CN110318117A - A kind of health high fluffy PE-PET composite fibre and preparation method thereof - Google Patents

A kind of health high fluffy PE-PET composite fibre and preparation method thereof Download PDF

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Publication number
CN110318117A
CN110318117A CN201910517649.3A CN201910517649A CN110318117A CN 110318117 A CN110318117 A CN 110318117A CN 201910517649 A CN201910517649 A CN 201910517649A CN 110318117 A CN110318117 A CN 110318117A
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CN
China
Prior art keywords
composite fibre
health
polyethylene
pet composite
polyethylene terephthalate
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Pending
Application number
CN201910517649.3A
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Chinese (zh)
Inventor
陈兴华
卓志明
林鹏
刘剑
吴学海
曾武
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Fujian Kangbaisai New Materials Co Ltd
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Fujian Kangbaisai New Materials Co Ltd
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Priority to CN201910517649.3A priority Critical patent/CN110318117A/en
Publication of CN110318117A publication Critical patent/CN110318117A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes
    • D01D5/092Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Multicomponent Fibers (AREA)

Abstract

The invention discloses a kind of health high fluffy PE-PET composite fibres and preparation method thereof, include the following steps: S1, polyethylene terephthalate raw material is dried;S2, by after drying polyethylene terephthalate and polyethylene melt in screw extruder, polyethylene, polyethylene terephthalate and the gas after melting are injected from the exocoel, lumen and inner cavity of three component composite spinneret components respectively again, and obtain tow after supercooling is dried, oils and wound;S3, tow is fallen into strand bucket through feeding-wheel, then the tow in multiple strand buckets is integrated to obtain boundling, health high fluffy PE-PET composite fibre is made in boundling after drawing-off, curling and cutting;The invention improves upon the preparation method of existing bulkiness composite fibre, the polyethylene of outer layer is closely coated on polyethylene terephthalate surface, is not susceptible to fiber decortication segregation phenomenon, the pliability and comfort of composite fibre can be improved.

