CN110338193B - Penoxsulam preparation and preparation method thereof - Google Patents

Penoxsulam preparation and preparation method thereof Download PDF

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CN110338193B
CN110338193B CN201910659847.3A CN201910659847A CN110338193B CN 110338193 B CN110338193 B CN 110338193B CN 201910659847 A CN201910659847 A CN 201910659847A CN 110338193 B CN110338193 B CN 110338193B
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penoxsulam
preparation
oil
weeds
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CN110338193A (en
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牛巍
张晓臣
李萍
张强
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Hubei Guangfulin Biological Preparation Co ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a penoxsulam preparation and a preparation method thereof, wherein the penoxsulam preparation comprises the following components in parts by weight: 5-20 parts of a weeding active ingredient, 2-5 parts of a dispersing auxiliary agent, 5-8 parts of a slow release agent, 3-5 parts of an emulsifier, 0.1-2 parts of an active agent and 50-80 parts of an oil-based solvent, wherein the weeding active ingredient is penoxsulam. Also disclosed is the use of a penoxsulam formulation for inhibiting the growth of one or more of grassy weeds, sedge weeds, broadleaf weeds. The penoxsulam preparation provided by the invention is applied to gramineous weeds, cyperaceous weeds and broadleaf weeds, and has the advantages of high weeding efficiency, good weeding effect, simple preparation method process and no pollution.

