CN110339791A - A kind of multi-functional synthesis device suitable for metal-organic framework material - Google Patents
A kind of multi-functional synthesis device suitable for metal-organic framework material Download PDFInfo
- Publication number
- CN110339791A CN110339791A CN201910574308.XA CN201910574308A CN110339791A CN 110339791 A CN110339791 A CN 110339791A CN 201910574308 A CN201910574308 A CN 201910574308A CN 110339791 A CN110339791 A CN 110339791A
- Authority
- CN
- China
- Prior art keywords
- metal
- organic framework
- fluid path
- framework material
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 66
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 49
- 239000012621 metal-organic framework Substances 0.000 title claims abstract description 49
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 49
- 230000007246 mechanism Effects 0.000 claims abstract description 100
- 238000006073 displacement reaction Methods 0.000 claims abstract description 39
- 239000012530 fluid Substances 0.000 claims abstract description 36
- 238000000967 suction filtration Methods 0.000 claims abstract description 29
- 239000000376 reactant Substances 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 22
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 238000000926 separation method Methods 0.000 claims abstract description 6
- 230000008520 organization Effects 0.000 claims abstract description 4
- 239000002699 waste material Substances 0.000 claims abstract description 4
- 239000012528 membrane Substances 0.000 claims description 13
- 229910001220 stainless steel Inorganic materials 0.000 claims description 13
- 239000010935 stainless steel Substances 0.000 claims description 13
- 238000001914 filtration Methods 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 3
- 238000002604 ultrasonography Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 238000005086 pumping Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 62
- 238000000034 method Methods 0.000 description 23
- 239000002184 metal Substances 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 17
- 230000008569 process Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 10
- 239000013384 organic framework Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000001994 activation Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000013110 organic ligand Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000010189 synthetic method Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/085—Funnel filters; Holders therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
- B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention belongs to materials synthesis equipment correlative technology fields, it discloses a kind of multi-functional synthesis devices suitable for metal-organic framework material, equipment includes gas displacement mechanism, filters mechanism, Ultrasonic Heating mechanism, the first fluid path and the second fluid path, gas displacement mechanism is removably attachable to filter mechanism, filters mechanism and portion gas displacement mechanism is contained in Ultrasonic Heating mechanism；First fluid path and the second fluid path are separately positioned on gas displacement mechanism and filter in mechanism；Gas displacement mechanism sends the synthetic product after reactant reaction to suction filtration mechanism for accommodating reactant and providing corresponding atmosphere for the reaction of reactant；Mechanism is filtered to be used for the metal-organic framework material and soluble impurity of synthetic product and the separation and drying of solvent；Second fluid path filters waste liquid within the organization for being discharged；Ultrasonic Heating mechanism is used to heat so that metal-organic framework material is dried suction filtration mechanism.The present invention improves synthetic ratio, and applicability is stronger.
Description
Technical field
The invention belongs to materials synthesis equipment correlative technology fields, and being suitable for metal more particularly, to one kind has machine frame
The multi-functional synthesis device of frame material.
Background technique
Metal-organic framework material (referred to as " MOFs ") is class I organic-inorganic hybridized material, by organic ligand and metal
Salt is self-assembly of, and the type of metal-organic framework material is extremely more, and diversified structure and outstanding porosity characteristic make metal
Organic framework materials be widely used in the absorption of gas with separate, be catalyzed, the fields such as energy storage.
Currently, there are many kinds of the synthetic methods of metal-organic framework material, for example, it is ultrasonic method, solvent-thermal method, paddling process, micro-
Wave heating method etc., and wherein solvent-thermal method is most conventional synthetic method, solvent-thermal method needs use ultrasonic machine, centrifuge,
Numerous instruments such as baking oven, vacuum drying oven, as the product in container shifts in different instruments, finally obtained metal has machine frame
Frame material will necessarily lose；Meanwhile synthesis process needs to operate a variety of different instruments, this also brings not to experimenter
Just.
