and ultraviolet light acrylate adhesive is not required to solidify after prolonged, just can reach final
Performance.And there is apparent price advantage, can be received by every field.Meanwhile ultraviolet light acrylate adhesive
Storage stability it is also preferable.Patent CN104419011A provide a kind of ultraviolet curing acrylic ester be formed in situ it is inviscid
The gasket on surface, the product have preferable bonding force to a part bonding substrate, have certain sealing function, but do not mention
And reprocess the application of aspect.Currently, still less about the ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization.
Summary of the invention
The purpose of the present invention is to provide a kind of ultraviolet lights to solidify the reworkable waterproof gasket cement of in-situ polymerization, above-mentioned to solve
Problem.
To achieve the above object, the invention provides the following technical scheme:
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization, including below according to the raw material of mass percent:
Acrylate prepolymer 55-75%, reactive diluent 15-40%, photoinitiator 1-5%, filler 0-5%, thixotropic agent 0-
5%, wax 0-0.1%, stabilizer 0-0.1%.
In a kind of optinal plan: the acrylic resin prepolymer is polyurethane acrylate resin prepolymer, polyester
Acrylate prepolymer, Epocryl prepolymer, organosilicon-modified acrylate prepolymer, reactive amines are modified
One of acrylate prepolymer or multiple combinations.
In a kind of optinal plan: the degree of functionality of resin is between 1-6 in the acrylic resin prepolymer.
In a kind of optinal plan: the degree of functionality of resin is between 1 and 3 in the acrylic resin prepolymer.
In a kind of optinal plan: the reactive diluent is active methyl acrylate monomer, the methacrylic acid
Ester monomer is hydroxy-ethyl acrylate, hydroxyethyl methacrylate, isobornyl acrylate, acrylic acid tetrahydrofuran ester, acrylic acid
Butyl ester, butyl methacrylate, Isooctyl acrylate monomer, isodecyl acrylate, triethylene-glycol dimethylacrylate, alcoxyl
Base dodecyl acrylate, vinyl neodecanoate, N, one of N- dimethylacrylamide or multiple combinations.
In a kind of optinal plan: the photoinitiator is 2- hydroxy-methyl phenyl-propane -1- ketone, 1- hydroxy-cyclohexyl
Phenyl ketone, 2- methyl-1-(4- methyl mercapto phenyl)-2- morpholinyl-1- acetone, benzoin dimethylether BDK, 2,4,6- trimethyl
Benzoyl diphenyl phosphine oxide, isopropyl thioxanthone, 2- benzyl -2- dimethylamino -1- (4- morpholinyl phenyl) butanone, benzene
One of bis- (2,4,6- trimethylbenzoyl) phosphine oxides of base, benzophenone, camphorquinone, 4- dimethyl ethyl aminobenzoate
Or multiple combinations.
In a kind of optinal plan: the filler includes one of talcum powder, zinc stearate, odium stearate or a variety of groups
It closes.
In a kind of optinal plan: the thixotropic agent includes fumed silica, organobentonite, polyamide wax, silicic acid
Sodium, magnesium silicate, fluosilicate, the silicate of lithium metasilicate, silica, cellulose-acetate propionate, one in acetylbutyrylcellulose
Kind or multiple combinations.
In a kind of optinal plan: the wax include polyethylene wax powder, polypropylene wax powder, polyamide wax powder, in paraffin mass
One or more combinations.
In a kind of optinal plan: the stabilizer be 2,6 di tert butyl 4 methyl phenol, hydroquinone, 1,4-benzoquinone,
One of phenothiazine, beta-phenyl naphthylamines, p-tert-Butylcatechol, methylene blue, p-hydroxyanisole or multiple combinations.
Compared to the prior art, beneficial effects of the present invention are as follows:
The ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization of the application is suitable for various plastic basis materials, various does not advise
The then exemplar of shape may replace silica gel sealing materials'use.Meanwhile the ultraviolet cured adhesive stick agent can in-situ polymerization, construction
It is simple process, easy to operate, it is only necessary to which that tens of seconds can be fully cured.Colloid after solidification is moderate to the bonding force of substrate, can be light
It is reprocessed.Hardness after solidification is high, and breaking strength is high, and elongation at break is high.