Description

A kind of health high fluffy PE-PET composite fibre and preparation method thereof
Technical field
The invention belongs to composite fibre preparation technical fields, and in particular to a kind of health compound fibre of high fluffy PE-PET Dimension and preparation method thereof.
Background technique
PE(polyethylene)/PET(polyethylene terephthalate), PE(polyethylene)/PP(polypropylene) etc. bi-components it is multiple Since cortex has low melting point, sandwich layer has higher melt, can form Through-Air Thermal Bonded Nonwovens by hot blast adhesion condensating fiber.It is this Bicomponent composite fibre is answered due to not using adhesive and soft comfortable in hygienic materials such as paper diaper, sanitary napkins extensively With.
The high fluffy of non-woven cloth assigns the fabulous comfort of hygienic material, high drain.The conventional compound fibre of PE/PP Arranged side by side, core-skin bias mode can be used on cross section structure, utilized two kinds of material stresses due to the compatibility of PE and PP for dimension With the disequilibrium of heat transfer, to obtain higher bulkiness.But due to the industrial scale of PET and it is recyclable the features such as, PET There is biggish cost advantage than PP, at present mainstream of the PE/PET as material in hygienic bicomponent fibre.
Application No. is the patents of CN201410481816.0 to disclose a kind of pleasant type modified polyester complex fiber that keeps warm Preparation method, the preparation method by the polyester master particle containing tourmaline powder and polyester slice blend melt spinning, pass through first First abnormal-shape spinneret plate produces a kind of functional hollow polyester preoriented yarn POY;Again by Modified polyester chips through melt spinning, A kind of cross polyester preoriented yarn POY is produced by the second abnormal-shape spinneret plate;Finally by functional hollow polyester preorientation It is multiple to obtain one kind pleasant type modified poly ester that keeps warm through elasticizer false twisting combined processing by silk POY and cross polyester preoriented yarn POY Condensating fiber.But due to PE/PET fiber, its two kinds of components are incompatible, eccentric or total using arranged side by side or core-skin such as on cross section structure The mode that consolute melts, influences the comfort of rear road non-woven cloth processing and hygienic material at phenomena such as easily causing fiber decortication separation. Summary of the invention
The object of the present invention is to provide a kind of health high fluffy PE-PET composite fibres, and it is multiple to improve existing PE/PET After melting extrusion, injection molding forms concentric structure for the preparation method of condensating fiber, polyethylene and polyethylene terephthalate PE/PET composite fibre, the polyethylene of outer layer are closely coated on polyethylene terephthalate surface, and it is de- to be not susceptible to fiber Skin segregation phenomenon, and the pliability and comfort of composite fibre can be improved.
Technical scheme is as follows:
A kind of health high fluffy PE-PET composite fibre, including successively molding cladding material, core material from outside to inside With the hollow layer formed by gas injection moulding;The cladding material, core material and hollow layer are concentric structure setting;The outer layer The fusing point of material is lower than the fusing point of core material.
Preferably, the cladding material is polyethylene;The core material is polyethylene terephthalate.
A kind of health preparation method of high fluffy PE-PET composite fibre, the specific steps are as follows:
S1, polyethylene terephthalate raw material is put into drying temperature be 80 DEG C ~ 190 DEG C under conditions of be dried 10min~60min;
S2, it the polyethylene terephthalate after drying is put into screw extruder melts, melt screw extruder Temperature from head upstream end to tail extruding end temperature increment, temperature range be 260 ~ 310 DEG C;Polyethylene is put into screw rod to squeeze Machine melts out, melts the temperature of screw extruder from head upstream end to tail extruding end temperature increment, temperature range It is 200 DEG C ~ 260 DEG C;The polyethylene, polyethylene terephthalate and the gas that squeeze out after melting are answered from three components respectively again The exocoel 40, lumen 41 and inner cavity 42 for closing spinneret component 4 inject, and obtain tow after supercooling is dried, oils and wound;
S3, tow is fallen into strand bucket through feeding-wheel, then the tow in multiple strand buckets is integrated to obtain boundling, boundling is by leading Health high fluffy PE-PET composite fibre is made after stretching, crimp and cutting off.
Preferably, the drying temperature of polyethylene terephthalate is 160 ~ 170 DEG C in the step S1.
Preferably, the extruder latter end temperature of polyethylene is 240 ~ 260 DEG C in the step S2.
Preferably, polyethylene terephthalate extruder latter end temperature is 300 ~ 310 DEG C in the step S2.
Preferably, the gas in the step S2 is nitrogen, air or inert gas, preferably air.
Preferably, the temperature of the cooling blowing in the step S2 is 10 DEG C ~ 40 DEG C
The invention has the following beneficial effects:
1, the present invention provides a kind of health high fluffy PE-PET composite fibre, polyethylene and polyethylene terephthalates For ester after melting extrusion, injection molding forms the PE/PET composite fibre of concentric structure, and the polyethylene of outer layer is closely coated on poly- to benzene Naphthalate surface is not susceptible to fiber decortication segregation phenomenon, and hollow layer can not only reduce the entirety of composite fibre The compression resilience performance of composite fibre also can be improved in density, and the pliability and comfort of composite fibre can be improved.
2, the present invention provides a kind of health high fluffy PE-PET composite fibre, outer layer PE fusing point is low, can carry out low Temperature bonding, middle layer of PET fusing point is higher, will not melt in low temperature adhesion, can play a supporting role, so as to keep compound fibre The bulkiness of dimension.