The atmosphere for synthesizing different organic framework materials requirements is different, and the synthesis of part metals organic framework materials can
It completes in air, and part metals organic framework materials synthesis process needs the participation of special gas, such as oxygen or two
Carbonoxide；There are also part metals organic framework materials, atmospheric environment interferes synthesis process, needs to close in inert gas
At.In addition, needing to remove the impurity in metal-organic framework material, this process is known as after metal-organic framework material synthesis
The activation (or being known as purifying) of metal-organic framework material, the specific implementation method of activation process is successively to use deionization
Water, organic solvent (ethyl alcohol, acetone etc.) repeated ultrasonic clean solid product, isolate solid product, finally dry isolated
Solid product, wherein the process of solid product separation is more difficult, the method for usually used centrifugation in laboratory, but this method
Time-consuming, and loss is more, and yield is lower, is not suitable for industrialized production；Another method is to remove soluble impurity by filtration method
And solvent, but the rate of filtration is extremely slow under normal pressure.Correspondingly, there is develop a kind of synthetic ratio to be preferably suitable for gold for this field
Belong to the technical need of the multi-functional synthesis device of organic framework materials.
Summary of the invention
Aiming at the above defects or improvement requirements of the prior art, the present invention provides one kind to be suitable for metal organic frame material
The multi-functional synthesis device of material, the environment needed based on metal-organic framework material synthesis and synthesis feature, are had for metal
The different of machine frame materials synthesis require to improve device, allow the synthesis device individually to complete metal organic
The synthesis overall process of frame material, while the loss during sample cleanup is avoided, so that the conjunction of metal-organic framework material
At more efficient and convenient, synthetic ratio is higher, and applicability is stronger.
To achieve the above object, the present invention provides a kind of multi-functional synthesis suitable for metal-organic framework material to set
Standby, the equipment includes gas displacement mechanism, filters mechanism, Ultrasonic Heating mechanism, the first fluid path and the second fluid path, the gas
Displacement mechanism is removably attachable to the suction filtration mechanism, and the gas displacement mechanism of the suction filtration mechanism and part is contained in institute
State Ultrasonic Heating mechanism；First fluid path and second fluid path are separately positioned on the gas displacement mechanism and the suction filtration
In mechanism；
Solvent is added into the gas displacement mechanism by first fluid path；The gas displacement mechanism is for accommodating
Reactant and corresponding atmosphere is provided for the reaction of reactant, and sends the synthetic product after reactant reaction to the suction filtration
Mechanism；The mechanism that filters is used for the metal-organic framework material and soluble impurity of the synthetic product and the separation of solvent
And it is dry；Second fluid path is for being discharged the suction filtration waste liquid within the organization；The Ultrasonic Heating mechanism passes through ultrasonic vibration
Reactant is mixed, is also used to heat the suction filtration mechanism to carry out the metal-organic framework material
It is dry.
Further, after synthetic product is from the gas displacement mechanism into the suction filtration mechanism, pass through first liquid
Adding liquid in gas displacement mechanism described in road direction, then the Ultrasonic Heating mechanism carries out ultrasound to the gas displacement mechanism
Cleaning.
Further, the gas displacement mechanism includes the first gas circuit, the second gas circuit, upper cavity and the first funnel, described
First gas circuit and second gas circuit are separately positioned on the upper cavity；The upper cavity is cylindrical, first funnel
It is arranged in the upper cavity, is located at the open end of the upper cavity；First air circuit connection passes through described in gas cylinder
One gas circuit is passed through predetermined gas into the upper cavity with reaction atmosphere needed for building reactant reaction；Second gas circuit connects
It is connected to vacuum pump, the upper cavity is vacuumized by the vacuum pump and second gas circuit.
Further, the gas displacement mechanism further includes the 4th valve, and first funnel is arranged in the 4th valve
On spout of funnel.
Further, the gas displacement mechanism further includes case lid, and the case lid is removably disposed in the upper cavity
Far from described one end for filtering mechanism, first fluid path is arranged on the case lid.
Further, the suction filtration mechanism includes the second funnel, lower chamber and third gas circuit, and the second funnel setting exists
In the lower chamber, the third gas circuit is arranged on the lower chamber, and it is located at second funnel and second liquid
Between road；The third air circuit connection is in vacuum pump.
Further, the suction filtration mechanism further includes filter membrane, and the filter membrane is arranged on second funnel, is used to filter
Except the solvent and soluble impurity in synthetic product.
Further, the filter membrane is using made of stainless steel.
Further, second fluid path includes stainless steel tube and the 7th valve, and one end of the stainless steel tube is protruded into described
It filters in mechanism, the 7th valve is arranged on the stainless steel tube.