Specific embodiment
Following embodiment can be described in detail the present invention, and each embodiment cited by the present invention is only to illustrate the present invention,
It is not used to limit the scope of the present invention.Any modification apparent easy to know or change made for the present invention are without departure from the present invention
Spirit and scope.
Embodiment 1
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization, including below according to the raw material of mass percent:
Acrylate prepolymer 55%, reactive diluent 40%, photoinitiator 5%.
Wherein, the acrylic resin prepolymer is polyurethane acrylate resin prepolymer, polyester acrylate resin
Prepolymer, Epocryl prepolymer, organosilicon-modified acrylate prepolymer, reactive amines modified acrylic ester resin
The ratios such as prepolymer are composed.
The degree of functionality of resin is 1 in the acrylic resin prepolymer.
The reactive diluent is active methyl acrylate monomer, and the methacrylate monomers are acrylic acid hydroxyl second
Ester, hydroxyethyl methacrylate, isobornyl acrylate, acrylic acid tetrahydrofuran ester, butyl acrylate, methacrylic acid fourth
Ester, Isooctyl acrylate monomer, isodecyl acrylate, triethylene-glycol dimethylacrylate, alkoxy dodecyl acrylic acid
Ester, vinyl neodecanoate, N, the ratio such as N- dimethylacrylamide are composed.
The photoinitiator is 2- hydroxy-methyl phenyl-propane-1- ketone, 1- hydroxy-cyclohexyl phenyl ketone, 2- methyl-1-
(4- methyl mercapto phenyl) -2- morpholinyl -1- acetone, the oxidation of benzoin dimethylether BDK, 2,4,6- trimethyl benzoyl diphenyl base
Phosphine, isopropyl thioxanthone, 2- benzyl -2- dimethylamino -1- (4- morpholinyl phenyl) butanone, bis- (the 2,4,6- trimethyls of phenyl
Benzoyl) ratio such as phosphine oxide, benzophenone, camphorquinone, 4- dimethyl ethyl aminobenzoate is composed.
Embodiment 2
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization, including below according to the raw material of mass percent:
Polyurethane acrylate prepolymer 60.8%, isobornyl acrylate 33.8%, 1- hydroxy-cyclohexyl phenyl ketone 1%, 2,4,
6- trimethyl benzoyl diphenyl base phosphine oxide 1%, talcum powder 3.35%, p-hydroxyanisole 0.05%.
Embodiment 3
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization, including below according to the raw material of mass percent:
Polyurethane acrylate prepolymer 64.1%, organosilicon-modified acrylate prepolymer 7.7%, isobornyl acrylate 5.1%,
N, N- dimethylacrylamide 5.1%, isodecyl acrylate 12.8%, 1- hydroxy-cyclohexyl phenyl ketone 1.3%, phenyl are double
(2,4,6- trimethylbenzoyl) phosphine oxide 1.25%, paraffin 0.05%, fumed silica 2.6%.
Embodiment 4
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization, including below according to the raw material of mass percent:
Polyurethane acrylate prepolymer 58.7%, reactive amines modified acrylic ester resin prepolymer 9.8%, isobornyl acrylate
9.8%, N, N- dimethylacrylamide 9.8%, acrylic acid tetrahydrofuran ester 4.9%, 1- hydroxy-cyclohexyl phenyl ketone
0.7%, 2,4,6- trimethyl benzoyl diphenyl base phosphine oxide 0.7%, phenyl bis- (2,4,6- trimethylbenzoyls) aoxidize
Phosphine 0.7%, fumed silica 4.9%.
Embodiment 5
A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization, including below according to the raw material of mass percent:
Acrylate prepolymer 74%, reactive diluent 15%, photoinitiator 1%, filler 4.9%, thixotropic agent 4.9%, wax
0.1%, stabilizer 0.1%.
The acrylic resin prepolymer is polyurethane acrylate resin prepolymer, polyester acrylate resin pre-polymerization
Object, Epocryl prepolymer, organosilicon-modified acrylate prepolymer, reactive amines modified acrylic ester resin pre-polymerization
The ratios such as object are composed.
The degree of functionality of resin is 6 in the acrylic resin prepolymer.