Description

Penoxsulam preparation and preparation method thereof
Technical Field
The invention relates to the technical field of pesticide synthesis, and particularly relates to a penoxsulam preparation and a preparation method thereof.
Background
Penoxsulam is a post-emergence herbicide developed by the united states of america, the benefin company of dow agro sciences, which is effective in controlling barnyard grass, moleplant seed, and annual sedge weeds by inhibiting acetolactate synthase (ALS), and is effective against a wide range of broadleaf weeds. Has broad-spectrum weed control activity, the lasting period is as long as 30-60 days, and the weed harm in all seasons can be basically controlled by one-time application.
Penoxsulam is a conductive herbicide, is absorbed by leaves, stems and roots of weeds, and is conducted to meristems through xylem and phloem to inhibit plant growth, so that growing points are dark green. The safety to rice is due to the rapid degradation of the active ingredient in the rice. The weeds stop growing soon after treatment, at which point competition for crop growth by the weeds is reduced to a minimum.
However, penoxsulam is a strong acetolactate synthase inhibitor, the herbicide is slow in appearance, weeds can die gradually after a certain time, and the death speed of the weeds is related to the accumulation amount of branched-chain amino acids in the bodies of the weeds. The selectivity of weeding is high, but the efficiency of weeding needs to be improved.
Disclosure of Invention
The invention aims to realize the technical purpose and provides a penoxsulam preparation with high weeding efficiency and good weeding effect and a preparation method thereof.
The technical purpose of the invention is realized by the following technical scheme: the penoxsulam preparation comprises the following components in parts by weight: 5-20 parts of a weeding active ingredient, 2-5 parts of a dispersing auxiliary agent, 5-8 parts of a slow release agent, 3-5 parts of an emulsifier, 0.1-2 parts of an active agent and 50-80 parts of an oil-based solvent, wherein the weeding active ingredient is penoxsulam.
As a further configuration of the invention: the dispersing auxiliary agent is one or a plurality of compositions of polycarboxylate, lignosulfonate or alkyl naphthyl sodium sulfate.
As a further configuration of the invention: the sustained release agent comprises the following components in parts by weight: 2-4 parts of polyvinyl alcohol, 0.5-1 part of cellulose acetate propionate and 2.5-3 parts of xanthan gum.
As a further configuration of the invention: the emulsifier comprises the following components in parts by weight: 0.5-1.5 parts of fatty alcohol-polyoxyethylene ether, 1-1.5 parts of magnesium lauryl hydroxypropyl sulfonate and 1.5-2 parts of styrylphenol polyoxyethylene ether.
As a further configuration of the invention: the active agent is dioctanoyl cystine.
As a further configuration of the invention: the oil-based solvent is one or more of peanut oil, soybean oil, rapeseed oil, palm oil, linseed oil, turpentine oil and corn oil.
The invention also provides application of the penoxsulam preparation in inhibiting growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
The invention also provides a preparation method of the penoxsulam preparation, which comprises the steps of adding the dispersing auxiliary agent, the slow release agent, the emulsifier and the active agent into the oil-based solvent, uniformly mixing and stirring, adding the penoxsulam under stirring by a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The invention has the beneficial effects that:
1. the invention develops a penoxsulam preparation, cellulose acetate propionate in a slow release agent can interact with cellulose of plant conduit cells to form a plant cellulose guide channel, and the transmission rate of penoxsulam in a weed conduit is improved, so that the rate of quickly transmitting the active weeding component penoxsulam to the whole plant body through the conduit acts on weeds, and the weeding efficiency is improved.
2. In the emulsifier in the penoxsulam preparation, the magnesium lauryl hydroxypropyl sulfonate and the penoxsulam change the oxidation-reduction original potential in weed plant cells, so that membrane lipid is peroxidized, and the withering of the weed cells is further accelerated.
3. The dicapryl cystine in the active agent in the penoxsulam preparation can inhibit the synthesis of glutamine, and induces the content of branched chain amino acid in weeds to rise under the action of protein conversion, so that the content of the branched chain amino acid in the plants quickly rises in a short time under the synergistic action of the dicapryl cystine and the penoxsulam, so that the proportion of the amino acid is disordered to cause metabolic disorder, and finally, the branched chain amino acid is quickly withered and withered.
Detailed Description
The technical solution of the present invention will be clearly and completely described below with reference to the specific embodiments. It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without making any creative effort, shall fall within the protection scope of the present invention.
A penoxsulam preparation and a preparation method thereof are disclosed, and concretely comprise the following embodiments:
example 1
Adding 2-5 parts of polycarboxylate, 2 parts of polyvinyl alcohol, 0.5 part of cellulose acetate propionate carboxylate, 2.5 parts of xanthan gum, 0.5 part of fatty alcohol-polyoxyethylene ether, 1 part of magnesium lauryl hydroxypropyl sulfonate, 1.5 parts of styrylphenol polyoxyethylene ether and 0.1 part of dioctylsarcocystine into 50 parts of peanut oil, mixing and stirring uniformly, adding 5 parts of penoxsulam under stirring of a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Example 2
Adding 5 parts of a mixture of lignosulfonate and alkyl naphthyl sodium sulfate, 4 parts of polyvinyl alcohol, 1 part of cellulose acetate propionate and 3 parts of xanthan gum, 1.5 parts of fatty alcohol-polyoxyethylene ether, 1.5 parts of magnesium lauryl hydroxypropyl sulfonate, 2 parts of styrylphenol polyoxyethylene ether and 2 parts of dioctylscystine into a mixture of 80 parts of soybean oil, rapeseed oil and palm oil, uniformly mixing and stirring, adding 20 parts of penoxsulam under stirring of a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Example 3
Adding 3 parts of lignosulfonate, 3 parts of polyvinyl alcohol, 0.8 part of cellulose acetate propionate carboxylate, 2.8 parts of xanthan gum, 1 part of fatty alcohol-polyoxyethylene ether, 1.3 parts of magnesium lauryl hydroxypropyl sulfonate, 1.8 parts of styrylphenol polyoxyethylene ether and 1 part of dioctylserine into a mixture of 70 parts of linseed oil, turpentine and corn oil, uniformly mixing and stirring, adding 10 parts of penoxsulam under stirring of a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Example 4
Adding 3 parts of lignosulfonate, 3 parts of polyvinyl alcohol, 2.8 parts of xanthan gum, 1 part of fatty alcohol-polyoxyethylene ether, 1.3 parts of magnesium lauryl hydroxypropyl sulfonate, 1.8 parts of styrylphenol polyoxyethylene ether and 1 part of dioctylsarcocystine into a mixture of 70 parts of linseed oil, turpentine and corn oil, uniformly mixing and stirring, adding 10 parts of penoxsulam under stirring of a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Example 5
Adding 3 parts of lignosulfonate, 3 parts of polyvinyl alcohol, 0.8 part of cellulose acetate propionate carboxylate, 2.8 parts of xanthan gum, 1 part of fatty alcohol-polyoxyethylene ether, 1.8 parts of styrylphenol polyoxyethylene ether and 1 part of dioctylsarcocystine into a mixture of 70 parts of linseed oil, turpentine and corn oil, uniformly mixing and stirring, adding 10 parts of penoxsulam under stirring of a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Example 6
Adding 3 parts of lignosulfonate, 3 parts of polyvinyl alcohol, 0.8 part of cellulose acetate propionate carboxylate, 2.8 parts of xanthan gum, 1 part of fatty alcohol-polyoxyethylene ether, 1.3 parts of lauryl hydroxypropyl magnesium sulfonate and 1.8 parts of styrylphenol polyoxyethylene ether into a mixture of 70 parts of linseed oil, turpentine and corn oil, uniformly mixing and stirring, adding 10 parts of penoxsulam under stirring of a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Comparative example
Adding 3 parts of lignosulfonate, 3 parts of polyvinyl alcohol, 2.8 parts of xanthan gum, 1 part of fatty alcohol-polyoxyethylene ether and 1.8 parts of styrylphenol polyoxyethylene ether into a mixture of 70 parts of linseed oil, turpentine and corn oil, uniformly mixing and stirring, adding 10 parts of penoxsulam under stirring by a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
The prepared penoxsulam preparation is used for inhibiting the growth of one or more of gramineous weeds, cyperaceous weeds and broadleaf weeds.
Detection method
The test is carried out according to the method specified in GB/T17980.40-2000 'pesticide field efficacy test criterion (I) herbicide control paddy field weed'. Cell area 30m2Random block permutation. Spraying stem leaves in the 2-3 leaf period of the weeds, wherein the spraying liquid amount is 450L/hm2. Draining water before application, and rehydrating 2 days after application. The control was performed in clear water for 4 replicates. Weed damage symptoms were recorded in detail after application.
Investigation of weed control Effect 1 time 10 days after the control Effect investigation, diagonally sampling and investigation of 4 points in each plot, each point is 0.25m2Recording the number of weed plants, measuring the fresh weight 40d after the application of the herbicide, and counting the weeding effect. The prevention effect calculation method comprises the following steps: the control effect is [ (CK-PT)/CK]X 100% (1) wherein: PT represents the number of remaining grass (or fresh weight) in the treated area, and CK represents the number of live grass (or fresh weight) in the blank control area.
The test results for the weed control effect of the test samples prepared in each of examples 1 to 6 of the present invention and the comparative example are as follows:
TABLE 1 herbicidal efficacy of sample 10d
Figure GDA0002174114590000041
Figure GDA0002174114590000051
The experimental results in table 1 show that, in examples 1 to 4, example 2 is good in effect, but example 3 is a low-cost and good-effect example, so that the best implementation mode is provided, compared with the comparative example, examples 1 to 3 are obviously superior in impurity removal effect on barnyard grass, moleplant seed, cyperus rotundus and monochoria vaginalis, the weeding effect is good within a short time of 10 days, the weeding effect is obviously superior to that of the herbicide on the market, and the market popularization prospect is good.