Further, first fluid path includes pipeline and the first valve, and first valve is arranged on the pipeline；It is described
One end of pipeline is protruded into the gas displacement mechanism；The pipeline is using made of glass.
In general, through the invention it is contemplated above technical scheme is compared with the prior art, it is provided by the invention suitable
Multi-functional synthesis device for metal-organic framework material mainly has the advantages that
1. the gas displacement mechanism is used to accommodate reactant and provide corresponding atmosphere for the reaction of reactant, and will be anti-
Synthetic product after answering object to react sends the suction filtration mechanism to；The suction filtration mechanism is for there is the metal of the synthetic product
Metal organic frame can be implemented separately in the separation and drying of machine frame frame material and soluble impurity and solvent, the synthesis device
The overall process of the synthesis of material, this makes the synthesis process of metal-organic framework material can be to avoid the use back and forth of more instruments
With the transfer repeatedly of sample, reduce the workload of operator, improve MOFs yield so that large-scale production MOFs become can
Energy.
2. the gas displacement mechanism is met for accommodating reactant and providing corresponding atmosphere for the reaction of reactant
MOFs under particular atmosphere and various air pressures, which is synthesized, to be required.
3. the suction filtration mechanism further includes filter membrane, the filter membrane is arranged on second funnel, is used to filter out synthesis
Solvent and soluble impurity in product.
4. the third air circuit connection vacuum pump, to be vacuumized to the lower chamber, so that MOFs sample and solvent
And be dissolved in impurity therein can quick separating, reduce filtration time, so that the purification of sample and drying process are more quick.
Detailed description of the invention
Fig. 1 is the schematic diagram of the multi-functional synthesis device provided by the invention suitable for metal-organic framework material.
In all the appended drawings, identical appended drawing reference is used to denote the same element or structure, in which: the first valve of 1-, 2-
Second valve, 3- third valve, the 4th valve of 4-, the 5th valve of 5-, the 6th valve of 6-, the 7th valve of 7-, 8- case lid, the first fluid path of 9-, 10- chamber
Body, 101- upper cavity, 102- lower chamber, the junction 103-, 11- filter membrane, 12- Ultrasonic Heating mechanism, the first funnel of 13-, 14-
Two funnels.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right
The present invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and
It is not used in the restriction present invention.As long as in addition, technical characteristic involved in the various embodiments of the present invention described below
Not constituting a conflict with each other can be combined with each other.
Referring to Fig. 1, the multi-functional synthesis device provided by the invention suitable for metal-organic framework material, the synthesis
Equipment includes gas displacement mechanism, filters mechanism, Ultrasonic Heating mechanism 12, the first fluid path 9 and the second fluid path, the gas displacement
Mechanism is removably attachable to the suction filtration mechanism, and the suction filtration mechanism is arranged in the Ultrasonic Heating mechanism 12；Described
One fluid path 9 is connected to the gas displacement mechanism, adds solvent into the gas displacement mechanism by first fluid path 9.
Second fluid path is connected to the suction filtration mechanism, is used to be discharged the waste liquid generated in the suction filtration mechanism.Wherein, the gas
Body is replaced atmosphere within the organization and is changed with the metal-organic framework material currently synthesized, has to meet the metal currently synthesized
The synthesis demand of machine frame frame material.The synthetic product progress metal for filtering mechanism and being used to synthesize the gas displacement mechanism
The separation and drying of organic framework materials and soluble impurity and solvent.The Ultrasonic Heating mechanism 12 by ultrasonic vibration come pair
The gas displacement mechanism is cleaned by ultrasonic, while it is also used to heat the suction filtration mechanism to complete to synthesis
The drying of metal-organic framework material.
The gas displacement mechanism includes the first gas circuit, the second gas circuit, upper cavity 101, case lid 8, the first funnel 13 and the
Four valves 4, the upper cavity 101 are cylindrical shape, and first gas circuit and second gas circuit are separately positioned on the upper cavity 101
Side, one end of first gas circuit is set in the upper cavity 101, and the other end is connected to gas cylinder.First gas circuit
For being passed through gas needed for air, oxygen, carbon dioxide, inert gas etc. react into the upper cavity 101.Second gas
The one end on road is set in the upper cavity 101, and the other end is connected to vacuum pump, can be to the gas by second gas circuit
Body replaces mechanism and carries out vacuumize process.