The reactive diluent is active methyl acrylate monomer, and the methacrylate monomers are acrylic acid hydroxyl second
Ester, hydroxyethyl methacrylate, isobornyl acrylate, acrylic acid tetrahydrofuran ester, butyl acrylate, methacrylic acid fourth
Ester, Isooctyl acrylate monomer, isodecyl acrylate, triethylene-glycol dimethylacrylate, alkoxy dodecyl acrylic acid
Ester, vinyl neodecanoate, N, the ratio such as N- dimethylacrylamide are composed.
The photoinitiator is 2- hydroxy-methyl phenyl-propane-1- ketone, 1- hydroxy-cyclohexyl phenyl ketone, 2- methyl-1-
(4- methyl mercapto phenyl) -2- morpholinyl -1- acetone, the oxidation of benzoin dimethylether BDK, 2,4,6- trimethyl benzoyl diphenyl base
Phosphine, isopropyl thioxanthone, 2- benzyl -2- dimethylamino -1- (4- morpholinyl phenyl) butanone, bis- (the 2,4,6- trimethyls of phenyl
Benzoyl) ratio such as phosphine oxide, benzophenone, camphorquinone, 4- dimethyl ethyl aminobenzoate is composed.
The filler is composed of talcum powder, zinc stearate, odium stearate according to mass ratio for 1:2:1.
The thixotropic agent by fumed silica, organobentonite, polyamide wax, sodium metasilicate, magnesium silicate, fluosilicate,
The silicate of lithium metasilicate, silica, cellulose-acetate propionate, acetylbutyrylcellulose etc. ratio be composed.
The wax is composed of ratios such as polyethylene wax powder, polypropylene wax powder, polyamide wax powder, paraffin masses.
The stabilizer is 2,6 di tert butyl 4 methyl phenol, hydroquinone, 1,4-benzoquinone, phenothiazine, beta-phenyl naphthalene
The ratios such as amine, p-tert-Butylcatechol, methylene blue, p-hydroxyanisole are composed.
The ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization of the application is suitable for various plastic basis materials, various does not advise
The then exemplar of shape may replace silica gel sealing materials'use.Meanwhile the ultraviolet cured adhesive stick agent can in-situ polymerization, construction
It is simple process, easy to operate, it is only necessary to which that tens of seconds can be fully cured.Colloid after solidification is moderate to the bonding force of substrate, can be light
It is reprocessed.Hardness after solidification is between ShoreA20-80, and breaking strength is between 2-10Mpa, and elongation at break is in 100-
Between 500%.
The reworkable waterproof of in-situ polymerization is solidified to the embodiment of the present application 2, embodiment 3 and the ultraviolet light obtained of embodiment 4
Sealant and existing ultraviolet curing acrylic ester adhesive are tested as a comparison case, and test method is as follows:
Tensile strength test method: GB1040.1-2006；Elongation at break test method: GB1040.1-2006；Hardness
Test method: GB/T531.1-2008.
Test data is as shown in the table:
| Number | Hardness (ShoreA) | Elongation at break (%) | Tensile strength (Mpa) |
| Embodiment 2 | 60 | 300% | 4.5 |
| Embodiment 3 | 45 | 130% | 2.5 |
| Embodiment 4 | 80 | 100% | 5.0 |
| Comparative example | 18 | 90% | 2 |
As can be seen from the above table, the reworkable waterproof gasket cement hardness of ultraviolet light solidification in-situ polymerization of the application, fracture are stretched
Long rate and drawstring strength character are superior to existing ultraviolet curing acrylic ester adhesive property.
The above, the only specific embodiment of the disclosure, but the protection scope of the disclosure is not limited thereto, it is any
Those familiar with the art can easily think of the change or the replacement in the technical scope that the disclosure discloses, and should all contain
It covers within the protection scope of the disclosure.Therefore, the protection scope of the disclosure should be subject to the protection scope in claims.
Claims (10)
1. a kind of ultraviolet light solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that including below according to quality percentage
The raw material of ratio: acrylate prepolymer 55-75%, reactive diluent 15-40%, photoinitiator 1-5%, filler 0-5%, thixotroping
Agent 0-5%, wax 0-0.1%, stabilizer 0-0.1%.
2. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that described third
Olefin(e) acid resin prepolymer is polyurethane acrylate resin prepolymer, polyester acrylate resin prepolymer, epoxy acrylate
One of resin prepolymer, organosilicon-modified acrylate prepolymer, reactive amines modified acrylic ester resin prepolymer are more
Kind combination.
3. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that described third
The degree of functionality of resin is between 1-6 in olefin(e) acid resin prepolymer.
4. ultraviolet light according to claim 3 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that described third
The degree of functionality of resin is between 1 and 3 in olefin(e) acid resin prepolymer.
5. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that the work
Property diluent be active methyl acrylate monomer, the methacrylate monomers be hydroxy-ethyl acrylate, methacrylic acid
Hydroxyl ethyl ester, isobornyl acrylate, acrylic acid tetrahydrofuran ester, butyl acrylate, butyl methacrylate, acrylic acid are different pungent
Ester, isodecyl acrylate, triethylene-glycol dimethylacrylate, alkoxy dodecyl acrylate, neodecanoic acid ethylene
Ester, N, one of N- dimethylacrylamide or multiple combinations.
6. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that the light
Initiator is 2- hydroxy-methyl phenyl-propane-1- ketone, 1- hydroxy-cyclohexyl phenyl ketone, 2- methyl-1-(4- methylthio phenyl
Base) -2- morpholinyl -1- acetone, benzoin dimethylether BDK, 2,4,6- trimethyl benzoyl diphenyl base phosphine oxide, isopropyl sulphur
Miscellaneous anthrone, 2- benzyl -2- dimethylamino -1- (4- morpholinyl phenyl) butanone, bis- (2,4,6- trimethylbenzoyl) oxygen of phenyl
Change one of phosphine, benzophenone, camphorquinone, 4- dimethyl ethyl aminobenzoate or multiple combinations.
7. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that described to fill out
Material includes one of talcum powder, zinc stearate, odium stearate or multiple combinations.
8. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that the touching
Become the silicic acid that agent includes fumed silica, organobentonite, polyamide wax, sodium metasilicate, magnesium silicate, fluosilicate, lithium metasilicate
One of salt, silica, cellulose-acetate propionate, acetylbutyrylcellulose or multiple combinations.
9. ultraviolet light according to claim 1 solidifies the reworkable waterproof gasket cement of in-situ polymerization, which is characterized in that the wax
Including one of polyethylene wax powder, polypropylene wax powder, polyamide wax powder, paraffin mass or multiple combinations.
10. -9 any ultraviolet lights solidify the reworkable waterproof gasket cement of in-situ polymerization according to claim 1, feature exists
In, the stabilizer be 2,6- di-tert-butyl-4-methy phenol, it is hydroquinone, 1,4-benzoquinone, phenothiazine, beta-phenyl naphthylamines, right
One of tert-butyl catechol, methylene blue, p-hydroxyanisole or multiple combinations.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910697218.XA CN110358493A (en) | 2019-07-30 | 2019-07-30 | A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910697218.XA CN110358493A (en) | 2019-07-30 | 2019-07-30 | A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110358493A true CN110358493A (en) | 2019-10-22 |
Family
ID=68221460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910697218.XA Pending CN110358493A (en) | 2019-07-30 | 2019-07-30 | A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110358493A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111057514A (en) * | 2019-12-23 | 2020-04-24 | 烟台信友新材料有限公司 | High-strength moisture-heat-resistant photocuring adhesive and preparation method thereof |
| CN111471139A (en) * | 2020-04-27 | 2020-07-31 | 孝感市易生新材料有限公司 | Soft photocuring 3D printing resin material and preparation method thereof |
| CN111690278A (en) * | 2020-07-09 | 2020-09-22 | 西卡(上海)管理有限公司 | Waterproof material |
| CN113462324A (en) * | 2021-07-09 | 2021-10-01 | 上海汉司实业有限公司 | Ultraviolet curing dust catching adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560370A (en) * | 2009-05-15 | 2009-10-21 | 烟台德邦科技有限公司 | Light-curable adhesive with shock absorption property |
| CN102911619A (en) * | 2012-10-31 | 2013-02-06 | 广东恒大新材料科技有限公司 | Assistant composite activated by ultraviolet light and adhesive containing composite |
| CN103525355A (en) * | 2013-10-16 | 2014-01-22 | 烟台德邦科技有限公司 | Ultraviolet curing adhesive for liquid crystal display television side frame and preparation method of ultraviolet curing adhesive |