Claims (5)

1. The penoxsulam preparation is characterized by comprising the following components in parts by weight: 5-20 parts of a weeding active ingredient, 2-5 parts of a dispersing assistant, 5-8 parts of a slow release agent, 3-5 parts of an emulsifier, 0.1-2 parts of an active agent and 50-80 parts of an oil-based solvent, wherein the weeding active ingredient is penoxsulam, the dispersing assistant is one or more of polycarboxylate, lignosulfonate and alkyl naphthyl sodium sulfate, and the slow release agent comprises the following components in parts by weight: 2-4 parts of polyvinyl alcohol, 0.5-1 part of cellulose acetate propionate and 2.5-3 parts of xanthan gum, wherein the emulsifier comprises the following components in parts by weight: 0.5-1.5 parts of fatty alcohol-polyoxyethylene ether, 1-1.5 parts of magnesium lauryl hydroxypropyl sulfonate and 1.5-2 parts of styrylphenol polyoxyethylene ether.
2. A penoxsulam formulation according to claim 1, wherein the active agent is dioctylcysteine.
3. A penoxsulam formulation according to claim 1, wherein the oil-based solvent is one or more of peanut oil, soybean oil, rapeseed oil, palm oil, linseed oil, turpentine, corn oil.
4. A penoxsulam formulation according to claim 1, wherein the penoxsulam formulation is used to inhibit the growth of one or more of grassy weeds, sedge weeds, broadleaf weeds.
5. A process for preparing a penoxsulam preparation according to claim 1, which comprises adding a dispersing aid, a slow-release agent, an emulsifier and an active agent into an oil-based solvent, mixing and stirring uniformly, adding penoxsulam under stirring by a high-speed shearing machine, and shearing for 20-30 min to obtain the penoxsulam preparation.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104872115A (en) * 2015-04-03 2015-09-02 安徽久易农业股份有限公司 Dispersible oil suspending agent additive for soybean oil system and dispersible oil suspending agent
CN107646834A (en) * 2017-06-25 2018-02-02 广东中迅农科股份有限公司 The dispersible oily suspension formulation and preparation method of a kind of modification
CN110913827A (en) * 2016-09-14 2020-03-24 诺赛尔股份有限公司 Tensioning cosmetic composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0710434A2 (en) * 2006-05-10 2011-08-09 Du Pont compositions and method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104872115A (en) * 2015-04-03 2015-09-02 安徽久易农业股份有限公司 Dispersible oil suspending agent additive for soybean oil system and dispersible oil suspending agent
CN110913827A (en) * 2016-09-14 2020-03-24 诺赛尔股份有限公司 Tensioning cosmetic composition
CN107646834A (en) * 2017-06-25 2018-02-02 广东中迅农科股份有限公司 The dispersible oily suspension formulation and preparation method of a kind of modification

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
氨基酸类表面活性剂的合成及其性能研究;梁亚琴;《中国博士学位论文全文数据库 工程科技Ⅰ辑》;20150715(第07期);B016-43 *

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Denomination of invention: A preparation method of pentafluorosulfonamide and its preparation

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