In present embodiment, one end that first gas circuit is located in the upper cavity 101 be located at reactant level hereinafter,
With gas in substitutional solution；One end that second gas circuit is located in the upper cavity 101 is located at reactant level or more, can lead to
Cross vacuum pump or directly complete to be evacuated by atmosphere and gas replenishment process, with build vacuum environment in the upper cavity 101 or
Person is directly as outlet side.
First gas circuit includes the first tracheae and the second valve 2, and second valve 2 is arranged on first tracheae, institute
The one end for stating the first tracheae is contained in the upper cavity 101, and the other end is connected to the gas cylinder, to pass through the gas cylinder to institute
It states in upper cavity 101 and is passed through specific gas, build specific reaction atmosphere.Second gas circuit includes the second tracheae and third valve 3,
The third valve 3 is arranged on second tracheae.One end of second tracheae is contained in the upper cavity 101, another
End is connected to vacuum pump, to be evacuated to the upper cavity 101, to build the vacuum environment in the upper cavity 101.
The case lid 8 is arranged on one end of the upper cavity 101, covers one end of the upper cavity 101.On described
Cavity 101 provides environment for accommodating reactant (metal salt, organic ligand).First funnel 13 is arranged in institute
The one end of upper cavity 101 far from the case lid 8 is stated, is contained in the upper cavity 101.The mouth direction of first funnel 13
The case lid 8, the 4th valve 4 are arranged on the spout of funnel of first funnel 13.
First fluid path includes pipeline and the first valve 1, and first valve 1 is arranged on the pipeline.The pipeline
One end enters in the upper cavity 101 after passing through the case lid 8.In present embodiment, the pipeline is using made of glass.
Wherein, solvent (water, ethyl alcohol, acetone etc.) is added into the upper cavity 101 by first fluid path.
The suction filtration mechanism includes lower chamber 102, the second funnel 14, filter membrane 11, the 5th valve 5 and third gas circuit, under described
Cavity 102 is cylindrical shape, is open towards first funnel 13.Second funnel 14 is arranged in the lower chamber 102,
It is open towards the junction 103 formed between the upper cavity 101 and the lower chamber 102.5th valve 5 is arranged in institute
On the spout of funnel for stating the second funnel 14.The edge of the filter membrane 11 is connected on the inner wall of the lower chamber 102, and its setting exists
On second funnel 14.The third gas circuit includes third tracheae and the 6th valve 6, and one end of the third tracheae passes through described
It is protruded into after Ultrasonic Heating mechanism 12 and the lower chamber 102 in the lower chamber 102, the other end is connected to vacuum pump.Described
Six valves 6 are arranged on the third tracheae.In present embodiment, the third tracheae is located at the lower section of second funnel 14；
The lower chamber 102 and the part upper cavity 101 are contained in the Ultrasonic Heating mechanism 12, the Ultrasonic Heating mechanism 12
With heating function.
Second fluid path includes stainless steel tube and the 7th valve 7, and the lower chamber 102 is protruded into one end of the stainless steel tube
Interior, the 7th valve 7 is arranged on the stainless steel tube.Second fluid path is used for useless by what is generated in the lower chamber 102
Liquid discharge.
In present embodiment, the filter membrane 11 is made of stainless steel；First tracheae, second gas
Pipe and the third tracheae are made of stainless steel material；The cavity 10 is made of metal material；The conjunction
The component for needing to contact with reactant in forming apparatus is not with reactant reaction, the equal high temperature resistant low pressure of component in the cavity 10
(0~300 DEG C, 0~0.1MPa).
Reactant is heated by the Ultrasonic Heating mechanism 12 in the upper cavity 101 and starts to react, and reacts generation
Product enters the lower chamber 102 by the 4th valve 4, and is added by first fluid path into the upper cavity 101
Solvent, to be cleaned by ultrasonic to the upper cavity 101.The filter membrane 11 filters out reaction product, while by described
Third gas circuit is vacuumized the solvent quickly to filter out in reaction product to the lower chamber 102 and is dissolved in solvent miscellaneous
Matter.Finally, the metal-organic framework material of 12 pairs of synthesis of the Ultrasonic Heating mechanism heats, being achieved in metal has machine frame
The vacuum drying of frame material, the metal-organic framework material after drying take out the synthesis that metal-organic framework material can be completed.