| CN106833498A (en) * | 2017-02-24 | 2017-06-13 | 广州回天新材料有限公司 | One kind sealing marine glue and its preparation method and application |
-
2019
- 2019-07-30 CN CN201910697218.XA patent/CN110358493A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560370A (en) * | 2009-05-15 | 2009-10-21 | 烟台德邦科技有限公司 | Light-curable adhesive with shock absorption property |
| CN102911619A (en) * | 2012-10-31 | 2013-02-06 | 广东恒大新材料科技有限公司 | Assistant composite activated by ultraviolet light and adhesive containing composite |
| CN103525355A (en) * | 2013-10-16 | 2014-01-22 | 烟台德邦科技有限公司 | Ultraviolet curing adhesive for liquid crystal display television side frame and preparation method of ultraviolet curing adhesive |
| CN106833498A (en) * | 2017-02-24 | 2017-06-13 | 广州回天新材料有限公司 | One kind sealing marine glue and its preparation method and application |
Non-Patent Citations (1)
| Title |
|---|
| 耿耀宗: "《现代水性涂料：工艺•配方•应用》", 31 March 2003, 中国石化出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111057514A (en) * | 2019-12-23 | 2020-04-24 | 烟台信友新材料有限公司 | High-strength moisture-heat-resistant photocuring adhesive and preparation method thereof |
| CN111057514B (en) * | 2019-12-23 | 2021-11-19 | 烟台信友新材料有限公司 | High-strength moisture-heat-resistant photocuring adhesive and preparation method thereof |
| CN111471139A (en) * | 2020-04-27 | 2020-07-31 | 孝感市易生新材料有限公司 | Soft photocuring 3D printing resin material and preparation method thereof |
| CN111690278A (en) * | 2020-07-09 | 2020-09-22 | 西卡(上海)管理有限公司 | Waterproof material |
| CN113462324A (en) * | 2021-07-09 | 2021-10-01 | 上海汉司实业有限公司 | Ultraviolet curing dust catching adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110358493A (en) | A kind of ultraviolet light solidification reworkable waterproof gasket cement of in-situ polymerization | |
| CN107709498B (en) | Polymerization initiator, polymerization system and the method using the system of encapsulating | |
| CN102056950B (en) | Curable compositions | |
| JP4459880B2 (en) | Energy ray curable resin composition and adhesive using the same | |
| CN103492504A (en) | Curable elastomer compositions with low temperature sealing capability | |
| US20110269894A1 (en) | Curable composition, cured article obtained therefrom and process for preparation of the same | |
| JPWO2006129678A1 (en) | Energy ray curable resin composition and adhesive using the same | |
| CN103608415A (en) | Low temperature curable adhesive compositions | |
| JP2004126211A (en) | Resin composition for sealing liquid crystal, and method of manufacturing liquid crystal display panel | |
| JP2014160251A (en) | Sealant composition for liquid crystal display device | |
| JP5499501B2 (en) | Adhesive composition | |
| CN101177599A (en) | Aromatic hydrocarbon-free environment-protection chloroprene rubber adhesive with high adhesive strength | |
| CN109266281A (en) | UV glue | |
| CN101851397A (en) | Synthetic resin and ultraviolet light curing adhesive prepared by using same | |
| CN105349086A (en) | Optical transparent adhesive composition and application thereof | |
| CN108456493A (en) | A kind of UV mercury lamps solidification EVA optical adhesive films and preparation method thereof | |
| KR102381767B1 (en) | A photocurable sealing agent composition, its preparation and its use | |
| CN101260184B (en) | Technique for synthesizing vinyl ester resin and application thereof in power plant smoke desulfurization by wet method | |
| CN103421209B (en) | Medium temperature curing initiator suitable for unsaturated resin products | |
| JP2019513165A (en) | Curable urethane acrylate compositions having bimodal molecular weight distribution | |
| CN109536087A (en) | Optics pressure sensitive adhesive and preparation method thereof | |
| US6228918B1 (en) | Low-temperature and low pressure unsaturated polyester resin composition | |
| JP5228882B2 (en) | Sealant composition | |
| JP5890634B2 (en) | Gasket material, gasket and hard disk drive, and method for manufacturing gasket | |
| CN106947235A (en) | A kind of acrylic diamond of high printing opacity |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191022 |
|
| RJ01 | Rejection of invention patent application after publication |