CN110343366A - A kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method - Google Patents

A kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method Download PDF

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Publication number
CN110343366A
CN110343366A CN201910629713.7A CN201910629713A CN110343366A CN 110343366 A CN110343366 A CN 110343366A CN 201910629713 A CN201910629713 A CN 201910629713A CN 110343366 A CN110343366 A CN 110343366A
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CN
China
Prior art keywords
epoxy
color light
compressive strength
variable color
high compressive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910629713.7A
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Chinese (zh)
Inventor
路劲松
邹建平
翁伟君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Intercalon Electronic Materials Co Ltd
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Shanghai Intercalon Electronic Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Intercalon Electronic Materials Co Ltd filed Critical Shanghai Intercalon Electronic Materials Co Ltd
Priority to CN201910629713.7A priority Critical patent/CN110343366A/en
Publication of CN110343366A publication Critical patent/CN110343366A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/38Layered products comprising a layer of synthetic resin comprising epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/40Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C17/00Pavement lights, i.e. translucent constructions forming part of the surface
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/02Bricks

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Epoxy Resins (AREA)

Abstract

The invention discloses a kind of variable color light-emitting intelligent brick high compressive strength epoxy materials, including epoxy material one and epoxy material two, the weight ratio of the epoxy material one are as follows: epoxy resin: filler material: reinforcing material: stone: curing agent: diluent=100/100~300/1~30/0~500/40~60/5~35, the weight ratio of the epoxy material two are as follows: epoxy resin: filler material: reinforcing material: curing agent: diluent=100/100~300/1~30/40~60/5~35.Variable color light-emitting intelligent brick high compressive strength epoxy material and the preparation method, it is formed by using the mode for being heating and curing and (heating 80~120 DEG C to solidify 2~4 hours), be conducive to improve shaping speed and curing degree, product heat resisting temperature more importantly can be improved, by being carrier using epoxy resin, enhanced using special reinforcing material, that is, ensure that light transmittance, and increase compression strength.