Multi-functional synthesis device provided by the invention suitable for metal-organic framework material, the synthesis device have single
The ability of metal-organic framework material synthesis overall process is solely completed, so that the synthesis process of metal-organic framework material can be to avoid
The transfer repeatedly of more instruments used back and forth with sample, reduces the workload of operator, improves metal organic frame material
The yield of material makes it possible that metal-organic framework material is mass produced.In addition, the upper cavity of the synthesis device and under
Gas circuit is respectively set in cavity, so that it includes the multiple gases atmosphere such as air, moving air, inert gas and vacuum that cavity, which meets,
Requirement of experiment；Meanwhile addition metal filtration film and vacuum pump in lower chamber so that metal-organic framework material and soluble impurity and
Solvent can quick separating, reduce filtration time, so that the purification of the metal-organic framework material and drying process are more
Fast.
As it will be easily appreciated by one skilled in the art that the foregoing is merely illustrative of the preferred embodiments of the present invention, not to
The limitation present invention, any modifications, equivalent substitutions and improvements made within the spirit and principles of the present invention should all include
Within protection scope of the present invention.
Claims (10)
1. a kind of multi-functional synthesis device suitable for metal-organic framework material, it is characterised in that:
The synthesis device includes gas displacement mechanism, filters mechanism, Ultrasonic Heating mechanism (12), the first fluid path (9) and second
Fluid path, the gas displacement mechanism are removably attachable to the suction filtration mechanism, and the suction filtration mechanism and the part gas are set
Structure of changing planes is contained in the Ultrasonic Heating mechanism (12)；First fluid path (9) and second fluid path are separately positioned on described
In gas displacement mechanism and the suction filtration mechanism；
By adding solvent in the first fluid path (9) Xiang Suoshu gas displacement mechanism；The gas displacement mechanism is for accommodating
Reactant and corresponding atmosphere is provided for the reaction of reactant, and sends the synthetic product after reactant reaction to the suction filtration
Mechanism；The mechanism that filters is used for the metal-organic framework material and soluble impurity of the synthetic product and the separation of solvent
And it is dry；Second fluid path is for being discharged the suction filtration waste liquid within the organization；The Ultrasonic Heating mechanism (12) passes through ultrasound
Vibration is also used to heat to the metal-organic framework material suction filtration mechanism mix reactant
It is dried.
2. being suitable for the multi-functional synthesis device of metal-organic framework material as described in claim 1, it is characterised in that: synthesis
After product is from the gas displacement mechanism into the suction filtration mechanism, pass through the first fluid path (9) Xiang Suoshu gas displacement machine
Adding liquid in structure, then the Ultrasonic Heating mechanism (12) is cleaned by ultrasonic the gas displacement mechanism.
3. being suitable for the multi-functional synthesis device of metal-organic framework material as described in claim 1, it is characterised in that: described
Gas displacement mechanism includes the first gas circuit, the second gas circuit, upper cavity (101) and the first funnel (13), first gas circuit and institute
The second gas circuit is stated to be separately positioned on the upper cavity (101)；The upper cavity (101) is cylindrical, first funnel
(13) setting is located at the open end of the upper cavity (101) in the upper cavity (101)；First air circuit connection in
It is anti-needed for reactant reaction to build to be passed through predetermined gas into the upper cavity (101) by first gas circuit for gas cylinder
Answer atmosphere；Second air circuit connection is in vacuum pump, by the vacuum pump and second gas circuit to the upper cavity (101)
It is vacuumized.
4. being suitable for the multi-functional synthesis device of metal-organic framework material as claimed in claim 3, it is characterised in that: described
Gas displacement mechanism further includes the 4th valve (4), and the 4th valve (4) is arranged on the spout of funnel of first funnel (13).
5. being suitable for the multi-functional synthesis device of metal-organic framework material as claimed in claim 3, it is characterised in that: described
Gas displacement mechanism further includes case lid (8), and the case lid (8) is removably disposed in the upper cavity (101) far from the pumping
One end of filter structure, first fluid path are arranged on the case lid (8).
6. the multi-functional synthesis device as described in any one in claim 1-5 suitable for metal-organic framework material, feature
Be: the suction filtration mechanism includes the second funnel (14), lower chamber (102) and third gas circuit, the second funnel (14) setting
In the lower chamber (102), the third gas circuit is arranged on the lower chamber (102), and it is located at second funnel
(14) between second fluid path；The third air circuit connection is in vacuum pump.