3, the present invention provides the preparation methods that a kind of health uses high fluffy PE-PET composite fibre, the poly- second after melting Alkene, polyethylene terephthalate and air are injected from the exocoel, lumen and inner cavity of three component composite spinneret components respectively, The hollow composite fiber of pencil can be formed after supercooling is dried, easy to operate, raw material is easy to get, and can effectively lower production cost.
Detailed description of the invention
Fig. 1 is preparation technology flow chart of the invention;
Fig. 2 is the cross-sectional structure schematic diagram of health high fluffy PE-PET composite fibre of the invention;
Fig. 3 is structural schematic diagram when three component composite spinneret components of the invention use.
Appended drawing reference indicates in figure are as follows:
1, cladding material;2, core material;3, hollow layer;4, three component composite spinneret component;40, exocoel;41, lumen;42, Inner cavity.
Specific embodiment
In order to better understand the present invention, below by embodiment to the present invention into further explanation, embodiment is served only for It explains the present invention, any restriction can't be constituted to the present invention.
Embodiment 1:
It is described according to a kind of health high fluffy PE-PET composite fibre and preparation method thereof above-mentioned referring to Fig. 1 to Fig. 3 Health is made according to the following steps with high fluffy PE-PET composite fibre:
S1,35min is dried under conditions of being 160 DEG C by polyethylene terephthalate raw material drying temperature;
S2, it the polyethylene terephthalate after drying is put into screw extruder melts, melt screw extruder Temperature from head upstream end to tail extruding end temperature increment, temperature range be 280 DEG C -280 DEG C -300 DEG C -305 DEG C -305 ℃-305℃;Polyethylene is put into screw extruder to melt, melt screw extruder temperature from head upstream end to Tail extruding end temperature increment, temperature range are 230 DEG C -230 DEG C -240 DEG C -260 DEG C -260 DEG C -260 DEG C;It again will be after melting Polyethylene, polyethylene terephthalate and the air exocoel 40 from three component composite spinneret components 4,41 and of lumen respectively Inner cavity 42 is injected, and obtains tow after 25 DEG C of coolings are dried, oil and wound;
S3, tow is fallen into strand bucket through feeding-wheel, then the tow in multiple strand buckets is integrated to obtain boundling, boundling is by leading Health high fluffy PE-PET composite fibre is made after stretching relaxation and cutting.
The performance parameter of health high fluffy PE-PET composite fibre obtained above is as follows: fiber number 3.3dtex, intensity Hollow rate 17% and non-woven fabrics specific volume is made in 2.5cN/dtex, extension at break 57%, 17/25mm of crispation number, crimpness 18% 165cm3/g。
Embodiment 2
It is described according to a kind of health high fluffy PE-PET composite fibre and preparation method thereof above-mentioned referring to Fig. 1 to Fig. 3 Health is made according to the following steps with high fluffy PE-PET composite fibre:
S1, polyethylene terephthalate raw material is respectively put into drying temperature be 165 DEG C under conditions of be dried 30min;
S2, it the polyethylene terephthalate after drying is put into screw extruder melts, melt screw extruder Temperature from head upstream end to tail extruding end temperature increment, temperature range be 280 DEG C -280 DEG C -290 DEG C -300 DEG C -300 ℃-300℃;Polyethylene is put into screw extruder to melt, melt screw extruder temperature from head upstream end to Tail extruding end temperature increment, temperature range are 220 DEG C -220 DEG C -240 DEG C -250 DEG C -250 DEG C -250 DEG C;It again will be after melting Polyethylene, polyethylene terephthalate and the air exocoel 40 from three component composite spinneret components 4,41 and of lumen respectively Inner cavity 42 is injected, and obtains tow after 30 DEG C of coolings are dried, oil and wound;
S3, tow is fallen into strand bucket through feeding-wheel, then the tow in multiple strand buckets is integrated to obtain boundling, boundling is by leading Health high fluffy PE-PET composite fibre is made after stretching relaxation and cutting.
The performance parameter of health high fluffy PE-PET composite fibre obtained above is as follows: fiber number 3.6dtex, intensity Hollow rate 19% and non-woven fabrics specific volume is made in 2.9cN/dtex, extension at break 63%, 21/25mm of crispation number, crimpness 22% 166cm3/g。
Embodiment 3
It is described according to a kind of health high fluffy PE-PET composite fibre and preparation method thereof above-mentioned referring to Fig. 1 to Fig. 3 Health is made according to the following steps with high fluffy PE-PET composite fibre:
S1, polyethylene terephthalate raw material is respectively put into drying temperature be 170 DEG C under conditions of be dried 20min;
S2, it the polyethylene terephthalate after drying is put into screw extruder melts, melt screw extruder Temperature from head upstream end to tail extruding end temperature increment, temperature range be 280 DEG C -280 DEG C -300 DEG C -310 DEG C -310 ℃-310℃;Polyethylene is put into screw extruder to melt, melt screw extruder temperature from head upstream end to Tail extruding end temperature increment, temperature range are 230 DEG C -230 DEG C -240 DEG C -250 DEG C -250 DEG C -250 DEG C;It again will be after melting Polyethylene, polyethylene terephthalate and the air exocoel 40 from three component composite spinneret components 4,41 and of lumen respectively Inner cavity 42 is injected, and obtains tow after 28 DEG C of coolings are dried, oil and wound;
S3, tow is fallen into strand bucket through feeding-wheel, then the tow in multiple strand buckets is integrated to obtain boundling, boundling is by leading Health high fluffy PE-PET composite fibre is made after stretching relaxation and cutting.
The performance parameter of health high fluffy PE-PET composite fibre obtained above is as follows: fiber number 3.7dtex, intensity Hollow rate 18% and non-woven fabrics specific volume is made in 3.1cN/dtex, extension at break 59%, 20/25mm of crispation number, crimpness 21% 164cm3/g。
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks Domain is included within the scope of the present invention.

Claims (8)

1. a kind of health high fluffy PE-PET composite fibre, it is characterised in that: including successively molding outer layer from outside to inside Material (1), core material (2) and the hollow layer (3) formed by gas injection moulding;The cladding material (1), core material (2) and Hollow layer (3) is concentric structure setting;The fusing point of the cladding material (1) is lower than the fusing point of core material (2).
2. a kind of health high fluffy PE-PET composite fibre as described in claim 1, it is characterised in that: the outer layer material Expect that (1) is polyethylene;The core material (2) is polyethylene terephthalate.
3. the preparation method that a kind of health as claimed in claim 2 uses high fluffy PE-PET composite fibre, which is characterized in that tool Steps are as follows for body:
S1, polyethylene terephthalate raw material is put into drying temperature be 80 DEG C ~ 190 DEG C under conditions of be dried 10min~60min;
S2, it the polyethylene terephthalate after drying is put into screw extruder melts, melt screw extruder Temperature from head upstream end to tail extruding end temperature increment, temperature range be 260 ~ 310 DEG C;Polyethylene is put into screw rod to squeeze Machine melts out, melts the temperature of screw extruder from head upstream end to tail extruding end temperature increment, temperature range It is 200 DEG C ~ 260 DEG C;The polyethylene, polyethylene terephthalate and the gas that squeeze out after melting are answered from three components respectively again Exocoel (40), lumen (41) and inner cavity (42) injection of spinneret component (4) are closed, and after supercooling blowing, oiling and winding Obtain tow;
S3, tow is fallen into strand bucket through feeding-wheel, then the tow in multiple strand buckets is integrated to obtain boundling, boundling is by leading Health high fluffy PE-PET composite fibre is made after stretching, crimp and cutting off.
4. the preparation method that a kind of health as claimed in claim 3 uses high fluffy PE-PET composite fibre, it is characterised in that: The drying temperature of polyethylene terephthalate is 160 ~ 170 DEG C in the step S1.
5. the preparation method that a kind of health as claimed in claim 3 uses high fluffy PE-PET composite fibre, it is characterised in that: The extruder latter end temperature of polyethylene is 240 ~ 260 DEG C in the step S2.
6. the preparation method that a kind of health as claimed in claim 3 uses high fluffy PE-PET composite fibre, it is characterised in that: Polyethylene terephthalate extruder latter end temperature is 300 ~ 310 DEG C in the step S2.
7. the preparation method that a kind of health as claimed in claim 3 uses high fluffy PE-PET composite fibre, it is characterised in that: Gas in the step S2 is nitrogen, air or inert gas.
8. the preparation method that a kind of health as claimed in claim 3 uses high fluffy PE-PET composite fibre, it is characterised in that: The temperature of cooling blowing in the step S2 is 10 DEG C ~ 40 DEG C.
CN201910517649.3A 2019-06-14 2019-06-14 A kind of health high fluffy PE-PET composite fibre and preparation method thereof Pending CN110318117A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111519275A (en) * 2020-04-16 2020-08-11 天津工业大学 Sheath-core structure composite fiber and nonwoven fabric comprising same
CN112095230A (en) * 2020-08-15 2020-12-18 福建冠泓工业有限公司 Super-soft super-fluffy spun-bonded non-woven fabric and preparation method thereof
CN113337919A (en) * 2021-06-11 2021-09-03 江苏惠康特种纤维有限公司 High-bulkiness super-soft PET and PE composite fiber and preparation method thereof
CN114182373A (en) * 2021-10-18 2022-03-15 浙江理工大学绍兴柯桥研究院有限公司 Preparation method of self-crimping regenerated polyester staple fiber
WO2022104644A1 (en) * 2020-11-19 2022-05-27 蔡欣航 Method for manufacturing composite fiber article

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CN111519275B (en) * 2020-04-16 2022-07-08 天津工业大学 Sheath-core structure composite fiber and nonwoven fabric comprising same
CN112095230A (en) * 2020-08-15 2020-12-18 福建冠泓工业有限公司 Super-soft super-fluffy spun-bonded non-woven fabric and preparation method thereof
WO2022104644A1 (en) * 2020-11-19 2022-05-27 蔡欣航 Method for manufacturing composite fiber article
CN113337919A (en) * 2021-06-11 2021-09-03 江苏惠康特种纤维有限公司 High-bulkiness super-soft PET and PE composite fiber and preparation method thereof
CN114182373A (en) * 2021-10-18 2022-03-15 浙江理工大学绍兴柯桥研究院有限公司 Preparation method of self-crimping regenerated polyester staple fiber

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