Description

A kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method
Technical field
The present invention relates to road pavement technical field, specially a kind of variable color light-emitting intelligent brick high compressive strength epoxy Material and preparation method.
Background technique
With the development of modern science and technology, intelligence is increasingly required, so to paving used in road traffic, landscape sign etc. Dress also has increasingly higher demands, and major requirement has the features such as compression strength is high, light transmission is good, changeable colour, with reach warning and Beautiful purpose.
Not only epoxy brick compares shortage currently on the market, this similar intelligent brick special product all compare shortage, not at Ripe, and there are complex process, producing efficiency are low, at high cost, compression strength is weaker, is easily broken off and high-low temperature resistant effect The disadvantages of poor and light transmittance is poor, on the market although similar products solve the problems, such as process structure or light transmittance, but mesh Preceding compression strength all wretched insufficiencies, therefore, it is contemplated that being proposed the problem of the advantages of arriving epoxy resin and existing market intelligent brick It is a kind of to be used for variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of variable color light-emitting intelligent brick high compressive strength epoxy materials Material and preparation method, solve asking for the brick compression strength wretched insufficiency of epoxy currently on the market mentioned above in the background art Topic.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of variable color light-emitting intelligent brick use High compressive strength epoxy material, including epoxy material one and epoxy material two, the weight ratio of the epoxy material one are as follows: asphalt mixtures modified by epoxy resin Rouge: filler material: reinforcing material: stone: curing agent: diluent=100/100~300/1~30/0~500/40~60/5~ 35, the weight ratio of the epoxy material two are as follows: epoxy resin: filler material: reinforcing material: curing agent: diluent=100/100~ 300/1~30/40~60/5~35.
Preferably, the epoxy resin is the mixing of one or both of bisphenol A epoxide resin or bisphenol F epoxy resin Object.
Preferably, the filler material is one or more mixtures of silicon dioxide compound.
Preferably, the reinforcing material is one or both of glass fibre or glass powder mixture.
Preferably, the stone is one or both of rubble or cobble mixture.
Preferably, the curing agent is modified amine curing agent.
Preferably, the diluent is epoxy active diluent.
It is used for cooperation above-mentioned material, it is proposed that a kind of system of variable color light-emitting intelligent brick high compressive strength epoxy material Preparation Method includes the following steps:
S1, it after epoxy resin, filler material, reinforcing material are weighed in proportion, stirs evenly;
S2, be put in proportion into diluent again, curing agent stirs evenly;
S3, when making epoxy material one, be put in proportion into stone, stir evenly, production epoxy material is second not Add stone.
Following epoxy brick, including the first epoxy layer, the bottom of first epoxy layer are made using above-mentioned material and method It is provided with the second epoxy layer, the inside of second epoxy layer is embedded with LED intelligent alterable Optical Line Board OL, second epoxy layer Bottom be provided with third epoxy layer, the bosom of the third epoxy layer is provided through and LED intelligent alterable optical link The conduit of plate connection, and the first epoxy layer and third epoxy layer are all made of epoxy material one and are made, the second epoxy layer is adopted It is made with epoxy material two.
Preferably, first epoxy layer is identical as the material of third epoxy layer and proportion, and the thickness of the first epoxy layer Less than third epoxy layer.
(3) beneficial effect
The present invention provides a kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation methods.Have Beneficial effect is as follows:
1. variable color light-emitting intelligent brick high compressive strength epoxy material and the preparation method, by being using epoxy resin Carrier is enhanced using special reinforcing material, that is, ensure that light transmittance, and increase compression strength.
2. variable color light-emitting intelligent brick high compressive strength epoxy material and the preparation method, by using being heating and curing The mode of (80~120 DEG C of heating solidifies 2~4 hours) forms;Be conducive to improve shaping speed and curing degree, improve work effect Rate, it is often more important that product heat resisting temperature can be improved, increase its compression strength.
Detailed description of the invention
Fig. 1 is partial sectional view of the present invention.
In figure: 1 first epoxy layer, 2 second epoxy layers, 3LED intelligent alterable Optical Line Board OL, 4 third epoxy layers, 5 conducting wires Pipe.
Specific embodiment
The present invention is further elaborated below by drawings and examples.
Referring to Fig. 1, the embodiment of the present invention is the following technical schemes are provided: a kind of high pressure resistance of variable color light-emitting intelligent brick Epoxy material, including epoxy material one and epoxy material two are spent, the weight ratio of the epoxy material one are as follows: epoxy resin: filling Material: reinforcing material: stone: curing agent: diluent=100/100~300/1~30/0~500/40~60/5~35, the ring The weight ratio of oxygen material two are as follows: epoxy resin: filler material: reinforcing material: curing agent: diluent=100/100~300/1~ 30/40~60/5~35.
Epoxy resin is one or both of bisphenol A epoxide resin or bisphenol F epoxy resin mixture, filler material two One or more mixtures, such as silicon powder, silica flour, quartz sand and talcum powder of silicon oxide compounds etc., reinforcing material are One or both of glass fibre or glass powder mixture, stone are one or both of rubble or cobble mixture, Gu Agent is modified amine curing agent, and diluent is epoxy active diluent.
It is used for cooperation above-mentioned material, a kind of system of variable color light-emitting intelligent brick high compressive strength epoxy material is now provided Preparation Method includes the following steps:
S1, it after epoxy resin, filler material, reinforcing material are weighed in proportion, stirs evenly;
S2, be put in proportion into diluent again, curing agent stirs evenly;
S3, when making epoxy material one, be put in proportion into stone, stir evenly, production epoxy material is second not Add stone.
Following epoxy brick, including the first epoxy layer 1 are made using above-mentioned material and method, the bottom of the first epoxy layer 1 is set It is equipped with the second epoxy layer 2, the inside of the second epoxy layer 2 is embedded with LED intelligent alterable Optical Line Board OL 3, the bottom of the second epoxy layer 2 It is provided with third epoxy layer 4, the bosom of third epoxy layer 4 is provided through to be connect with LED intelligent alterable Optical Line Board OL 3 Conduit 5, and the first epoxy layer 1 and third epoxy layer 4 are all made of epoxy material one and are made, the second epoxy layer 2 uses ring Oxygen material two is made, and the first epoxy layer 1 is identical as the material of third epoxy layer 4 and proportion, and the thickness of the first epoxy layer 1 Less than third epoxy layer 4.
The preparation principle of above-mentioned epoxy brick are as follows: color epoxy brick can be changed for this kind of Intelligent luminous, make the first ring first Oxygen layer 1, i.e., by adding epoxy resin, filler material, reinforcing material, stone, modified amine curing agent, ring in epoxy bricks die Oxygen resin reactive diluents are simultaneously mixed according to 100/100~300/1~30/0~500/40~60/5~35 ratio, thick Within 1 centimetre of degree, then, the second epoxy layer 2 is made, i.e., by using epoxy resin, filler material, reinforcing material, modified amine Curing agent, epoxide resin reactive diluent are simultaneously mixed according to 100/100~300/1~30/40~60/5~35 ratio, It is controlled with a thickness of 2~3.5 centimetres, then places LED lamp panel 3 on the surface of the second epoxy layer 2, meanwhile, conducting wire in conduit 5 Quantity be no less than two, make conducting wire in the middle edge of LED lamp panel 3, third epoxy layer 4 then made, by using epoxy Resin, filler material, reinforcing material, stone, modified amine curing agent, epoxide resin reactive diluent and according to 100/100~ 300/1~30/0~500/40~60/5~35 ratio mixes, control third epoxy layer 4 with a thickness of 1~2 centimetre, Being heating and curing, (80~120 DEG C of heating solidifies 2~4 hours) is i.e. plastic afterwards, and by break away from moulds, epoxy brick can have been made At.
Epoxy brick designed by this programme has the property that
1) compression strength: >=35MPa
2) use temperature range: -20 DEG C~120 DEG C
3) tensile-sbear strength (in conjunction with aluminum material): >=10MPa
4) dielectric strength: >=17KV/mm
5) cure shrinkage :≤2%
Working principle: it in use, after epoxy resin, filler material, reinforcing material are weighed in proportion, stirs evenly, then presses Ratio investment diluent, curing agent stir evenly, and when making epoxy material one, are put in proportion into stone, stir evenly, Second stone is not added in production epoxy material, the characteristic using epoxy resin and modified amine curing agent is stirred evenly, using heating The mode for solidifying (80~120 DEG C of heating solidifies 2~4 hours) forms, and is conducive to improve molding speed by the way of being heating and curing Degree and curing degree and raising product heat resisting temperature increase its compression strength, and the weight ratio of epoxy material one are as follows: asphalt mixtures modified by epoxy resin Rouge: filler material: reinforcing material: stone: curing agent: diluent=100/100~300/1~30/0~500/40~60/5~ 35, the weight ratio of epoxy material two are as follows: epoxy resin: filler material: reinforcing material: curing agent: diluent=100/100~300/ 1~30/40~60/5~35.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (10)

1. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material, including epoxy material one and epoxy material two, It is characterized in that: the weight ratio of the epoxy material one are as follows: epoxy resin: filler material: reinforcing material: stone: curing agent: diluent =100/100~300/1~30/0~500/40~60/5~35, the weight ratio of the epoxy material two are as follows: epoxy resin: fill out Charge: reinforcing material: curing agent: diluent=100/100~300/1~30/40~60/5~35.
2. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material according to claim 1, it is characterised in that: The epoxy resin is one or both of bisphenol A epoxide resin or bisphenol F epoxy resin mixture.
3. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material according to claim 1, it is characterised in that: The filler material is one or more mixtures of silicon dioxide compound.
4. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material according to claim 1, it is characterised in that: The reinforcing material is one or both of glass fibre or glass powder mixture.
5. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material according to claim 1, it is characterised in that: The stone is one or both of rubble or cobble mixture.
6. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material according to claim 1, it is characterised in that: The curing agent is modified amine curing agent.
7. a kind of variable color light-emitting intelligent brick high compressive strength epoxy material according to claim 1, it is characterised in that: The diluent is epoxy active diluent.
8. a kind of variable color light-emitting intelligent brick preparation method of high compressive strength epoxy material, includes the following steps:
S1, it after epoxy resin, filler material, reinforcing material are weighed in proportion, stirs evenly;
S2, be put in proportion into diluent again, curing agent stirs evenly;
S3, when making epoxy material one, be put in proportion into stone, stir evenly, production epoxy material stone is second not added Son.
9. a kind of variable color light-emitting intelligent brick epoxy made by high compressive strength epoxy material according to claim 1 Brick, it is characterised in that: including the first epoxy layer (1), the bottom of first epoxy layer (1) is provided with the second epoxy layer (2), institute The inside for stating the second epoxy layer (2) is embedded with LED intelligent alterable Optical Line Board OL (3), the bottom setting of second epoxy layer (2) Have third epoxy layer (4), the bosom of the third epoxy layer (4) is provided through and LED intelligent alterable Optical Line Board OL (3) The conduit (5) of connection, and the first epoxy layer (1) and third epoxy layer (4) are all made of epoxy material one and are made, the second ring Oxygen layer (2) is made using epoxy material two.
10. a kind of variable color light-emitting intelligent brick ring made by high compressive strength epoxy material according to claim 9 Oxygen brick, it is characterised in that: first epoxy layer (1) is identical as the material of third epoxy layer (4) and proportion, and the first epoxy layer (1) thickness is less than third epoxy layer (4).
CN201910629713.7A 2019-07-12 2019-07-12 A kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method Pending CN110343366A (en)

Priority Applications (1)

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CN201910629713.7A CN110343366A (en) 2019-07-12 2019-07-12 A kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method

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Application Number Priority Date Filing Date Title
CN201910629713.7A CN110343366A (en) 2019-07-12 2019-07-12 A kind of variable color light-emitting intelligent brick high compressive strength epoxy material and preparation method

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CN110343366A true CN110343366A (en) 2019-10-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111549605A (en) * 2020-04-28 2020-08-18 上海闰龙电子材料有限公司 Color-changeable luminous intelligent brick and installation steps and method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2701901Y (en) * 2004-01-15 2005-05-25 邱秀敏 Semiconductor artistic floor tile
CN203947037U (en) * 2014-05-27 2014-11-19 宿州典跃新型建筑材料有限公司 A kind of epoxy resin luminous ground
CN104177777A (en) * 2014-08-12 2014-12-03 铜陵国鑫光源技术开发有限公司 Epoxy resin material for LED (light-emitting diode) package and preparation method of epoxy resin material
RU2650989C1 (en) * 2017-05-02 2018-04-18 Сергей Константинович Кормилицын Illuminating construction component with high light transmittance
CN109485366A (en) * 2018-12-07 2019-03-19 新沂市福田石英材料有限公司 A kind of modified mortar for building

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2701901Y (en) * 2004-01-15 2005-05-25 邱秀敏 Semiconductor artistic floor tile
CN203947037U (en) * 2014-05-27 2014-11-19 宿州典跃新型建筑材料有限公司 A kind of epoxy resin luminous ground
CN104177777A (en) * 2014-08-12 2014-12-03 铜陵国鑫光源技术开发有限公司 Epoxy resin material for LED (light-emitting diode) package and preparation method of epoxy resin material
RU2650989C1 (en) * 2017-05-02 2018-04-18 Сергей Константинович Кормилицын Illuminating construction component with high light transmittance
CN109485366A (en) * 2018-12-07 2019-03-19 新沂市福田石英材料有限公司 A kind of modified mortar for building

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* Cited by examiner, † Cited by third party
Title
邱忠良, 中国水利水电出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111549605A (en) * 2020-04-28 2020-08-18 上海闰龙电子材料有限公司 Color-changeable luminous intelligent brick and installation steps and method thereof

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Application publication date: 20191018