7. being suitable for the multi-functional synthesis device of metal-organic framework material as claimed in claim 6, it is characterised in that: described
Filtering mechanism further includes filter membrane (11), and the filter membrane (11) is arranged on second funnel (14), is used to filter out synthesis and produces
Solvent and soluble impurity in object.
8. being suitable for the multi-functional synthesis device of metal-organic framework material as claimed in claim 7, it is characterised in that: described
Filter membrane (11) is using made of stainless steel.
9. the multi-functional synthesis device as described in any one in claim 1-5 suitable for metal-organic framework material, feature
Be: second fluid path includes stainless steel tube and the 7th valve (7), and the suction filtration mechanism is protruded into one end of the stainless steel tube
Interior, the 7th valve (7) is arranged on the stainless steel tube.
10. the multi-functional synthesis device as described in any one in claim 1-5 suitable for metal-organic framework material, feature
Be: first fluid path (9) includes pipeline and the first valve (1), and first valve (1) is arranged on the pipeline；The pipe
The one end in road is protruded into the gas displacement mechanism；The pipeline is using made of glass.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910574308.XA CN110339791B (en) | 2019-06-28 | 2019-06-28 | Multifunctional synthesis equipment suitable for metal organic framework material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910574308.XA CN110339791B (en) | 2019-06-28 | 2019-06-28 | Multifunctional synthesis equipment suitable for metal organic framework material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110339791A true CN110339791A (en) | 2019-10-18 |
| CN110339791B CN110339791B (en) | 2020-06-02 |
Family
ID=68177090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910574308.XA Active CN110339791B (en) | 2019-06-28 | 2019-06-28 | Multifunctional synthesis equipment suitable for metal organic framework material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110339791B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111921528A (en) * | 2020-06-28 | 2020-11-13 | 济南大学 | Method and system for preparing slurry bed Fischer-Tropsch synthesis catalyst slurry by pyrolyzing MOFs |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105037444A (en) * | 2015-06-19 | 2015-11-11 | 哈尔滨工业大学 | Synthetic method of metal organic frameworks Co-MOF-74 |
| CN105236389A (en) * | 2015-12-02 | 2016-01-13 | 南京大学 | Mass preparation method and device of graphene quantum dots |
| CN205649904U (en) * | 2016-05-19 | 2016-10-19 | 肇庆东洋铝业有限公司 | Dull and stereotyped vacuum suction filter device of aluminum paste |
| US20170037511A1 (en) * | 2006-08-31 | 2017-02-09 | Entegris, Inc. | Solid precursor-based delivery of fluid utilizing controlled solids morphology |
| CN107029670A (en) * | 2017-04-20 | 2017-08-11 | 华中科技大学 | A kind of metal organic framework moulding material and its forming method |
| CN206454332U (en) * | 2016-12-06 | 2017-09-01 | 中设设计集团股份有限公司 | A kind of silting blocking Suction filtration device based on ultrasonication |
| CN107159132A (en) * | 2017-06-07 | 2017-09-15 | 华中科技大学 | CO2/ CO selective absorbents and preparation method thereof |
| CN108276582A (en) * | 2017-12-27 | 2018-07-13 | 华中科技大学 | A kind of application of metal-organic framework materials and preparation method and formaldehyde adsorption |
| CN108484929A (en) * | 2018-06-11 | 2018-09-04 | 天津城建大学 | A kind of metal organic frame synthesis MIL-53 (Al)-AO based on amidoxime2Preparation method |
| CN108929676A (en) * | 2018-07-02 | 2018-12-04 | 湖北大学 | A kind of preparation method of composition metal organic framework materials UiO-67 |
| CN109267145A (en) * | 2018-08-30 | 2019-01-25 | 济南大学 | A kind of four acid anhydrides Zn-MOF crystalline material of naphthalene and its preparation method and application |
| CN109400906A (en) * | 2018-12-12 | 2019-03-01 | 太原理工大学 | The method of more metal MOFs materials is directly prepared using bimetal complex |
-
2019
- 2019-06-28 CN CN201910574308.XA patent/CN110339791B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170037511A1 (en) * | 2006-08-31 | 2017-02-09 | Entegris, Inc. | Solid precursor-based delivery of fluid utilizing controlled solids morphology |
| CN105037444A (en) * | 2015-06-19 | 2015-11-11 | 哈尔滨工业大学 | Synthetic method of metal organic frameworks Co-MOF-74 |
| CN105236389A (en) * | 2015-12-02 | 2016-01-13 | 南京大学 | Mass preparation method and device of graphene quantum dots |
| CN205649904U (en) * | 2016-05-19 | 2016-10-19 | 肇庆东洋铝业有限公司 | Dull and stereotyped vacuum suction filter device of aluminum paste |
| CN206454332U (en) * | 2016-12-06 | 2017-09-01 | 中设设计集团股份有限公司 | A kind of silting blocking Suction filtration device based on ultrasonication |
| CN107029670A (en) * | 2017-04-20 | 2017-08-11 | 华中科技大学 | A kind of metal organic framework moulding material and its forming method |
| CN107159132A (en) * | 2017-06-07 | 2017-09-15 | 华中科技大学 | CO2/ CO selective absorbents and preparation method thereof |
| CN108276582A (en) * | 2017-12-27 | 2018-07-13 | 华中科技大学 | A kind of application of metal-organic framework materials and preparation method and formaldehyde adsorption |
| CN108484929A (en) * | 2018-06-11 | 2018-09-04 | 天津城建大学 | A kind of metal organic frame synthesis MIL-53 (Al)-AO based on amidoxime2Preparation method |
| CN108929676A (en) * | 2018-07-02 | 2018-12-04 | 湖北大学 | A kind of preparation method of composition metal organic framework materials UiO-67 |
| CN109267145A (en) * | 2018-08-30 | 2019-01-25 | 济南大学 | A kind of four acid anhydrides Zn-MOF crystalline material of naphthalene and its preparation method and application |
| CN109400906A (en) * | 2018-12-12 | 2019-03-01 | 太原理工大学 | The method of more metal MOFs materials is directly prepared using bimetal complex |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111921528A (en) * | 2020-06-28 | 2020-11-13 | 济南大学 | Method and system for preparing slurry bed Fischer-Tropsch synthesis catalyst slurry by pyrolyzing MOFs |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110339791B (en) | 2020-06-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104955982B (en) | Chemical vapor depsotition equipment with particle separator | |
| CN207153705U (en) | A kind of reactor with solid-liquid separation function | |
| CN111715164B (en) | Reaction kettle | |
| CN110339791A (en) | A kind of multi-functional synthesis device suitable for metal-organic framework material | |
| CN110270133A (en) | A kind of integral post plate preparation method and application based on PE sieve plate conjugation chemistry group | |
| CN201187939Y (en) | Three-in-one multifunctional drying apparatus | |
| CN101307981A (en) | Three-in-one multifunctional drying apparatus | |
| CN206631578U (en) | A kind of high purity graphite process units | |
| CN220003969U (en) | Device for continuously separating and purifying MOFs | |
| CN102190292B (en) | Device for preparing fullerene | |
| CN212417330U (en) | Circulating tail gas absorbing device for chemical production | |
| CN210346149U (en) | Bipyramid vacuum filtration desiccator | |
| CN210385857U (en) | Filtering type reaction vessel for polypeptide synthesis | |
| CN214287518U (en) | Tail gas treatment device is used in tricalcium phosphate production and processing | |
| CN212092011U (en) | A filter equipment for dialysis | |
| CN207418857U (en) | A kind of chemical deposition device with protection baffle | |
| CN105836927A (en) | Separated purifying device of industrial waste liquid | |
| CN205570339U (en) | A combination equipment for chemical synthesis | |
| CN206391679U (en) | A kind of filter | |
| CN214512817U (en) | Supersound soxhlet extraction element | |
| RU2142314C1 (en) | Extractor | |
| CN215901757U (en) | A multi-functional reation kettle for medicine pilot scale | |
| CN212533118U (en) | Ultrasonic cleaning vibration plate of atmospheric pressure chemical vapor deposition equipment | |
| CN216472257U (en) | Nitrogen purification device convenient to clearance | |
| RU186728U1 (en) | LABORATORY DEVICE FOR WASHING POWDER CHEMICAL REACTIONS FROM EXTERNAL IMPURITIES |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |